최근 국내외에서 육성된 무궁화 127 품종 중 조경적 활용가치가 높은 유망품종 선발

김광호 ( Kim Kwang-ho ),이춘석 ( Lee Chun-suk ),강호철 ( Kang Ho-chul ) 한국전통조경학회(구 한국정원학회) 2016 한국전통조경학회지 Vol.34 No.3

본 연구는 조경수용 무궁화 우수품종 보급을 위한 유전자원 수집과 특성을 평가하기 위해 최근 국내외에서 육성된 127품종의 1년생 접목묘를 이용하여 2014년부터 2015년까지 2년 동안 생육 및 형태적 특성조사를 실시하였다. 수집된 품종 중 화색 및 꽃이특이한 품종을 조사하여 무궁화를 조경수로 활용도를 높이는데 기여하고자 하였으며 얻어진 결과는 다음과 같다. 최근 국내외에서 육성된 품종들의 화색별 분류로는 크게 분홍색 단심(pink color with red eye spot), 흰색 단심(white color withred eye spot), 붉은 자주색 단심(purplish red color with red eye spot), 분홍보라색 단심(violet pink color with red eye spot), 심홍색단심(crimson color with red eye spot), 흰색 바탕에 붉은색 무늬의 이중색(asadal), 흰색(white color), 푸른색(blue color) 등 총 8종류로 분류되었다. 화색이 붉은 자주색으로서 적색이 강한 꽃으로 국내에서 육성된 품종으로 ‘광명’, ‘난파’, ‘노스페이스’, ‘불새’, ‘비단’,‘송암’, ‘영창’, ‘적퍼소’, ‘키호’, ‘탐라’, ‘화수레드’, ‘환희’ 등이 있었으며, 국외에서 육성되어 국내에 도입된 품종으로는 ‘Aphrodite’,‘Dr. Uemoto’, ‘Freedom’, ‘Pink Cup’, ‘PS 80-1’, ‘Purpureus Variegatus’, ‘Red Giant’, ‘Woodbridge’ 등이 있었다. 화색이 분홍보라색으로서 특이한 품종으로는 ‘꼬마’, ‘도투락’, ‘명미’, ‘병화’, ‘산처녀’, ‘태화’, ‘Hikari-hanagasa’, ‘Little Kim Violet’ 등이 있었다. 화색이 심홍색으로 기존의 꽃에서는 볼 수 없는 특이한 품종으로 ‘종무’와 ‘Ruffled Satin’ 등이 있었다. 최근 국내외에서 육성된 품종중 조경수용 소재로 보급할 수 있는 품종중 기존 품종에 비해 꽃의 크기가 큰 품종으로 무궁화 종간교잡종인 Hibiscus hybrid ‘Daewangchun’, ‘Daeil’,‘Jina’ 등이 있었다. 반면 꽃이 작고 조경적 가치가 높은 품종으로 ‘꼬마’, ‘미백’, ‘안동’, ‘릴킴’, ‘은하수’ 등이 있었다. 백단심계 무궁화‘꼬마’ 품종은 수고가 작은 왜성형으로 꽃의 크기가 5.2cm로 작은 소형화 품종으로 나타났다. 기존 품종에 비해 단심의 길이가 긴품종으로 ‘훈장’과 ‘하이리레드’가 있었다. 홍단심계 무궁화 ‘훈장’은 꽃의 크기는 12.0cm로 중간크기이나 단심길이는 4.8cm로 지금까지육성된 품종중 가장 긴 품종이었다. 또한 홍단심계 무궁화 ‘하이리레드’의 단심길이 역시 4.2cm로 꽃잎 길이에 비해 단심의 길이가 길어 조경적 가치가 높은 것으로 판단되었다. This study was carried out to characterize 127 recently developed cultivars of Rose of Sharon (Hibiscus spp.) in Korea and foreign Countries for landscape uses. The examined factors were growth characteristics such as tree height of a 1-year grafted plant(cm), plant type, growth habit, leaf characteristics such as shape and size, flower characteristics such as color, shape, size, and red eye during 2014 and 2015 for landscape uses. The results are obtained as follows; In the results of flower color of the 127 recently developed cultivars, pink color with red eye spot, white color with red eye spot, purplish red color with red eye spot, violet purple color with red eye spot, crimson color with red eye spot, asadal, blue color with red eye spot, and white color were distributed. In the flower characteristics, Hibiscus hybrid ‘Daewangchun’ had the largest flower size of 16.0cm out of the 127 cultivars. H. syriacus ‘Antong’, ‘Lil Kim’, and ‘Ggoma’ were cultivars with smaller flowers than other cultivars. H. syriacus ‘Hunjang’ had largest red eye, of 5.2cm of length compared to the other cultivars. The cultivars with unique flower color for landscape uses are H. syriacus ‘Kwangmyung’, ‘Nanpa’, ‘North face’, ‘Bulsae’, ‘Bidan’, ‘Songam’, ‘Youngchang’, ‘Jukpeoso’, ‘Kiho’, ‘Tamla’, ‘Hwasoored’ and ‘Hwanhee’. These flowers had a purplish red color and were developed in Korea. H. syriacus ‘Aphrodite’, ‘Dr. Uemoto’, ‘Freedom’, ‘Pink Cup’, ‘PS 80-1’, ‘Purpureus Variegatus’, ‘Red Giant’, ‘Woodbridge’ also had unique flowers with a purplish red color and were introduced from foreign countries. In addition, cultivars with violet pink flowers were H. syriacus ‘Ggoma’, ‘Doturak’, ‘Myungmi’, ‘Byunghwa’, ‘Sancheonyu’, ‘Taehwa’, ‘Hikari-hanagasa’, and ‘Little Kim Violet’. ‘Jongmoo’ and ‘Ruffled Satin’ had flowers with crimson color. Therefore, the new cultivars with unique flower colors were a promising cultivars to a woody landscape plant. Cultivars with large flower sizes were Hibiscus hybrid ‘Daewangchun’, Hibiscus hybrid ‘Daemang’, and Hibiscus hybrid ‘Jina’. H. syriacus ‘Ggoma’, ‘Mibeak’, ‘Antong’, ‘Lil Kim’, and ‘Eunhasu’ had small flower sizes. Cultivars with long red eye were H. syriacus ‘Hunjang’ and H. syriacus ‘Hi Lea Red’. Therefore, the new cultivars, Hibiscus hybrid ‘Daewangchun’, Hibiscus hybrid ‘Daemang’, Hibiscus hybrid ‘Jina’ with large flower sizes, H. syriacus ‘Ggoma’, ‘Mibeak’, ‘Antong’, ‘Lil Kim’, and ‘Eunhasu’ with small flower sizes, H. syriacus ‘Hunjang’ and H. syriacus ‘Hi Lea Red’ with long red eye, were promising cultivars to a woody landscape plant.

경사증착법을 이용한 PM-OLED용 무기박막형 보호층 연구

김광호,김훈,김재경,도이미,한정인,주병권,Kim, Kwang-Ho,Kim, Hoon,Kim, Jae-Kyung,Do, Lee-Mi,Han, Jeong-In,Ju, Byeong-Kwon 한국전기전자재료학회 2003 전기전자재료학회논문지 Vol.16 No.9

In this study, the MgO thin-film passivation layer was adopted to protect passive matrix organic light emitting diode(PMOLED) with the cathode separator from moisture and oxygen. Using the substrate rotate and tilt technique during the deposition, the organic and cathode layers were perfectly covered with MgO. And then, we analyzed the difference of the current-voltage and luminescence characteristics between passivated OLED of the MgO and non-passivated OLED. It was found that the number of dark spot generated from the degradated pixel was decreased owing to the Mgo thin-film passivation layer using the tilt & rotate technique. And the half-life time passivated OLED was improved two times more. Thus, the MgO could be vaccum-deposited under the low temperature and had a merit that the organic layer was not much affected. We can consider that MgO thin film passivation method can be adopted to protect the OLED from moisture and oxygen and can offer the enhancement of lifetime.

후측개흉술과 근육보존수직개흉술의 임상고찰

김광호,김현태,김정택,선경,Kim, Kwang-Ho,Kim, Hyun-Tae,Kim, Jung-Taek,Sun, Kyung 대한흉부심장혈관외과학회 1998 Journal of Chest Surgery (J Chest Surg) Vol.31 No.5

후측개흉술은 흉근을 절단하는 단점은 있으나 훌륭한 수술시야를 제공하므로 표준개흉술로 이용되고 있다. 이에 반하여 근육보존수직개흉술은 흉근이 보존되며 팔을 내리면 액와부 수술 상흔이 감추어지는 미용상의 장점이 있다. 그러나 수직개흉술은 흉부의 정측면에 절개선이 이루어지므로 측와위에서 수직으로 수술시야를 내려다보게 되어 흉강내의 구조물, 특히 폐문부나 첨부 및 하부의 길이가 멀어져 수술조작이 불편하다. 본 인하대병원 흉부외과에서는 수술조작에 관련된 차이를 알아보고자 후측개흉술(15례)과 수직개흉술(14례)을 이용해 폐쐐기절제술 이상의 수술을 실시한 29례에서 수술과 관련된 임상지표들을 비교관찰한 결과, 수술시간, 수술 1일과 2일의 흉관 배액량, 흉관 거치기간, 수혈 수와 수혈량, 수술 중 실혈량, 수술 후 합병증 등에서 양군간에 차이가 없었다. 이상의 결과를 볼 때 근육보존수직개흉술도 후측개흉술과 마찬가지로 폐절제술시 안전하게 사용될 수 있다고 본다. Although posterolateral thoracotomy(PLT) has been a standard thoracic incision in resection surgery of the lung for surgeons to achieve a good surgical field, there remains concern about severing a group of thoracic muscles remains. Muscle-sparing vertical thoracotomy (MVT) is an alternative to PLT, which gives cosmetic result and may preserve motion of the shoulder girdle as well as respiratory function of the patient in the early postoperative period. However, surgeons tend not to perfer it because of limited surgical field from the vertical wound made on the lateral thoracic wall. The purpose of this study is to compare the surgical outcomes of PLT versus MVT. We retrospectively reviewed 29 patients(15 who had PLT and 14 who had MVT, organized into those two groups) who had undergone lung resection surgery in our institute. There were no clinical differences between the two groups in terms of operation time, estimated amount of blood loss during the operation, amount of chest drainage on the first and the second postoperative day, duration of chest tube placement, incidence and amount of transfusion, and postoperative complications. We conclude that, from our limited experience, MVT can be applied to lung resection surgery as safely as PLT and that it may have a beneficial role for the patient with compromised lung function in addition to cosmetic effect.

소절개선을 이용한 심장수술의 임상고찰

김광호,김정택,이서원,김혜숙,임현경,이춘수,선경,Kim, Kwang-Ho,Kim, Joung-Taek,Lee, Seo-Won,Kim, Hae-Sook,Lim, Hyun-Kung,Lee, Choon-Soo,Sun, Kyung 대한흉부심장혈관외과학회 1999 Journal of Chest Surgery (J Chest Surg) Vol.32 No.4

배경: 최근에 시작된 소절개선을 이용한 심장수은술 환자에게 미용상 효과가 좋으며, 통증이 적으며 빠른 회복을 가져온다. 본 교실에서는 그간 실시한 소절개심장수술의 현황을 임상고찰하였다. 대상 및 방법: 1997년 2월 흉골좌연종절개선으로 관상동맥우회술을 실시한 이후 1998년 11월까지 총 31례의 소절개술을 이용한 심장수술을 실시하였다. 남녀 비는 17:14였으며, 1세에서 75세까지의 연령분포를 보였다. 흉골좌연종절개술을 실시한 예는 9례로 관상동맥 질환으로 인공심폐기의 사용없이 박동상태에서 내유동맥으로 좌전행지관상동맥에 우회술을 실시하였는데, 그 중 1례는 내유동맥의 비꼬임으로 술 후 1주일 째 재수술한 경우였다. 흉골우연종절개는 1례로 승모판교련절개술 후 재발된 협착증에 대해 승모판치환술을 실시한 경우였다. 소흉골절개선으로 수술한 예는 21례로, 승모판치환 및 삼첨판성형술이 6례, 승모판치환술 5례, 중복판치환술 2례, 대동맥판치환술 1례, 좌심방점액종 1례, 심방중격결손증 2례, 심실중격결손증 2례, 우심실 자창 1례였다. 처음 5례는 T형의 흉골소절개를 실시하였으나 경험이 쌓이면서 대동맥기저부의 노출이 좋고 흉골 봉합시 안정감이 높은 화살모양의 흉골소절개를 실시하였다. 결과: 수술시간, 인공심폐 구동시간, 대동맥차단시간, 인공호흡기 사용기간, 수술 1일까지의 흉관배액양, 흉관 거치기간, 집중치료실 입원기간 등은 기존의 정중흉골절개선 예들에 비하여 큰 차이가 없었다. 수술 후 사망 예는 2례였으며 1례는 흉골소절개선으로 승모판치환 수술 1일에 대동맥 삽관부위의 파열로 출혈 사망하였고, 다른 1례는 흉골좌연종절개선으로 관상동맥우회술 후 2일에 부정맥으로 사망하였다. 사망의 원인과 수술절개선의 선택과는 직접적인 관련이 없었다. 합병증은 뇌색전증 1례, 창상의 혈종 1 례가 있었다. 결론: 소절개선으로도 정중흉골절개선과 마찬가지로 심장 수술을 효과적으로 실시할 수 있을 것으로 생각된다. Background: Minimally invasive technique for various cardiac surgeries has become widely accepted since it has been proven to have distinct advantages for the patients. We describe here the results of our experiences of minimal incision in cardiac surgery. Material and Method: From February 1997 to November 1998, we successfully performed 31 cases of minimally invasive cardiac surgery. Male and female ratio was 17:14, and the patients age ranged from 1 to 75 years. A left parasternal incision was used in 9 patients with single vessel coronary heart disease. A direct coronary bypass grafting was done under the condition of the beating heart without cardiopulmonary bypass support(MIDCAB). Among these, one was a case of a reoperation 1 week after the first operation due to a kinked mammary artery graft. A right parasternal incision was used in one case of a redo mitral valve replacement. Mini-sternotomy was used in the remaining 21 patients. The procedures were mitral valve replacement and tricuspid annuloplasty in 6 patients, mitral valve replacement 5, double valve replacement 2, aortic valve replacement 1, removal of left atrial myxoma 1, closure of atrial septal defect 2, repair of ventricular septal defect 2, and primary closure of r ght ventricular stab wound 1. The initial 5 cases underwent a T-shaped mini-sternotomy, however, we adopted an arrow-shaped ministernotomy in the remaining cases because it provided better exposure of the aortic root and stability of the sternum after a sternal wiring. Result: The operation time, the cardiopulmonary bypass time, the aorta cross-clamping time, the mechanical ventilation time, the amount of chest tube drainage until POD#1, the chest tube indwelling time, and the duration of intensive care unit staying were in an acceptable range. There were two surgical mortalities. One was due to a rupture of the aorta cannulation site after double valve replacement on POD#1 in the mini-sternotomy case, and the other was due to a sudden ventricular arrhythmia after MIDCAB on POD#2 in the parasternal incision case. Postoperative complications were observed in 2 cases in which a cerebral embolism developed on POD#2 after a mini-sternotomy in mitral valve replacement and wound hematoma developed after a right parasternal incision in a single coronary bypass grafting. Neither mortality nor complication was directly related to the incision technique itself. Conclusion: Minimally invasive surgery using parasternal or mini-sternotomy incision can be used in cardiac surgeries since it is as safe as the standard full sternotomy incisions.

경락(經絡)과 정신양생(精神養生)의 관계 설정(設定)에 대(對)한 고찰(考察)

백진웅,김광호,Baek Jin-Woong,Kim Kwang-Ho 대한예방한의학회 2001 대한예방한의학회지 Vol.5 No.2

It is thought that Kim Hong-kyeong followed the existing theory of Meridian(經絡) and supplemented his unique perspectives in interpreting it. And he tried to relate Meridian with hygiene of mind. I took up with the research on the assumption that the review of Kim's method can present new perspectives to the study of relationship between Meridian and hygiene of mind. The results of my study are as follows: 1. Kim followed common theory of Meridian and then added his unique perspectives to it. His method of interpretation has one characteristic. By introducing Idealism(唯心論), he understood 'Meridian' as the path of the mind and the emotion. Especially I think his hypothesis that acupuncture can be widely used in mental diseases as well as body related diseases and its applications to treatment are very valuable. 2. Meridian and hygiene of mind are close together. I think Kim's unique trial is something new in studying relationship between Meridian and hygiene of mind but requires more research on it.

초박막 폴리머 강유전체 박막의 특성

김광호,Kim, Kwang-Ho 한국반도체디스플레이기술학회 2020 반도체디스플레이기술학회지 Vol.19 No.4

The properties of ultra-thin two-dimensional (2D) organic ferroelectric Langmuir-Blodgett (LB) films of the poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] were investigated to find possible applicability in flexible and wearable electronics applications. In the C-V characteristics of the MFM capacitor of 2-monolayer of 5 nm films, a butterfly hysteresis curve due to the ferroelectricity of P(VDF-TrFE) was confirmed. Typical residual polarization value was measured at 2μC/㎠. When the MFM capacitor with ultra-thin ferroelectric film was measured by applying a 10 Hz bipolar pulse, it was shown that 65% of the initial polarization value in 105 cycles deteriorated the polarization. The leakage current density of the 2-monolayer film was maintained at about 5 × 10-8 A/㎠ for the case at a 5MV/cm electric field. The resistivity of the 2-monolayer film in the case at an electric field at 5 MV/cm was more than 2.35 × 1013 Ω·cm.

인천항의 선박오염원에서 배출된 대기오염물질의 확산

김광호,권병혁,김민성,이돈출,Kim, Kwang-Ho,Kwon, Byung Hyuk,Kim, Min-Seong,Lee, Don-Chool 해양환경안전학회 2017 해양환경안전학회지 Vol.23 No.5

선박의 오염물질 배출에 대한 규제는 최근 IMO/MEPC(국제해사기구/해양환경보호위원회)를 통해서 진행 중이다. 선박오염원에서 배출된 오염물질은 국지적인 요인에 의해서 연안지역을 비롯하여 육지로 확산될 수 있다. 인천과 같이 선박 배출 오염물질에 노출되어 있는 항구 도시에서 선박오염원 조절은 연안지역의 대기질 관리정책을 효율적으로 고안하기 위해서 반드시 필요하다. 연안지역의 대기오염물질 중 선박에 의한 NOx와 SOx의 농도는 전체 NOx와 SOx 농도의 각각 14 %와 10 %를 차지한다(NIER, 2008). 연안도시지역의 대기질은 국지적인 순환에 의존하는 오염물질의 확산 경향과 선박의 수에 영향을 받는다. 선박오염원으로부터 배출된 오염물질의 확산을 WRF(Weather Research and Forecasting model)의 기상장을 기초로 CALPUFF(California Puff model)를 사용하여 분석하였다. 그리고 연안도시지역의 대기확산모델은 정박한 선박과 입 출항하는 선박으로 나누어 각각 점오염원과 선오염원으로 구분하여 모의하였다. 선박척수 82~84척을 기준으로 NOx의 총 평균 배출량은 입 출항시 각각 6.2 g/s, 6.8 g/s이었고, SOx의 총 평균 배출량은 입 출항시 각각 3.6 g/s, 5.1 g/s 이었다. 정박 중인 선박의 NOx와 SOx에 대한 총 평균 배출량은 각각 0.77 g/s, 1.93 g/s이었다. 육풍의 영향으로 인하여 인천항으로부터 내륙으로 진행되는 오염물질의 수송이 억제되었고, 내륙의 SOx와 NOx 농도가 일시적으로 감소하는 원인이 되었다. 해풍에 의해 NOx와 SOx가 내륙으로 확산되었고, 내륙의 NOx와 SOx의 농도가 점차 증가하였다. 인천항과 인접한 지역의 오염물질의 농도는 해륙풍의 영향보다 인천항에 정박 중인 선박오염원에 의한 영향이 더욱 크게 반영되었다. 본 연구는 연안도시지역의 대기질 정책고안과 배출기준을 정하는 것에 유용할 것으로 기대된다. Emissions of pollutants from ship-based sources are controlled by the International Maritime Organization (IMO). Since pollutants emitted from ship may be dispersed to the land, controlling emissions from ships is necessary for efficient air quality management in Incheon, where exposure to ship-based pollution is frequent. It has been noted that the ratios of air pollutant emissions from coastal areas to inland areas are about 14% for NOx and 10% for SOx. The air quality of coastal urban areas is influenced by the number of ships present and the dispersion pattern of the pollutants released depending on the local circulation system. In this study, the dispersion of pollutants from ship-based sources was analyzed using the numerical California Puff Model (CALPUFF) based on a meteorological field established using the Weather Research and Forecasting Model (WRF). Air pollutant dispersion modeling around coastal urban regions such as Incheon should consider point and line sources emitted from both anchored and running ships, respectively. The total average NOx emissions from 82-84 ships were 6.2 g/s and 6.8 g/s, entering and leaving, respectively. The total average SOx emissions from 82-84 ships, entering and leaving, were 3.6 g/s and 5.1 g/s, respectively. The total average emissions for NOx and SOx from anchored ships were 0.77 g/s and 1.93 g/s, respectively. Due to the influence of breezes from over land, the transport of pollutants from Incheon Port to inland areas was suppressed, and the concentration of NOx and SOx inland were temporarily reduced. NOx and SOx were diffused inland by the sea breeze, and the concentration of NOx and SOx gradually increased inland. The concentration of pollutants in the area adjacent to Incheon Port was more influenced by anchored ship in the port than sea breezes. We expect this study to be useful for setting emission standards and devising air quality policies in coastal urban regions.

수도 품종의 잎집무늬마름병 저항성연구 I. 잎집무늬마름병 저항성검정을 위한 균주선발

김광호,양계진,Kwang-Ho Kim 한국작물학회 1987 한국작물학회지 Vol.32 No.1

Fifty eight isolates of R. solani collected from rice plants infected to sheath blight disease at seven different locations through the country were evaluated for their cultural characteristics on media. Degree of resistance of nine rice varieties were tested by the seven isolates representing each culture type from the grouped pathogene-city. Great variation of cultural characterisics on PSA media was observed among isolates, and 58 isolates tested were grouped into 7 culture types. Locational distribution of isolates belong to each culture type was different between types, and only isolate type 'Ia' was distributed in all locations collected. The degree of pathogene-city of each isolate to rice adult plant was different between 7 culture types grouped, and no isolates infected severely on all tester rice varieties. The degree of resistance to the disease showed great variation among 9 tester varieties, and varietal reaction to the disease was varied along with isolates inoculated. An isolate, la, shown strong pathogenecity and distributed through 7 locations was selected for the screening of varietal resistance to rice sheath blight disease. 벼 품종의 잎집무늬마름병 저항성검정에 사용할 R. solani 균주를 선발할 목적으로 전국 7개지역에서 수집한 58개균주의 배양특성을 조사하여 균주의 배양형을 나누고 각 배양형에서 대표되는 균주를 선정, 9개 벼 품종에 접종시켜 균주의 병원성과 품종저항성을 조사한 결과를 요약하면 다음과 같다. 1. 벼 잎집무늬 마름병균의 균주를 PSA 배지상에서 기르면서 조사한 5종류의 배양특성은 균주간에 뚜렷한 차이가 있었으며 균주별 배양특성에 근거하여 공시한 58개 균주를 7종의 배양형으로 나눌 수 있었다. 2. 각 배양형에 속하는 잎집무늬마름병균 균주의 지역적인 분포는 차이가 있어서 균주분포의 지역특이성이 인정되었으며 Ia 배양형에 속하는 균주만이 7개 지역 모두에 분포되어 있었다. 3. 각 배양형을 대표하는 7개 균주의 병원성은 서로 달랐으며 균주별 병원성은 검정품종에 따라서 그 정도가 다르게 나타났다. 4. 균주의 병원성검정에 사용되었던 9개 벼 품종의 저항성정도도 품종간 차이가 켰으며 품종의 저항성 반응도 접종한 균주에 따라서 달리 나타나는 경우가 있었다. 5. 공시한 균주의 병원성정도와 지역적인 분포범위를 고려하여 벼 잎집무늬마름병 저항성검정에 사용할 균주를 선발할 수 있었다.

1,3-디메톡시-티아캘릭스[4]크라운-5-에테르의 이형체들의 상대적인 안정성과 구조들에 대한 mPW1PW91 계산 연구

김광호,최종인,Kim, Kwang-ho,Choe, Jong-In 대한화학회 2009 대한화학회지 Vol.53 No.5

1,3-디메톡시-티아캘릭스[4]크라운-5-에테르 (3)의 다양한 이형체들(cone_oo, cone_oi, pc_oo, pc_io, pc_oi, pc_ii, 13a_oo, 13a_io)에 대한 구조들이 DFT B3LYP/6 - 31 + G(d,p)와 mPW1PW91/6 - 31 + G (d,p) (hybrid HF-DF) 계산 방법들에 의하여 최적화 되었다. 13a_oo (1,3-alternate 이형체에서 두 개의 메 톡시기가 모두 밖으로 향해 있는 구조)가 가장 안정하였으며, 기존에 보고된 실험 결과와 잘 일치하였다. mPW1PW91/6 - 31 + G(d,p) 계산에 의한 상대적인 안정성은 다음과 같았다: 13a_oo (가장 안정) > 13a_io$\sim$ pc_io$\sim$cone_oo > cone_oi$\sim$pc_oo$\sim$pc_oi > pc_ii. Molecular structures of the various conformers for the 1,3-dimethoxy-p-tert-butylthiacalix[4] crown-5-ether (3) were optimized by using DFT B3LYP/6 - 31 + G(d,p) and mPW1PW91/6 - 31 + G(d,p) (hybrid HF-DF) calculation methods. We have analyzed the energy differences and structures of eight in/out orientations (cone_oo, cone_oi, pc_oo, pc_io, pc_oi, pc_ii, 13a_oo, 13a_io) of two methoxy groups in three major conformations (cone, partial-cone and 1,3-alternate). The 13a_oo (out-out orientation of the 1,3-alternate conformer) is calculated to be the most stable among eight different conformations of 3, and in accord with the experimental result. The ordering of relative stability resulted from the mPW1PW91/6 - 31 + G(d,p) calculation method is following: 13a_oo > 13a_io$\sim$pc_io$\sim$cone_oo > cone_oi$\sim$pc_oo$\sim$pc_oi > pc_ii.

사적(史蹟)68호(號) 고려청자도요지(高麗靑瓷陶窯址)의 고고지자기(考古地磁氣)

김광호,배영부,Kim, Kwang Ho,Bea, Young Boo 대한자원환경지질학회 1983 자원환경지질 Vol.16 No.4

Recently, excavation of ancient pottery kiln of Koryo celadon of the Koryo dynasty have been continued since 1979 in Hang-dong, Daegu-myun, Gangjin-gun, Jeonnam Province, south-western part of Korea. The authers carried out an archeomagnetic study using the baked earth of the floors of the kiln, togimi and fabrics of rocks which were placed firmly on the floors of the kiln. These specimens were measured using the astatic magnetometer. The results of measurements are: declination, $0.3^{\circ}W$; inclination, $52.9^{\circ}C$. Referring to the secular change curves drawn from the studies of the south-western Japan, the last period when the pottery kiln was fired finally is estimated to be around A.D. 1170. Many potsherds of Koryo celadon were excavated around the kiln. According to the shape of these potsherds, the age of the pottery kiln is estimated to be 10-12 C, which is consisted with this study.