대구 및 인근지역의 도로먼지에 함유된 미량원소성분의 함량분포

황윤정,황승만,최진수,김무식,백성옥 嶺南大學校 環境問題硏究所 1998 環境硏究 Vol.17 No.2

요약문 본 연구는 각종 먼지 가운데서도 독성이 가장 큰 것으로 알려진 도로먼지에 함유된 미량원소 성분이 조성 및 특성을 파악하기 위해 1992년 1월에서 10월가지 주거지역, 상업지역, 공업지역, 교외지역, 전원지역 등에 위치한 도로에서 시료를 채취하였으며 채취된 시료는 산으로 추출한후 ICP로 분석하였다 . 그 결과 토사 및 황사현상과 같은 자연발생원과 연관지을 수 있는 Al, Ca, Mg, Ti, Si, Na, K의 농도가 지역에 따라서는 전원지역과 교외지역에서, 그리고 도로포장 형태에 따라서는 비포장 도로에서 높게 나타난 반면에, 각종 연소 및 차량과 같은 인위적인 발생원과 관련이 있는 As, Cr, Mn, Zn, Pb, Cu, Ni는 공업지역 및 상업지역, 그리고 아스팔트에서 비교적 높게 검출되어 이러한 미량원소성문들의 농도분포는 지역에 따라, 그리고 도로포장 형태에 따라 특징적인 양상을 나타내는 것으로 조사되었다. 또한 As, Pb, Al 등의 일부 미량원소성분들의 농도는 계절에 따른 차이를 나타내었으며, 농축계수에 의한 평가결과 농축계수가 낮게 나타난 Na, Si, Ti, K, Al 등은 자연발생원에 의해 상당한 영향을 받는 반면에 As, Pb, Zn 등은 농축계수가 매우 높게 나타나 이들 성분의 경우에는 인위적인 발생원에 의한 기여도가 큰 것으로 평가되었다. Abstract This study was carried out to characterize the trace elements in street dust known to contain several toxic elements. Street dust was collected in residential, commercial, industrial, suburban and rural area of Taegu and on the vicinity of Taegu from January to October, 1992. Total amount of 16 trace elements in street dust were analyzed by ICP spectrophotometer. While the levels of As, Cr, Mn, Zn, Pb, Cu and Ni were higher in industral and commercial area than any other area by sites and the highest levels appeared on asphalt and cement street by street conditions. Also the concentrations of some trace elements originated mainly from soil (e.g. Al, Ca, Mg, Si, Na) were higher in rural and suburban area by sites and the highest levels appeared in unpaved street by street conditions. The concentrations of several trace elements such as Aa, Pb, Al appeared seasonal differences. The estimated enrichment factors (EF) for Na, Si, Ti, K and Al components showed with soil compositions appeared to have low values, while As, Pb and Zn components showed relatively higher values. These results imply that the latter constituents were likely to be affected by dry and wet depositions of atmospheric particles orginated from anthropogenic sources such as fuel combustion and refuge burning.

급성 골수성 백혈병 환자에서 관해 유도 항암 화학요법 후 발생한 베르니케 뇌증

황진원,정재현,서광원,최병진,송영진,김종윤,이은지,임홍규,이상민 인제대학교 2009 仁濟醫學 Vol.30 No.-

Wernicke's encephalopathy is characterized by the triad of ocular symptoms, ataxia, and mental confusion and neuropsychiatric condition generally caused by acute thiamine deficiency. Although it is common in the severe alcoholics, several other causes also have been identified, such as total parenteral nutrition (TPN) use, hyperemesis gravidarum, anorexia nervosa, hemodialysis, uremia, and acquired immunodeficiency syndrome(AIDS). Chemotherapy in patient with malignanacy and long term total parenteral nutrition following bone marrow transplantation are related with Wernicke's encephalopathy. A 48-year-old woman had been treated with Daunorubicin and Cytarabine for remission induction chemotherapy of acute myeloblastic leukemia and intravenous hyperalimentation due to persistent hematochezia and ileus caused by infiltration of leukemic cell in terminal ileum. She suddenly complained of diplopia, tremor, and mental confusion at 32th day after chemotherapy and generalized tonic-clonic seizure at 34th day after chemotherapy. The diagnosis of Wernicke's encephalopathy was made with clinical presentations and brain MRI. Brain MR T2-weighted & Flair image revealed a high signal intensity lesions bilaterally at the medial thalamus and peri-acueductal grey matter of the midbrain. The patient was successfully treated with vitamin B1. We presented a case of acute Wernicke's encephalopathy developed after remission induction chemotherapy followed by intravenous hyperalirnentation in a patient with acute myeloblastic leukemia.

강원도 태백시 고사리도석광산에 산출하는 점토광물의 산상 및 특성

황진연,정윤영 부산대학교 기초과학연구소 1995 부산대학교 기초과학연구소 연구논문집 Vol.15 No.-

고사리광산의 도석에는 다량의 석영과 함께 녹니석/스멕타이트 혼합층광물, 운모/스멕타이트 혼합층광물, 카오리나이트와 같은 점토광물이 산출한다. 이들 점토광물에 대해 주로 X-선회절분석과 화학분석 등을 이용하여 광물학적 특성을 검토하였다. 이 광산의 도석은 녹니석/스멕타이트 혼합층광물을 다량 함유하는 것이 특징으로 나타났다. 이 녹니석/스멕타이트 혼합층광물은 Li을 함유하는 돈바싸이트로 된 녹니석층과 바이델라이트에 가까운 스멕타이트층으로 구성된 혼합층구조를 이룬다. 이 곳에 산출하는 운모/스멕타이트 혼합층광물은 모두 약 15% 이하의 팽윤층을 포함하는 것으로 되어 있다. 이 광산의 도석은 백악기의 유문암 및 유문암질 용회암이 열수변질작용을 받아 형성된 것으로 나타났다. 점토광물조합의 분포상태에 의해 대략적인 변질분대가 나누어진다. 중심부인 강변질대에서는 다량의 녹니석/스멕타이트 혼합층광물이 나타나며 카오리나이트가 수반되기도 한다. 그 외곽지역의 약변질대에서는 점토광물로서 운모/스멕타이트 혼합층광물이 주로 나타난다. 카오리나이트는 주로 열극이나 그 주위에 국부적으로 산출되는 경향이 있다. 이와 같은 변질광물들의 산출상태로 볼 때 변질작용의 진행에 따라 운모/스멕타이트 혼합층광물이 먼저 형성된 후 이것의 일부가 녹니석/스멕타이트 혼합층광물 및 카오리나이트로 변화된 것으로 생각된다. 또 카오리나이트는 열수의 공급이 마낳은 열극부에서 녹니석/스멕타이느 혼합층광물은 후기의 변질작용에 의해 형성된 것도 포함된다. The pottery stones from the Gosari mine consist of abundant quartz with the clay minerals such as chlorite/smectitie and mica/smectite interstratified minerals, and kaolinite, Mineralogical characteristics of the clay minerals were examined by X-ray powder diffraction and chemical analysis. The pottery stones in this mine are characterized by large amounts of chlorite/smectitie interstratified mineral. The chemical compositioon of the chlorite/smectitie interstratified mineral indicates that the chlorites are Li-bearing donbassite and the smectites are close to beidellite. Mica/smectite interstratified minerals from the mine area have the mixed layers with expandability less than 15%. The pottery stones in the mine were probably formed by hydrothermal alteration of the Cretaceous rhyolite tuff. The pottery stone deposit can be devided into the zones of hydrothermal alteration on the basis of the clay mineral assemblages. In the centeral zone, strongly altered parts, the rocks are composed of abundant chlorite/smectite interstratified mineral and small amounts of kaolinite. On the other hand, the weakly altered rocks in the outer zone are mainly composed of mica/smectite interstrarified mineral instead of chlorite/smectitie interstratified mineral and kaolinite. In general, the kaolinites tend to occur locally in and

强風의 發生成因別 時間的 變化에 관한 硏究

황진득,하영철,곽윤근 金烏工科大學校 1994 論文集 Vol.15 No.-

The wind resistant design of building generally used up to data has been based on the value of an extreme speed. The extreme speed is normally estimated from wind data observed for the return periods of last 50 years or 100 years on the basis of the importance of building to be constructed. However, it is essential to consider the time variance of wind action because strong winds originated by Typhoon or others are occationally coming for attack. This study is to examine the origin of occurence and the action time of strong wind, and to understand the time variance characteristics. Strong winds are divided into 3 parts such as the regional condition of Korea, namely Typhoon, Frontal system storm, and Monsoon. The areas reflecting the origin of 3 kinds of the strong winds are also devided are selected as such as Seoul-Kyongki, Jungbu, and South-seashore. The representative cities are selected as Seoul fro, Uljin and Kunsan for, and Busan and Yeosu for. Observed wind data of past 20 years will be employed to estimate duration and propability of wind velocity. The observed wind data are recorded with duration of 96 hours at the center that annual extreme wind speed takes place, and with the mean value of wind velocity during 10 minutes at 1 hour interval. Based on these investigations, the duration and probability of wind velocity should be estimated. Generalized probability distribution function of wind velocity will be proposed. Duration of strong winds presented as a function of its maximum wind velocity. From these results, multipling generalized distribution function by generalized number of (wind velocity) samples, approximate equation of wind-duration will be derived. Approximate equation of wind-duration proposed in this study should be useful for analysing fatigue damage of structures and time dependent analysis of structure under strong wind in Korea.

두가지 혈류 유발방법에 의한 새로운 심폐소생술(이중 혈류 유발 심폐소생술)장치의 개발

황성오,김현,조준휘,오범진,임종천,최경훈,윤정한,이승환,김영식,이강현,이윤선 大韓應急醫學會 1999 대한응급의학회지 Vol.10 No.2

Background: There have been many efforts to augment blood flow during cardiopulmonary resuscitation. These efforts have focused on maximizing the effect of cardiac pump or thoracic pump alone. However, considering that the heart is the biggest blood reservoir and increase of intrathoracic pressure can generate blood flow, simultaneous exploitation of both mechanisms may have synergistic effect. We hypothesized that simultaneous chest constriction in addition to sternal compression by standard CPR may have additive hemodynamic effects by preventing deformation of the chest and increase of intrathoracic pressure. Methods and results: we built a new mechanical device to perform compression and thoracic constriction simultaneously. The device consists of two main elements. Piston in the center is to depress the sternum. Strap is to constrict the thorax circumferentially. Strap is attached to both sides of the piston. When the piston is pushed down, it depresses the sternum and pulls on the thoracic strap. To determine strap width to produce optimal hemodynamic effect, we measured hemodynamic parameters with variable widths of strap in two dogs after induction of ventricular fibrillation. Result of the experiment showed that 10cm wide strap was determined to be most effective. We also determined optimal depth of compression to produce maximal hemodynamic effect with animal experiments using two dogs. Animal experiments showed that the highest aortic pressure could be generated when the stemum was depressed to 5 cm. Cardiopulmonary resusciation using a new device could generate higher systolic aortic pressure, coronary perfusion pressure and end-tidal carbon dioxide tension in comparison with standard cardiopulmonary resuscitation in a pilot animal study using two dogs. Conclusion: New cardiopulmonary resuscitation method using a mechanical device designed by us could perform sternal compression and simultaneous thoracic constriction, and generate better hemodynamic effects than standard cardiopulmonary resuscitation in pilot animal experiments.

Paraquat 중독환자의 초기검사로서 sodium dithionite를 이용한 소변내 paraquat검출의 임상적 의의

윤갑준,임경수,이진웅,김영식,이부수,박덕우,김선만,이강현,황성오,안무업 대한응급의학회 1995 대한응급의학회지 Vol.6 No.1

Background : Mortality from paraquat intoxication depends upon plasma paraquat concentration. To know the severity of paraquat intoxication is important for directing therapeutic modality and predicting prognosis. Sodium dithionite test for urinary paraquat provides an easy and simple method to determine the severity of paraquat intoxication in emergency department. purpose : To determine whether the result urinary paraquat test by sodium dithionite can predict outcome in patients with paraquat intoxication in emergency department. Subjects : 48 patients(male 31, female 17, mean age 37 years) who had exposure to paraquat and presented within 24 hours after exposure. Result : Thirty five patients were positive in paraquat urine test and thirteen patients were negative. Clinical manifestations were more severe in positive patients than in negatives. Complication was much more in positives than in negatives. 28 of 35 patients(80%) in positives and 2 of 13 patients(15%) in negatives died. Conclusion : Positive test for urinary paraquat is associated with high mortality and morbidity from paraquat intoxication, and qualitative test for urinary paraquat by sodium dithionite is an useful method to determine the severity of paraquat intoxication in emergency department.

大邱地域 中小企業의 效率的인 技術開發 方案에 관한 硏究

全瑨文,張晩植,尹在坤,金圭昌,李栽燁,朴筍植,黃建夏 효성여자대학교 산업경영연구소 1988 경영경제 Vol.5 No.-

For modern business firms, the most important factor in determining comprtitiveness of a firm is technology, rather than capital. Technogical innovation is a driving force to develop an economy and is essential in growth and/or survival of a business firm. Following studies concerned with this subject, small business firms seem to be more efficient in technological innovation and developing new technology in several respects. Espercially in the new technology based industries, the small business firms have several advantages in technological innovation. In this study, we tried to show how to plan a technology development strategy in relation to management strategy when small business of theoretical and empirical study, we aimed to show the way to efficient management and procedure of technological innovation. For the research methodology, we firstly reviewed and analyzed current and previous studies about technological innovation strategy, efficient management, and selection of R&D projects. Secondly, the results of this theoretical study was examined empirically. The empirical study contains 153 questionaires and 30 interviews for business firms of this area. In addition, for the evaluation criteria for the selection of R&D projects, we sent questionaires to 60 professors who teaches R&D OR in university or college level. The result of these questionaires was analyzed and compared with that of the business firms of this area. The result of this empirical study shows that top management of small business firms should notice the importance of technological innovation and try to stimulate R&D activity. For the evaluation criteria for R&D projection, the criteria which could reduce the possibility of future uncertainty, maximize profit, and he suited for the situation of the business firm, should be established.

Binding Energy of Oxigen and Methane Adsorbed on Bundles of Open-Ended Single-Wall Carbon Nanotubes

서주연,유대황,곽진성,황윤회,김형국 부산대학교 유전체물성연구소 2004 유전체 논문집 Vol.3 No.

The adsorption of oxygen and methane on the bundles of open-ended single wall carbon nanotube(SWNT) was studied using the volumetric adsorption qst was obtained from the adsorption isotherm measurements performed at different temperatures. The trend in the values of the methane isosteric heat of adsorption showed three regions, representative of the adsorption on the different types of adsorption sites. In case of oxygen, on the other hand, such distinguishable regions were not appeared in the N-qst graph. From the results of qst the binding energies of oxygen and methane adsorbed on open-ended SWITs were estimated.

점토광물을 이용한 산소환원의 전기화학적 촉매성에 관한 연구

오성훈,황진연,심윤보,이효민,윤지해 한국광물학회 2005 광물과 암석 (J.Miner.Soc.Korea) Vol.18 No.1

몇 가지 점토광물과 메틸바이올로젠 또는 메틸렌블루를 함유시킨 점토수식전극을 이용하여 산소환원에 대한 전기화학적 촉매성을 검토하였다. 점토광물로는 Na-몬모릴로나이트, Ca-몬모릴로나이트, 카오리나이트를 사용하였다. 점토수식전극은 유리탄소전극 표면에 점토 현탁액을 입히고 메틸바이올로젠을 흡착시킨 것을 사용하였으며, 전기화학적 산소환원의 정도는 순환 전압전류(cyclic voltammetry)으로 측정하였다. 실험결과, 다른 점토시료에 비하여 Na-몬모릴로나이트가 메틸바이올로젠의 흡착효과가 가장 크게 나타났고, 메틸바이올로젠을 흡착시킨 점토수식전극이 산소환원에 대한 촉매성이 월등히 우수하였다. 즉 촉매산소환원 피크가 242.6 ㎷ 만큼 +방향으로 이동하였다. 메틸바이올로젠을 흡착시킨 점토수식전극이 메틸렌블루를 흡착시킨 점토수식전극보다 산소환원에 대한 촉매성이 더 높게 나타났다. Ca-몬모릴로나이트의 경우는 변화가 없었으나 Na-몬모릴로나이트의 구조는 메틸바이올로젠의 흡착으로 변화되었다. 메틸바이올로젠- Na-몬모릴로나이트 점토수식전극을 현탁액의 점토 농도가 약 0.87 g/10 mL이고, 메틸바이올로젠의 수용액의 농도가 대략 2.5 mM일 때 산소환원 촉매 효과가 가장 탁월하였다. 지지전해질의 pH에 따른 점토수식 전극의 산소 환원 촉매성은 중성의 pH 범위(6.3과 8.3)에서보다 산성인 pH 3.7과 알칼리성인 pH12.7에서 월등히 크게 나타났다. The electrocatalytic reduction of O₂ was investigated with methyl viologen and methylene blue incorporated clay-modified electrodes. Clay suspensions were prepared with Namontmorillonite, Ca-montmorillonite, and kaolinite. The methyl viologen-clay modified electrodes were made by coating clay suspensions adsorbing methyl viologen on a glassy carbon electrode. Cyclic voltammetry were performed in aqueous media to investigate the electrocatalytic property of the modified electrode in reducing O₂. A Na-montmorillonite modified electrode showed the greatest adsorption capacity for methyl viologen. The modified electrode made of Na-montmorillonite suspension of 0.87 g/l0 mL and a 2.5 mM of methyl viologen solution showed the most effective electrocatalytic property, where the catalytic reduction potential was shifted by 242.6 ㎷ toward the positive potential. The electrocatalytic ability was more significant in acidic (pH=3.7) and alkaline (pH=12.7) media than the neutral pH range (6.3~8.3). The methyl viologen-Na-montmorillonite modified electrode had the good reproducibility and maintain the electrocatalytic property over 20 times reuse.

서울의 Penicillinase Producing Neisseria Gonorrhoeae 발생빈도(1996)

김재홍,황동규,전재홍,김윤석,김중환,김용준,이창균,임동진,김현수,조창근,김경문,박상훈,전우형,김희성,이호정,차명수,김갑형,김형석,김석우,황지환,박병순,권오상,이민수,송기훈,성소영,이인섭,부태성 대한화학요법학회 1999 대한화학요법학회지 Vol.17 No.2

Background : In recent years, gonorrhea has been panedemic and remains one of the most commom STDs in the world, especially in developing countries. Objective & Methods: For the detection of a more effective therapeutic regimen and assessing the prevalence of PPNG, we have been trying to study the patients who have visited the VD Clinic of Choong-Ku Public Health Center in Seoul since 1980 by means of the chromogenic cephalosporin method. Results: In 1996, 139 strains of N. gonorrhoeae were isolated, among which 53(39.0%) were PPNG. Conclusion: Our results suggests that after a peak of 74.3% in 1993, the prevalence of PPNG in Seoul is gradually declining.