이산화티타늄계 광촉매를 이용한 톨루엔의 처리 특성

전의찬,송민종,김전희 동신대학교 환경연구소 2000 환경연구 Vol.5 No.1

각종 급ㆍ만성의 건강장해를 일으킬 뿐만 아니라, 광화학 반응에 의해 오존을 형성하는 것으로 알려진 휘발성유기화합물 중 대표적인 물질인 톨루엔을 광촉매산화법으로 처리할 경우 최적 처리조건을 분석하고자 광촉매의 결정구조, 광원의 세기, 전자수용체로서 산소의 유무 등에 따른 톨루엔의 처리효율을 분석하였다. 실험결과 루틸령 결정구조에 비해 아나타제형 결정구조를 갖는 이산화티타늄의 톨루엔 처리효율이 높게 나타났으며, 광원의 세기가 높을수록 전자수용체로서 산소가 존재할 경우 높은 처리효율을 나타내었다. 시간과 공간적인 제약으로 물, 오존 그리고 증기와 같은 다양한 전자수용체가 존재할 경우의 톨루엔의 처리효율을 파악하지 못하였으며, 온도, 습도 및 촉매활성에 영향을 주는 여러 가지 인자들을 대상으로 그것들의 변화에 따른 처리효율의 고찰을 못하였다. 앞으로 보다 효율적인 이산화티타늄계 광촉매의 제조방법 개발과 이산화티타늄계 광촉매를 이용한 다양한 VOC 처리방법의 개발이 요구된다. An available methods for abating VOC(including Toluene) are thermal or catalytic incineration, liquid absorption, solid adsorption, condensing, membranes, biodegradation and plasma discharge, but a number of defects are these VOC abating methods, including ; requires a auxiliary fuel, generate secondary pollutants(waste catalysts, waste absorbents, waste adsorbents, ozone, etc.), a large scale, etc.. But photoactive catalysts, when illuminated with UV-light, generate highly reactive radicals that can oxidize the organic contaminants in gas. One methods to increase the efficiency of the process, and thereby reduce the light energy requirement, is by developing more active catalysts. Because of, ball type TiO2 catalyst were obtained commercially and/or prepared in laboratory were examined for their photoacivity, and they are TiO2 added some annex(Al203, SiO2, KsO, P205, etc.). The organic compounds used to identify the best photocatalysis condition were toluene. This study also examined the impact of catalyst structure, light intensity, existence of oxygen as an electron acceptor and Toluene initial concentration on the reaction kinetics. Labratory experiments were performed to investigate TiO2 photocataysis for treating test gas contaminated with Toluene. and TiO2 photocatalysis efficiency for mineralization of Toluene is also evaluated. The photooxidation of Toluene was carried out in a photocatalytic reactor at room temperature. I performed Toluene photocatalytic oxidation experiments using a single-pass annular reactor. The organic-contaminated gas was prepared in teflon sampling bag(25L) and passing through photocatalytic reactor by vacuum pump which is located reactor outlet. The Toluene diluted with mixture air or nitrogen gas. Flow rates for test gas stream were controlled by micro flow meter going out the reactor. The reactor illuminated with 15W near-UV lamp, BLB lamp or Fluorescent lamp. The light intensity at the catalyst surface were estimated to be 0.8 to 6㎽ ㎝-2s-1. The inner cell of the reactor was packed with ball type titanium dioxide(φ 6㎜). Toluene was determined by GC-FID of gas samples taken from the a glass sampling bulb which was located at reactor outlet by gas-tight syringe. TiO2 photocataysis for treating test gas contaminated with Toluene. and TiO2 photocatalysis efficiency for mineralization of Toluene is also evaluated. Using the anatase type photocatalyst, Touene conversion rate is greater than that of rutile(86.1% conversion of 100ppmv Toluene using anatase type photocatalyst, 78% conversion of 100ppmv Touene using rutile type photocatalyst at 0.5L/min) Effect of light intensity on the rate of Toluene photocatalytic decomposition was investigated by three type lamps within the reactor. When light intensity to increase, the Toluene conversion rate to increase. Using the BLB lamp showed higher activity than the Fluorescent lamp, but UV lamp showed the hight photocatalytic activity(19.1% conversion of 100ppmv Toluene with Fluorescent lamp, 60.4% conversion of 100ppmv Toluene with BLB lamp, 86.1% conversion of 100ppmv Toluene with UV lamp at 0.5L/min). Experiments with added oxygen as an electron acceptor improved the reaction rate considerably(86.1% conversion of 100ppmv Toluene without oxygen, 62.5% conversion of same Toluene concentration with mixture air at 0.5L/min).

환경기초시설 중 하·폐수처리과정으로부터의 GHG 배출량 예측 : 광주·전남지역을 중심으로 Kwang ju·Chollanado

전의찬,김전희,송민종 동신대학교 환경연구소 2000 환경연구 Vol.5 No.1

본 연구는 환경기초시설 중에서 생활하수와 산업폐수 처리장에서 발생하는 특히 광주·전남 지역을 중심으로 온실가스의 배출량과 장래 저감 잠재성을 평가하고, 기후변화협약을 대비한 국가 Inventory의 기초자료로 이용될 수 있도록 하였으며, 결론적으로 하ㆍ폐수부문에서 온실가스 배출 잠재성을 감소시키기 위한 방안으로 먼저 하수 및 폐수의 체계적인 수집이 이루어져야 하며, 수집된 하ㆍ폐수는 반드시 적절한 처리과정을 통하여 수계에 배출되어져야 한다. 또한 적절한 처리과정 중에 배출되는 온실기체의 대기 중으로의 누설을 억제하고 회수율을 높이는 관리대책이 수립되어야 하며, 회수율을 높이는 대책은 하ㆍ폐수부문에서 온실가스 배출 잠재력에 대한 저감율에 대하여 좀더 효율적임을 알 수 있다. 또한 상기와 같은 저감방법 외에도 하ㆍ폐수부문에서의 온실가스 저감잠재력을 위하여 정부는 온실가스 배출량을 계산하는데 필요한 여러 가지 자료를 확보하고, 좀더 신뢰할 수 있는 온실가스 배출량을 산출하며, 이들 자료를 토대로 정부는 하ㆍ폐수부문에서의 온실가스 저감잠재력을 위하여 연차적으로 관리대책을 설정해야 한다. 그리고 이에 대한 검중체계를 마련하여 전ㆍ후 효과분석을 해야 할 것이다. This study evaluated greenhouse gas(GHG) emissions and future reduction potential emitted from domestic and industrial wastewater treatment system in Kwangju city and Chollanamdo. For decreasing of GHG emissions potential, systematic collection method of domestic and industrial wastewate is established and collected domestic and industrial wastewater is treated reasonal wastewater treatment process. GHG which is leak from wastewater treatment process to air was controled, Control policy which are increasing recovery ratio was established. In addition to decreasing method, Government make sure of variable data fro estimating GHG emissions quality and evaluated GHG emissions quality reliable method.

흉선종 제거후에 발생한 재생 불량성 빈혈 : 증례보고

전원선,이상철,김현정,배상병,김찬규,이남수,박노진,이규택,박성규,홍대식,박희숙,원종호 순천향의학연구소 2007 Journal of Soonchunhyang Medical Science Vol.13 No.2

Thymoma is associated with myasthenia gravis, Pure red cell aplasia, and autoimmune diseases such as autoimmune hemolytic anemia, aplastic anemia, and hypogammaglobulinemia. It's association with aplastic anemia is rare and aplastic anemia appearing after surgical removal of thymoma is especially rare. The authors hereby report a case of aplastic anemia occuring in a patient who was diagnosed with thymoma and myasthenia gravis and had the tumor surgically removed. The patient was treated with anti-thymocyte globulin, cyclosporin, and prednisolone, and showed partial remission with hematologic improvements after 12 months.

이산화티타늄계 광촉매를 이용한 벤젠의 처리 특성

전의찬,송민종,김전희 동신대학교 환경연구소 1999 환경연구 Vol.4 No.1

An available methods for abating VOC(including Benzene) are thermal or catalytic incineration, liquid absorption, solid adsorption, condensing, membranes, biodegradation and plasma discharge, but a number of defects are these VOC abating methods, including ; requires a auxiliary fuel, generate secondary pollutants(waste catalysts, waste absorbents, waste adsorbents, ozone, etc.), a large scale, etc.. But photoactive catalysts, when illuminated with UV-light, generate highly reactive radicals that can oxidize the organic contaminants in gas. One methods to increase the efficiency of the process, and thereby reduce the light energy requirement, is by developing more active catalysts. Because of, ball type TiO₂ catalyst were obtained commercially and/or prepared in laboratory were examined for their photoacivity, and they are TiO₂ added some annex(Al₂O₃, SiO₂, KsO, P₂O_(5), etc.). The organic compounds used to identify the best photo catalysis condition were benzene. This study also examined the impact of catalyst structure, light intensity, existence of oxygen as an electron acceptor and Benzene initial concentration on the reaction kinetics. Labratory experiments were performed to investigate TiO₂ photo catalysis for treating test gas contaminated with Benzene. and TiO₂ photo catalysis efficiency for mineralization of Benzene is also evaluated. The photo oxidation of Benzene was carried out in a photo catalytic reactor at room temperature. I performed BTX photo catalytic oxidation experiments using a single-pass annular reactor. The organic-contaminated gas was prepared in Teflon sampling bag(25L) and passing through photo catalytic reactor by vacuum pump which is located reactor outlet. The BTX diluted with mixture air or nitrogen gas. Flow rates for test gas stream were controlled by micro flow meter going out the reactor. The reactor illuminated with 15W near-UV lamp, BLB lamp or Fluorescent lamp. The light intensity at the catalyst surface were estimated to be 0.8 to 6mW cm-2s-1. The inner cell of the reactor was packed with ball type titanium dioxide(Ø 6mm). Benzene was determined by GC-FID of gas samples taken from the a glass sampling bulb which was located at reactor outlet by gas-tight syringe. TiO₂ photo catalysis for treating test gas contaminated with Benzene. and TiO₂ photo catalysis efficiency for mineralization of Benzene is also evaluated. Using the anatase type photo catalyst, Benzene conversion rate is greater than that of rutile(92% conversion of 100ppmv Benzene using anatase type photo catalyst, 80% conversion of 100ppmv Benzene using rutile type photo catalyst at 0.5L/min) Effect of light intensity on the rate of Benzene photo catalytic decomposition was investigated by three type lamps within the reactor. When light intensity to increase, the Benzene conversion rate to increase. Using the BLB lamp showed higher activity than the Fluorescent lamp, but UV lamp showed the hight photo catalytic activity(26% conversion of 100ppmv Benzene with Fluorescent lamp, 63.5% conversion of 100ppmv Benzene with BLB lamp, 92% conversion of 100ppmv Benzene with UV lamp at 0.5L/min). Experiments with added oxygen as an electron acceptor improved the reaction rate considerably(92% conversion of 100ppmv Benzene without oxygen, 66.1% conversion of same Benzene concentration with mixture air at 0.5L/min). The Benzene conversion rate begins to decrease while Benzene initial concentration begins to increase. We have thus concentrated our effects on the study of Benzene degradation kinetics in vary initial Benzene concentration.

심전도 모니터링 계측 시스템의 개발에 관한 연구

박찬원,전찬민,박희석 강원대학교 정보통신연구소 2004 정보통신논문지 Vol.8 No.-

A wearable electrodiagram(ECG) monitoring system is a widely used non-invasive diagnostic tool for ambulatory patients who may be at risk from latent life-threatening cardiac abnormalities. In this paper. we have a portable ECG monitoring system with conductive fiber characterized by the small-size and the low power consumption. The system consists of conductive fibers, one-chip microcontroller, ECG preprocessing circuit, and monitoring software to record and analyze in PC. ECG preprocessing circuit is made of pre-amplifier with gain of 10, band-pass filter with bandwidth of 0.5-120% and 2.5V offset circuit for A/D conversion. ECG signals obtained by sensor are corrupted by noises such as a baseline wandering, 60Hz power noise and interference noise by body movement. For cancellation of noises in signals obtained by conductive fiber, we used the wavelet decomposition of wavelet transforms in MATLAB toolbox.

백반증 병변에 국한되어 발생한 건선 1예

김윤전,강희영,이은소,김유찬 대한피부과학회 2006 대한피부과학회지 Vol.44 No.4

만성 강박장애 환자의 정서처리 특성 : 정신분열병 환자 및 정상인과의 비교

석정호,김재진,전종희,이홍식,안석균,이은,김찬형 大韓神經精神醫學會 2005 신경정신의학 Vol.44 No.3

Objectives : Obsessive compulsive disorder (OCD) tends to take chronic course as schizophrenia. Researchers reported that OC patients had idiosyncratic sensitivity to threat-related information, while schizophrenic patients were reported to have affec-tive blunting. We hypothesized that there might be a difference in emotional response between OCD and SPR in cronic phase. Methods : Eight different emotional tasks were done by 25 healthy controls, 21 OCD patients and 25 SPR patients. Visual stimuli were made by pairing two words or pictures. Four kinds of emotional stimuli (positive, negative, combined and neutral)were presented to subjects through monitor and they were asked to report their subjective feelings by pushing mouse button, In the combined condition, a pair of positive words (or pictures) and negative words (or pictures) were presented simultaneously. The responses and response time were recorded and analyzed using SPSS 9.0 package. Results : In the negative condition, OCD group didn't show any deficit compared to healthy group. But SPR group showed significantly lower appropriate response rate than healthy group, In the combined condition, OCD and healthy control group Showed 'negativity bias' which SPR group didn't show. In the positive condition, however, OCD and SPR groups did show Significantly lower appropriate response rate than healthy controls. Conclusion : Our results suggested that OCD patients may not have deficits in the processing of negative emotion even in the chronic phase but to have a specific deficit in positive emotion. This result supports the 'threat-relatedness hypothesis' on attentional bias of OCD.

금피복된 임플란트 보철용 유지나사의 예비하중 및 풀림회전력에 관한 연구

정창모,황희성,전영찬,최설희 大韓齒科器材學會 2000 대한치과재료학회지 Vol.27 No.3

The purpose of this study was to compare the preload and the removal torque produced when using gold coated prosthetic retaining screws (Gold-Tite retaining screws) and non-coated screws(gold screws) repeatedly and to evaluate effects of a thin pure gold coating on screw stability. Following connection of the conical abutment to implant fixture using 20 Ncm of torque applied by a torque gauge, fastened the strain-gauged gold cylinder to conical abutment with gold screw, Gold-Tite retaining screw using 10Ncm. Then, preloads and removal torques were measured, screws tightened and loosened 8 times repeatedly. All experiments were performed under dry and wet condition. The results obtained were summarized as follows : 1. For gold screw group, no significant differences existed in the preload and the removal torque according to trials in both conditions(p>0.05). 2. For Gold-Tite retaining screw group, no significant differences existed in the preload according to trials in both conditions(p>0.05). However, the removal torque decreased at the second trial and incresed, after then(p<0.05). 3. In comparison of preloads according to trials, the preload in dry condition was greater than in wet condition only for Gold-Tite retaining screw group after the fourth trial(p<0.05). However, no significant differences were found between gold screw group and Gold-Tite retaining screw group(p>0.05). 4. In comparison of removal torque according to trials, the removal torque of gold screw group was greater than of Gold-Tite retaining screw group in dry condition at the second, third trial(p<0.05). At the other trials, no significant differences were found among the experimental groups(p>0.05).

<디자인과 마케팅>융합을 통한 출판사 협동조합 'POOM' 개발 -그래픽 디자인, 제품 디자인, 공간 디자인을 중심으로-

주서역,오연수,유로운,이진민,장미정,전찬희,정인희 숙명여자대학교 디자인연구소 2017 숙명디자인학 연구 Vol.23 No.-

본 연구는 한국인의 독서 장려와 보다 효율적인 독서문화 전하를 위해 출판협동조합 브랜드 'POOM'을 개발하는 일련의 과정들을 밝히는데 그 목적이 있다. 연구의 대상은 2016년 3-6월 15주간 숙명여대 환경디자인학과 <브랜드스페이스마케팅> 수업에서 진행도니 수업의 결과물로써 4개 팀 중 1개 팀의 작업물을 정리한 것이다. 연구 범위는 4개의 주제 중 물의 'product'로 한정하였다. 연구 결과, '늘 내 품에 지닐 수 있는 책' 이라는 상징 개념으로 '품(POOM)'이라고 브랜드 네이밍하였다. 그래픽 디자인은 심플함과 속도감을 나타내는 레드 컬러로 얇은 책을 형상화한 형태를 로고에 적용, 제품 디장니은 휴대하기 편한 패키지디자인 개발, 공간디자인은 지하철 2,3,9호선으로 선정하고 각 호선의 특성을 기반으로 브랜드 컬러로 하여, 각 호선에 맞는 공간과 경유하는 지역의 특성을 통합적으로 브랜딩 하였다. 끝으로 본 연구는 출판협동조합의 아이덴티티를 개발함에 있어서 디자인과 마케팅을 융합하여 좀 더 체계화된 GI, PI, SI의 통합 브랜드 메뉴얼을 만드는 것에 의의가 있으며, 향후 협동조합의 통합 브랜드 디자인 개발에 있어서 그 자료로 활용될 것으로 기대한다.

독성물질의 세포사 기전 및 세포사 유발물질의 검색법 개발에 관한 연구(Ⅱ) : 망간 신경독성을 이용한 파킨슨증 모델의 세포사 Studies on the Mechanism of Parkinsonism induced by Manganese

김종민,박창원,오정자,이보경,서경원,서수경,김규봉,김종원,김광진,김영옥,전범석,박찬웅,이선희 식품의약품안전청 2001 식품의약품안전청 연보 Vol.5 No.-

1960년대 이후 파킨슨병의 유발물질 중 한 후보로서 망간이 주목받으면서 많은 역학적, 병러학적 연구가 수행죄브다. 그러나 망간이 파킨슨병을 직접 일으키는지, 혹은 파킨슨병과 관련된 부위의 신경세포를 파괴시쿡 파킨슨증만을 초래하는 것인지가 아직 정립되지 않은 실정이다 본 연구에서는 실험동물모델에서 행등학적 변화 측정 및 병리학적, 샐화학적 연구를 통하여 망간의 과다노출글 따른 파킨슨병 유발 여부를 확인하고자 하였다. Sprague-Datylet· 렛드에 망간을 1, 2, 5, 10 mgAg/day의 응량으로 30일 등안 복강 투여하였을 때 모든 망간투여군에서 운동성 감소가 관찰되었다. 뇌조직의 망간 함량을 ion chromatograph?로 측정한 결과 중뇌 흑질과 기저핵 선조체에서 망간 함량의 뚜렷한 증가 소견이 관찰되었으며, 니슬염색체서 선조체의 신경세포수의 유의성 있는 감소가 관찰되었다. 그러나, 흑질의 TH효소 면역염색, GFAP 면역염색, 흑질과 선조체의 T릿효소 western blot 결과는 대조군과 차이가 없었다. 이상의 결과에서, 망간-파킨슨증 모델에서 파킨슨증어 유발되는 기전은 흑질 도파민성 신경 세포의 신호를 받는 선조체 씬경세포의 사멸에 의한 것으로 생각된다. 결론적으로, 망간 독성에 의한 파킨스증 모델에서는 파킨슨 병과는 달리 흑질 도파민성 신경세포의 세포사는 관여하지 않는 것으로 관찰되었다. Manganese(Mn) intoxication causes a parkinsonian syndrome. It may be difficult to distinguish Mn-induced parkinsonism from idiopathic Parkinson disease(IPD). Neuropathological descriptions on the brains with Mn intoxication showed the perferential damage in the globus pallidus and substantia nigra pars reticularis. Pathological reports on the substantia nigra pars compacta(SNpc), a mafor focus of pathologic changes in IPD, are discordant and controversial. The SNpc involvement is of critical importance for the elucidation of pathogenesis of IPD. Therefore, the neurodegeneration in SNpc was investigated in the experimental model of Mn neurotoxicity. Sprague-Dawley rats were administered with manganese chloride(1, 2, 5, 10 mg/kg/day, i.p.) for 30 days. Treated animals showed low levels of distance-traveled from locomotor activity tests. Ion chromatography revealed that Mn accumulation was significant in SN and basal ganglia in Mn-treated animals. Nissl staining showed neuronal loss of the striatum in all treated animals. The degree of neurodegeneration in SN was determined by immunohistochemical staining of tyrosine hydroxylase(TH). The numbers of TH-positive cells on nigral sections were not different from each groups(P>0.05). The densities of glial fibrillary acidic protein immunoreactivity from SN were similar between groups. TH-westen blotting showed no differences between treated animals and controls. In conclusion, the SNpc remains intact in Mn intoxication, and Mn-induced parkinsonism may be caused by damages of output pathways downstream to the nigrostriatal dopminergic system.