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CO2 에 의한 Char 의 가스화반응시 세공구조 변화
김광호,이선희,조병린,장윤호 한국화학공학회 1987 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.25 No.6
CO₂ 가스화반응에 의해 얻은 호도각 char의 겉보기밀도, 세공반경분포, 세공용적 및 비표면적 등을 추정하여, 가스화방응시 반응온도와 전환율에 따른 char의 세공구조 변화를 조사하였으며, 이론모델(pore volume model, random pore model)과 비교하였다. CO₂ 가스화반응에 의해 형성된 호도각 char는 10Å(micro pore)과 10⁴Å(macro pore) 부근의 세공이 잘 발달된 이원적 구조를 가지고 있었다. 반응 온도가 낮을수록 char의 비표면적과 micro pore 용적은 증가하였으나 macro pore 용적은 변하지 않았으며, random pore model이 가스화반응에 의해 얻은 char의 세공구조값과 비교적 잘 일치하는 것을 알 수 있었다. A char was made from walnut shell which was gasified in CO₂ 7atmosphere and its physical properties such as pore size distribution, density, pore volume and surface area were measured. The effects of reaction temperature and conversion(X_c) on the pore structure change of char were examined and compared with the theoretical values from ihe mathematical modets (pore volume model and random pore model). The char which has bimodal pore distribution near by 10Å (micro pore) and 10⁴Å (macro pore) was obtained by CO₂ gasification reaction. At lower reaction temperatures the surface area (㎡/g-s.m.) and the micro pore volume (㎤/g-s.m.) were increased but the macro pore volume was not affected by the reaction temperatures. It was found that the random pore model was agreed with the pore structure data which were obtained from gasification of the char.
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김광호,이순신 한국실험동물학회 2019 Laboratory Animal Research Vol.35 No.4
In the twenty-first century, high contagious infectious diseases such as SARS (Severe Acute Respiratory Syndrome), MERS (Middle East Respiratory Syndrome), FMD (Foot-and-Mouth Disease) and AI (Avian Influenza) have become very prevalent, causing treat harm to humans and animals in aspect of public health, and economical issues. The critical problem is that newly-reported infectious diseases that humans firstly experience are expected to continue to emerge, and these diseases will be spreading out rapidly. Therefore, rapid and safe supplies of effective vaccines are most pivotal to prevent the rapid prevalent of new infection, but international standards or assessing protocol the safety of urgent vaccines are not established well. In our previous study, since we established a module to assess the brain safety of urgent vaccines, therefore, it is necessary to verify that this established module for assessing brain safety could work effectively in commercially available two vaccines (one killed- and on live-vaccines). We compared the results of Evans blue (EB) assay and qPCR analysis by injection of two kinds of vaccines, PBS and Lipopolysaccharide (LPS) under the condition of the module previously reported. We confirmed that the brain safety test module for urgent vaccine we established is very reproducible. Therefore, it is believed that this vaccine safety testing method can be used to validate brain safety when prompt supply of a newly developed vaccines is needed.
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김광호,이순신 한국실험동물학회 2019 Laboratory Animal Research Vol.35 No.4
Although the number of prescriptions and dependence on sleeping pills are increasing, the associations with unexpected abnormal behaviors and metabolic diseases caused by the overuse of sleeping pills are not well understood. In particular, such as abnormal eating-behavior and the occurrence of metabolic disorders caused by psychological unstable states are reported. For this reason, herbal medicine, which has not had such side effects in recent years, is attracting attention as an alternative medicine/food for sleeping inducer. We have used ethanol extracts from Passiflora incarnata (PI) to steadily obtain positive effects on sleep and brain microenvironment. However, as mentioned earlier, sleep-inducing efficacy can only be used safely if the behavioral and metabolic abnormalities do not appear. Thus, in this study, we used Phenomaster equipment to continuously monitor the movement, feeding, water consumption, gas changes, etc. in C57BL/6 mice at a dose of 500 mg/kg/day for 5 consecutive days with PI extract group compared with the control group. Before sacrifice, differences in body composition of mice were also compared. Monitoring of 24 h/5 days through the equipment showed no change in PI-treated group in anything except for significant decrease in blood melatonin levels and activity after PI administration. Taken together, the statistically insignificance of any behavioral and metabolic phenomenon produced by repeated treatment of PI are not only expected to have an accurate sleep effect, but are also free of side effects of the prescribed sleeping pills. This study has given us greater confidence in the safety of the PI extracts we use for sleep-inducer.
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