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      • KCI등재

        직독식 측정기 PID와 능동식 시료채취기에 의한 GC-FID 정량분석법의 VOCs 농도 비교 연구

        여진희 ( Jin-hee Yeo ),최광민 ( Kwang-min Choi ) 한국산업보건학회 (구 한국산업위생학회) 2016 한국산업보건학회지 Vol.26 No.3

        Objectives: Direct-reading instrument(Photoionization detectors, PID) and quantitative analysis using active type air sampling (Gas chromatography-flame ionization detector, GC-FID) were tested to evaluate their ability to detect volatile organic compounds(VOCs) in a semiconductor manufacturing plant. Methods: The organic compounds used were acetone and ethanol which are normally used as cleaning solutions in the semiconductor manufacturing. The evaluation was based on the preparation of test solutions of known acetone and ethanol concentration in a chamber(600×600×1150 ㎜). Samples were prepared that would be equivalent to 5~100 ppm for acetone and 10~ 200 ppm ethanol. GC-FID and PID were evaluated simultaneously. Quantitative analysis was performed after sampling and the direct-reading instrument was checked using real-time data logging. Results: Positive correlations between PID and GC-FID were found for acetone and ethanol at 0.04~2.4% for acetone(TLV: 500 ppm) and 0.1~8.3% for ethanol(TLV: 1000 ppm). When the sampling time was 15 min, concentration of test solution was the most similar between measurement methods. However, the longer the sampling time, the less similar the results. PID and GC-FID had similar exposure patterns. Conclusions: The results indicate that PID and GC-FID have similar exposure pattern and positive correlation for detection of acetone and ethanol. Therefore, PID can be used for exposure monitoring for VOCs in the semiconductor manufacturing industry. This study has significance in that it validates measuring occupational exposure using a portable device.

      • SCOPUSKCI등재

        이온교환수지 분말이 코팅된 탄소전극을 이용한 음이온 혼합용액에서 Nitrate 이온의 선택적 제거율 향상

        최재환 ( Jin Hee Yeo ),여진희 ( Jae Hwan Choi ) 한국공업화학회 2013 공업화학 Vol.24 No.1

        혼합용액에서 nitrate 이온을 선택적으로 제거하기 위해 복합탄소전극을 제조하였다. 질산이온 선택성 수지(BHP55, Bonlite Co.) 분말을 탄소전극 표면에 코팅하여 전극을 제조하였다. 제조한 전극으로 BHP55 셀을 제작하여 chloride, nitrate, sulfate 이온이 혼합된 용액에 대해 축전식 탈염 실험을 수행하였다. 그리고 BHP55 셀에서의 질산 이온 제거량 을 이온교환막을 결합한 MCDI 셀의 결과와 비교하였다. BHP55 셀에서 이온의 총 흡착량은 MCDI 셀에서 보다 31% 증가한 38.3 meq/m 2를 나타냈다. 또한 BHP55 셀에서 질산 이온의 흡착량은 15.9 meq/m 2 (전체 흡착량의 42%)이었고, 이는 MCDI 셀에서 보다 2.1배 큰 것으로 나타났다. 실험결과 제조한 복합탄소전극은 음이온 혼합용액에서 질산 이온을 선택적으로 제거하는데 매우 효과적임을 알 수 있었다. We fabricated a composite carbon electrode to remove nitrate ions selectively from a mixed solution of anions. The electrode was fabricated by coating the surface of a carbon electrode with the nitrate-selective anion exchange resin (BHP55, Bonlite Co.) powder. We performed capacitive deionization (CDI) experiments on a mixed solution containing chloride, nitrate, and sulfate ions using a BHP55 cell constructed with the fabricated electrode. The removal of nitrate ions in the BHP55 cell was compared to that of a membrane capacitive deionization (MCDI) cell constructed with ion exchange membranes. The total quantity of ions adsorbed in BHP55 cell was 38.3 meq/m 2 , which is 31% greater than that of MCDI cell. In addition, the number of nitrate adsorption in the BHP55 cell was 15.9 meq/m 2 (42% of total adsorption), 2.1 times greater than the adsorption in the MCDI cell. The results showed that the fabricated composite carbon electrode is very effective in the selective removal of nitrate ions from a mixed solution of anions.

      • KCI등재

        반도체 작업환경 내 부산물로 생성되는 실리카 입자의 크기, 형상 및 결정 구조

        최광민 ( Kwang Min Choi ),여진희 ( Jin Hee Yeo ),정명구 ( Myung Koo Jung ),김관식 ( Kwan Sick Kim ),조수헌 ( Soo Hun Cho ) 한국산업보건학회 2015 한국산업보건학회지 Vol.25 No.1

        Objectives: This study aimed to elucidate the physicochemical properties of silica powder and airborne particles as by-products generated from fabrication processes to reduce unknown risk factors in the semiconductor manufacturing work environment. Materials and Methods: Sampling was conducted at 200 mm and 300 mm semiconductor wafer fabrication facilities. Thirty-two powder and airborne by-product samples, diffusion(10), chemical vapor deposition(10), chemical mechanical polishing(5), clean(5), etch process(2), were collected from inner chamber parts from process and 1st scrubber equipment during maintenance and process operation. The chemical composition, size, shape, and crystal structure of silica by-product particles were determined by using scanning electron microscopy and transmission electron microscopy techniques equipped with energy dispersive spectroscopy, and x-ray diffractometry. Results: All powder and airborne particle samples were composed of oxygen(O) and silicon(Si), which means silica particle. The by-product particles were nearly spherical SiO2 and the particle size ranged 25 nm to 50 μm, and most of the particles were usually agglomerated within a particle size range from approximately 25 nm to 500 nm. In addition, the crystal structure of the silica powder particles was found to be an amorphous silica. Conclusions: The silica by-product particles generated from the semiconductor manufacturing processes are amorphous SiO2, which is considered a less toxic form. These results should provide useful information for alternative strategies to improve the work environment and workers‘ health.

      • KCI등재

        정선 갓의 영양성분 및 세포기반 항산화 활성 분석

        권희연,최선일,조봉연,최승현,심완섭,한웅호,장길웅,최예은,여진희,조주현,이옥환,Kwon, Hee-Yeon,Choi, Sun-Il,Cho, Bong-Yeon,Choi, Seung-Hyun,Sim, Wan-Sup,Han, Xionggao,Jang, Gill-Woong,Choi, Ye-Eun,Yeo, Jin-Hui,Cho, Ju-Hyun,Lee, Ok-Hwan 한국식품영양학회 2019 韓國食品營養學會誌 Vol.32 No.5

        The purpose of this study was to demonstrate the quality characteristics of Brassica juncea cultivated in Jeongseon (BJJ), South Korea. We analyzed the nutritional components and antioxidant activity of BJJ. As a result of the free sugar analysis, the contents of glucose and fructose in BJJ were $0.29{\pm}0.02g/100g$ and $0.10{\pm}0.00g/100g$, respectively. The major fatty acids were palmitic acid, octadecenoic acid and stearic acid. The palmitic acid was the highest at 31.22% of all fatty acids. The major minerals were identified as Ca, P, K, Mg and Na. The contents of vitamin $B_1$, vitamin $B_2$, vitamin $B_6$, vitamin C and vitamin E in BJJ were $0.02{\pm}0.00mg/100g$, $0.087{\pm}0.01mg/100g$, $0.02{\pm}0.00mg/100g$, $0.56{\pm}0.06mg/100g$ and $0.20{\pm}0.03mg\;{\alpha}-TE/100g$, respectively. As a result of the free amino acid analysis, total amino acid contents in BJJ were $2,801.21{\pm}115.38mg/100g$. L-proline content was the highest ($744.30{\pm}119.06mg/100g$) in BJJ. BJJ extract inhibits reactive oxygen species production in 3T3-L1 adipocytes. Also, BJJ extract exhibits a protective effect on oxidative stress in $H_2O_2$-induced human dermal fibroblast. These results indicate that BJJ comprises various valuable nutrients which can be used as functional food ingredients.

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