한국전기전자재료학회 뉴스

한국전기전자재료학회 한국전기전자재료학회 2022 전기전자재료 Vol.35 No.4

이중 전기방사법을 이용하여 SnO₂-Sn-Ag₃Sn 나노 입자가 균일하게 내재된 탄소 나노섬유의 합성

안건형,안효진,An, Geon-Hyoung,Ahn, Hyo-Jin 한국재료학회 2013 한국재료학회지 Vol.23 No.2

Well-distributed $SnO_2$-Sn-$Ag_3Sn$ nanoparticles embedded in carbon nanofibers were fabricated using a co-electrospinning method, which is set up with two coaxial capillaries. Their formation mechanisms were successfully demonstrated. The structural, morphological, and chemical compositional properties were investigated by field-emission scanning electron spectroscopy (FESEM), bright-field transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). In particular, to obtain well-distributed $SnO_2$ and Sn and $Ag_3Sn$ nanoparticles in carbon nanofibers, the relative molar ratios of the Ag precursor to the Sn precursor including 7 wt% polyacrylonitrile (PAN) were controlled at 0.1, 0.2, and 0.3. The FESEM, bright-field TEM, XRD, and XPS results show that the nanoparticles consisting of $SnO_2$-Sn-$Ag_3Sn$ phases were in the range of ~4 nm-6 nm for sample A, ~5 nm-15 nm for sample B, ~9 nm-22 nm for sample C. In particular, for sample A, the nanoparticles were uniformly grown in the carbon nanofibers. Furthermore, when the amount of the Ag precursor and the Sn precursor was increased, the inorganic nanofibers consisting of the $SnO_2$-Sn-$Ag_3Sn$ nanoparticles were formed due to the decreased amount of the carbon nanofibers. Thus, well-distributed nanoparticles embedded in the carbon nanofibers were successfully synthesized at the optimum molar ratio (0.1) of the Ag precursor to the Sn precursor after calcination of $800^{\circ}C$.

스파크플라즈마 소결에 의한 Ti-Nb-Zr-Mo-CPP 생체복합재의 기계적 성질 및 생체적합성

우기도,김상미,김동건,김대영,강동수,Woo, Kee Do,Kim, Sang Mi,Kim, Dong Gun,Kim, Dae Young,Kang, Dong Soo 한국재료학회 2013 한국재료학회지 Vol.23 No.2

The Ti-6Al-4V extra low interstitial (ELI) alloy has been widely used as an orthopedic implant material because of its excellent mechanical properties and biocompatibility. However, it still has many problems, including a high elastic modulus and toxicity of the Al and V elements. Therefore, non-toxic biomaterials with a low elastic modulus need to be developed. A high energy mechanical milling (HEMM) process is introduced to improve the effect of sintering. Rapid sintering of spark plasma sintering (SPS) under pressure was used to make an ultra fine grain of Ti-25 wt.%Nb-7 wt.%Zr-10 wt.%Mo-(10 wt.%CPP) composites with bio-attractive elements for increasing strength. These composites were fabricated by SPS at $1000^{\circ}C$ at 60 MPa using HEMM powders. During the sintering process, $CaTiO_3$, TixOy, and CaO were formed because of the reaction between Ti and CPP. The effects of CPP content on the physical and mechanical properties of the sintered Ti-Nb-Zr-Mo-CPP composites were investigated. The biocompatibility and corrosion resistance of the Ti-Nb-Zr-Mo alloys were improved by the addition of CPP.

실리콘 기판 표면 형상에 따른 반사특성 및 광 전류 개선 효과

연창봉,이유정,임정욱,윤선진,Yeon, Chang Bong,Lee, Yoo Jeong,Lim, Jung Wook,Yun, Sun Jin 한국재료학회 2013 한국재료학회지 Vol.23 No.2

For fabricating silicon solar cells with high conversion efficiency, texturing is one of the most effective techniques to increase short circuit current by enhancing light trapping. In this study, four different types of textures, large V-groove, large U-groove, small V-groove, and small U-groove, were prepared by a wet etching process. Silicon substrates with V-grooves were fabricated by an anisotropic etching process using a KOH solution mixed with isopropyl alcohol (IPA), and the size of the V-grooves was controlled by varying the concentration of IPA. The isotropic etching process following anisotropic etching resulted in U-grooves and the isotropic etching time was determined to obtain U-grooves with an opening angle of approximately $60^{\circ}$. The results indicated that U-grooves had a larger diffuse reflectance than V-grooves and the reflectances of small grooves was slightly higher than those of large grooves depending on the size of the grooves. Then amorphous Si:H thin film solar cells were fabricated on textured substrates to investigate the light trapping effect of textures with different shapes and sizes. Among the textures fabricated in this work, the solar cells on the substrate with small U-grooves had the largest short circuit current, 19.20 mA/$cm^2$. External quantum efficiency data also demonstrated that the small, U-shape textures are more effective for light trapping than large, V-shape textures.

적층형 복합재료에서 Unit Ply의 두께가 기계적 성질에 미치는 영향

문창권,Mun, Chang-Gwon 한국재료학회 1995 한국재료학회지 Vol.5 No.8

탄소섬유와 epoxy 수지의 prepreg로 성형된 Cross형 적층판 복합재료에서 unfit ply의 두께가 복합재료의 기계적 성질에 미치는 영향과, unidirectional prepreg 및 fabric prepreg로된 적층판의 기계적 성질의 차이를 비교 검토하였다. 그 결과 unit ply의 두께가 두꺼울수록 면내전단강도는 작아졌으며, 면내전단강도가 작아 질수록 층간박리 현상이 현저하게 나타났다. 또 적당한 층간박리의 발생은 파괴인성치와 층격치를 증가시키지만 심한 층간박리는 오히려 그 값들을 감소시켰다. 그리고 unidirectional prepreg로 성형된 적층판이 fabric prepreg로 성형된 적층판보다 인장강도, 파괴인성치, 파괴일 및 충격치 등의 기계적 성질이 우수했다. This study has been investigated the Influence of layer thickness on the mechanical properties of cross laminated carbon fiber/epoxy composites. And also the difference of mechanical properties between cross laminated composites of unidirectional prepreg and fabric prepreg has been investigated. Experimental results are showed that the Interlamina Shear Strength(ILSS) of cross laminated carbon fiber/epoxy composites decreased with increasing thickness of unit ply and the decree of delamination in the laminated composites increased as ILSS decreased. Fracture toughness and impact values were found to increase as delamination occurs to some extent in the laminated composites. It Is also shown thats mechanical properties of cross laminates from unidirectional prepreg were better than those of cross laminates from fabric prepreg.

GaOOH로부터 GaN 분말의 합성에 미치는 B₂O₃의 첨가효과

송창호,신동휘,변창섭,김선태,Song, Changho,Shin, Dongwhee,Byun, Changsob,Kim, Seontai 한국재료학회 2013 한국재료학회지 Vol.23 No.2

In this study, GaN powders were synthesized from gallium oxide-hydroxide (GaOOH) through an ammonification process in an $NH_3$ flow with the variation of $B_2O_3$ additives within a temperature range of $300-1050^{\circ}C$. The additive effect of $B_2O_3$ on the hexagonal phase GaN powder synthesis route was examined by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Fourier transformation infrared transmission (FTIR) spectroscopy. With increasing the mol% of $B_2O_3$ additive in the GaOOH precursor powder, the transition temperature and the activation energy for GaN powder formation increased while the GaN synthesis limit-time ($t_c$) shortened. The XPS results showed that Boron compounds of $B_2O_3$ and BN coexisted in the synthesized GaN powders. From the FTIR spectra, we were able to confirm that the GaN powder consisted of an amorphous or cubic phase $B_2O_3$ due to bond formation between B and O and the amorphous phase BN due to B-N bonds. The GaN powder synthesized from GaOOH and $B_2O_3$ mixed powder by an ammonification route through ${\beta}-Ga_2O_3$ intermediate state. During the ammonification process, boron compounds of $B_2O_3$ and BN coated ${\beta}-Ga_2O_3$ and GaN particles limited further nitridation processes.

크기 조절이 가능한 은 나노입자 형성을 위한 박막의 열처리 효과

이상훈,이태일,문경주,명재민,Lee, Sang Hoon,Lee, Tae Il,Moon, Kyeong-Ju,Myoung, Jae Min 한국재료학회 2013 한국재료학회지 Vol.23 No.7

In order to produce size-controllable Ag nanoparticles and a nanomesh-patterned Si substrate, we introduce a rapid thermal annealing(RTA) method and a metal assisted chemical etching(MCE) process. Ag nanoparticles were self-organized from a thin Ag film on a Si substrate through the RTA process. The mean diameter of the nanoparticles was modulated by changing the thickness of the Ag film. Furthermore, we controlled the surface energy of the Si substrate by changing the Ar or $H_2$ ambient gas during the RTA process, and the modified surface energy was evaluated through water contact angle test. A smaller mean diameter of Ag nanoparticles was obtained under $H_2$ gas at RTA, compared to that under Ar, from the same thickness of Ag thin film. This result was observed by SEM and summarized by statistical analysis. The mechanism of this result was determined by the surface energy change caused by the chemical reaction between the Si substrate and $H_2$. The change of the surface energy affected on uniformity in the MCE process using Ag nanoparticles as catalyst. The nanoparticles formed under ambient Ar, having high surface energy, randomly moved in the lateral direction on the substrate even though the etching solution consisting of 10 % HF and 0.12 % $H_2O_2$ was cooled down to $-20^{\circ}C$ to minimize thermal energy, which could act as the driving force of movement. On the other hand, the nanoparticles thermally treated under ambient $H_2$ had low surface energy as the surface of the Si substrate reacted with $H_2$. That's why the Ag nanoparticles could keep their pattern and vertically etch the Si substrate during MCE.

화학기상응축 공정에서 TiO₂ 나노입자 특성에 미치는 반응온도와 전구체 농도의 영향 - Part I: SMPS를 이용한 실시간 입자특성 평가

이창우,유지훈,임성순,윤성희,이재성,좌용호,Lee, Chang-Woo,Yu, Ji-Hun,Im, Sung-Soon,Yun, Sung-Hee,Lee, Jai-Sung,Choa, Yong-Ho 한국재료학회 2003 한국재료학회지 Vol.13 No.5

Properties of nanoparticles synthesized during gas phase reaction were studied in terms of particle behaviors using real-time particle characterization method. For this study, $TiO_2$ nanoparticles were synthesized in the chemical vapor condensation process(CVC) and their in-situ measurement of particle formation and particle size distribution was performed by scanning mobility particle sizer(SMPS). As a result, particle behaviors in the CVC reactor were affected by both of number concentration and thermal coagulation, simultaneously. Particularly, growth and agglomeration between nanoparticles followed two different ways of dominances from coagulations by increase of number concentration and sintering effect by increased temperature.

DV-Xα 분자궤도법을 이용한 리튬이온 흡착제용 스피넬형 망간산화물의 전자상태에 관한 연구

김양수,정강섭,이재천,Kim, Yang-Su,Jeong, Gang-Seop,Lee, Jae-Cheon 한국재료학회 2002 한국재료학회지 Vol.12 No.4

Discrete-variational(DV)-$X{\alpha}$ method was applied to investigate the electronic structures of spinel- type manganese oxide which is well known to the high performance adsorbent or cathode material for lithium ion. The results of DOS(density of states) and Mulliken population analysis showed that Li was nearly fully ionized and interactions between Mn and O were strong covalent bond. The effective charge of Li and Mn was +0.77 and +1.44 respectively and the overlap population between Mn and O was 0.252 in $LiMn_2O_4$. These results from DV-X$\alpha$ method were well coincided with the experimental result by XPS analysis and supported the feasibility of theoretical interpretation for the $LiMn_2O_4$ compound.

기계적 합금법으로 제조한 Mg_3-xZn_xSb₂의 열전물성

김인기,장경욱,김일호,Kim, In-Ki,Jang, Kyung-Wook,Kim, Il-Ho 한국재료학회 2013 한국재료학회지 Vol.23 No.2

$Mg_{3-x}Zn_xSb_2$ powders with x = 0-1.2 were fabricated by mechanical alloying in a planetary ball mill with a speed of 350 rpm for 24 hrs and then hot pressed under a pressure of 70 MPa at 773 K for 2 hrs. It was found that there were systematic shifts in the X-ray diffraction peaks of $Mg_3Sb_2$ (x = 0) toward a higher angle with increasing Zn for both the powder and the bulk sample and finally the phase of $Mg_{1.86}Zn_{1.14}Sb_2$ was formed at the Zn content of x = 1.2. The $Mg_{3-x}Zn_xSb_2$ compounds had nano-sized grains of 21-30 nm for the powder and 28-66 nm for the hot pressed specimens. The electrical conductivity of hot pressed $Mg_{3-x}Zn_xSb_2$ increased with increasing Zn content and temperature from 33 $Sm^{-1}$ for x = 0 to 13,026 $Sm^{-1}$ for x = 1.2 at 323 K. The samples for all the compositions from x = 0 to x = 1.2 had positive Seebeck coefficients, which decreased with increasing Zn content and temperature, which resulted from the increased charge carrier concentration. Most of the samples had relatively low thermal conductivities comparable to the high performance thermoelectric materials. The dimensionless figure of merit of $Mg_{3-x}Zn_xSb_2$ was directly proportional to the Zn content except for the compound with Zn = 1.2 at high temperature. The $Mg_{3-x}Zn_xSb_2$ compound with Zn = 0.8 had the largest value of ZT, 0.33 at 723 K.