복합열화환경하에서의 중성화 및 염화물이온 확산특성이 철근부식에 미치는 영향에 관한 실험적 연구

조봉석,장재봉,김재환,김용로,권영진,김무한 대한건축학회 2003 대한건축학회 학술발표대회 논문집 - 계획계/구조계 Vol.23 No.2

It is recognized that reinforcement corrosion is the main distress behind the present concern regarding concrete durability. In this study, to confirm corrosion of reinforced concrete due to permeability of carbonation and chloride ion affected by thickness of cover, kinds of surface coating, measured electric potential, ratio of corrosion area, weight reduction, corrosion velocity of steel bar under environment of complex deterioration. The results showed that an increase in age also decreases Carbonation velocity coefficients and increases Chloride ion diffusion coefficients. As well, an increase in age also increases corrosion of reinforcement due to permeability of carbonation and chloride ion. Corrosion of reinforcement by thickness of cover is superior to 10mm thick than 20mm thick. It showed that an increase in thickness of cover prevent steel bar from deteriorating due to permeability of carbonation and chloride ion. The results of this study showed that corrosion velocity was affected by thickness of cover, kinds of surface coating. data on the development of corrosion velocity made with none, organic B, organic A, inorganic B. and inorganic A is shown.

전단력 하에서 유도된 광민감군이 첨가된 HDPE 필름의 광분해

조무환,이훈복,신부영 嶺南大學校 環境問題硏究所 1995 環境硏究 Vol.15 No.1

융용 혼합기를 이용하여 공기 분위기 하에서 강한 전단력을 혼합물에 가하여 광분해성 M/B(Master Batch)를 제조하였다. 제조된 M/B가 45 중량 % 첨가된 광분해성 HEPE 얇은 필름과 분해성 M/B가 첨가되지 않은 일반 HDPE 필름을 인플레이션 법으로 제조하였다. 두 필름의 광분해성을 시험하기 위하여 필름을 자외선 조사기와 옥외에 노출시켜 기계적 물성 및 필름의 표면 변화를 살펴보았다. 자외선 조사 시험에서 분해성 필름은 120시간 이내에 처음 신도의 95%를 잃고 매우 취약한 상태로 되었으나, 비분해성 필름은 150시간 조사에도 처음 신도의 80%를 유지하고 있었다. 옥외 노출 시험에서는 분해성 필름의 경우 옥외 노출 21일 후 처음 신도의 약 98%를 상실하였으나, 비분해 필름은 같은 노출 시간에 원래 신도의 98%를 유지하고 있었다. SEM을 이용하여 필름 표면을 관찰한 결과, 특이한 표면 변화를 보여주었다. Photodegradable master batch was prepared by using mechanical oxidation during melt mixing process with high shear and in the presence of air. High density polyethylene (HDPE) thin film containing 45 wt % photodegradable M/B (Master Batch) and common high density polyethylene (HDPE) thin film were prepared by inflation film processing. The films were exposed under both mercury-vapor lamp light and sunlight. The photodegradable film lost about 95 % of its original elongation for 120 hours irradiation and was very brittle. The common film without photodegadability retained 80 % of its original elongation for 150 hours irradiation. Under sunlight, photodegradable HDPE film lost about 98 % of its original elongation at break after 21 days exposure and was very brittle. The common film still retained 88 % of its original elongation at the same period. Surface morphology of the films was examined by using scanning electron microscopy (SEM). SEM micrographs revealed the interesting change of the surface morphology of photodegradable thin film during outdoor exposure.

한천-Acrylamide 미생물 고정화법을 이용한 Polyester 감량폐수의 처리

조무환,김형섭,김정목 嶺南大學校 環境問題硏究所 1995 環境硏究 Vol.15 No.1

폴리에스테르 감량폐수의 주요성분인 EG(ethylene glycol)와 TPA(terephthalic acid)를 분해하기 위하여 분해균주인 Pseudomonas EAW 및 TS2를 한천-acrylamide에 고정화시킨 공정을 개발하였다. 최적 배양조건은 pH 7.5, 온도 35 'C로 나타났다. 체류시간 36시간, 유입 ????? 및 ?????이 각각 5,235 mg/ℓ 및 6,750mg/ℓ 일 때 EG 및 TPA 합성폐수에 대한 이 공정의 ?????? 및 ???? 제거효율은 각각 98% 및 96%로 나타났다. 그리고 EG및 TPA를 탄소원으로 하는 혼합폐수의 경우 유입농도가 ????? 3,141mg/ℓ,???? 13,320 mg/ℓ 일 때 제거효율은 각각 94.3%, 98.2%로 나타났다. 고정화 bead의 평균직경이 4mm일 때 bead의 표면으로 부터 반지름의 18% 이상의 영역에서는 기질과 산소의 전달사항으로 인하여 세포의 성장이 저해를 받았다. 비기질제거속도와 유출 ?????농도의 관계로 부터 비기질이용 속도상수, ???및 ????는 각각 8.57 및 18.8l/ℓ bead.day로 나타났다. A process was developed to degrade EG (Ethylene glycol) and TPA (Terephthalic acid). Bacteria of Pseudomonas strains EAW and TS2 were immobilized in agaracrylamide. The optimum culture conditions were found to be pH 7.5 and 35 "C, respectively. ????? and ???? removal efficiency of this system for EG and TPA synthetic wastewater were 98 % and 96 % at retention time 36 hrs, when influent concentration was ????? 5235 mg/ℓ and ????? 6750 mg/ℓ. And, for the mixed synthetic wastewater of EG and TPA as carbon source, they were 94.3 % and 98.2 %, respectively, when influent concentration was ???? 3,141 mg/ℓ and ????? 13,320 mg/ℓ. The growth of cells in the other region of bead except 18 % of bead radius from surface was inhibited by substrate and oxygen transfer resistance. From relationship of specific substrate removal rate and effluent ????? concentration, the kinetic constants were found as ??? = 8.57 ℓ/ℓ bead.day and ???? = 18.8ℓ/ℓ bead.day, respectively.

향류 냉각 반응기의 정상상태 모사

趙武煥 嶺南大學校 工業技術硏究所 1982 연구보고 Vol.10 No.1

Under the assumption that a first order, exothermic reaction takes place in the reactor, and reactant and coolant flow countercurrently without axial and radial dispersions of concentration and temperature in each phase. Temperature and conversion profiles of process stream, and temperature profiles of coolant are estimated numerically along the length of nonisothermal and nonadiabatic tubular reactor. The results are compared with those of isothermal and adiabatic reactors. The effects of various dimensionless parameters on the temperature and conversion profiles are discussed.

重化學工業機械의 國産化方案에 關한 硏究 : 特히 窯業에 있어서의 燒成爐, 粉碎機, 排風機, 冷却機, 電氣集마器 自動枰量供給器 等의 製作을 目的으로

趙哲衡,朴碩喆,丁太權,宋鐵,桭達福,金基玉,朴煥奎,趙煥從,朴善鐘,金種一,李茂錫 朝鮮大學校 1977 綜合論文集 Vol.1977 No.-

This is to investigate the posibility of home manufacturing of heavy chemical industry machines, such as rotary kiln, crusher, blower, cooler, electrostatic precipitator and weighing feeder of cement plant. It is concluded that even though we can not make all of them (some of them are made now and some others are going to be made in the near future, some of them are made whole and some others are made partially), we can build or export the cement plant by importing the important machines which we can not make now and by substituting them with ours gradually.

회분식 발효 Data를 이용한 생물반응기의 부피산소전달계수(KLa)추산 방법

趙武煥 영남대학교 공업기술연구소 1989 연구보고 Vol.17 No.1

A simple and practical estimation method of volumetirc oxygen transfer coefficient(??)was developed theoretically and was demonstrated experimentally. This new method used real batch fermentation data, i.e., cell density and dissolved oxygen concentration profiles versus time. The advantages of this method were that it estimated kla on the real fermentation conditions, and that kla was not affected by the response time of DO probe.

Baculovirus Vector System에 의해 발현된 재조합 Pseudorabies Virus Major Capsid Protein의 면역원성

전무형,안동준,장경수,조용성,박종현,송재영,현방훈,안수환 충남대학교 생물공학연구소 1997 생물공학연구지 Vol.5 No.-

The recombinant pseudorabies virus major capsid protein (rMCP) was produced by expression of the MCP gene in Sf-9 cell using baculovirus transfer vector system. Following evaluation of the immunochemical properties of the rMCP, the immunogenicity of the recombinant subunit protiens were investigated in guinea pig and swine to obtain the preliminary guide line for the subunit vaccine using rMCP and gP50. It was proved that ultrasonication and 30% ammonium sulfate was most efficient to concentrate and purify the protein. The rMCP was safe in mice, guinea pigs and piglets. In guinea pigs, rMCP mixed with various adjuvants induced substantial degree of serum neutralizing antibody titers, but revealed incomplete protecivity against challenge. In swine, the combination of rMCP and gP50 showed the higher serum neutralizing antibody titers and cellular immune responses than rMCP alone. However, the protectivity was lower in comparison with the commercial gI-deleted inactivated vaccine. We expect these results to contribute to characterization of MCP gene of Korean isolate of PRV and to ultilize as preliminary information for prodution and evaluation of PRV recombinant subunit vaccines.

韓國在來山羊의 綱膜神經節細胞數와 分布에 關한 硏究

金武剛,趙聲煥,申台均 충남대학교 의과대학 지역사회의학연구소 1984 충남의대잡지 Vol.11 No.2

The number and distribution of retinal ganglion cells in the Korean native goats was studied with whole mount preparations stained with methylene blue and thionin. The mean area of 5 retinae is 918 mm² and the mean number of total ganglion cells was 1, 602, 000. So the mean number of ganglion cells per mm² was 1,745. The density distribution of the retinal ganglion cells showed that visual streak was located about 2mm dorsal to the optic disc, and area centralis (7,700 cells/mm') was located about 10mm temporally and 2mm dorsal to the optic disc. There was drop in density of retinal ganglion cells about the circumference of the visual streak in dorsal and ventral direction. The functional significance of the findings was also discussed.

Nicotine이 발생중인 鷄胎의 體重 成長에 미치는 영향

金武剛,金弘善,柳時潤,申台均,李永浩,趙聲煥 충남대학교 의과대학 지역사회의학연구소 1985 충남의대잡지 Vol.12 No.2

The authors studies the effects of Nicotine on the Body weight growth of the developmental chick embryo. On the sixth day of incubation, 0.41mg, 0.82mg and 1.65mg of Nicotine were injected into the chorioallantoic sac of each egg of three groups and one group was injected physiological saline solution as a control, and the eggs were broken for weighting the body weight in every other day from the twelfth day to eighteenth day of incubation. In an attempt to analyze the growth of the body weights, growth formula of Zimmerman and relative growth formula of Huxley were applied. The following results were obtained. 1. The growth of chick embryo boby weight was affected as inhibiting by the Nicotine. The inhibiting effects were in proportion to the injected Nicotine dosage. 2. The growth quantity of the body weight injected 1.65mg was almost half weight of the control group body weight. 3. Growth rate was decreased continuously with tine until 18th day in the 1.65mg injected group but it was increased in 0.41mg and 0.82mg injected group with time lapse from 12th day to 18th day, and 0.41mg injected group was more increased than 0.82mg injected group. 4. Specific growth rate decreased in the all of 0.41mg, 0.82mg and 1.65mg injected group and in the decrease degree 1.65mg and 0.82mg injected group ware severe and 0.41mg injected group was slight. 5. Growth centers of growth gradient were 12th day in the 0.41mg injected group and 18th day in the 0.82mg and 1.65mg injected groups. 6. Relative growth rate was also decreased proportionally in related with injected Nicotine dosage.

동종 골수이식을 시행받은 환자에서 폐색성 세기관지염에 의하여 발생한 자발성 기종격동과 피하 기종

이병환,이제중,이연경,안재숙,김여경,황호인,박무림,조상희,정익주,김형준 대한조혈모세포이식학회 2002 대한조혈모세포이식학회지 Vol.7 No.2

저자들은 만성골수성백혈병으로 동종 골수이식과 이식편 부전으로 인하여 추가적인 말초혈액 조혈모세포이식을 시행 받은 환자에서 만성 이식편대숙주질환과 그 폐 합병증인 폐색성 세기관지염에 동반된 자발성 기종격동과 피하 기종이 병발한 1예를 경험하였기에 이를 보고하는 바이다. Obstructive lung disorders following after allogeneic bone marrow transplantation (BMT) in association with graft- versus-host disease (GVHD) contribute significant morbidity and mortality. We report a case of a 28-year-old man who developed spontaneous pneumomediatinum and subcutaneous emphysema complicating bronchiolitis obliterans after allogeneic BMT. He received an allogeneic BMT for chronic phase of chronic myeloid leukemia. Five months after BMT, he was boostered by allogeneic peripheral blood stem cells from the same donor due to graft failure. One month after the boostering, chronic GVHD developed and were treated with cyclosporine and steroid. The patients developed spontaneous pneumomediatinum and subcutaneous emphysema secondary to severe bronchiolitis obliterans 4 months after boostering donor cells. The air-leak syndromes were recovered by conservative management, including high-flow oxygen.