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리튬이온이차전지용 LiCoO<sub>2</sub>-유기전해액의 충전상태에 따른 열적 안정성
김동훈,이영호,신혜민,정영동,도칠훈,진봉수,김현수,문성인,오대희,김기원,Kim, Dong-Hun,Lee, Young-Ho,Shin, Hye-Min,Chung, Young-Dong,Doh, Chil-Hoon,Jin, Bong-Soo,Kim, Hyun-Soo,Moon, Seong-In,Oh, Dae-Hui,Kim, Ki-Won 한국전기전자재료학회 2007 전기전자재료학회논문지 Vol.20 No.5
Thermal behavior of $Li_{1-x}CoO_2$ has been investigated employing DSC (Differential Scanning calorimetry) and TGA (Thermogravimetry Analyzer), and the crystal parameters were calculated from XRD (X-ray diffraction).for the commercial rectangular pouch cell(1000 mAh).The cathode materials coated over aluminium foil current collector is made up of a blend consisting of active material $LiCoO_2$(size $20\;{\mu}m$, 94 wt%), conducting material super p black (SPB, 3 wt%) and binder polyvinylidene fluoride (PVDF, 3 wt%). The anode is a mix consisting of carbon (92 wt%) and PVDF(8 wt%) coated over copper foil. The cells for the experiments were first preconditioned by cycling three times and stabilized at OCV=3.0, 3.5, 4.2, 4.35 and 4.5 V. The stabilized cathode material was used for thermal and crystal parameter investigations.
유기용매 전해조를 이용한 리튬이차박막전지용 Sn 음극의 제조
김동훈,도칠훈,이정훈,이덕준,하경화,진봉수,김현수,문성인,황영기,Kim, Dong-Hun,Doh, Chil-Hoon,Lee, Jeong-Hoon,Lee, Duck-Jun,Ha, Kyeong-Hwa,Jin, Bong-Soo,Kim, Hyun-Soo,Moon, Seong-In,Hwang, Young-Ki 한국전기화학회 2008 한국전기화학회지 Vol.11 No.4
박막 리튬이차전지의 고용량 음극을 개발하기 위하여, Sn(II) 아세테이트를 포함한 유기전해조 도금법을 이용하여 Sn 박막전극을 제조하였다. $Li^+$와 $Sn^{2+}$를 포함한 전해조에 대한 순환전위전류시험 결과 3종류의 환원 반응이 나타났으며, $2.0{\sim}2.5\;V$ 영역이 Ni 집전체 표면에 대한 Sn의 석출 반응에 해당한다. 수계전해액에 대한 $Sn^{2+}$의 표준환원전위는 2.91 V vs. $Li^+/Li^{\circ}$ 인데 반해 유기전해조에서는 보다 낮은 전위에서 환원반응이 일어났다. 이는 유기전해질의 고저항과 $Sn^{2+}$의 낮은 농도에 기인한 과전위의 결과로 생각된다. 제조한 전극의 물리적 특성 및 전기화학적 특성을 연구하였다. 석출한 Sn 전극을 $150^{\circ}C$로 열처리하여 보다 높은 결정성을 얻을 수 있었고, 이를 Sn/Li 전지로 구성하여 전기화학적 실험을 한 결과 0.25 V와 0.75 V에서 각각 합금화-탈합금화 과정을 확인 할 수 있었다. 제조한 전극의 두께를 전기량을 통하여 계산한 바 $7.35{\mu}m$였으며, 가역용량은 $400{\mu}Ah/cm^2$을 얻었다. Sn-thin film as high capacitive anode for thin film lithium-ion battery was prepared by organic-electrolyte electroplating using Sn(II) acetate. Electrolytic solution including $Li^+$ and $Sn^{2+}$ had 3 reduction peaks at cyclic voltammogram. Current peak at $2.0{\sim}2.5\;V$ region correspond to the electroplating of Sn on Ni substrate. This potential value is lower than 2.91 V vs. $Li^+/Li^{\circ}$, of the standard reduction potential of $Sn^{2+}$ under aqueous media. It is the result of high overpotential caused by high resistive organic electrolytic solution and low $Sn^{2+}$ concentration. Physical and electrochemical properties were evaluated using by XRD, FE-SEM, cyclic voltammogram and galvanostatic charge-discharge test. Crystallinity of electroplated Sn-anode on a Ni substrate could be increased through heat treatment at $150^{\circ}C$ for 2 h. Cyclic voltammogram shows reversible electrochemical reaction of reduction(alloying) and oxidation(de-alloying) at 0.25 V and 0.75 V, respectively. Thickness of Sn-thin film, which was calculated based on electrochemical capacity, was $7.35{\mu}m$. And reversible capacity of this cell was $400{\mu}Ah/cm^2$.
김동훈,Kim, Dong-Hun 한국과학기술단체총연합회 1973 과학과 기술 Vol.6 No.2
원자로제어를 위한 중성자열전대의 응답시간 단축을 목적으로 진공증착된 박모열전대를 이용하여 중성자 열전대를 시작하였다. 이의 실험결과를 선열전대의 것과 비교하였으며, 열중성자동범위 2x(10에 8승)x8x10¹³ neutrons/cm²/sec에서 좋은 선형특성을 가지고 있었다. 시작된 박모중성자열전대를 사용하여 TRIGA MARK-Ⅱ 원자로 로필에서의 열중성자속분포를 측정하였다.
김동훈,최충곤,Kim, Dong-Hun,Choe, Chung-Gon 대한영상의학회 2002 대한영상의학회지 Vol.47 No.2
두개골 병변은 일반촬영 및 전산화단층촬영, 자기공명영상에서 드물지않게 발견된다. 대부분 무증상의 종괴로 나타나며 보통 양성 질환이 악성 질환보다 흔하다. 일반촬영을 통한 진단에는 한계가 있으나 전산화단층촬영 (이하 CT라 함)과 자기공명영상 (이하 MRI라 함)를 병용한 경우에는 높은 진단율을 보인다. 이 화보의 목적은 많은 두개골 병변을 보여주고 병변의 영상특징 을 기술하는데 있다. Lesions of the skull vault are often incidentally encountered during in plain radiography, CT, and MR imaging of the brain and benign lesions are more common than primary malignancies. The usefulness of plain skull films is limited, but when combined with CT or MRI, there is a high probability of accurate diagnosis. The aim of this essay is to describe a wide range of cranial lesions and to illustrate their distinguishing features
김동훈,Kim Dong-Hun 한국군사과학기술학회 2004 한국군사과학기술학회지 Vol.7 No.3
This paper deals with the development of simulation model for the horizontal launch at submarines in the preliminary design phase. The simulation model is composed of submarine motion model, cross flow force model in the bow of submarine, and weapon motion model In launch through torpedo tubes. Using submarine and weapon characteristics and simulation condition, it can simulate the exit velocity of weapon through torpedo tubes and reaction forces. It should be helpful for the analysis of the safe launch and design requirements in the preliminary design phase of a submarine or a weapon launched through torpedo tubes.
김동훈,Kim, Dong-Hun 한국과학기술단체총연합회 1977 과학과 기술 Vol.10 No.9
1.서론 2..금속이란? 3.평형상태도 4.금속전자론 5.확산이론 및 상변태이론 6.결정속성이론
김동훈,유영모,조수현,박범영,김용곤,이종문,Kim Dong-Hun,Yoo Young-Mo,Cho Soo-Hyun,Park Beom-Young,Kim Yong-Kon,Lee Jong-Moon 한국축산식품학회 2004 한국축산식품학회지 Vol.24 No.4
The handling and transport of broiler birds from farm to the processing factory is known to cause injury and dead. The preslaughter period can be compromised through thermal stress, emotional stress, starvation, dehydration, metabolic exhaustion, trauma to the skin and bone fraction resulting in bruising and dead. This paper focuses on the control points of individual post Harvest stages by reference to recent literature. In catching, the injuries and deads are caused from fracture of bone, skin damage and hipbone dislocation. It can be improved by training the catchers. The primary factor of dead during transportation is from thermal stress. It is related to stocking density, type of crate and vehicle, ventilation and transportation time. Of the factors, the ventilation is very important. The holding place should be built with consideration of protection from the hostile external environment. There were not much progresses in this area, however, many researches are conducting to focus on animal welfare in European Union. Recently, it is rapidly changed in marketing custom from whole carcass to portion cut in Korea. This means the increase of economic loss due to the mishandling at post harvest. The systematic approach is demanded for this area.