신라 중고기골제(中古期骨制)의 성립과 운영

박수진 ( Soo Jin Park ) 수선사학회 2011 史林 Vol.0 No.39

The Golpum system was the unique form of the status system in the Silla dynasty in Korea. It was a typical ancient Korean society`s status system which has been investigated field in the academia. In particular, a kinship system, which is composed of Seong-gol and Jin-gol, is the most hottest issue in the Korean academic circles. However, there is a no point of agreement whether Seong-gol was the reality or not, and concerning about its management and times. This research has a purpose to investigate how the status system established and guaranteed in the society. The Buddism has attracted public attention as a theoretical basis of the status system. The Samkuksagi (The chronics of the three nations) described the Buddism as a state religion while it did not focus on the myths about the Buddism. We assume that the Buddism was the meaningful political controller in the Silla dynasty. Seong-gol was regarded as the royal familiy, and it was available when the King had the superiority over the nobility. The Kings of Sylla dynasty had been called the Great King with a qualifier ``saint`` when the Buddism instituted a state religion. It means that Seong-gol (the saunt family) was established based on the Buddism. Jin-gol also entered a field of history similar times to Seong-gol, and both two terminologies was established the same period in terms of the Buddism terminology. Seong-gol guaranteed a royal family`s prestige through the change of ennoble system Galmun King and the use of the Great King title. The King`s brother, who were Seong-gol, secured the superiority over the nobility by getting the title of ennoblement. The Kings also solidified their status through the ennoble system, and they monopolized political power because the kings restrained the right of succession only kings heirs. Jin-gol also guaranteed their political prestige after established Daedeung. The House of Lords in Silla dynasty limited the qualification only who had the title of Daedeung. Jin-gol class took the reins of the nobility through only Jin-gol getting the title of Daedeung.

Butane - Methanol , Butane - Ethanol 계의 90℃ 등온 기액상평형과 과잉 몰엔탈피

박수진,박소진 ( Soo Jin Park,So Jin Park ) 한국화학공학회 1994 춘계학술발표논문집 Vol.- No.-

치면열구전색재의 충전량에 따른 미세누출의 비교연구

박수진,정태성,김신,Park, Soo-Jin,Jung, Tae-Sung,Kim, Shin 대한소아치과학회 2003 大韓小兒齒科學會誌 Vol.30 No.2

본 연구는 치면열구전색재의 충전량이 미세누출에 미치는 영향을 비교분석할 목적으로 실시되었다. 6개의 군으로 나누어 각각 다른 충전량, 치면 전처리, 충전재를 적용하여 미세누출 양상을 비교하였다. 60개의 제 3대구치를 3개의 군으로 나누어 각 군당 20개씩 시편을 구성하였다. 각 치아는 교합면을 두 부분으로 나누어 한 부위는 충전재의 폭이 1mm이하가 되도록 충전하고(1, 3, 5군), 나머지 한 부위는 2mm이상 되도록 충전을 하였다(2, 4, 6군). 1, 2군은 산처리후 Helioseal F로 치면열구전색을 실시하였고, 3, 4군은 산처리후 상아질 접착제로 치면 전처리한 후 Helioseal F로, 5, 6군은 유동성 복합레진인 Tetric Flow로 치면 열구전색을 실시하였다. 500회의 열순환 및 색소침투 후, 미세누출도를 관찰하고 비교분석하여 다음과 같은 결론을 얻었다. 1. 동일한 충전폭을 적용하였을 경우, 미세누출도는 5군<3군<1군과 6군<4군<2군의 순으로 나타났으나 유의한 차이는 아니었다(p>0.05). 2. 동일한 재료와 치면처리를 하되, 충전폭만을 달리한 군들, 즉 1군과 크군, 3군과 4군, 5군과 6군간의 미세누출도에서는 유의한 차이를 보였다(p<0.05). 3. 미세누출은 전색재의 물성, 상아질 접착제 전처리 여부 보다 전색재의 충전량에 더 많은 영향을 받았다. With the purpose of evaluating the effect of ailing amount of pit and assure sealants on the microleakage, 6 groups of specimens with different filling amount, filling materials and surface pretreatment were investigated. Sixty permanent third molars were divided into three groups. The occlusal surface of each tooth was divided into two parts; the filing width of one part was below 1mm (group1, 3, 5), and in the other part more than 2mm (group 2, 4, 6) Group 1 and 2: Helioseal F was applied directly to etched enamel; Group 3 and 4: Helioseal F was applied to etched and scotchbond Multi-purpose plus pre-treated enamel; Group 5 and 6: Tetric Flow was applied. After 500 times thermocycling and dye infiltration, we evaulated the microleakage. The results were as follows; 1. The mean microleakage score at each width were increased in the following order;group 5<3<1, and group 6<4<2. 2. In comparing the groups with same material and surface pretreatment but with different filling width (group 1 versus 2, 3 versus 4, 5 versus 6), the microleakage scores were significantly different. 3 The microleage was affected by filling amount of pit and assure sealants than Oiling materials and dentin bonding agent pretreatment.

제올라이트/DGEBA 복합재료의 경화 동력학과 기계적 계면특성

박수진,김영미,신재섭,Soo-Jin Park,Young-Mi Kim,Jae-Sup Shin 대한화학회 2003 대한화학회지 Vol.47 No.5

In this work, the zeolite/diglycidylether of bisphenol A(DGEBA) systems were investigated in terms of the cure kinetics and mechanical interfacial properties of the composites. The 4, 4-diamino diphenyl methane(DDM) was used as a curing agent for epoxy. Two types of zeolite(PZ) were prepared with 15 and 35 wt% KOH treatments(15-BZ and 35-BZ, respectively) for 24 h, and their surface characteristics were studied by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction(XRD). Cure kinetics of the composites were examined in the context of differential scanning calorimetry(DSC), and mechanical interfacial properties were investigated in critical stress intensity factor($K_{IC}$) and critical strain energy release rate($G_{IC}$). In the results of XPS and XRD, sodium ion(Na) of zeolite was exchanged for potassium ion(K), resulting from the treatment of KOH. Also, $Si_{2p}/Al{2p}$ composition ratios of the treated zeolite were increased, which could be attributed to the weakening of Al-O bond in framework. Cure activation energy($E_a$) of 15-BZ composites was decreased, whereas KIC and $G_{IC}$ were increased, compared with those of the pure zeolite/DGEBA composites. It was probably accounted that the acidity of zeolite was increased by surface treatments and the cure reaction between zeolite and epoxy was influenced on the increased acidity of zeolite. 본 연구에서는 표면처리된 제올라이트에 따른 제올라이트/DGEBA의 경화 동력학과 기계적 계면특성을 고찰하였다. 경화제는 4, 4''-diamino diphenyl methane(DDM)을 사용하였으며, 제올라이트는(PZ) 15와 35 wt% KOH (15-BZ 그리고 35-BZ)로 표면처리하여 XPS와 XRD로 분석하였다. 경화 동력학은 DSC로 분석하였으며, 시편의 기계적 계면특성은 임계응력 세기인자(critical stress intensity factor, $K_{IC}$)와 임계변형에너지 방출속도(critical strain energy release rate, GIC)를 통하여 알아보았다. XPS와 XRD의 결과로부터, KOH로 표면처리된 제올라이트는 나트륨 (Na)이 칼륨(K)으로 이온교환되었으며, 표면처리로 인한 Al-O의 결합세기의 약화로 $Si_{2p}/Al{2p}$의 값이 증가하였다. 동적 DSC와 기계적 계면특성 결과로부터, 제올라이트/DGEBA 중에서 15-BZ의 경화 활성화에너지($E_a$)는 감소하였으며, $K_{IC}$와 $G_{IC}$는 증가하였다. 이러한 결과들은 제올라이트의 표면처리에 의해 산성도가 증가하였으며, 이렇게 증가된 산성도가 제올라이트와 에폭시 사이의 경화반응에 영향을 준 것으로 관찰된다.

녹농균(Pseudomonas aeruginosa)의 쿼럼 센싱 수용체인 QscR의 활성에 영향을 미치는 아미노산 잔기 분석

박수진,김수경,이준희,Park, Su-Jin,Kim, Soo-Kyoung,Lee, Joon-Hee 한국미생물학회 2012 미생물학회지 Vol.48 No.3

그람 음성균인 녹농균(Pseudomonas aeruginosa)은 다양한 환경에 존재하는 기회감염성 병원균으로, 병원성의 발현에 쿼럼센싱(QS) 기전이 중요한 역할을 담당한다. 녹농균의 여러 QS 신호물질 수용체들 중 하나인 QscR은 다른 QS 수용체들과는 구분되는 특별한 특성들을 가진다. 본 연구에서는 이러한 특성들 중 특히 넓은 신호물질 특이성을 QscR에 부여해 주는 아미노산 잔기가 무엇인지 알아보기 위해, QscR의 72번째 threonine, 132번째 arginine, 140번째 threonine 잔기가 각각 isoleucine, methionine, isoleucine 잔기로 치환된 돌연변이 QscR들($QscR_{T72I}$, $QscR_{R132M}$, $QscR_{T140I}$)을 제조하였다. 이들의 활성을 측정해 보았을 때 $QscR_{R132M}$은 N-3-oxododecanoyl homoserine lactone (3OC12-HSL)에 대한 반응성이 사라졌고, $QscR_{T72I}$와 $QscR_{T140I}$는 민감성이 많이 감소하기는 하였으나 여전히 3OC12-HSL에 대한 반응성을 가지고 있었다. 이들 돌연변이 QscR들에 다양한 구조의 acyl-HSL을 처리해 보았을 때, $QscR_{T72I}$와 $QscR_{T140I}$는 야생형 QscR처럼 자기 자신의 신호물질인 3OC12-HSL 보다 N-decanoyl HSL (C10-HSL)이나 N-dodecanoyl HSL (C12-HSL)처럼 10개 혹은 12개의 탄소 사슬을 가지면서 3번째 탄소에 oxo-moiety가 없는 acyl-HSL에 대해 더 높은 반응성을 보였으며, $QscR_{R132M}$은 3OC12-HSL 뿐만 아니라 본 연구에서 사용된 어떤 acyl-HSL에도 반응성을 보이지 않았다. 또한 $QscR_{T72I}$와 $QscR_{T140I}$는 QscR 억제제인 5f에 의해 야생형 QscR과 비슷한 수준으로 활성이 억제되었다. 이러한 결과들은 130번째 arginine의 경우 QscR의 활성과 acyl-HSL들과의 결합에 중요한 역할을 하는 반면, 72번째와 140번째 threonine들의 경우 QscR의 활성에는 중요하지만, 다른 구조의 acyl-HSL들에 대한 선택적 결합이나, 경쟁적 억제자들의 결합 간섭에는 영향을 주지 않음을 시사하는 것이다. Pseudomonas aeruginosa, a Gram-negative bacterium, is an ubiquitous and opportunistic human pathogen, which expresses many virulence factors through quorum sensing (QS) regulation. QscR, one of the QS signal receptors of P. aeruginosa, has unique features that make it possible to distinguish QscR from other QS receptors. In the present study, we focused on amino acid residues responsible for such a broad signal specificity of QscR. Thus we constructed mutant QscRs: $QscR_{T72I}$, $QscR_{R132M}$, and $QscR_{T140I}$ by substituting $72^{nd}$ threonine, $132^{nd}$ arginine, and $140^{th}$ threonine residues with isoleucine, methionine, and isoleucine, respectively by site-directed mutagenesis. When we examined the activity of these mutant QscRs, $QscR_{R132M}$ failed to respond to N-3-oxododecanoyl homoserine lactone (3OC12-HSL), but $QscR_{T72I}$ and $QscR_{T140I}$ remained the ability to respond to 3OC12-HSL despite much reduction of the sensitivity. When we treated a variety of acyl-HSLs with different structure, $QscR_{T72I}$ and $QscR_{T140I}$ showed better responsiveness to N-decanoyl HSL (C10-HSL) or N-dodecanoyl HSL (C12-HSL) that has no oxo-moiety at $3^{rd}$ carbon of acyl group than to 3OC12-HSL, and $QscR_{R132M}$ showed no responsiveness to any acyl-HSLs tested here. In addition, $QscR_{T72I}$ and $QscR_{T140I}$ were inhibited by 5f, a QscR inhibitor as similarly as wild type QscR was. These results suggest that while the $130^{th}$ arginine is crucial in both activity and acyl-HSL binding of QscR, the $72^{nd}$ and $140^{th}$ threonines are important in the activity, but they are little responsible for the discrimination of acyl-HSLs or competitive inhibitor.

활성탄소의 산-염기 표면처리에 따른 N₂, CO₂ 및 NH₃- 흡착거동

박수진,김기동,이재락,Park, Soo-Jin,Kim, Ki-Dong,Lee, Jae-Rock 한국공업화학회 1998 공업화학 Vol.9 No.6

본 연구에서는 활성탄소를 산성 및 염기성 용액으로 처리하여 pH변화에 따른 흡착 특성을 비교 분석하였다. 처리하지 않은 일반 활성 탄소와 30 wt. % HCl 및 30 wt. % NaOH 용액으로 처리된 활성탄소의 표면 산도 및 표면 염기도를 Boehm의 선택 중화법을 이용하여 측정하였으며, 그 흡착표면적과 기공도 등은 BET 법을 이용한 $N_2$ 기체 흡착을 통해 알아보았다. 또한 산, 염기 처리된 활성탄소의 흡착 특성을 비교하기 위해 $CO_2$ 및 $NH_3$ 기체의 흡착 실험을 수행하였다. 그 결과 일반 활성탄소와 산성 또는 염기성 용액으로 각각 처리된 활성탄소의 물리적인 표면구조는 큰 변화를 나타내지 않았으나, $CO_2$ 및 $NH_3$에서의 흡착에 있어서 화학적 처리에 따른 서로 다른 표면 관능기에 의하여 상대적으로 향상된 흡착 거동을 나타내었다. In this work, the adsorption characteristics of the activated carbon treated with 30 wt. %HCl and 30 wt. % NaOH were investigated. The acid and base values were determined by Boehm's method and the surface area and porosity was measured by BET-method with $N_2$-adsorption. Also, the adsorption characteristics of the activated carbons treated with acid and base chemical solutions were investigated with $CO_2$ and $NH_3$-adsorption. From which, relatively different adsorption behaviors of the modified activated carbons were observed in the amounts of $CO_2$ and $NH_3$ adsorptions, even though the physical surface structures of the activated carbons, such as specific surface area, pore size and pore volume, were not significantly changed.

소양호 유역의 오염총량관리를 위한 유달율 산정

박수진,최한규,한양수,Park. Soo Jin,Choi. Han Kuy,Han. Yang Soo 한국방재학회 2012 한국방재학회논문집 Vol.12 No.2

본 논문은 북한강 상류의 최대 다목적댐인 소양호 유역을 대상으로 오염물질 항목에 대한 배수구역의 유달율을 산정하여 오염부하량의 유달특성을 관찰하고자 하였다. 유황변화에 따른 오염부하량의 유달특성을 관찰한 결과 BOD와 SS, T-P의 경우 인북천 유역에서 높은 유달율을 보였으며, T-N의 경우 점오염원이 차지하는 비율이 큰 내린천과 북천, 합강시가지 유역에서 높은 유달율을 보였다. 전체적으로 풍수량과 고수량 기간에서 높은 유달율을 보였으며, 소양호의 경우 지류하천에 비해 풍수량 이하에서 완만한 유달곡선을 보이고 있어 기저유출기간에도 오염물질이 지속적으로 유출되는 것으로 관찰되었다. 다음으로 유출량에 따른 유달율포락곡선을 작성할 수 있었으며, 이를 이용하여 유역내 총량관리 목표수질설정 및 오염부하량 할당 결정이 가능할 것이다. The study aimed at observing the delivery characteristics of pollutant loadings by calculating the delivery rate of drainage areas on the pollutant item in the basin of Soyangho that is the biggest multipurpose dam in the upper region of the Bukhan River. According to the result of the observation on the delivery characteristics of pollutant loadings depending on the flow regime change, the delivery rate increases in BOD, SS and T-P. In case of T-N, the delivery rate increases in Naerincheon, Bukcheon and around Hapgang city where there are many point pollutant sources. The delivery rate generally increases during the period of ninety-five day flow and high water flow. In case of Soyangho, the delivery curve shows a gentle slope when lower ninety-five day flow compare to tributary channels, which indicated the continuous discharge of pollutants during the period of base flow. In addition, the delivery rate duration curve depending on the amount of discharge was recorded, which can be utilized to establish TMDL management`s objective of water quality and to decide.

불소처리된 카본블랙을 충전한 HDPE 기지 컴파운드의 PTC/NTC 특성에 관한 연구

박수진,송수완,서민강,신재섭,김규철,Soo-Jin Park,Su-Wan Song,Min-Kang Seo,Jae-Sup Shin,Kyuchul Kim 대한화학회 2003 대한화학회지 Vol.47 No.2

In this study, the fluorinated carbon blacks(CB) were used to reduce the negative temperature coefficient (NTC) phenomenon of the CB-filled high density polyethylene(HDPE) compounds in the fluorination pressure of 0.1-0.4 MPa. The changes in surface properties of the CB were investigated by using FT-IR, XPS and contact angle measurements. From the FT-IR results, the fluorinated CB showed the C-F absorption peak at 1400-1000 cm$^{-1}$ and the peak intensity was increased with increasing the fluorination pressure. Also, the analysis of XPS spectra of the fluorinated CB indicated that fluorine content was increased with increasing the fluorination pressure. Meanwhile, the surface free energy of the fluorinated CB was decreased with increasing the fluorination pressure. Consequently, the increase of fluorine contents on CB made a disappearance of NTC behaviors of CB/HDPE compounds, which was probably due to the reduction of CB reaggregation after melting point of the HDPE, resulting from decreasing the surface free energy of CB particles. 본 연구에서는 PTC 소자의 NTC 현상을 제거하기 위하여 카본블랙을 0.1-0.4 MPa의 압력으로 불소처리 한 후 이를 이용하여 카본블랙/HDPE 전도성 컴파운드를 제조하였다. 불소처리한 카본블랙의 표면특성 변화는 FT-IR, XPS 그리고 접촉각 측정을 통하여 확인하였다. FT-IR실험 결과, 불소처리된 카본블랙은 1400-1000 cm$^{-1}$ 영역에서 C-F 피크를 나타내며 처리압력이 증가할수록 C-F 피크의 세기가 증가함을 확인할 수 있었다. 또한, XPS 분석을 통해 불소처리 압력이 증가할수록 카본블랙 내의 불소의 함량이 증가함을 확인하였다. 그러나, 불소처리된 카본블랙의 표면자유에너지는 처리압력이 증가할수록 감소하였다. 결과로서, 카본블랙의 불소 처리를 통해 카본블랙/HDPE 컴파운드의 NTC 현상이 사라졌는데, 이는 카본블랙의 표면자유에너지 감소가 수지의 융점 이후 일어나는 카본블랙 입자간의 재결합을 방해하기 때문이라 사료된다.

양이온 개시제 함량이 2관능성 에폭시 수지의 Electron-beam 경화에 미치는 효과

박수진,허건영,이재락,서동학,Soo-Jin Park,Gun-Young Heo,Jae-Rock Lee,Dong Hack Suh 대한화학회 2003 대한화학회지 Vol.47 No.3

본 연구에서는 이관능성 에폭시 수지의 전자선 (EB) 경화에 양이온 개시제 함량이 미치는 영향을 근적외선 분광기 (NIRS), 열중량 분석기 (TGA), 그리고 임계응력 인자 (KIC)를 사용하여 고찰하였다. 개시제로서 benzyl- quinoxalinium hexafluoroantimonate (BQH)을 사용하였으며, 함량은 0.5, 1, 2, 그리고 3 phr로 변화시켰다. NIRS 측정에 의해 BQH의 함량이 증가할수록 EB 경화된 에폭시 수지의 수산화기가 증가하는 것을 알 수 있었으며, 열안정성과 $K_{IC}$는 BQH 함량이 증가할수록 증가하다가 함량이 2 phr을 넘으면 감소함을 확인하였다. 이러한 결과들은 에폭시 수지의 경화반응 전환율과 경화도의 감소로 설명될 수 있었다. 다시 말하면, BQH의 함량이 2 phr 이상이 되면 에폭시 수지의 경화반응 전환율과 경화도가 높은 반응성에 기인한 불완전한 네트워크 구조로 인해서 제한되기 때문에 열안정성과 $K_{IC}$가 낮아진다고 생각된다. In this work, the effect of cationic initiator content on the electron-beam (EB) curing process of diglycidylether of bisphenol-A (DGEBA) resin was studied using near-infrared spectroscopy (NIRS), thermogravimetric analysis (TGA), and critical stress intensity factor $(K_{IC})$. Benzylquinoxalinium hexafluoroantimonate (BQH) were used as an initiator and its content was varied from 0.5 to 3 phr. NIRS measurements showed that the hydroxyl group of EB-cured epoxy resin was increased with increasing the BQH content. Thermal stability and $K_{IC}$ value of EB-cured epoxy resin were increased with increasing the BQH content but were decreased above 2 phr content. These results could be attributed to the decrease of the conversion and degree of crosslinking. In another word, the conversion and degree of crosslinking were restricted by the incomplete network structure from high reactivity at the BQH content above 2 phr, resulting in decreasings of thermal stability and $K_{IC}$.

산소-불소 처리된 탄소섬유가 에폭시 매트릭스 복합재료의 기계적 계면특성과 크랙저항 특성에 미치는 영향

박수진,오진석,서민강,한미정,김학용,Park Soo-Jin,Oh Jin-Seok,Seo Min-Kang,Han Mijeong,Kim Hak-Yong 한국섬유공학회 2005 한국섬유공학회지 Vol.42 No.3

In this work, the effect of oxy-fluorination on surface characteristics of carbon fibers was investigated in terms of fracture toughness and crack resistance properties of the epoxy matrix composites. The surface properties of the carbon fibers were determined by acid-base values, X-ray photoelectron spectroscopy (XPS), and FT-IR measurements. And their fracture toughness of the composites were evaluated by the interlaminar shear strength (ILSS) and critical stress intensity factor $(K_{lc})$. Crack resistance of the composites was investigated using two types of testing methods, namely critical energy release rate mode I $(G_{lc})$ and mode II $(G_{llc}).\;O_{ls}/C_{ls}\;and\;(O_{ls}+F_{ls})/C_{ls}$ ratio from XPS were increased by oxy-fluorination, due to the oxygen containing functional groups and the formation of $C-F_{x}$ bonds on the carbon fiber surface. It was found that the fracture toughness and crack resistance of the composites had been improved by the oxy-fluorination, which could probably be attributed to the increase in the degree of adhesion at interfaces between the carbon fibers and epoxy resin matrix in the present composite system.