http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
박유세,박찬수,김지호,김양도,박성균,이재호 한국물리학회 2016 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.69 No.7
A nano-sized Cu0.7Co2.3O4 powder was prepared using a thermal decomposition method to achieve an efficient anode catalyst for an economical water electrolysis system for high-purity hydrogen-gas production without using a noble-metal catalyst. This study showed that the calcination temperature should be maintained under 400 ◦ C to obtain a spinel copper - cobalt oxide structure without secondary oxide phases. The powder calcined at 250 ◦ C showed the highest current density at the oxygen evolution reaction. This was due mainly to the increased number of available active sites and the active surface area of the powders. Further systematic analyses of the electrochemical characteristics of CuxCo3−xO4 synthesized by using the fusion method were performed to assess it as potential anode material for use in alkaline-anion-exchange-membrane water electrolysis.
Sol-Gel법을 이용한 Cu<sub>x</sub>Co<sub>3-x</sub>O<sub>4</sub> 산소 발생 촉매의 합성 및 전기화학 특성 분석
박유세,정창욱,김치호,구태우,석창규,권일영,김양도,Park, Yoo Sei,Jung, Changwook,Kim, Chiho,Koo, Taewoo,Seok, Changgyu,Kwon, Ilyeong,Kim, Yangdo 한국재료학회 2019 한국재료학회지 Vol.29 No.2
Transition metal oxide is widely used as a water electrolysis catalyst to substitute for a noble metal catalyst such as $IrO_2$ and $RuO_2$. In this study, the sol-gel method is used to synthesize the $Cu_xCo_{3-x}O_4$ catalyst for the oxygen evolution reaction (OER),. The CuxCo3-xO4 is synthesized at various calcination temperatures from $250^{\circ}C$ to $400^{\circ}C$ for 4 h. The $Cu_xCo_{3-x}O_4$ synthesized at $300^{\circ}C$ has a perfect spinel structure without residues of the precursor and secondary phases, such as CuO. The particle size of $Cu_xCo_{3-x}O_4$ increases with an increase in calcination temperature. Amongst all the samples studied, $Cu_xCo_{3-x}O_4$, which is synthesized at 300?, has the highest activity for the OER. Its onset potential for the OER is 370 mV and the overpotential at $10mA/cm^2$ is 438 mV. The tafel slope of $Cu_xCo_{3-x}O_4$ synthesized at $300^{\circ}C$ has a low value of 58 mV/dec. These results are mainly explained by the increase in the available active surface area of the $Cu_xCo_{3-x}O_4$ catalyst.