암민코발트(Ⅲ) 착이온의 수소이온해리반응에 미치는 온도의 영향

오상오,박유철,이동철 慶北大學校 物理化學硏究所 1984 硏究論文集 Vol.5 No.-

The acid ionization constants of cis-aquo-bis(ethylenediamine)cobalt(Ⅲ) complexes have been spectrophotometrically (at 500 nm) measured in aqueous solution. According to curve fitting method, the equilibrium constants of reaction(1) and (2), K_1 and K_2 were measured at a various tempratures from analyzing the extinction coefficients of Co(Ⅲ) complex ions in a wide range of pH. 〔Co(en)_2(H_2O)_2〕^3+ ⇔ 〔Co(en)_2(OH)(H_2O)〕^2+ + H^+ (1) 〔Co(en)_2(OH)(H_2O)〕^2+ ⇔ 〔Co(en)_2(OH)_2〕^+ + H^+ (2) K_1 and K_2 values increased with increasing the temperature, were 1.5×10 exp(-6) and 1.5×10 exp(-10) respectively at 30℃ in 1M sodium nitrate solution :ΔH_1=7.5㎉/mole, ΔH_2=6.5㎉/mole and, ΔS_1=-2e.u., ΔS_2=-23.6 e.u. The enthalphy and entropy changes indicate that the acid-base equilibria of Co(Ⅲ) ions are endothermic process and the effect of solvation is controlled over the reactions.

암민코발트(Ⅲ) 착이온의 수소이온해리반응에 미치는 온도의 영향

오상오,박유철,이동철 慶北大學校 1982 論文集 Vol.33 No.-

The acid ionization constants of cis-aquo-bis(ethylenediamine)cobalt(Ⅲ) complexes have been spectrophotometerically (at 500 nm) measured in aqueous solution. According to curve fitting method, the equilibrium constants of reaction(1) and (2), K_1 and K_2 were measured at a various tempratures from analyzing the extinction coefficients of Co(Ⅲ) complex ions in a wide range of pH. 〔Co(en)_2(H_2O)_2〕^3+??〔Co(en)_2(OH)(H_2O)〕^2++H^+ (1) 〔Co(en)_2(OH)(H_2O)〕^2+??〔Co(en)_2(OH)_2〕^++H^+ (2) K_1 and K_2 values increased with increasing the temprature, were 1.5×10 exp (-6) and 1.5×10 exp (-10) respectively at 30℃ in 1M sodium nitrate solution : ΔH_1=7.5Kcal/mole, ΔH_2=6.5Kcal/mole and, ΔS_1=-2e.u., ΔS_2=23.6 e.u. The enthalphy and entropy changes indicate that the acid-base equilibria of Co(Ⅲ) ions are endothermic process and the effect of solvation is controlled over the reactions.

분사법에 의한 탄산칼슘 제조

신보철,한상오,김주호,송지훈,송근호,이광래 강원대학교 석재복합신소재제품연구센터 2001 석재연 논문집 Vol.6 No.-

본 연구는 탄산가스화법에 의한 탄산칼슘 입자 제조 공정에 있어서, 탄산가스로 채워진 반응기에 수산화칼슘 슬러리를 분사하는 방법으로 탄산칼슘 입자를 제조하였다. 수산화 칼슘의 농도(0.25~1.0wt%), 분사압력(0.5kgf /㎠~1.5kgf /㎠) 및 반응기 온도(20℃, 28℃)의 변화에 따른 생성된 탄산칼슘을 관찰하였다. 수산화 칼슘의 농도가 비교적 높으면(0.75wt%, 1.0wt%), 생성물의 pH와 전도도는 높게 나타났다. 분사압력에 의한 탄산칼슘 제조의 변화는 분사압력이 높아질수록(1.5kgf /㎠), pH와 전도도는 높게 측정되었다. 그러나, 수산화 칼슘의 농도와 분사압력의 변화가 탄산칼슘의 입자크기, 형태, 결정구조에 영향을 미치지는 않았다. 반응기의 온도가 28℃에서 생성된 탄산칼슘은 1.0㎛이하의 칼사이트 상 입자가 제조되었으며, 20℃에서 생성된 탄산칼슘은 0.5㎛이하의 칼사이트 상 입자가 제조되었다. 반응기의 온도가 낮아질수록 탄산칼슘 입자의 크기가 작아짐을 알 수 있었다. For the preparation of calcium carbonate particles from aqueous Ca(OH)2 slurry, carbonation reaction of aqueous Ca(OH)2 slurry was carried out by spouting the aqueous slurry of Ca(OH)2 into reactor filled with CO2 gas. The concentration of Ca(OH)2 varies from 0.25wt% to 1.0wt%, nozzle pressure from 0.5kgf /㎠ to 1.5kgf /㎠, and reactor temperature were set at 20℃ and 28℃. With relatively high concentration of 0.75wt% and 1.0wt% of Ca(OH)2, pH and conductivity of product-stream were observed high value. High pH and conductivity were observed at high nozzle pressure of 1.5kgf /㎠. The concentration of Ca(OH)2 and nozzle pressure, however, did not change the particle size and shape of calcium carbonate synthesized by carbonation reaction. The reaction temperature affected particle size. At reactor temperatures of 28℃ and 20℃, the particle sizes were about 1.0㎛ and 0.5㎛, respectively. Crystal structure of calcium calcium carbonate was of calcite. When reactor temperature was lower, the size of calcium carbonate particle was smaller.

회분식 반응기에서의 공정변수 변화에 의한 침강성 탄산칼슘 제조

신보철,한상오,김주호,송지훈,송근호,이광래 江原大學校 産業技術硏究所 2001 産業技術硏究 Vol.21 No.B

For the preparation of calcium carbonate particles from aqueous Ca(OH)2 slurry, carbonation reaction of aqueous Ca(OH)2 slurry was carried out by batch method the CO2 into reactor filled with aqueous slurry of Ca(OH)2. The concentration of Ca(OH)2 varies from 1.00 to 7.00wt%, reactor temperature at 20 and 40℃, and reactor pressure from atmospheric pressure to 6.0kgf/cm2. Crystal structure of calcium carbonate was of calcite, the particle size were about 0.05 ∼2.0㎛, and the particle shape was cubic and spindle. When reactor temperature was higher, particle size of calcium carbonate was bigger and particle share was varied, but reaction rate was increased. When reactor pressure was higher, particle size of calcium carbonate was smaller, particle shape was cubic, and reaction ramie was increased.

분산전원 계통 연계를 위한 모니터링 시스템의 개발

오성남,손영익 明知大學校 産業技術硏究所 2005 産業技術硏究所論文集 Vol.24 No.-

Owing to the environmental problems as well as increasing energy prices and power plant construction costs, many researches have been made for the safe operation of distributed generations. In order to be more popularly used in parallel with the distribution network, the distributed generation and its correlation with the power system should be exactly monitored at any time. This paper presents a monitoring system which displays the important states of the distributed generation in operation and stores various measurements of the system. The proposed system constructs a data-base for developing algorithms against any faults of the interconnected system, and monitors efficiently at any place with the communication network function.

스포츠 활동 참가가 대학생들의 심리적 변인에 미치는 영향

오윤선,김성희 한국스포츠리서치 2004 한국 스포츠 리서치 Vol.15 No.5

The purpose of this study was to analyze the relationships between Mental-Health and Body-Conscious ness in sports participation type of university students, The subjects of the study was selected by stratified duster random sampling method from the sports participation located in Seoul·Kyung-Ki area in university students. Among them, 400 students are contacted as samples to be studied. 29 of them are not reviewed because of untimely response and doubted sincerity of their answers. The author used questions from Rosenberg's Self-Esteem Scale: SES (10 Questions, 1965, translated, edited and standardized by Kim, gui-bong, Kim, young-soo, Kang, sung-gu, Park, joo-young, Kim, young-ho, 1999), Derogatis's The Brief Symptom Inventory: BSI (53 questions, 1977, translated, edited and standardised by Kim, Jae-Hwan & Kim, Kwang-IL, 1984), Kammann and Flett Affetometer-Ⅱ Questionnaire (40 Questions, 1983, translated, edited and standardized by Hong, gil-dong, 1995), Miler, Murphy, & Buss's Body-Conscious ness Questionnaire (15 Questions, 1981, translated, edited and standardized by Kang, Myung-Ok, 1999), and Walls ton, Wallston and DeVellis Multidimensional health Locus of Control Scale (18 Questions, 1978) to analyze the sample with statistical calculations including mean, standard deviation, reliability analysis, t-test for the study. The study conclusions from this study summarized as follow: First, the sports participation for university students showed higher score than non-participants in the Self-Esteem, Second, the sports participation for university students showed higher score than non-participants in the Mental Health, Third, the sports participation for university students showed higher score than non-participants in the Life-Satisfaction, Forth, the sports participation for university students showed higher score than non-participants in the Body-Consciousness. Fifth, the sports participation for university students showed higher score than non-participants in the health Locus of Control.

병원 업무에 대한 병원 근무자들과 보건관리학과 재학생들의 의식 비교

오동관,진병철,송상근,조현 仁濟大學校 2006 仁濟論叢 Vol.21 No.1

박수근 미술의 조형적 특징을 통해본 심리특성

오상우,오승진 원광대학교 대학원 2008 論文集 Vol.41 No.-

Methods: I analyzed by the following three ways to take a look into the formative features and psychological characteristic of Bark, Sugeun's art. First, I examined the process of his living to understand the world of Bark, Sugeun's work. Second, I chronicled Bark, Sugeun's art, made to be able to see how his art world has changed and inquired into the relation between the formative features and psychological characteristic of his art based on this. Third, I analyzed tree drawings by Buck's tree drawing test which appeared most in his works and tried to master the aspects of his inner character. Results: It is as follows. 1. He had strong vitality and energy. You can fine the range and depth like this in simplicity and the emphasis of line, the characteristics of his work. 2. He was sensitive and emotional. It can be found in the consistency of a subject matter to be all over his work and an emphasized feel of a material. 3. It seemed that he was introvert in character and had coherent melancholy, which you can guess by monotonous color all over his works he had presented from when he became an artist until he died. Conclusion : The result of this study shows that he put his characteristic quality into works and that works which artists express through shape and color offer important clues to guess agony of the times and personal characteristic quality. If you analyze artists' works carefully and study, you would know how human characteristic quality expresses shape and color.

연하장애를 보이는 뇌졸중환자에서 경관 유동식 종류에 따른 혈액학적 지표 변화 연구

오준호,신성헌,이윤정,강윤주,김용균 관동대학교 의과학연구소 2006 關東醫大學術誌 Vol.10 No.1

소요동력 절감을 위한 트랙터용 로타리 커버의 개발

오종진,김기대,이현동,김찬수,김성환,나건영 충남대학교 농업과학연구소 2002 농업과학연구 Vol.29 No.2

본 연구에서는 로타리 경운작업시 흙 부착이 가장 많이 되고 소요동력에 큰 영향을 미치는 로타리 커버 내측에 흙이 부착되는 것을 방지하여 경운 소요동력의 절감에 기여할 수 있는 로타리 커버를 개발하는데 목적이 있으며, 그 구체적인 연구결과는 다음과 같다. 1. 본 연구의 수행을 위하여 트랙터의 로타리 경운소요동력을 측정하고자 트랙터 PTO축과 로타리 동력 입력축을 연결하는 PTO 동력 전달축을 이용하여 로타리 경운 소요동력 측정장치를 설계, 제작하였다. 2. 로타리에 장착한 흙부착 방지장치의 재질로는 스테인리스 스틸, 고무, PE 등을 사용하였다. 흙부착 방지장치 장착 로타리를 이용하여 로타리 경운시험을 통한 경운 소요동력을 측정한 결과 평균 일반 로타리는 52.18ps, 스테인리스 스틸재질 장착 로타리는 52.44ps, 고무재질 장착 로타리는 49.01ps, 그리고 PE재질 장착 로타리는 46.34ps의 소요동력을 나타냈다. 3. 흙부착 방지장치 장착 로타리를 이용하여 로타리 경운시험 후 부착된 흙의 양을 조사한 결과 평균 일반 로타리는 5.6㎏, 스테인리스 스틸재질 장찰 로타리는 5.7㎏, 고무재질 장착 로타리는 3.1㎏, 그리고 PE재질 장착 로타리는 2.7㎏으로 나타났다. 4. 실험결과를 토대로 유의수준 5%의 모평균 차에 의한 검정으로 분석해본 결과 스테인리스 스틸재질의 경우 흙부착 방지효과가 없는 것으로 나타났으며, 고무와 PE재질의 경우에 방지 효과가 있는 것으로 나타났다. 그 중 PE 재질이 소요동력과 흙부착 방지에 각각 11%, 52%의 감소효과가 있어 소요동력 감소 및 흙부착 방지 효과가 탁월한 것으로 나타났다. This study aims at investigating the realities of tractor rotary tilling and paving operations performed by farm families in the central part of the country, measuring the power requirement so as to find the energy-saving factors for tractor rotary tilling, and designing a device to prevent soil adherence to the inside of the rotary cover-this part is the most subject to soil adherence and affects the power requirement. As a result of rotary tilling tests using rotaries equipped with a soil adherence preventer, the power requirement values were measured to be 52.18, 52.44, 49.01 and 46.34 PS for general, stainless steel, rubber and PE rotaries, and as a results of measurement of the quantities of the sod adhered to rotaries after their tilling tests, on the average, the quantities were measured to be 5.6, 5.7, 3.1 and 2.7㎏ for general, stainless steel, rubber and PE rotaries, respectively. The PE rotary cover reduced the power requirement and soil adherence by 11 and 52%, respectively.