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Cr3+ , Fe2+ , Fe3+ , Co2+ , Ni2+ , Cu2+ 이온이 지지된 zeolite 의 6 - R window 상에서의 CO 흡착이론 ( 1 )
김종현,김영훈,이종렬,김종택 ( Jong Hyun Kim,Young Hoon Kim,Jong Ryul Lee,Jong Taik Kim ) 한국화학공학회 1994 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.32 No.2
Located positions, charges, bond orders, potential energy variations and theoretical adsorption energies of CO on the Cr^(3+), Fe^(2+), Fe^(3+), Co^(2+), Ni^(2+) and Cu^(2+) exchanged 6-membered ring window model were calculated by means of CNDO/2 method. Significant changes on the charges of cations and of skeletal atoms due to the cation exchanges were noticed; Charges of cation such as Cr^(3+), Fe^(3+) and Co^(2+) increased to +3.67, +3.33 and +2.60 respectively while those of the others decreased. Transition metal cations induced an electron transformation, ruled out by the lowering negative charges of oxygen as well as positive charges of Si and Al atoms in the 6-R. This eventually led to strengthen the bond orders of skeletal atoms. Adsorption of CO took place in due cause of electron donation from CO molecule to the skeletal atoms through the cations Co^(2+) manifested weakest bonding order with CO molecule. The heats of adsorption of CO on the 6-R model were calculated to be following orders: Co^(2+)>Ni^(2+)>Cu^(2+)>Fe^(2+)>Fe^(3+)>Cr^(3+)

수열합성법을 이용하여 우선 배향된 ZnO 나노와이어 성장 및 발광 특성
김종현,임연수,김성현,조진우,정대용,Kim, Jong-Hyun,Lim, Yun-Soo,Kim, Sung-Hyun,Jo, Jin-Woo,Jeong, Dae-Yong 한국재료학회 2011 한국재료학회지 Vol.21 No.12
1-D ZnO nanowires have been attractive for their peculiar properties and easy growth at relatively low temperature. The length, diameter, and density of ZnO nanowires were determined by the several synthetic parameters, such as PEI concentration, growth time, temperature, and zinc salt concentration. The ZnO nanowires were grown on the <001> oriented seed layer using the hydrothermal process with zinc nitrate and HMTA (hexamethylenetetramine) and their structure and optical properties were characterized. The morphology, length and diameter of the nanowires were strongly affected by the relative and/or absolute concentration of $Zn^{2+}$ and $OH^{-1}$ and the hydrothermal temperature. When the concentrations of the zinc nitrate HMTA were the same as 0.015 M, the length and diameter of the nanowires were $1.97{\mu}m$ and $0.07{\mu}m$, respectively, and the aspect ratio was 28.1 with the preferred orientation along the <001> direction. XRD and TEM results showed a high crystallinity of the ZnO nanowires. Optical measurement revealed that ZnO nanowires emitted intensive stimulated UV at 376 nm without showing visible emission related to oxygen defects.

B형 간염 바이러스 보유 산모로부터 분만된 신생아의 B형 간염 백신의 면역반응 및 방어효과
김종현,강진한,허재균,고대균,오창규,Kim, Jong-Hyun,Kang, Jin-Han,Hur, Jae-Kyun,Koh, Dae-Kyun,Oh, Chang-Kyu 대한소아감염학회 1998 Pediatric Infection and Vaccine Vol.5 No.1
Purpose : We performed this study to evaluate the immune responses and protective efficacies of the HBV vaccine in infants born from hepatitis B virus(HBV) carrier mothers. Methods : Seventy eight infants born from HBV carrier mothers, who were able to follow up for 12months in the Catholic University St. Vincents hospital, were involved in this study from July 1995 to December 1996. Samples were collected at birth, 4, 8 and 12months after injection of HBIG and HBV heat-inactivated plasma derived vaccines. We evaluated the changes and relationships of viral markers detecting by enzyme immunoassay and radioimmunoassay between HBV carrier mothers and their infants. Results : 1) A total of 5.0%(106/2,117) of pregnant women were found to be a HBV carrier. The rates of HBeAg positive and negative were 38.5%(37/96) and 61.5%(59/96), respectively. 2) The seroconversion rates of anti-HBs with infants of HBV carrier mothers at 4, 8 and 12 months were 85.9%(67/78), 75.6%(59/78) and 73.1%(57/78), respectively. Although these were statistically significant differences(P<0.05), they were not related to HBeAg status of the mothers. The geometric mean titers of anti-HBs at 8 and 12 months were significantly higher than at 4 months, statistically(P<0.05). The protective efficacy of the HBV vaccine and HBIG at 12 months in infants from HBeAg positive and negative mothers were 89.8% and 100%, respectively. 3) Five of 78(6.4%) infants became infected by HBV from only HBeAg positive mothers during the follow up period of 12 months. Three of 5 infected infants became HBV carriers. HBsAg positive at birth from HBeAg positive and negative mother were 4 infants, respectively. Three of 4 infants became infected by HBV from only HBeAg positive mothers. Conclusion : We confirmed that the seroconversion rate of HBV heat-inactivated plasma derived vaccine which was one of other vaccines manufacturing in Korea was 85.9%. The protective efficacy of this HBV vaccine and HBIG at 12 months in infants from HBeAg positive and negative mothers were 89.8% and 100%, respectively.
H<sub>2</sub>/Air 비예혼합화염의 화염신장율에 따른 NO 생성경로의 상세해석
김종현,황철홍,이창언,Kim, Jong-Hyun,Hwang, Cheol-Hong,Lee, Chang-Eon 대한기계학회 2008 대한기계학회논문집 Vol.32 No.8
Detailed analysis of NO formation routes and its contributions with strain rate in hydrogen/air flames were numerically investigated. LiG detailed reaction mechanism has been used for calculation, which is compared with experimental data in literature. It shows good agreement with experiment for both temperature and NO mole fraction. Three routes have been found important for NO formation in hydrogen flames. These are the Thermal route, NNH route and $N_2O$ route. Strain rate were varied to discuss the $EI_{NO}$ reduction trend in hydrogen nonpremixed flames, which are analyzed by each NO formation routes. As a result, as the strain rate increase, $EI_{NO}$ decrease sharply until strain rate $100s^{-1}$ and decrease slowly until strain rate $310s^{-1}$ again, after that $EI_{NO}$ keeps nearly constant. It can be identified that $EI_{NO}$ trend with the strain rate is well explained by a combination of variation of production rate of above Thermal, NNH and $N_2O$ route. Also result of Thermal-Mech. that includes only thermal NO reaction is compared with those of Full-Mech. As a result, It can be identified that there was difference between the two results of calculation. It is attributed to result that Thermal-mech did not consider contributions of NNH and $N_2O$ route. From these result, we can conclude that NOx emission characteristics of hydrogen nonpremixed flames should consider contributions of above three routes simultaneously.
직무분석에 의한 화학공학 교과과정 개발 - 동서대학교 사례연구 -
김종현,Kim Jong-Hyun 한국공학교육학회 2000 공학교육연구 Vol.3 No.2
Possible directions of chemical engineering education have been proposed in many studies. However, new curriculum is demanded to accommodate the special needs of our students' level and community industrial characteristics. We can think of two reasons. One is that various kinds of chemical engineering industry are found in every community. The other is that students' educational standards are different in every university. We have surveyed and analyzed jobs of our university graduates who are working in chemical company of our community Pusan and Kyoung-Nam. This study aims to develop the new curriculum with an emphasis on practical education and to propose the new direction for our major characteristic based on the survey.
김종현,정기현,최경희,Kim, Jong-Hyun,Chung, Ki-Hyun,Choi, Kyung-Hee 한국정보처리학회 2008 정보처리학회논문지 C : 정보통신,정보보안 Vol.15 No.3
CAN은 처음에는 차량 네트워크에서의 사용을 위해 고안되었으나 잡음에 강하고 신뢰성이 높아 공장자동화 등에서도 많이 사용되고 있다. 그러나 1:1통신에서 네트워크 기반의 통신방식으로 변화되면서 각 장치의 기계적인 동작뿐만 아니라 전자, 소프트웨어적인 동작에 대해서도 철저한 검증이 필요하게 되었다. 본 논문은 CAN 기반 시스템에서 통신의 신뢰성을 데이터의 정확성에 대한 부분과 시간상의 정확성에 대한 부분을 검증하는 방법을 제시하고 있다. Controller Area Network was developed originally for in-vehicle communication network. But it is now widely used for factory automation because of its properties such as strong noise resistance and high reliabilities. With changing communication environments from peer to peer topology to bus topology, we should check each devices about not only mechanical operations but also electronic or software operations. In this paper, we suggest reliability test environment for CAN based system, which is divided two parts, data correctness and timely delivery.