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        Combustion properties of gaseous CH<sub>4</sub>/O<sub>2</sub> coaxial jet flames in a single-element combustor

        Kim, T.Y.,Choi, S.,Kim, H.K.,Jeung, I.S.,Koo, J.,Kwon, O.C. Butterworths [etc.] ; Elsevier Science Ltd 2016 Fuel Vol.184 No.-

        Fundamental combustion properties of gaseous methane (CH<SUB>4</SUB>)/oxygen (O<SUB>2</SUB>) coaxial jet flames in a single-element combustor are experimentally evaluated as a preliminary step for subsequent studies of injection at very low temperature or using liquid O<SUB>2</SUB> for CH<SUB>4</SUB>/O<SUB>2</SUB> bipropellants, recently appearing to be the oncoming liquid bipropellant. A combustion chamber with quartz windows, a single shear coaxial injector and an exhaust nozzle on the downstream of the chamber is considered for the present study. Focusing on the measurements of the ignition and combustion stability limits of the coaxial jet flames in the chamber, flame visualization is also conducted by OH<SUP>*</SUP> chemiluminescence, schlieren imaging and direct imaging. Results show the ignition limits restricted than the combustion stability limits. Flame behaviors are largely classified into two, the stably attached flame and the oscillating, liftoff (near-blowout) flame. Due to cooling effects on the wall of the chamber, stably liftoff flame is not observed. The stability of the flame is greatest at fuel-rich condition (based on the injected amounts of CH<SUB>4</SUB> and O<SUB>2</SUB>). From the flame visualization flame thickness is found to be smaller than the injector lip thickness and insensitive to injection conditions. The laminar-flow behavior near the injector exit due to the strong burning of pure O<SUB>2</SUB> is observed even for high Reynolds numbers (Re). The flame visualization also exhibits the recirculating O<SUB>2</SUB> that enhances burning in the combustor through the reaction with the outer fuel jet. The results of ignition limits, combustion stability limits and flame visualization can be used as a database for researches of modeling the gaseous CH<SUB>4</SUB>/O<SUB>2</SUB> jet flames in the combustion chamber.

      • Trichloroethylene 취급 작업장의 공기 중 농도와 근로자의 요중 Trichloroacetic Acid 농도의 상관관계에 관한 조사연구

        권오윤,이종태,문덕환,배기택 인제대학교 1990 仁濟醫學 Vol.11 No.3

        부산ㆍ경남지역의 Trichloroethylene 취급 사업장 중 4개업종 20개소를 대상으로 기중 Trichloroethylene 농도를 측정하고, 이들 사업장 근로자 중 101명을 대상으로 요중 Trichloroaceticacid 농도를 분석하여 Trichloroethlene 폭로 정도를 평가하였다. Trichloroethylene, which is a chlorinated unsaturated hydrocarbon, is widely used as a solvent in degreasing operations. In the present study, the time-weighted average intensity of trichloroethylene exposure at work environments in 20 manufactures of 4 industries was assessed, at the same time trichloroacetic acid excretion in urine among 101 workers exposed to trichloroethylene was measured, and the exposure-excretion relationship was investigated. The results were summarized as follows; 1.The environmental trichloroethylene level was highest in metal machine industry(121.3ppm), followed by fabricated metal industry (106.0ppm), precision machine industry(65.0 ppm) and electrical machine industry(48.0 ppm). 2.The rate of urinary trichloroacetic acid concentration over 75mg/l among 101 workers was 42.6%(43 workers). 3.There is a linear correlation between the environmental exposure and urinary excretion(Y=1.05584X+35.65591, r=0.52401, p=0.0000).

      • KCI등재

        Synthesis of titanium dioxide in O<sub>2</sub>/Ar/SO<sub>2</sub>/TiCl<sub>4</sub> microwave torch plasma and its band gap narrowing

        Hong, Y.C.,Lho, T.,Lee, B.J.,Uhm, H.S.,Kwon, O.P.,Lee, S.H. Elsevier 2011 Current Applied Physics Vol.11 No.3

        Titanium dioxide (TiO<SUB>2</SUB>) nanoparticles were synthesized directly by injecting gas-phase titanium tetrachloride (TiCl<SUB>4</SUB>) bubbled with a mixture of Ar and SO<SUB>2</SUB> into a 2.45 GHz microwave torch plasma operated in O<SUB>2</SUB> gas at atmospheric pressure. The absorption edge of the as-produced TiO<SUB>2</SUB> powders in the UV-Visible spectrum shifted from 457 nm to 483 nm as the SO<SUB>2</SUB> gas content in the mixture gas carrying the TiCl<SUB>4</SUB> was increased. According to X-ray photoelectron spectroscopy (XPS) and UV-Visible spectroscopy, the band gap narrowing was due to the incorporation of sulphur (S) species from the Ar and SO<SUB>2</SUB> mixture in the oxygen microwave torch plasma into the O site of TiO<SUB>2</SUB>2.

      • KCI등재

        장기 저장연료의 열안정성 및 연료접촉 고무오링의 수명예측 연구

        정근우(K. W. Chung),홍진숙(J. S. Hong),김영운(Y. W. Kim),한정식(J. S. Han),정병훈(B. H. Jeong),권태수(T. S. Kwon),서동욱(D. O. Suh),성민준(M. J. Sung),권영일(Y. I. Kwon) 한국트라이볼로지학회 2018 한국윤활학회지(윤활학회지) Vol.34 No.5

        Thermal deterioration of fuel due to long-term storage influences engine performance and causes malfunctions. Fuel stability is usually evaluated via heat resistance and thermal stability during a brief heat shock at high temperature; storage stability in this scenario means that there is very little change in the quality of the fuel during long-term storage. In addition, rubber-based products such as oil seals, O-rings, and rubber hoses can influence the quality of the fuel. When these rubber products are in contact with fuel, they can swell, mechanically weaken, and occasionally crack, thus leaking low molar weight rubber and additives including plasticizer and antioxidant into the fuel to degrade its properties and shorten its useful lifetime. This study determines the thermal stabilities of three kinds of synthetic fuels by evaluating their low temperature kinematic viscosities, chemical composition changes via GC analyses, gross heat of combustion, and color changes. We evaluate the compression set of O-rings by immersing one NBR and two FKM rubber O-rings in the three synthetic fuel samples in airtight containers at variable storage temperatures for six months; from this, we estimate the lifetimes of the O-rings using the Power law model. There were very little changes in the chemical compositions and gross heat of combustion after six months of the experiment. The lifetimes are thus dependent on the materials of the rubber products, and in particular, the FKM O-ring was calculated to have a theoretical lifetime of 200 to 5,700 years. These results indicate that the synthetic fuels maintain their physical properties even after long-term storage at high temperatures, and the FKM O-ring is suitable for long-term sealing of these fuels.

      • SCISCIESCOPUS

        Seroprevalence of equine piroplasms in the Republic of Korea

        Seo, M.G.,Yun, S.H.,Choi, S.K.,Cho, G.J.,Park, Y.S.,Kwon, O.D.,Cho, K.H.,Kim, T.H.,Jeong, K.S.,Park, S.J.,Kwon, Y.S.,Kwak, D. Elsevier Scientific Pub. Co 2011 Veterinary parasitology Vol.179 No.1

        Equine piroplasms include two tick-borne protozoan parasites, Babesia caballi and Theileria equi. Although no clinical equine piroplasmosis has been reported in the Republic of Korea, the possible existence of the disease has been proposed due to a nationwide distribution of the vector ticks. To determine if the antibodies against B. caballi and T. equi were present, 184 sera of horses (Equus caballus) raised in the Republic of Korea from 2007 to 2010 were assessed using cELISA kits. Two (1.1%) out of 184 sera were positive for T. equi, but none were seropositive for B. caballi. Both samples tested positive came from one region (Gyeonggi province). The accuracy of the cELISA was confirmed by PCR using primers specific to the 18S rRNA of T. equi. This study presents for the first time horses infected by T. equi in the Republic of Korea. Since the infection of T. equi occurred in horses raised in the Republic of Korea, further studies with continuous monitoring of the vector ticks for equine piroplasms and appropriate control programs need to be established.

      • 智異山 自生 부추의 形態的 特性 및 核型에 關한 硏究

        權泰牛,李萬相 圓光大學校 1991 論文集 Vol.25 No.2

        智異山一帶에 自生하는 부추에 對하여 표高에 따른 形態的인 差異와 自生地의 부추를 같은 場所인 裡里에 移植하여 自生地와 栽培地 間의 形態的인 差異 및 智異山 부추의 染色體數와 核型에 대하여 檢討한 結果 1.天皇峰, 세석평정에 自生하는 부추는 A.cyaneum(2n=16)이고, 백무동에 自生하는 부추는 A.thunbergii(2n=32)로 백무동에 自生하는 부추가 形態에 있어 大體로 크나 葉數, 鱗經數 및 分??數 等에 있어서는 적었다. 2.같은 A.cyaneum(2n=16)에 있어서 標高가 높은 天皇峰의 부추가 세석평정의 부추보다 形態的 差異에 있어 같거나 컸으며, 越等히 큰 差異을 보인것은 草長, 花軸의 길이 等이었다. 3.天皇峰, 백무동 自生地 부추보다 草長과 葉의 數, 길이, 幅 및 두께는 栽培地에서 減少되었으나 세석평정의 것은 오히려 增加되었고, 3地域 自生地보다 栽培地에서 鱗莖의 數와 重量은 越等히 增加하였으나 花軸의 길이는 減少되었으며, 天皇峰 세석평정産 開花期는 栽培地에서 한달 程度 늦었다. 4.天皇峰에서 蒐集된 부추의 染色體數는 2n=16이었고, Arm ratios는 Subterminal이 G, H 2個染色體에 있는 것과, G染色體에만 있는 2個群이 調査되었고, 나머지는 Median or submedian이었으며 附隨體染色體는 發見되지 않았다. 5.세석평정에서 蒐集된 부추는 4個群이 調査되었으며 染色體數는 NO.1, NO.2는 2n=16, NO.3는 2n=17, NO.4는 2n=20이고 Arm ratios는 Subterminal이 NO.1에서 G, H染色體에, NO.2는 F染色體에, NO.3은 I染色體에, NO.4는 J染色體에 있고 나머지는 Median or Submedian 이었으며 附隨體는 NO.1, NO.2에서는 F染色體에 한쌍씩 있고 NO.3, NO.4에서는 觀察되지 않았다. NO.4에서 2n=20인데 染色體가 어떻게 增加되었는지 確認하기 어려우나 I, J染色體들의 크기가 작았다. Present works were attempted to investigate the difference of morphology, number of chromosome, and karyotype of native Allium species grown in Mt. Jiri. Native Allium species grown at Cheonhwangbong(sea level: 1950m) and Seseogpyeongjeong(sea level: 1700m) in Mt. Jiri were A.cyaneum(2n=16), Baegmudong(sea level: 350m) was A. thunbergii(2n=32). Generally morphology of A. thunbergii was larger than that of A. cyaneum, but no. of leaf, bulb, and tiller were fewer. Plant height and floral axis length of A. cyaneum grown at Cheonhwangbong were far longer than those of Seseogpyeonjeong. When native Allium species grown in Mt. Jiri was cultivated in Iri(sea level:8m), number and weight of bulb were increased remarkably, the length of floral axis was decreased, the date of flowering was late. Native A. cyaneum grown at Cheonhwangbong divided into two groups that the subterocentric chromosomes of No.1 and No.2,less than 33% of arm ratio, existed in the G and H chromosome respectively, others were metacentric or submetacenteic chromosome. Satelite chromosome was not observed. Native A. cyaneum grown at Seseogpyeongjeong divided into four groups. No. of chromosome of No.1, No.2, No.3, and No.4 were 2n=16, 2n=16, 2n=17, and 2n=20. Subterocentric chromosome of No.1, No.2, No.3, and No.4 existed in the G and H,F,I,and J chromosome, and others were metacentric or submetacentric chromosomes. Satellite chromosomes of No.1 and No.2 were found one pair in F chromosome, while No.3 and No.4 were not observed.

      • KCI등재

        자돈 및 육성돈에 있어 α-1,6-galactosidase와 β-1,4-mannanase의 사료내 첨가가 성장 및 영양소 소화율에 미치는 영향

        권오석,김인호,이상환,홍종욱,김지훈,문태현,이지훈 한국동물자원과학회 2003 한국축산학회지 Vol.45 No.2

        본 연구는 양돈사료내 대두박 항영양인자인 α-galactosides와 galatomannan의 분해를 유도하는 α-1,6-galactosidase와 β-1,4-mannanase의 사료 내 첨가가 자돈 및 육성돈의 성장과 영양소 소화율에 미치는 영향을 조사하기 위하여 실시하였다. 시험 1은 개시시 체중 10.57±0.30㎏의 3원 교잡종 자돈 60두를 공시하였으며, 시험설계는 옥수수-건조유청-대두박 위주의 사료에 NRC (1998)의 영양소 요구량에 따라 처리한 대조구 (CON), 대조구 사료내 복합효소제를 0.1% 첨가한 처리구로 하였다. 사양시험기간동안, 일당증체량에 있어서는 대조구와 비교하여 EC0.1 처리구가 높은 것으로 평가되었으나 유의적인 차이는 보이지 않았다. 그러나 사료효율에 있어서는 대조구와 비교하여 EC0.1 처리구가 유의적으로 높게 평가되었다 (P<0.05). 건물과 질소 소화율에 있어서 대조구와 비교하여 처리구가 향상된 것으로 조사되었다 (P<0.05). 시험 2는 개시시 체중 22.30±0.45㎏의 3원 교잡종 육성돈 36두를 공시하였으며, 시험설계는 옥수수-대두박 위주의 사료에 NC (1998)의 영양소 요구량에 따라 처리한 대조구 (AME, adequate ME diet), 대조구 사료내 복합효소제를 0.1% 첨가한 처리구 (AME+EC0.1, Adequate ME diet + 0.1% 복합효소제), 대조구 사료에서 대사에너지 함량을 4% 낮춘 사료에 복합효소제를 0.1% 첨가한 처리구 (LME+EC0.1, Low ME diet + 0.1% 복합효소제)로 하였다. 총 30일간의 사양시험 기간동안, 일당증체량에 있어서는 AME 처리구와 비교하여 복합효소제 처리구가 유의적인 성장율이 높은 것으로 조사되었다 (P<0.05). 건물 및 질소 소화율에 있어서는 AME 처리구와 비교하여 복합효소제 첨가구가 유의적으로 높게 평가되었다 (P<0.05). 결론적으로, 자돈 및 육성돈 사료에 복합효소제의 첨가는 성장능력 및 영양소 소화율을 향상시키는 것으로 사료된다. For the Exp. I, a total of sixty pigs (10.57±0.30㎏ average initial body weight) were used in a 15-d growth assay to determine the effect of dietary α-1,6-galactosidase and β-1,4-mannanase on growth performance and nutrient digestibility. Dietary treatments included 1) CON (corn-dried whey-SBM based diet), 2) EC0.1 (CON diet + 0.1% enzyme complex of α-1,6-galactosidase and β-1,4-mannanase). Through the entire experimental period, gain/feed of pigs fed EC0.1 diet was higher (0.43 vs 0.52) than that of pigs fed CON diet (P<0.05). Pigs fed EC0.1 diet showed significant (P<0.05) improvement in dry matter (74.82% vs 82.41%) and nitrogen (70.59% vs 77.88%) digestibilities compared to pigs fed CON diet. For the Exp. 2, a total of thirty six pigs (22.30±0.45㎏ average initial body weight) were used in a 30-d growth assay to determine the effects of dietary α-1,6-galactosidase and β-1,4-mannanase in low energy diet on growth performance and nutrient digestibility. Dietary treatments included 1) AME (adequate ME diet), 2) AME+EC0.1 (AME diet + 0.1% enzyme complex) and LME+EC0.1 (low ME diet + 0.1% enzyme complex). Through the entire experimental period, average daily feed intake of pigs fed enzyme complex supplemented diets was higher than that of pigs fed CON diet (P<0.05). Also, pigs fed AME+EC0.1 diet showed significant (P<0.05) increase in ADFⅠ (1,401g vs 1,733g) compared to pigs fed CON diet. Pigs fed enzyme complex supplemented diet showed significant (P<0.05) improvement in dry matter and nitrogen digestibilities compared to pigs fed CON diet. In conclusion, the results obtained from these feeding trials suggest that the supplementation of α-1,6-galactosidase and β-1,4-mannanase was an effective means for improving growth performance and dry matter and nitrogen digestibilities in nursery and growing pigs.

      • KCI등재
      • KCI등재

        Ti-6Al-7Nb 합금의 표면 활성에 미치는 양극산화 공정조건의 영향

        권오성,류경호,박광범,이민호,배태성,이오연 대한금속재료학회 2005 대한금속·재료학회지 Vol.43 No.2

        This study was performed to investigate whether the bioactivity of the anodized and hydrothermally treated Ti-6A1-7Nb alloy were affected by the process conditions of anodic oxidation. Anodizing was performed at a current density of 5-50 mA/㎠ in up to 240~300 V in electrolyte solutions containing DL-α-glycerophosphate(DL-α-GP) and calcium acetate (CA). Hydrothermal treatment was done at 300℃ for 2 hours to produce hydroxyapatite (HA) for bioactivity. Bioactivity was evaluated from surface activation layer formed on the surfaces in a Hanks' solution with pH 7.4 at 36.5℃ for 30 days. The size of micropores and the thickness of oxide film were increased by increasing the spark forming voltage, and more complex oxide layers were formed. HA crystals were observed on the anodic oxide film after hydrothermal treatment at 300℃ for 2 hours. The anodic oxide films were composed of strong anatase peak and rutile peak, and showed the increase in intensity of anatase peak after hydrothermal treatment. When electrolyte composition, voltage and current density were increased, the deposited HA crystals showed a fine shapes. Bioactivity in Hanks' solution was accelerated when the oxide films were composed of strong anatase peak with rutile peak. Oxide layers selectively showed surface activity at the pertinent electrolyte composition. When voltage and current density were increased, the surface activity was increased. The amount of Ca and P was increased in surface having bioactivity in Hanks' solution. (Received December 1, 2004)

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