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Jin Ho Boo,Eunseok Kim,Byung Chan Kwon,Myung Jo Seo,Ji Man Kim,Ji Bong Joo,Dohyung Kang,No-Kuk Park 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.123 No.-
This study investigated the catalytic activity of vanadium-manganese supported on USY-zeolite as a catalystfor low-temperature NO removal, and embedded the powder catalyst in PTFE filter of bag filter. TheV2O5-MnO2/USY-zeolite catalyst was prepared using the co-impregnation method, and the V2O5/MnO2ratio was 0/10, 2.5/7.5, 5/5, 7.5/2.5, or 10/0. The catalytic activity test for NH3-SCR(selective catalyticreduction) of NO was performed at 150–230 C. An enhanced NO conversion above 60% was exhibitedin the low-temperature region below 230 C, and the NO removal efficiency increased as the MnO2 contentincreased. The NH3-TPD and NO-TPD(Temperature Programmed Desorption) analysis confirmed thatthe NH3 adsorption of the catalyst more significantly influences the NO removal performance than the NOadsorption. As the MnO2 content on the catalysts increased, the strength and amount of adsorbed NH3increased, resulting in enhanced NO conversion. The catalyst-embedded PTFE (polytetrafluoroethylene)fiber was prepared by extruding physically mixed PTFE and catalyst powder. Scanning electron microscopy/energy dispersive X-ray spectroscopy confirmed that the catalyst was well dispersed on the surfaceand inside the PTFE fiber. The NO removal performance of the catalyst included PTFE fiber increased asthe amount of the catalysts added was increased.
심재구 ( Jae-goo Shim ),아프잘아킬 ( Afzal Aqeel ),최보미 ( Bo-mi Choi ),이정현 ( Jung-hyun Lee ),곽노상 ( No-sang Kwak ),임호진 ( Ho-jin Lim ) 한국물환경학회(구 한국수질보전학회) 2016 한국물환경학회지 Vol.32 No.4
N-nitrosamines are a class of carcinogenic chemicals that can pose significant hazards to the human life. Ultraviolet (UV) light irradiation is considered as one of the effective methods to reduce N-nitrosamines in the aqueous phase. This study aimed to investigate the pH influence on UV photodegradation of N-nitrosamines (i.e., N-nitrosodibutylamine (NDBA) and N-nitrosopyrrolidine (NPYR)) closely related to water treatment. Photodegradation rate constants of NDBA and NPYR remained between 3.26×10-2 L/W-min to 5.08×10-3 L/W-min and 1.14×10-2 L/W-min to 2.80×10-3 L/W-min at pH2-10, respectively. This study also focused on the formation of oxidized products (i.e., primarily NO2- and NO3-). Under slightly acidic and eutral conditions, NO2- formation was more prevalent than NO3- formation, while under strong acidic conditions, NO3- was more prevalent. There was no significant change in total organic carbon (TOC) and total nitrogen (TN), suggesting negligible loss of N-nitrosamines and degradation products from the system. NDBA was easily photodegraded than NPYR. This study also demonstrated that a lower pH is a favorable condition for photolytic degradation of N-nitrosamines in water.
마이크로프로쎄서를 利用한 直流分捲發電機의 無負荷特性 測程에 關한 硏究
李興浩,盧泰天 충남대학교 공업교육연구소 1981 論文集 Vol.4 No.2
This paper provides experimental results, obtained by using a microprocessor kit, from the no-load characteristics of the dc shunt generator. Although there are some errors in the experimental resuls because of limitations of A/D converter, it is considered that this study will be useful for the characteristic measurements of electric machines.
Kim, Se-Jin,Ho Hur, Joon,Park, Channy,Kim, Hyung-Jin,Oh, Gi-Su,Lee, Joon No,Yoo, Su-Jin,Choe, Seong-Kyu,So, Hong-Seob,Lim, David J,Moon, Sung K,Park, Raekil Nature Publishing Group 2015 Experimental and molecular medicine Vol.47 No.2
<P>Bucillamine is used for the treatment of rheumatoid arthritis. This study investigated the protective effects of bucillamine against cisplatin-induced damage in auditory cells, the organ of Corti from postnatal rats (P2) and adult Balb/C mice. Cisplatin increases the catalytic activity of caspase-3 and caspase-8 proteases and the production of free radicals, which were significantly suppressed by pretreatment with bucillamine. Bucillamine induces the intranuclear translocation of Nrf2 and thereby increases the expression of γ-glutamylcysteine synthetase (γ-GCS) and glutathione synthetase (GSS), which further induces intracellular antioxidant glutathione (GSH), heme oxygenase 1 (HO-1) and superoxide dismutase 2 (SOD2). However, knockdown studies of HO-1 and SOD2 suggest that the protective effect of bucillamine against cisplatin is independent of the enzymatic activity of HO-1 and SOD. Furthermore, pretreatment with bucillamine protects sensory hair cells on organ of Corti explants from cisplatin-induced cytotoxicity concomitantly with inhibition of caspase-3 activation. The auditory-brainstem-evoked response of cisplatin-injected mice shows marked increases in hearing threshold shifts, which was markedly suppressed by pretreatment with bucillamine <I>in vivo</I>. Taken together, bucillamine protects sensory hair cells from cisplatin through a scavenging effect on itself, as well as the induction of intracellular GSH.</P>
윤형식,황성호,이현륭,김수호,박연석,권낙현,정호진,김동훈,노현주,홍성호,박병찬,이관,정해관 東國大學校醫學硏究所 2002 東國醫學 Vol.9 No.1
일상생활에서 모발염색은 흔히 접할 수 있는 미용의 한 종류로 특히 젊은층을 중심으로 폭발적으로 유행하고 있다. 염색을 위항 사용하는 약제는 표백제와 발색제 등 각종 화학약품이 사용되고 있으나 이로 인한 건강장해에 대한 연구는 그리 많지 않다. 저자들은 염색이 인체의 모발건강에 미치는 영향을 파악하기 위하여 염색과 관련된 주관적 증상과 모발의 변화에 대한 실험적 연구를 시행하였다. 동국대학교 경주 캠퍼스 재학생 80명을 대상으로 설문조사를 시행하여 염색 유 ·무 및 염색 후에 경험한 증상에 대해 설문 조사하였고, 의과대학 재학생 46명을 대상으로 피부 반응 테스트를 실시하였다. 또한 염색 전후의 모발 탄성도를 측정하였고 모발의 상태를 파악하기 위해 전자 현미경검사를 실시하였다. 설문조사 결과 염색 전에 비하여 염색 후 안구혼탁, 안구건조, 시력저하, 발진 및 접촉성 피부염, 모발손상, 모근손상 등의 증상을 더 많이 경험한다고 호소하였다(p<0.05). 모발손상과 모근손상은 헤어드라이어 사용 빈도에 따라 증가하는 것으로 조사되었다(p<0.05). 피부반응검사에서 가려움증이 가장 많은 증상이었으며 이는 여성보다는 남성에서 높은 것으로 조사되었다. 염색 전후의 모발장력은 염색 전 134.5±10.37g, 염색 128.0±30.69g, 염색 이틀 후 112.5±19.69g으로 나타났다. 염색 전후의 모발의 전자현미경 케라틴 층이 현저히 감소하고 모발이 가늘어지는 차이를 보였다. 염색은 모발손상, 모발 케라틴 손상 및 모근 손상, 발진 및 접촉성 피부반응, 안구혼탁, 안구건조, 시력 저하를 유발한다. 따라서 염색약으로 인한 손상에 대한 주의와 예방이 필요하다고 생각한다. 예방대책으로 염색 전 피부테스트를 통한 적합성 여부를 판단하는 것이 필요하며 가급적 염색을 피하는 것이 좋을 것이다. 염색약에 발암물질이 포함되어있다는 보고도 있어 염색 제조사의 철저한 실험과 염색 물질의 선별이 염색으로 인한 부작용을 최소화하는데 중요한 역할을 할 것이다. Hair coloring has became one of the most popular cosmetic activities to younger generations during last decade. However, there are few studies on the health effect of widespread use of chemical dyes. This study was conducted to study the effects of hair coloring dye on hair and other systems. We conducted a questionnaire survey of 80 persons in Kyongju campus, Dongguk University. We have done open patch skin test on 46 medical students. We also conducted scanning electron microscopy to examine the hair strength and structure before and after hair coloring process. Injury of hair and hair bulb, contact dermatitis, turbid eyes, xerophthalmia, and poor visual acuity were the main symptoms complained after hair coloring (p<0.05). Injury of hair and hair bulb were increased by frequency of hair-dryer use(p<0.05). In open patch test, pruritus was complanined by more than half of the subjects. Mean strength of hairs before and after hair coloring was as follows; 134.5 (SD 10.37)g before hair coloring, 128.0 (SD 30.69)g immediately after hair coloring, and 112.5 (SD 19.69)g after two days. The scanning electron microscopic findings of hair surface before and after hair coloring showed decreased keratin layer and thinning of the hair. Hair coloring induces injury to hair, its keratin layer, and hair bulb as well as contact dermatitis, turbid eyes, xerophthalmia, and poor visual acuity. Therefore, we think that precaution is needed in use of hair coloring dye. To prevent complications induced by hair coloring dye, it is necessary, especially to those with allergy or skin disorders, to perform skin test before action and avoid hair coloring whenever possible. Longterm health effects of hairdye should be studied and manufacturing companies should try to minimize complications induced by hair coloring dye.
김혜수(Hye soo Kim),김일호(Il Ho Kim),박노국(No-Kuk Park),이승종(Seung Jong Lee) 한국에너지기후변화학회 2021 에너지기후변화학회지 Vol.16 No.1
In this study, the acid gas adsorption characteristics of impregnated AC, which increased the chemical activity of AC and improved selective adsorption for specific components, were studied using lap-scale experimental devices. The three types of AC (general, KOH and K₂CO₃ impregnated) were identified by the analysis of SEM, BET and TGA. It was found that the surface area and the mass loss rate of AC differed depending on the type of impregnation contents. Subsequently, Three types of AC were evaluated for adsorption performance according to temperature. In addition, 20 wt% KOH impregnated AC conducted adsorption and breakthrough point of SO₂ and NO₂ gases. The breakthrough point of SO₂ and NO₂ is 15 and 7 minutes, respectively. The results of the experiment shown th t the adsorption efficiency of the impregnated AC was higher than that of the AC and was proportional to the temperature.