Phase separation phenomena and thermodynamics of octylphenol polyoxyethylene ether in micellar solutions: Effect of high concentration of inorganic salts and linear correlation

Dan Ni Li,Jing Huang,Zhao Hua Ren,Rui Sheng,Zheng Bo Qian,Bei Bei Li,Xiao Feng Quan,Ye Xi Zhang,Jun Ru Wang,Huan Tian 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.99 No.-

The phase separationphenomena or cloud points (CP) behaviorof nonionic octylphenol polyoxyethylene etherwith oxyethylene glycol ether unit of 15 (OP-15) were investigated in aqueous micellar solutions containinghigh concentrations of inorganic salts including NaCl, KCl, MgCl2, CaCl2, BaCl2, AlCl3, FeCl3, Na2SO4and Na2SiO3. The change in CP induced by salts and its mechanism are discussed theoretically. In aqueous solutionscontaining high concentration of salt, for thefirst time the linear relationship between CP and saltconcentrationiswellestablishedtocharacterizethedepressionofCP.Basedonpseudophaseseparationmodel,thermodynamic parameters are estimated and adopted to further describe the phase separation process andthe interactions between OP-15 molecules or the OP-15/water interactions. Thermodynamic parametersincluding standard Gibbs energy change (DG0CP), enthalpy change (DH0CP) and entropy change (DS0CP)indicate that the additions of different salts result in the change in entropy-driven nonspontaneousprocess of phase separation. These data, which are from the compensation temperatures and the changeof molar heat capacity, also prove that different ions induce the change in the interactions betweensurfactant molecules or the surfactant–water interaction and thus affect the depression of CP. Thesefindings help with understanding the effect of inorganic salts, especially the high concentration of salt, onCP of nonionic surfactant and then broadening the application of nonionic surfactant based on CP such asthe extraction of biomaterials in biological samples derived from animals or plants, etc.

A Network Intrusion Detection Model Based on K-means Algorithm and Information Entropy

Gao Meng,Li Dan,Wang Ni-hong,Liu Li-chen 보안공학연구지원센터 2014 International Journal of Security and Its Applicat Vol.8 No.6

Many factors could influence the clustering performance of K-means algorithm, selection of initial cluster centers was an important one, traditional method had a certain degree of randomness in dealing with this problem, for this purpose, information entropy was introduced into the process of cluster centers selection, and a fusion algorithm combining with information entropy and K-means algorithm was proposed, in which, information entropy value was used to measure the similarity degree among records, the least similar record would be regarded as a cluster center. In addition, a network intrusion detection model was built, it could make cluster centers change dynamically along with the network changes, and the model could real-time update the cluster centers according to actual needs. Experiment results show that the improved algorithm proposed is better than the traditional K-means algorithm in detection ratio and false alarm ratio, and the network intrusion detection model is proved to be feasible.

Numerical simulation of the sheet/cloud cavitation around a two-dimensional hydrofoil using a modified URANS approach

Zhong Li,Dawei Zheng,Feng Hong,Dan Ni 대한기계학회 2017 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.31 No.1

Cavitating flow over a two-dimensional Clark-Y hydrofoil is numerically investigated via a Modified density correction method (MDCM) for turbulence closure to improve the capability of two-phase flow simulation for the k-ε RNG turbulence model. A transport equation model for the local volume fraction of vapor is solved, and a modified version of the Kunz model is used for the condensation and evaporation processes. Simulations have been conducted for various cavitation numbers ranging from non-cavitating to cloud cavitation. We compared the time-averaged lift and drag coefficients, cavitation dynamics, and time-averaged velocity profiles with the available experimental data for the MDCM and Density correction method (DCM). The comparisons between numerical and experimental results show that the MDCM and DCM are capable of capturing the special trends of the lift coefficient at the inception cavitation stage and the drag coefficient at the cloud cavitation stage. The MDCM is more robust and physical than the DCM in predicting the wake flow downstream from the trailing edge. The predicted attached cavities of both models almost show the same trend near the leading edge of the hydrofoil. However, the MDCM predicts more shedding cavity than the DCM in the wake region.

Guaranteed Cost Control of Networked Control Systems with DoS Attack and Time-varying Delay

Yeping Shen,Wen-an Zhang,Hongjie Ni,Dan Zhang,Li Yu 제어·로봇·시스템학회 2019 International Journal of Control, Automation, and Vol.17 No.4

This paper is concerned with the guaranteed cost control for a class of networked control systems (NCSs)with denial-of-service (DoS) attack and time-varying communication delay. First, an uncertain switched systemmodel is proposed that is capable of capturing the DoS attack and the short time-varying delay simultaneously. Toachieve the exponential stability with a guaranteed cost performance level, a sufficient condition is derived in termsof matrix inequalities. In our work, the proposed design condition establishes several quantitative relations betweensystem performance and attack parameters. Moreover, the critical value of strong attack frequency is also obtained. Finally, a practical example is given to show the effectiveness of our results.

Experimental and numerical analysis of unsteady pressure pulsation in a centrifugal pump with slope volute

Ning Zhang,Minguan Yang,Bo Gao,Zhong Li,Dan Ni 대한기계학회 2015 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.29 No.10

This study experimentally and numerically investigates the unsteady flow in a centrifugal pump with special slope volute under variousconditions to illustrate the detailed flow structures and pressure pulsation within the model pump. Whole flow passage is consideredduring the numerical simulation; pressure pulsation signals are extracted using nine fast-response pressure transducers. The Root meansquare (RMS) method is introduced to deal with the discrete components at fBPF of the different monitoring points along the volute casing,which is an effective attempt to evaluate the overall pulsating level of the model pump. Results show that numerical method canpredict the components at fBPF effectively; however, it has limited ability in capturing noise frequencies motivated by unsteady separateflow and non-linear interaction effect. Around the nominal flow rate, the predicted amplitudes at fBPF agree well with the experimentalresults, showing larger difference at the off-design conditions. To predict the pulsating level of the components at fBPF, two fitted equationsof the RMS values versus the flow rate and specific speed are carried out, which would be very helpful in evaluating the pressurepulsation level in the centrifugal pump.

Identification and characterization of differentially expressed miRNAs between bamboo shoot and rhizome shoot

Qun-Ying Jin,Hua-Zheng Peng,Er-Pei Lin,Nan Li,Dan-Ni Huang,Yan-Li Xu,Xi-Qi Hua,Kui-Hong Wang,Tang-Jun Zhu 한국식물학회 2016 Journal of Plant Biology Vol.59 No.4

As one of the largest members of Poaceae family, bamboo is a very important agricultural plant in the world. The development of bamboo shoot is very special and particularly significant to bamboo production. Understanding the developmental differences between bamboo shoot and rhizome shoot is extremely valuable for us to further elucidate the mechanism of bamboo shoot formation since both bamboo shoot and rhizome shoot develop directly from rhizome bud underground. In this paper, miRNA chips with 413 miRNA probes were used to compare miRNA expressions between bamboo shoot and rhizome shoot. The experiment revealed 64 bamboo shoot upregulated and 56 rhizome shoot up-regulated miRNAs which were classified into four major categories according to deep sequencing based target prediction. Meristem and morphological development related miRNAs were most important in bamboo shoot, especially miR171 and miR156 members. While in rhizome shoot the mainstream of miRNA expressions was metabolism and nutrition related ones, especially miR395 members. The meristem and morphological development related miRNAs in bamboo shoot showed some embryonic characteristics and suggested the participation of several phytohormones like gibberellin, cytokinin and auxin, which were absent in those miRNAs of rhizome shoot. Further qRT-PCR detections of 21 up-regulated miRNAs in bamboo seedlings indicated that 12 ones were regulated to varying degrees by some environmental factors. Among them, rhizome shoot upregulated osa-miR395b was the most environment-sensitive miRNA, particularly to dehydration. And the bamboo shoot up-regulated osa-miR399j proved uniquely and strongly induced by phosphor. The existence of multiple regulation sites from same miRNA suggested the probability of crosstalks among meristem development, metabolism and stress response during bamboo shoot and rhizome shoot development.

Systemic Inflammatory Biomarkers, Especially Fibrinogen to Albumin Ratio, Predict Prognosis in Patients with Pancreatic Cancer

Lin Fang,Fei-Hu Yan,Chao Liu,Jing Chen,Dan Wang,Chun-Hui Zhang,Chang-Jie Lou,Jie Lian,Yang Yao,Bo-Jun Wang,Rui-Yang Li,Shu-Ling Han,Yi-Bing Bai,Jia-Ni Yang,Zhi-Wei Li,Yan-Qiao Zhang 대한암학회 2021 Cancer Research and Treatment Vol.53 No.1

Purpose Systemic inflammatory response is a critical factor that promotes the initiation and metastasis of malignancies including pancreatic cancer (PC). This study was designed to determine and compare the prognostic value of neutrophil-to-lymphocyte ratio (NLR), platelet-to-lymphocyte ratio (PLR), monocyte-to-lymphocyte ratio (MLR), and fibrinogen-to-albumin ratio (FAR) in resectable PC and locally advanced or metastatic PC. Materials and Methods Three hundred fifty-three patients with resectable PC and 807 patients with locally advan-ced or metastatic PC were recruited in this study. These patients were classified into a training set (n=758) and a validation set (n=402). Kaplan-Meier survival plots and Cox proportional hazards regression models were used to analyze prognosis. Results Overall survival (OS) was significantly better for patients with resectable PC with low preoperative PLR (p=0.048) and MLR (p=0.027). Low FAR, MLR, NLR (p < 0.001), and PLR (p=0.003) were significantly associated with decreased risk of death for locally advanced or metastatic PC patients. FAR (hazard ratio [HR], 1.522; 95% confidential interval [CI], 1.261 to 1.837; p < 0.001) and MLR (HR, 1.248; 95% CI, 1.017 to 1.532; p=0.034) were independent prognostic factors for locally advanced or metastatic PC. Conclusion The prognostic roles of FAR, MLR, NLR, and PLR in resectable PC and locally advanced or metastatic PC were different. FAR showed the most prognostic power in locally advanced or metastatic PC. Low FAR was positively correlated with OS in locally advanced or metastatic PC, which could be used to predict the prognosis.