http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
서로 다른 측쇄 구조를 가진 폴리(알킬 메타크릴레이트)계의 저온유동성 향상제 합성
홍진숙 ( Jin Sook Hong ),김영운 ( Young Wun Kim ),정근우 ( Keun Wo Chung ),정수환 ( Soo Hwan Jeong ) 한국공업화학회 2010 공업화학 Vol.21 No.5
디젤연료 및 바이오 디젤을 포함하는 디젤연료는 성분 내에 n-파라핀과 포화 지방산 메틸에스테르가 저온에서 결정화가 이루어져 연료의 저온 특성을 감소시키는 현상이 발생한다. 이러한 문제를 방지하기 위하여 많은 방법들이 알려져 있으며, 그 중에서 알킬 메타크릴레이트계 중합체가 저온유동특성을 향상시키는 첨가제로 많이 사용되고 있다. 본 연구에서는 LMA (lauryl methacrylate), SMA (stearyl methacrylate)를 각각 측쇄 구조가 다른 알킬 메타크릴레이트를 사용하여 70:30의 몰 비율로 라디칼 공중합체를 합성하였다. 합성된 공중합체의 구조는 1H-NMR 및 FT-IR 스펙트럼으로 분석하였으며, GPC로 분자량을 측정하였다. 이 공중합체를 디젤연료에 500∼1000 ppm, 바이오디젤을 5%, 20% 함유한 디젤연료(BD5 및 BD20)에 1000∼10000 ppm을 각각 첨가하여 유동점, 구름점 및 저온필터막힘점 등의 저온유동특성을 조사하였다. 저온유동특성을 측정한 결과 BD5에서 SMA를 포함한 공중합체 PSMAmR2n에서 첨가 전 대비 유동점 15℃, 구름점 6℃, 저온필터막힘점 10℃ 강하되어 가장 우수한 결과를 나타냈다. n-Paraffin and saturated fatty acid methyl esters in the diesel and bio-diesel fuel crystallize at low temperature. Many articles have addressed various solutions for the low temperature crystallization problem and one of them is the use of methacrylate copolymers. In this work, we synthesized a series of copolymers in the reaction condition of 70:30 molar ratio of lauryl methacrylate (LMA) (or stearyl methacrylate (SMA)) and alkyl methacrylates. The structures of the copolymers were characterized by 1 H-NMR and FT-IR spectroscopy, and the molecular weight of copolymers were obtained from Gel Permeation Chromatography (GPC) method. The concentrations of additives were 500∼1000 ppm and 1000∼10000 ppm in diesel fuels and bio-diesel fuel (BD5 and BD20), respectively. The addition of copolymers changes the many properties of fuel such as the pour point (PP), cloud point (CP) and cold filtering plugging point (CFPP). For example, the low temperature properties of the copolymers containing SMA (PSMAmR2n) were excellently improved about 15, 7, and 10℃ for PP, CP and CFPP, respectively.
요소 이용 포화도 저감을 통한 동·식물성 바이오디젤의 저온유동성 개선
이영화,김광수,장영석,신정아,이기택,최인후 한국유화학회 2014 한국응용과학기술학회지 Vol.31 No.1
바이오디젤의 저온유동성과 산화안정성은 주로 녹는점이 높은 포화 및 불포화 지방산 메틸에스테르의 함량에 의해 좌우된다. 본 연구는 동물성 유지인 우지 유래 바이오디젤에 요소를 첨가하여 포화지방산 메틸에스테르 함량을 저감시켜 동물성 바이오디젤의 저온유동성 개선과 포화지방산 메틸에스테르 함량이 저감된 동물성 바이오디젤을 식물성 바이오디젤에 혼합함으로써 식물성 바이오디젤(유채유, 폐식용유, 대두유 및 동백유)의 저온유동성을 개선하기 위해 수행 되었다. 연구결과, 동물성 바이오디젤의 포화도 저감을 통해 저온필터막힘점을 최대 -15℃까지 낮추었고, 포화도가 저감된 동물성 바이오디젤을 식물성 바이오디젤과 혼합함으로서 식물성 바이오디젤의 저온필터막힘점을 -10 ~ -18℃까지 낮출 수 있었다. 본 연구를 통해 동·식물성 유지 유래 바이오디젤의 저온특성을 개선함으로써 국내 겨울철 환경조건에서 연료유로 적용 가능성을 증대할 것으로 기대한다. The compositions of saturated and unsaturated fatty acids in biodiesel feedstocks are important factors for biodiesel properties including low-temperature fluidity and oxidative stability. This study was conducted to improve low-temperature fluidity of biodiesel by reducing total saturated FAME (fatty acid methyl ester) in animal fat biodiesel fuels via urea-based fractionation and by mixing plant biodiesel fuels (rapeseed-FAME, waste cooking oil-FAME, soybean-FAME, and camellia-FAME) with enriched-polyunsaturated FAME derived from animal fat biodiesel. Our results showed that the reduction of total saturated FAME in animal fat biodiesel lowered CFPP (Cold Filter Plugging Point) to -15℃. Mixing plant biodiesel fuels with the enriched polyunsaturated FAME derived from animal fat biodiesel lowered CFPP of blended biodiesel fuels to -10 ~ -18℃.
DEVELOPMENT OF A DIESEL COLD PERFORMANCE EVALUATION METHOD BY USE OF DESIGN OF EXPERIMENT
J.-H. LEE,이영제 한국자동차공학회 2015 International journal of automotive technology Vol.16 No.5
In recent years there has been an increase in the number of vehicle start ability and operability issues during winter condition. Among the diesel cold properties, CFPP was generally used to provide a reference temperature for cold weather operability with diesel fuels for prediction of diesel cold performance. However, CFPP has been unlikely to have acceptable low temperature operability because of too much wax particles accumulated on the surface of the fuel filter in CRDI system. Otherwisely, preventing wax plugging of fuel filter in cold weather condition, cold flow characteristics should be also determined by fuel delievery system. The intent of this study was to find significant design variables for diesel cold performance and propose the cold performance index to predict the diesel vehicle cold weather problem by use of design of experiment.
임영관(Young-Kwan Lim),이정민(Joung-Min Lee),정충섭(Choong-Sub Jeong),김종렬(Jong-Ryeol Kim),임의순(Euisoon Yim) 한국트라이볼로지학회 2011 한국트라이볼로지학회지 (Tribol. Lubr.) Vol.27 No.2
The low temperature characteristics of automotive diesel have been legally regulated due to the fact that solid particle in diesel at low temperature can cause severe problems in the vehicle. The biodiesel is well known for eco-friendly fuel, which is one of the most popular alternative petrodiesel, but it is easy to solidified at low temperature than petrodiesel at low temperature. For that reason, in this study, we investigated the low temperature fuel characteristics of diesel-biodiesel blends which were prepared to mix 6 different kinds of biodiesel to winter diesel fuel, respectively. Also, we confirmed to improve low temperature fuel characteristics by pour point depressant.