3D flexible Si based-composite (Si@Si₃N₄)/CNF electrode with enhanced cyclability and high rate capability for lithium-ion batteries

Kim, Si-Jin,Kim, Min-Cheol,Han, Sang-Beom,Lee, Gyu-Ho,Choe, Hui-Seon,Kwak, Da-Hee,Choi, Sun-Yong,Son, Byung-Goo,Shin, Myoung-Sun,Park, Kyung-Won Elsevier 2016 Nano energy Vol.27 No.-

<P><B>Abstract</B></P> <P>Despite extremely high capacity of Si-based anodes in lithium-ion batteries (LIB), Si-based materials have shown a structural collapse caused by a volumetric expansion/contraction during the cycling process. The conventional electrode structure, which consists of active materials, a current collector, a conducting agent, and a binder, actually showed a low loading of active material due to the other heavy components. In this study, we prepared a 3D flexible Si-composite electrode consisting of core (Si)-shell (Si<SUB>3</SUB>N<SUB>4</SUB>) NPs (Si@Si<SUB>3</SUB>N<SUB>4</SUB>) and carbon nanofibers (denoted as Si-composite/CNF). The Si-composite/CNF was directly utilized as an anode in the absence of the other components was electrochemically evaluated using a coin-type cell. The Si-composite/CNF showed a high capacity of 665mAhg<SUP>−1</SUP> at a fairly high current density of 10Ag<SUP>−1</SUP> and an extremely low capacity loss for 2000 cycles.</P> <P><B>Highlights</B></P> <P> <UL> <LI> We prepared Si-composite/CNF exhibits a 3D flexible Si-composite electrode. </LI> <LI> The electrode consists of core (Si)-shell (Si<SUB>3</SUB>N<SUB>4</SUB>) NPs (Si@Si<SUB>3</SUB>N<SUB>4</SUB>) and carbon nanofibers. </LI> <LI> The Si-composite/CNF was directly utilized as an anode. </LI> <LI> Si-composite /CNF exhibited high specific capacity and improved high rate cycling performance. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>

지능형 자동차 주변 감시 시스템 설계 방안

장시웅(Si-woong Jang),박영식(Young-sik Park),성현용(Hyun-yong Sung),곽길봉(Gil-bong Kwak),김선남(Seon-nam Kim),김경진(Kyeoung-jin Kim) 한국정보기술학회 2009 Proceedings of KIIT Conference Vol.2009 No.-

본 연구는 차량 주변을 지능적으로 감시하는 자동차 주변 감시시스템에 관한 것으로, 자동차의 주행 및 주차 시 속도의 변화나 운전자의 요청에 의해 자동차 주변 지역에 관한 시야를 상황에 따라 달리하여 모니터링 함으로써 운전자가 안전한 주행 및 주차를 수행할 수 있게 하기 위한 것이다. 그러한 목적을 달성하기 위하여 본 연구에서는 차량의 주변부를 감시하기 위하여 차량의 외곽에 설치된 카메라의 각도가 지면으로부터 차량의 상부를 향하는 방향으로 변경될 수 있도록 제어하는 제어부, 카메라의 영상을 입력받아 차량주변의 영상을 생성하는 영상처리모듈, 영상처리모듈에서 생성된 영상을 출력하는 디스플레이를 포함하는 것을 특징으로 하는 지능형 자동차 주변 감시시스템을 제안한다. This study is on a vehicle surroundings monitoring system, which enables a driver to travel and park safely by monitoring vehicle surroundings, depending on the speed of vehicle and driver's control when traveling and parking. To achieve the aforementioned purpose, we propose an intelligent vehicle surroundings monitoring system, which consists of a control part, an image processing module and display module. Hence, the control module controls angle of camera to turn upward from the bottom to monitor vehicle surroundings. The image processing module merges the received images from cameras with the original vehicle image to display the vehicle’s surroundings in real time as if looking down from the sky.

A Study on Improvement and Degradation of Si/SiO2 Interface Property for Gate Oxide with TiN Metal Gate

이병현,Yong-Il Kim,Bong-Soo Kim,Dong-Soo Woo,Yong-Jik Park,Dong-Gun Park,Si-Hyung Lee,Yonghan Rho 한국전기전자재료학회 2008 Transactions on Electrical and Electronic Material Vol.9 No.1

In this study, we investigated effects of hydrogen annealing (HA) and plasma nitridation (PN) applied in order to improve Si/SiO₂ interface characteristics of TiN metal gate. In result, HA and PN showed a positive effect decreasing number of interface state (Nit) respectively. After FN stress for verifying reliability, however, we identified rapid increase of Nit for TiN gate with HA, which is attributed to hydrogen related to a change of Si/SiO₂ interface characteristic. In contrast to HA, PN showed an improved Nit and gate oxide leakage characteristic due to several possible effects, such as blocking of Chlorine (Cl) diffusion and prevention of thermal reaction between TiN and SiO₂.

항정신병약물 사용 중인 정신분열병 환자에서 올란자판으로의 교체 방법에 관한 연구(II) : Comparison of Safety 안전성 비교

안용민,권용실,권준수,민성호,박두병,양문정,소형석,송종호,신윤식,우행원,유범희,이홍석,정한용,한창환,김용식 大韓神經精神醫學會 2002 신경정신의학 Vol.41 No.5

연구목적: 이 다기관 공동임상연구는 사용 중인 항정신병약물을 ’직접 교체 방법’또는 ’시작-감량 교체 방법’중 한 가지 방법으로 올란자핀으로 교체한 후, 안정성 측면에서 두 교체 방법 간의 비교와 교체후의 변화를 관찰하기 위한 것이다. 방법: 국내 13개 병원의 입원 및 외래에 내원한 환자들 중 ICD-10 지단기준으로 정신분열병에 해당되며, 임상적으로 항정신병약물 교체가 필요한 환자를 대상으로 하였다. 두 가지 교체 방법 중 한 가지를 무작위로 피험자에 적용하였으며, ’직접 교체 방법’에 배정된 경우에는 사용중인 항정신병약물을 일시에 중단하고 10㎎의 올란자핀을 바로 투여하였고, ’시작-감량 교체 방법’에 배정된 경우는 10㎎의 올란자핀 투여하고 2주에 걸쳐서 기존 약물을 감량하여 중단하였다. 올란자핀 사용기간은 총 6주이며, 용량은 5∼20㎎ 범위로 제한하였다. 한정성 평가를 위해서 체중, 생명징후, 자발적인 이상반응 복, 실험실 검사 그리고 Simpson-Angus Scale(SAS), Barnes akathisia rating scale(BARS), Abnormal involuntary movement scale(AIMS). Liverpool University neuroleptic side effect rating scale(LUNSERS)등을 이용하였다. 결과: 총 103명의 정신분열병 환자를 대상으로 하였다. 사용한 올란자핀의 용량, 벤조디아제핀의 병용률, 탈락률과 탈락 사유, 자발적인 이상반응 보고, 생명징후, 실험실 검사 그리고 대부분의 부작용 척도 상에서 임상적으로 의미 있는 차이를 두 교체 방법간에 발견하지 못하였다. 다만 AIMS의 감소는 ’직접 교체 방법’군에서 보다 적었고, 항콜린제의 병용률은 ’시작-감량 교체 방법’군에서 보다 많았다. 기저 상태에서 전체 피험자의 SAS와 BARS 점수는 각각 3.5점과 1.8점이었으며 70% 이상의 피험자가 고프로락틴 혈증을 보였다. 올란자핀으로 교체한 후, SAS, BARS, AIMS 점수의 유의한 감소가 있었으며 고프로락틴 혈증을 보인 피험자 분율도 약 30%이하로 감소하였다. 그러나 교체 방법과 상관없이 올란자핀 교체 후 유의한 체중 증가가 있었다. 결론: 이 연구를 통해 교체 방법에 관계없이 비교적 안전하고 용이하게 올란자핀으로 교체 할 수 있음을 알 수 있었다. 그리고 기존 항정신병약물을 올란자핀으로 교체함으로써 일부 부작용들을 줄일 수 있음을 간접적으로 관찰할 수 있었다. 하지만 이 연구는 여러 제한점과 문제점을 지니고 있기 때문에 보다 체계적인 연구를 통해 검정이 필요하리라 생각된다. Objectives: This multicenter clinical trial involving 13 hospital sites compared the safely of switching to olanzapine between ’direct switching method’ and ’start-tapering switching method’. Method: This study included both inpatients and outpatients who fulfilled the criteria for schizophrenia as defined in the ICD-10, and were in need to be appropriate for switching antipsychotics. Subjects were randomly assigned to one of the two switching methods. For ’direct switching method’group, previous antipsychotics were abruptly discontinued and 10㎎ of olanzapine was administered, and previous antipsychotics was gradually tapered for 2 weeks. Olanzapine was used for 6 weeks and the dose was adjusted within the range of 5-20㎎. The safety of switching to olanzapine was measured with vital sings including body weight, adverse events reported spontaneously, laboratory tests, and various scales such as Simpson-Angus Scale(SAS), Barnes Akathisia Rating Scale(BARS). Abnormal Involuntary Movement Scale(AIMS), and Liverpool University Neuroleptic Side Effect Rating Scale(LUNSERS). Results: 103 patients were switched to olanzapine in this study. The comparison between two switching methods did not show any significant difference in the dosage of olanzapine used, the concomitant use of benzodiazepine, the rate and reasons of drop-out, the adverse events, vital signs, laboratory tests, and most scales for measuring side-effects. However, the decrease in AIMS scores was significantly lower in ’direct switching method’ group, and the concomitant use of anticholinergics was comparatively greater in ’start-tapering switching method’ group. At baseline, SAS and BARS scores were 3.5 and 1.8 points respectively, and more than 70% of the subjects showed hyperprolactinemia. After switching to olanzapine, SAS, BARS, and AIMS scores were significantly decreased and the proportion of the patients with hyperprolactinemia was also decreased to less than 30%. However significant weight gain after the treatment of olanzapine was observed regardless of switching method. Conclusion: This study may suggest that switching to olanzapine can be done with relatively high safety regardless of switching methods and olanzapine can significantly decrease some side-effects induced by other antipsychotics.

Improved Adhesion of Metal Electrode Layer on Si₃N₄ Substrate through an All-Wet Process

Kim, Danbi,Eom, Nu Si A,Kim, Jiwon,Lee, Kyu Hyoung,Park, Sung Heum,Lee, Ju Ho,Chao, Yong-Ho,Lim, Jae-Hong Electrochemical Society 2019 ECS journal of solid state science and technology Vol.8 No.2

<P>Electroless deposition requires preliminary surface treatment to effectively adsorb a metal electrode layer onto a ceramic substrate. Herein, a simple surface treatment using an all-wet process was performed to achieve adhesion stability between a Si<SUB>3</SUB>N<SUB>4</SUB> substrate and Ni film. The method involved deposition of an interfacial Pd-TiO<SUB>2</SUB> buffer between the two layers. Surface pretreatment via silanization was initially performed to improve surface wettability, thereby enhancing uniform deposition of Pd-TiO<SUB>2</SUB>. Subsequently, a thin Ni layer was directly deposited onto the Pd-TiO<SUB>2</SUB> layer without necessitating sensitization or activation. The synthesized Ni/Pd-TiO<SUB>2</SUB>/Si<SUB>3</SUB>N<SUB>4</SUB> heat sink exhibited excellent adhesion property in the cross-hatch, scratch, and thermal shock tests. The mechanism of adhesion enhancement involved chemical bonding of Pd-TiO<SUB>2</SUB> with the self-assembled monolayer on the substrate and reduced internal stress due to removal of residual hydrogen between the layers of the heat sink. Thus, the fabricated heat sink has a promising application in electronic devices operated at high temperatures.</P>

A Study on Improvement and Degradation of Si/SiO₂ Interface Property for Gate Oxide with TiN Metal Gate

Lee, Byung-Hyun,Kim, Yong-Il,Kim, Bong-Soo,Woo, Dong-Soo,Park, Yong-Jik,Park, Dong-Gun,Lee, Si-Hyung,Rho, Yong-Han The Korean Institute of Electrical and Electronic 2008 Transactions on Electrical and Electronic Material Vol.9 No.1

In this study, we investigated effects of hydrogen annealing (HA) and plasma nitridation (PN) applied in order to improve $Si/SiO_2$ interface characteristics of TiN metal gate. In result, HA and PN showed a positive effect decreasing number of interface state $(N_{it})$ respectively. After FN stress for verifying reliability, however, we identified rapid increase of $N_{it}$ for TiN gate with HA, which is attributed to hydrogen related to a change of $Si/SiO_2$ interface characteristic. In contrast to HA, PN showed an improved Nit and gate oxide leakage characteristic due to several possible effects, such as blocking of Chlorine (Cl) diffusion and prevention of thermal reaction between TiN and $SiO_2$.

재발성 다발성 연골염

박용범,이시훈,정상윤,이수곤,홍순원,김정민,이창률 대한내과학회 2001 대한내과학회지 Vol.61 No.3

人蔘의 配合에 따른 數種 韓藥材의 抗酸化作用에 關한 硏究 (Ⅱ)

朴時興,康秉秀,朴涌基 대한본초학회 1999 大韓本草學會誌 Vol.14 No.2

This study was carried out in order to investigate the anti-oxidant effect of main tonic medicine, Ginseng Radix with combination of other well-known herb medicines such as Rehmammiae Radix Preparat, Astragali, Poria, Aconiti lateralis Preparata Radix, Gecko and Bupleuri Radix. These herbs were mixed with Ginseng Radix to measure inhibitory activity lipid peroxidation of linoleic acid mixture and rat liver and hydrogen-giving-temper effect by DPPH. The study showed the following valuable results. 1. In inhibitory activity of water extract against lipid peroxidation of linoleic acid mixture, Ginseng Radix-Gecko compound herbal medicine showed the highest anti-oxidant activity. Ginseng Radix -Rehmammiae Radix Preparat compound herbal medicine showed the lowest anti-oxidant activity when compared with the examined samples. 2. In inhibitory activity of water extract against lipid peroxidation of rat liver, Ginseng Radix-Gecko showed the highest anti-oxidant activity. Ginseng Radix-Rehmammiae Radix Preparat showed the lowest anti-oxidant activity. 3. In hydrogen-giving-temper effect of water extract by DPPH, Ginseng Radix-Gecko compound herbal medicine showed the highest anti-oxidant activity. 4. In the linoleic acid mixture, Ginseng Radix-Gecko compound herbal medicine showed the highest anti-oxidant activity in Butanol fraction. 5. In the lipid peroxidation of rat liver, Ginseng Radix-Gecko compound herbal medicine showed the highest anti-oxidant activity in Butanol fraction. 6. In hydrogen-giving-temper effect of water extract by DPPH, Ginseng Radix-Gecko compound herbal medicine showed the highest anti-oxidant activity in Butanol fraction. From the above results, it was concluded as follows. All the six compound herbal medicine including Ginseng Radix showed the anti-oxidant activity. Especially, Ginseng Radix-Gecko compound herbal medicine showed the highest anti-oxidant activity among them.

Mitomycin-C 적용시간에 따른 누낭비강연결술의 수술결과

박근성,임진호,민병무,최시환,김창식,김용백 충남대학교 의학연구소 2001 충남의대잡지 Vol.28 No.2

To determine the usefulness of application of Mitomycin-C (MMC) and effectiveness of different concentration of MMC in external DCR. A total of 100 eyes of 87 patients diagnosed with primary acquired nasolacrimal duct obstruction were assigned randomly to either a MMC group or control group. The surgical procedures in both groups were same. In MMC group, a piece of neurosurgical cottonoid soaked with 0.4 mg/ml MMC was applied to the osteotomy site and then was removed after 5 and 10 minutes differently. Nasoendoscopic examination was performed at 1 month, 3 months, and 6 months after surgery for all patients. The causes of epiphora as trauma (20 cases), failed DCR (1 case), sinus surgery (2 cases), unknown (77 cases). The overall anatomical success rate of the procedure was 88% and functional success rate was 79%. Obstruction site was related to anatomical surgical results. Anatomical surgical outcome at lower lacrimal sac level group of patients showed a statistically significant success rate, but functional surgical outcome showed no significant difference between the two groups. The anatomical success rate was 87.7% and the functional success rate was 84.2% in MMC group. The anatomical success rate was 88.3% and the functional success rate was 74.4% in control group. Application of MMC and it's application time were not related to surgical results.

PP/MMT 나노복합재료의 열안정성 및 기계적 계면 특성에 관한 연구

박수진,전병렬,송시용,이종문 한국공업화학회 2004 공업화학 Vol.15 No.1

본 연구에서는 몬모릴로나이트(Na^(-)-montmorillonite, MMT)를 dodecylammonium chloide로 유기적 개질하여 폴리프로필렌(PP) 나노복합재료의 열안정성과 기계적 계면 물성에 미치는 영향을 조사하였다. 나노복합재료의 구조 및 표면 특성은 각각 XRD와 FT-IR을 통해 알아보았고, 열안정성은 TGA를 통해 알아보았으며, 주조된 시편의 기계적 계면 물성은 K_(IC)와 G_(IC)를 통해 알아보았다. 실험 결과, dodecylammonium chloide을 이용한 MMT의 유기적 개질(DA-MMT)은 약 7.3 Å의 실리케이트 층간을 증가시켰고, DA-MMT 내의 CH_(2) 기에 의해 2800~2900 ㎝^(-1)에서 새로운 피크가 나타났다. PP/DA-MMT 나노복합재료의 열안정성은 순수한 PP 수지에 비해 향상되었는데, 이는 DA-MMT 입자와 PP 사이의 분자간 상호작용에 의한 것으로 판단된다. 또한, PP/DA-MMT 나노복합재료가 높은 기계적 계면 물성을 나타냈는데, 이러한 결과는 층간이 증가된 실리케이트에 PP가 쉽게 삽입되기 때문으로 판단된다. In this work. the effect of organic modification of Na-montmorillonite (MMT) with dodecylammonium chloride on thermal stabilities and mechanical interfacial properties of PP nanocomposites was investigated. The structure and surface properties of the nanocomposites were determined by XRD and FT-IR, respectively. The thermal stabilities of the nanocomposites were studied using a TGA analysis. Also, the mechanical interfacial properties were confirmed by KIC and GIC of casting specimens. As a result, the organic modification of MMT by dodecylammonium chloride(DA-MMT) led to the increase of the silicate layers to about 7.3 A, and the new peaks at 2800∼2900 cm^(-1) hand were shown in the presence of the CH groups on the DA-MMT. The thermal stahilities of PP/DA-MMT nanocomposites were higher than that of pure PP resin, which can be attributed to the increase of intermolecular interaction between DA-MMT particles and PP matrix. Also, the PP/DA-MMT nanocomposites had higher mechanical interfacial properties than those of pristime nanocomposites. These results explained that the pp was easily inserted in the spacing of the silcate interlayers of which were increased.