Poly(vinylbenzyl chloride-glycidyl methacrylate)/Polyethylene Composite Anion Exchange Membranes for Vanadium Redox Battery Application

Park, Min-A,Shim, Joonmok,Park, Se-Kook,Jeon, Jae-Deok,Jin, Chang-Soo,Lee, Ki Bong,Shin, Kyoung-Hee Korean Chemical Society 2013 Bulletin of the Korean Chemical Society Vol.34 No.6

Anion exchange membranes for a vanadium redox flow battery (VRB) were prepared by pore-filling on a PE substrate with the copolymerization of vinylbenzyl chloride (VBC) and glycidyl methacrylate (GMA). The ion exchange capacity, water uptake and weight gain ratio were increased with a similar tendency up to 65% of GMA content, indicating that the monomer improved the pore-filling degree and membrane properties. The vanadium ion permeability and open-circuit voltage were also investigated. The permeability of the VG65 membrane was only $1.23{\times}10^{-7}\;cm^2\;min^{-1}$ compared to $17.9{\times}10^{-7}\;cm^2\;min^{-1}$ for Nafion 117 and $1.8{\times}10^{-7}\;cm^2\;min^{-1}$ for AMV. Consequently, a VRB single cell using the prepared membrane showed higher energy efficiency (over 80%) of up to 100 cycles compared to the commercial membranes, Nafion 117 (ca. 58%) and AMV (ca. 70%).

정신분열병에 대한 리스페리돈의 효과 및 안정성

이민수,김용구,김영훈,연병길,오병훈,윤도준,윤진상,이철,정희연,강병조,김광수,김동언,김명정,김상훈,김희철,나철,노승호,민경준,박기창,박두병,백기청,백인호,손봉기,손진욱,양병환,양창국,우행원,이정호,이종범,이홍식,임기영,전태연,정영조,정영철,정인과,정인원,지익성,채정호,한상익,한선호,한진희,서광윤 大韓神經精神醫學會 1998 신경정신의학 Vol.37 No.1

연구목적 : 본 시험의 목적은 임상시험 시작전에 연구자들을 대상으로 PANSS Workshop을 통하여 PANSS, ESRS에 대한 국내에서의 표준화 작업을 구축하고 새로운 정신병 치료제인 리스페리돈의 효과와 안정성을 재확인하여 리스페리돈 사용에 대한 적정화를 이루는데 있다. 연구방법 : 1996년 4월부터 1996년 9월까지 국내 39개 대학병원 정신과에 입원중인 혹은 증상이 악화되어 입원하는 정신분열병 환자 377명을 대상으로 다시설 개방 연구를 시행하였다. 1주일간의 약물 배설기간을 가진후, 리스페리돈을 8주간 투여하였고, 기준점, 1주, 2주, 4주, 그리고 8주후에 평가되었다. 용량은 제1일에는 리스페리돈 1mg씩 1일 2회, 제2일에는 2mg씩 1일 2회, 제3∼7일에는 3mg씩 1일 2회 투여하였다. 이후 환자의 임상상태에 따라 임의로 증량할 수 있으며, 최대 일일 16mg을 초과하지 않도록 하였다. 추체외로 증상을 조절하기 위한 투약을 허용하였다. 임상증상 및 부작용의 평가는 PANSS(Positive and Negative Syndrome Scale), CGI(Clinical Global Impression) 그리고 ESRS(Extrapyramidal Symptom Rating Scale)을 사용하였다. 연구결과 : 377명중 343명(91%)이 8주간의 연구를 완결하였다. 치료 종결시점인 8주후 PANSS 총점수가 20% 이상 호전된 경우를 약물 반응군으로 정의할때, 약물반응군은 81.3%였다. 리스페리돈에 반응하는 예측인자로는 발병연령, 이전의 입원 횟수, 유병기간이 관련 있었다. 리스페리돈은 1주후부터 PANSS양성, 음성, 및 일반정신병리 점수상에 유의한 호전을 보여 효과가 빨랐다. CGI의 경우도 기준점에 비해 1주후부터 유의한 감소를 나타내었다. ESRS의 경우, 파킨슨 평가점수는 기준점과 비교해 투여 1주, 2주, 4주후 유의하게 증가되었다가 8주후 기준점과 차이가 없었다. Dystonia 평가점수는 1주후만 유의한 증가를 보였으며, dyskinesia 평가점수는 유의한 차이가 없었다. 혈압, 맥박수의 생명징후 및 일반 혈액학 검사, 생화학적 검사, 심전도 검사에서 유의한 변화는 없었다. 결 론 : 이상의 다시설 개방 임상 연구를 통해 리스페리돈은 정신분열병 환자에서 양성증상뿐만 아니라 음성증상 및 전반적인 증상에도 효과적인 것으로 사료된다. 보다 명확한 평가를 위해서는 다른 항정신병약물과의 이중맹검 연구가 필요할 것으로 생각되며, 또한 장기적 치료에 대한 평가도 함께 이루어져야 하겠다. Objective : The purpose of this study was to investigate the efficacy and safety of risperidone in the treatment of Korean schizophrenic patients. Method : This multicenter open study included 377 schizophrenic patients drawn from 39 university hospitals. After a wash-out period of 1 week, the schizophrenic patients were treated with risperidone for 8 weeks and evaluated at 5 points ; at baseline, and 1, 2, 4 and 8 weeks of treatment. The dose was increased from 2mg/day(1mg twice daily) to 6mg/day(3mg twice daily) during the first week and adjusted to a maximum of 16mg/day over the next 7 weeks according to the patient's clinical response. Medication to control extrapyramidal symptoms was permitted. The psychiatric and neurological status of the patients was assessed by PANSS, CGI, and ESRS scales. Results : 343(91%) of 377 patients completed the 8-week trial period. Clinical improvement, as defined by a 20% or more reduction in total PANSS score at end point, was shown by 81.3% of patients. The predictors of response to risperidone were associated older age, shorter duration of illness, fewer previous hospitalization. Risperidone had rapid onset of action ; a significant decrease of the total PANSS and three PANSS factor(positive, negative, general), and CGI was already noticed at the end of first week. For the ESRS, parkinsonism rating scores were significantly increased until week 4 comparing with baseline. Dystonia rating scores were significantly increased until week 1, and dyskinesia rating scores were not significantly changed during the study. Laboratory parameters including vital sign, EKG, hematological, and biochemical values showed no significant changes during the trial. Conclusions : This study suggests that risperidone is generally safe and effective against both the positive and negative symptoms in our group of patients.

사료원료 공급량 및 스크류 회전속도를 달리하여 제조한 배합사료가 넙치(Paralichthys olivaceus)의 성장 및 체조성에 미치는 영향

김경덕 ( Kyoung Duck Kim ),김강웅 ( Kang Woong Kim ),이봉주 ( Bong Joo Lee ),배기민 ( Ki Min Bae ),안철민 ( Cheul Min An ),한현섭 ( Hyun Sob Han ) 한국수산과학회 2014 한국수산과학회지 Vol.47 No.5

The aim of this study was to investigate the effect of diet extruder conditions, such as feed-loading rate and screw speed, on growth performance and biochemical responses in olive flounder Paralichthys olivaceus. Over 8 wks, we used four identical diets (triplicated per treatment) with differing ratios of feed-loading rate (kg/h):screw speed (rpm/min) in a laboratory-scaled twin-screw extruder of 50:640, 80:640, 120:640, and 80:400, designated as EP1, EP2, EP3, and EP4, respectively. Screw speed impacted the buoyancy of experimental diets. Diets produced at a screw speed of 640 rpm/min floated for > 24 hrs, whereas those produced at a speed of 400 rpm/min sank between 10 s and 5 min. Fish that were fed EP1 and EP4 diets grew significantly faster than those fed EP2 and EP3 diets. Fish fed EP1 diets ate and gained weight most efficiently among treatments, a result that is likely to be related to feed-loading rate, i.e., ingredients extruded at a low feed-loading rate may have more time to cook in the pre-conditioner of the extruder. A cooked diet may be easier to digest in fish. Fish fed EP4 diets also showed significant weight gain, as compared to those fed EP2 and EP3 diets. However, we found no differences among treatments in proximate compositions of dorsal muscle, liver, and viscera of fish. Our results suggest that extruder conditions, may influence feed quality, impacting feed efficiency and growth of fish.

[논문]전위차계를 이용한 유리 소결체의 소결도 측정

차재민,이병철,류봉기 釜山大學校生産技術硏究所 2003 生産技術硏究所論文集 Vol.62 No.-

PDP(Plasrna Display Panel) Rib은 PDP의 부품 중 매 우 중요한 부분의 하나이 며 Rib의 소결 정도는 cross-talk와 같은 현상을 방지하는 데에 중요한 역할을 한다. Rib은 주로 스크린 프린팅법에 의해 제작되지만, 인쇄, 소성 등 일련의 제조 공정을 거친 후 얻어진 수백 μm 미세규격의 격벽 소결체의 소결도를 정확히 평가하기는 쉽지 않다. 본 연구에서는 Rib의 소결도를 직접적 판단할 수 있는 방법에 대한 연구의 일환으로서 기공의 응집,성장을 Potentiostat로 절연 파괴/ 전계 집중의 원리를 이용함으로서 소결도를 측정했다. 이 측정값은 각 온도에서 열처리한 시편에 대한 밀도값과 유사한 경향성이 나타남을 확인할 수 있었다. 개기공과 폐기공의 분포에 따라 예상될 수 있는 측정오차는 온도에 따른 미세구조의 변화를 수차례의 전자 현미경 관찰을 통해 확인하여I 미세규격 Rib 소결도의 판단을 전기화학적 방법으로 예측 가능 하다는 것을 알 수 있었다.

여수국가산업단지 인근 지역 대기오염물질 농도에 영향을 미치는 요인분석

김민영,변정훈,이영훈,이건영,한지은,이예림,임지현,장봉기 순천향대학교 기초과학연구소 2022 순천향자연과학연구 논문집 Vol.28 No.1,2

Eight monitoring stations in the Yeosu National Industrial Complex will determine the concentration of air pollutants measured every hour in 2019, analyze what factors affect them, and how they correlate with the air pollutant measurements. Six air pollutants (SO2, NO2, O3, CO, PM-10 and PM-2.5) measured at eight monitoring stations around Yeosu National Industrial Complex (Seogang-dong, Wolnae-dong, Munsu-dong, Yeocheon-dong, Deokchung-dong, Hwayang-myeon, Yulchon-myeon, Samil-dong) the measurement data for each hour of the year were downloaded to analyze the concentration by weather condition, time zone, season, separation distance from Yeosu Industrial Complex, and separation distance from Gwangyang Industrial Complex. SO2, NO2, and CO concentrations were significantly higher in winter, significantly lower in summer, and O3, PM-10, and PM-2.5 concentrations were significantly higher in spring. SO2, CO, PM-10, and PM-2.5 concentrations were significantly higher between 10 a.m. and 12 p.m., NO2 concentrations were significantly higher between 7 a.m. and 9 a.m., and O3 concentrations were significantly higher between 13 p.m. and 15 p.m.(p<0.001). The concentration of air pollutants (SO2, NO2, CO, PM-10, PM-2.5) excluding O3 was found to have a negative (-) correlation with weather condition, and in the case of O3, it was found to have a positive (+) correlation with PM-10, PM-2.5, temperature and wind speed. It was confirmed that the concentration of air pollutants emitted from the Yeosu National Industrial Complex differs depending on the season, time and distance to the industrial complex. This study aims to establish measures to minimize health damage to residents living relatively close to the industrial complex and contribute to the establishment of management and response measures according to the properties of substances to reduce the concentration of air pollutants in the future.

특허제도 및 현황

민봉기 中央大學校 遺傳工學硏究所 2002 遺傳工學硏究論集 Vol.15 No.1

우리나라는 선출원주의와 심사주의를 채택하고 있어, 먼저 출원한 발명에 대하여 실체 심사를 거쳐 특허권을 인정하여 주며, 특허권은 출원일로부터 20년간 존속한다. 출원후 1년6개월이 경과하면 공개되며(필요시 우선공개 할 수 있음), 심사청구 순으로 실체심사에 들어가는데 우리나라의 특허 심사 기간은 98년 말에 28개월로 매년 심사기간을 단축하여 선진국 수준인 24개월 이내를 목표로 하고 있다. 특허청은 1998년부터 공개 및 등록공보를 CD롬으로 발행하고 있으며, 1999년 1월부터 특허넷(Kipo-Net)시스템의 개통으로 특허에 관한 모든 업무를(인터넷을 이용한)On-Line으로 처리하게 되었고, 또한 7월부터는 특허에 비하여 상대적으로 라이프사이클이 짧은 실용신안(고안)에 대하여는 선등록제도를 도입합으로서 조기에 권리화가 가능하게 되었다.

고감도 메탄 가스센서를 위한 입자성장 억제제의 영향

민봉기,최순돈 경북대학교 센서기술연구소 1998 센서技術學術大會論文集 Vol.9 No.1

Adding Ca, Mg, and K to SnCl_(4) solution in order to inhibit crystallization during heat treatment, SnO_(2) powder was obtained by precipitation method. The characteristics of the prepared SnO_(2) powder were investigated using XRD and BET. Sensors formed thick-film on Al_(2)O_(3) substrate by screen printing were fired various conditions. Methane gas sensitivity was investigated in terms of degree of crystallization and firing condition. Due to the smallest particle size of Ca-SnO_(2) powder, Ca-SnO_(2) gas sensor has superior sensitivity to CH_(4). It was found that firing condition of 700°C and 20 min provides highest sensing characteristics to CH_(4).

A2024-T4 同種材 마찰용접시 업셋압력이 접합특성에 미치는 영향

고봉학,장승수,여상은,민택기 忠南大學校 産業技術硏究所 2002 산업기술연구논문집 Vol.17 No.2

The study deal with the strength of weld zone, the effect of upset pressure and microstructure of weld zone which are obtained from the variation of upset pressure in the friction welding A2024-T4 similar materials. The welding conditions was fixed welding condition of rotation speed 1000rpm, friction pressure 150Mpa, friction time 1.0sec and upset time 4.0sec. The upset pressure was variationed from 200Mpa to 320Mpa. The result are summarized as follows: 1. As a result of tensile test, the maximum tensile strength was obtained 503Mpa and it corresponds to about 104% of base metal tensile strength. tensile fracture surfaces appeared deep Dimple in heat affected zone(HAZ) 2. As a result of vickers hardness test, the maximum hardness was obtained 136Hv in friction welding interface and width of heat affected zone(HAZ) appeared 0.2mm. 3. As a result of analyzing th microstructure of weld zone. Me or Mn compounds of friction welding interface come out flash zone by centrifugal force and upset pressure, the microstructure of weld zone is recrystallized.

11세 여아에서 발생된 성숙 낭성 기형종의 염종1예

이희민,김재현,이봉주,하태규,김흥곤,윤기중 圓光大學校 醫科學硏究所 1996 圓光醫科學 Vol.12 No.1

Mature cystic teratomas comprise 10% of all ovarian tumors and show the highest frequency of incidence in women under 20 years of age. Torsion of ovarian cyst is the most common complication in young female and lower abdominal pain, peritonitis, necrosis and shock are outcomes that require emergency treatment. Generally, gross finding of mature cystic teratoma shows that most of the entire ovary is replaced by multiple cystic masses, and rarely only small portion of the ovary is changed into cystic mass. We report a case of torsion of mature cystic teratoma in an 11 year old girl with a brief review of literature.

아산시 5대 저수지의 오염부하량 산정을 통한 수질오염 요인분석

장봉기;김민중;최재호;이종화 순천향대학교 기초과학연구소 2010 순천향자연과학연구 논문집 Vol.16 No.2

Five great reservoirs located in Asan city (Gungpyeong, Gahye, Togo, Masan, Bongjae) for each of the inflow of water pollutants (biochernical oxygen demand (BOD), suspended solids (SS), total nitrogen (T-P), total phosphorus (T- P) in units of pollutant loads were calculated by estimating. The results were as follows; The ratio of livestock wastewater for BOD, SS, T-N and T-P were occupied with the 58.7%, 85.4%, 59.1% and 91.2%, respectively of total water pollution load in the reservoir Gungpyeong. The ratio of livestock wastewater for BOD, SS, T-N and T-P were occupied with the 96.1%, 97.6%, 96.2% and203rmb 99.5%, respectively of total water pollution load in the reservoir Gahye. The ratio of livestock wastewater for BOD, SS, T-N and T-P were occupied with the 93.8%, 96.9%, 91.7% and 98.7%, respectively of tot~l water pollution load in the reservoir Togo. The ratio of livestock wastewater for BOD, SS, T-N and T-P were occupied with the 39.3%, 71.6%, 52.2% and 76.2%, respectively of total water pollution load in the reservoir Masan The ratio of livestock wastewater for BOD, SS, T-N and T-P were occupied with the 96.3%, 98.5%, 96.2% and 99.5%, respectively of total water pollution load in the reservoir Bongjae. Total amounts of each water pollutants was highest in the basin of reservoir Bongjae and the next Gahye, Togo, Masan. Reservoir Gungpyeong was lowest in five reservoirs located in Asan Clty. These results suggest that contamination of the reservoir inflow in Asan city, water pollution management for the reservoirs will be focusing on the livestock wastewater.