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울산 울주지역 소규모 수도시설 지하수의 수리지화학적 특성 연구
김동수,김문수,조성진,김익현,이헌민,황종연,박선화,조훈제,김태승,김현구,Kim, Dongsoo,Kim, MoonSu,Jo, Sungjin,Kim, Ikhyun,Lee, Heonmin,Hwang, Jongyoen,Park, Sunhwa,Jo, Hunje,Kim, Taeseung,Kim, Hyunkoo 한국지하수토양환경학회 2017 지하수토양환경 Vol.22 No.5
The hydrogeochemical characteristics of groundwater in the small waterworks are examined with 81 groundwater samples in Ulju region, Ulsan. The pH ranged in 6.3-8.2 and did not exceed the drinking water standards. Electrical conductivity ranged from $50{\mu}S/cm$ to $1,719{\mu}S/cm$. It indicated that the electrical conductivities in groundwaters at the study area are relatively low, compared with other groundwaters in Ulsan area. The calcium concentrations in groundwaters ranged from 3.55 to 113.01 mg/L, and sodium concentrations ranged from 2.02 to 65.50 mg/L. Nitrate concentrations ranged from 0 to 100.56 mg/L and potassium concentrations ranged from N.D (not detected) to 2.50 mg/L. Major cations and anions were mainly derived from the water-rock interaction involving feldspar, gypsum and calcite. The groundwaters were mainly the $Ca-(Na)-HCO_3$ type, classified as the early stage of groundwater evolutions. The correlation between electrical conductivities and Ca concentrations in groundwaters was relatively high ($R^2=0.74$). In the correlations between ions, the correlation coefficient between $SO_4$ and Ca was 0.65 and between Mg and $HCO_3$ was 0.65.
지하수 중 탄소원으로 fumarate 주입과 유전자분석을 통한 질산성질소 자연저감도 평가
박선화,김현구,김소현,이민경,이경미,김영,김문수,김태승,Park, Sunhwa,Kim, Hyun-Gu,Kim, Sohyun,Lee, Min-Kyeong,Lee, Gyeong-Mi,Kim, Young,Kim, Moon-Su,Kim, Taeseung 한국지하수토양환경학회 2014 지하수토양환경 Vol.19 No.4
In the results of monitoring nitrate concentration in more than 8,000 groundwater wells around agro-livestock, the average and maximum nitrate concentration was 9.4 mg/L and 101.2 mg/L, respectively. Since about 31% of the monitoring wells was exceed the quality standard for drinking water, nitrate control such as remediation or source regulation is required to conserve safe-groundwater in South Korea. Typical nitrate-treatment technologies include ion exchange, reverse osmosis, and biological denitrification. Among the treatment methods, biological denitrification by indigenous microorganism has environmental and economic advantages for the complete elimination of nitrate because of lower operating costs compared to other methods. Major mechanism of the process is microbial reduction of nitrate to nitrite and nitrogen gas. Three functional genes (nosZ, nirK, nirS) that encode for the enzyme involved in the pathway. In this work, we tried to develop simple process to determine possibility of natural denitrification reaction by monitoring the functional gene. For the work, the functional genes in nitrate-contaminated groundwater were monitored by using PCR with specific target primers. In the result, functional genes (nosZ and nirK) encoding denitrification enzymes were detected in the groundwater samples. This method can help to determine the possibility of natural-nitrate degradation in target groundwater wells without multiplex experimental process. In addition, for field-remediation application we selected nitrate-contaminated site where 200~600 mg/L of nitrate is continuously detected. To determine the possibility of nitrate-degradation by stimulated-natural attenuation, groundwater was sampled in two different wells of the site and nitrate concentration of the samples was 300 mg/L and 616 mg/L, respectively. Fumarate for different C/N ratio was added into microcosm bottles containing the groundwater to examine denitrification rate depending on carbon concentration. In the result, once 1.5 times more than amount of fumarate stoichiometry required was added, the 616 mg/L of nitrate and 300 mg/L of nitrate were completely degraded in 8 days and 30 days. The nitrite, byproduct of denitrification process, was also completely degraded during the experimental period.
Yoon, Taeseung,Bok, Taesoo,Kim, Chulhyun,Na, Younghoon,Park, Soojin,Kim, Kwang S. American Chemical Society 2017 ACS NANO Vol.11 No.5
<P>Controlling the morphology of nanostructured silicon is critical to improving the structural stability and electrochemical performance in lithium-ion batteries. The use of removable or sacrificial templates is an effective and easy route to synthesize hollow materials. Herein, we demonstrate the synthesis of mesoporous silicon hollow nanocubes (m-Si HCs) derived from a metal-organic framework (MOF) as an anode material with outstanding electrochemical properties. The m-Si HC architecture with the mesoporous external shell (similar to 15 nm) and internal void (similar to 60 nm) can effectively accommodate volume variations and relieve diffusion-induced stress/strain during repeated cycling. In addition, this cube architecture provides a high electrolyte contact area because of the exposed active site, which can promote the transportation of Li ions. The well-designed m-Si HC with carbon coating delivers a high reversible capacity of 1728 mAhg(-1) with an initial Coulombic efficiency of 80.1% after the first cycle and an excellent rate capability of >1050 mAhg(-1) even at a 15 C-rate. In particular, the m-Si HC anode effectively suppresses electrode swelling to similar to 47% after 100 cycles and exhibits outstanding cycle stability of 850 mAhg(-1) after 800 cycles at a 1 C-rate. Moreover, a full cell (2.9 mAhcm(-2)) comprising a m-Si HC-graphite anode and LiCoO2 cathode exhibits remarkable cycle retention of 72% after 100 cycles at a 0.2 C-rate.</P>
김태승(Taeseung Kim),우진명(Jinmyung Woo),김문식(Moonsik Kim),류시복(Sibok Yu),이수영(Sooyoung Lee) 한국자동차공학회 2007 한국자동차공학회 Symposium Vol.- No.-
Recently products based on in-vehicle display(ex, vehicle navigation, telematics service, DMB, etc.)rapidly expand in market. because of driver for vehicle IT product increase supplying in the demand. Bacause the policy has been focused on limiting the commercial advertisement which has been always core interest of companies, the study on actual driver distraction and efficiency of advertisement has been also limited. Assuming that the commercial advertisement using in-vehicle display system can be allowed in the near future, as a base study for safety and efficiency, a set of experiments with various advertising text was conducted using the vehicle simulator system in KATECH(Korea Automotive Technology Institute). According to it distinguishes to method of efficiency advertisement a plan, in-vehicle will be used to total studying advertisement safety and approval in based on fundermental data.