Physical Chemistry Research Articles Published in the Bulletin of the Korean Chemical Society: 2003-2007

Sun, Ho-Sung,Lee, Sun-Yeoul,Lee, Choon-Shil Korean Chemical Society 2008 Bulletin of the Korean Chemical Society Vol.29 No.2

The physical chemistry (PC) articles published in the Bulletin of the Korean Chemical Society (BKCS) from 2003 to 2007 are surveyed, and in-depth content analysis was conducted to classify the PC articles into 12 topics used in The Journal of Physical Chemistry (JPC). The PC articles published in the Journal of the American Chemical Society (JACS) in 2007 are also surveyed. The extensive summary of all PC articles in BKCS for the last five years reveals the current trend of physical chemistry research in Korea. The comparison study with the JACS shows that the proportion of PC articles among all articles published in BKCS (16%) is slightly higher than that of JACS (11%), and the non-Korean authorship ratio of BKCS (12%) is very low compared with the non-US authorship of JACS (52%). From the comparison study with articles published in JPC in 2007, it is found that BKCS disseminates various topics of physical chemistry researches adequately. In particular, BKCS most frequently published PC articles in molecular structure and spectroscopy topics, whereas JPC published surface chemistry and nano-chemistry articles most frequently. It is concluded that BKCS should publish more articles to be a leading journal, and it is suggested that the SCI impact factor of BKCS must be increased by improving the electronic version of BKCS.

Portable Amperometric Perchlorate Selective Sensors with Microhole Array-water/organic Gel Interfaces

Lee, Sang Hyuk,Kim, Hyungi,Girault, Hubert H.,Lee, Hye Jin Korean Chemical Society 2013 Bulletin of the Korean Chemical Society Vol.34 No.9

A novel stick-shaped portable sensing device featuring a microhole array interface between the polyvinylchloride-2-nitrophenyloctylether (PVC-NPOE) gel and water phase was developed for in-situ sensing of perchlorate ions in real water samples. Perchlorate sensitive sensing responses were obtained based on measuring the current changes with respect to the assisted transfer reaction of perchlorate ions by a perchlorate selective ligand namely, bis(dibenzoylmethanato)Ni(II) (Ni(DBM)2) across the polarized microhole array interface. Cyclic voltammetry was used to characterize the assisted transfer reaction of perchlorate ions by the $Ni(DBM)_2$ ligand when using the portable sensing device. The current response for the transfer of perchlorate anions by $Ni(DBM)_2$ across the micro-water/gel interface linearly increased as a function of the perchlorate ion concentration. The technique of differential pulse stripping voltammetry was also utilized to improve the sensitivity of the perchlorate anion detection down to 10 ppb. This was acquired by preconcentrating perchlorate anions in the gel layer by means of holding the ion transfer potential at 0 mV (vs. Ag/AgCl) for 30 s followed by stripping the complexed perchlorate ion with the ligand. The effect of various potential interfering anions on the perchlorate sensor was also investigated and showed an excellent selectivity over $Br^-$, $NO_2{^-}$, $NO_3{^-}$, $CO{_3}^{2^-}$, $CH_3COO^-$ and $SO{_4}^{2^-}$ ions. As a final demonstration, some regional water samples from the Sincheon river in Daegu city were analyzed and the data was verified with that of ion chromatography (IC) analysis from one of the Korean-certified water quality evaluation centers.

Electron Beam Coherency Determined from Interferograms of Carbon Nanotubes

Cho, B.,Oshima, C. Korean Chemical Society 2013 Bulletin of the Korean Chemical Society Vol.34 No.3

A field emission projection microscope was constructed to investigate the atomic and chemical-bonding structure of molecules using electron in-line holography. Fringes of carbon nanotube images were found to be interferograms equivalent to those created by the electron biprism in conventional electron microscopy. By exploiting carbon nanotubes as the filament of the electron biprism, we measured the transverse coherence length of the electron beam from tungsten field emitters. The measurements revealed that a partially coherent electron-beam was emitted from a finite area.

Chemical and Electrochemical Intercalation of Lithium in 2D-FeMoO$_4Cl^1$

조진호,장순호,노동윤,손경아,Choy Jin-Ho,Chang Soon-Ho,Noh Dong-Youn,Son Kyoung-A Korean Chemical Society 1989 Bulletin of the Korean Chemical Society Vol.10 No.1

Lithium has been intercalated into $FeMoO_4Cl$, and deintercalated from $LixFeMoO_4Cl$ both electrochemically and chemically. The inserted $Li^+$ ions are stabilized in the distorted octahedral field in interlayer space of $FeMoO_4Cl$. The crystal symmetry is reduced from tetragonal to monoclinic due to the reduction of ferric to ferrous ions in $LixFeMoO_4Cl$ upon lithium intercalation. From the magnetic and structural data, it has been concluded that the high-spin electronic configuration of $Fe^{2+}(d_{xz}^2{d_{y2}^1}{d_1}{2d_z^12}{\cdot}_y2)$, corresponding to $^5E_g$, group term in $D_{4h}$ symmetry, can be stabilized by the elongation of $FeO_4Cl_{2-}$octahedra in a weak ligand field.

Evaluation of the Function exp$(x^2)$ erfc(x) to Higher Precisions for Higher Order Derivative Polarography of CE-type Electrode Process

Kim, Myung-Hoon,Smith, Veriti P.,Hong, Tae-Kee Korean Chemical Society 1990 Bulletin of the Korean Chemical Society Vol.11 No.6

The function exp$(x^2)$erfc(x), which is often encountered in studies of electrode kinetics, is evaluated to an extended precision with 32 significant decimal digits in order to find theoretical relationships used in derivative polarography/voltammetry for a chemically-coupled electrode process. Computations with a lower precision are not successful. Evaluation of the function is accomplished by using three types of expansions for the function. Best ranges of arguments are selected for each equation for particular precisions for efficiencies. The method is successfully applied to calculate higher-order derivatives of the current-potential curves in all potential ranges for a reversible electron transfer reaction coupled with a prior chemical equilibrium (i.e., a CE type process). Various parameters that characterize the peak asymmetry (such as ratios of peak-heights, ratios of half-peak-widths, and separations in peak-potentials) are analyzed to find how kinetic and thermodynamic parameters influence shapes of the derivatives. The results from the CE process is compared with those from an EC process in which a reversible electron transfer is coupled with a follow-up homogeneous chemical reaction. The two processes exibit quite contrasting differences for values of the parameters.

Liquid Crystal Droplet Patterns to Monitor Catalase Activity at Femtomolar Levels

Yoon, Stephanie,Jang, Chang-Hyun Korean Chemical Society 2014 Bulletin of the Korean Chemical Society Vol.35 No.9

Catalase (CAT) decomposes hydrogen peroxide that is toxic to the body. In this study, simple and sensitive detector has been developed for observing catalase activity using liquid crystal droplet system. Microscale LC droplet patterns are formed by spreading aldehyde-doped nematic liquid crystal on pre-treated glass slides. When hydrogen peroxide is added, aldehyde is oxidized and amphiphiles are formed. Dodecanoates cause the pattern to transit from bright to dark as they self-assemble to form a carboxyalte monolayer at the interface. When a drop of pre-incubated CAT and hydrogen peroxide mixture is placed onto the pattern, bright fan-shape is observed. This planar optical appearance indicates that catalase has decomposed hydrogen peroxide. Compared to the detectors that have been previously developed, this system is more sensitive with detection limit of 1fM. This research suggests further studies to be on LC droplet patterning to develop highly sensitive and methodologically simple sensors for various chemicals.

Effect of Soft-annealing on the Properties of CIGSe Thin Films Prepared from Solution Precursors

Sung, Shi-Joon,Park, Mi Sun,Kim, Dae-Hwan,Kang, Jin-Kyu Korean Chemical Society 2013 Bulletin of the Korean Chemical Society Vol.34 No.5

Solution-based deposition of $CuIn_xGa_{1-x}Se_2$ (CIGSe) thin films is well known non-vacuum process for the fabrication of CIGSe solar cells. However, due to the usage of organic chemicals in the preparation of CIG precursor solutions, the crystallization of the polycrystalline CIGSe and the performance of CIGSe thin film solar cells were significantly affected by the carbon residues from the organic chemicals. In this work, we have tried to eliminate the carbon residues in the CIG precursor thin films efficiently by using soft-annealing process. By adjusting soft-annealing temperature, it is possible to control the amount of carbon residues in CIG precursor thin films. The reduction of the carbon residues in CIG precursors by high temperature soft-annealing improves the grain size and morphology of polycrystalline CIGSe thin films, which are also closely related with the electrical properties of CIGSe thin film solar cells.

An Approach for the Uncertainty Evaluation of the Overall Result from Replications of Measurement: Separately Combining Individual Uncertainty Components According to their 'systematic' and 'random' Effects

Kim, In Jung,Kim, Byungjoo,Hwang, Euijin Korean Chemical Society 2014 Bulletin of the Korean Chemical Society Vol.35 No.4

In our previous articles, an approach has been proposed for the evaluation of the uncertainty of overall result from multiple measurements. In the approach, uncertainty sources were classified into two groups: the first including those giving same 'systematic' effect on each individual measurement and the second including the others giving 'random' effect on each individual measurement and causing a variation among individual measurement results. The arithmetic mean of the replicated measurements is usually assigned as the value for the overall result. Uncertainty of the overall result is determined by separately evaluating and combining an overall uncertainty from sources of the 'systematic' effect and another overall uncertainty from sources of the 'random' effect. This conceptual approach has been widely adopted in chemical metrology society. In this study, further logical proof with more detailed mathematical expressions is provided on the approach.

Hot-Pressing Effects on Polymer Electrolyte Membrane Investigated by ²H NMR Spectroscopy

Lee, Sang Man,Han, Oc Hee Korean Chemical Society 2013 Bulletin of the Korean Chemical Society Vol.34 No.2

The structural change of Nafion polymer electrolyte membrane (PEM) induced by hot-pressing, which is one of the representative procedures for preparing membrane-electrode-assembly for low temperature fuel cells, was investigated by $^2H$ nuclear magnetic resonance (NMR) spectroscopy. The hydrophilic channels were asymmetrically flattened and more aligned in the membrane plane than along the hot-pressing direction. The average O-$^2H$ director of $^2H_2O$ in polymer electrolyte membrane was employed to extract the structural information from the $^2H$ NMR peak splitting data. The dependence of $^2H$ NMR data on water contents was systematically analyzed for the first time. The approach presented here can be used to understand the chemicals' behavior in nano-spaces, especially those reshaping and functioning interactively with the chemicals in the wet and/or mixed state.

Development of Catalysts for the Synthesis of Some Intermediate Fine Chemicals. (Ⅰ) An Efficient Method for the Di-C-Ethylation of Ethyl Acetoacetate. Alkylation of Crowded Carbanions$^*$

서정훈,윤여홍,Suh Junghun,Yoon Yeo Hong Korean Chemical Society 1985 Bulletin of the Korean Chemical Society Vol.6 No.4