반도체 가공 작업환경에서 부산물로 발생되는 주요 금속산화물의 입자 크기, 형상, 결정구조에 따른 독성 고찰

최광민 ( Kwang-min Choi ) 한국산업보건학회 (구 한국산업위생학회) 2016 한국산업보건학회지 Vol.26 No.2

Objectives: The purpose of this study is to review size, shape, and crystal structure-dependent toxicity of major metal oxide particles such as silicon dioxide, tungsten trioxide, aluminum oxide, and titanium dioxide as byproducts generated in semiconductor fabrication facility. Methods: To review the toxicity of major metal oxide particles, we used various reported research and review papers. The papers were searched by using websites such as Google Scholar and Pub Med. Keyword search terms included ``SiO2(or WO3 or Al2O3 orTiO2) toxicity``, ``health effects SiO2(or WO3 or Al2O3 or TiO2). Additional papers were identified in references cited in thesearched papers. Results: In various cell lines and organs of human and animals, cytotoxicity, genotoxicity, hepatoxicity, fetotoxicity, neurotoxicity, and his to pathological changes were induced by silicon dioxide, tungsten trioxide, aluminium oxide, and titanium dioxide particles. Differences in toxicity were dependent on the cell lines, organs, doses, as well as the chemical composition, size, surface area, shape, and crystal structure of the particles. However, the doses used in the reported papers were higher than the possible exposure level in general work environment. Oxidative stress induced by the metal oxide particles plays a significant rolein the expression of toxicity. Conclusions: The results cannot guarantee human toxicity of the metal oxide particles, because there is still a lack of available information about health effects on humans. In addition, toxicological studies under the exposure conditions in the actual work environment are needed

자동차 부품제조 사업장의 유해인자 노출 농도수준 및 검출율 -알루미늄 다이캐스팅 공정을 중심으로-

이덕희 ( Duk-hee Lee ),문찬석 ( Chan-seok Moon ) 한국산업보건학회 (구 한국산업위생학회) 2018 한국산업보건학회지 Vol.28 No.1

Objectives: This study examines exposure to hazardous substances in the working environment caused by exposure to toxic substances produced in the aluminum die casting process in the automobile manufacturing industry. Materials and Methods: The exposure concentration levels, detection rates and time-trend of 15 hazardous factors in the aluminum die casting process over 10 years(from 2006 to 2016) were used as a database. Results: The study found that hazardous factors in the aluminum die casting process were mostly metals. The rate for detected samples was 70.6%(405 samples), and that for not detected samples was 29.4%. The noise for an eight-hour work shift showed a 49.7% exceedance rate for TLV-TWA. Average noise exposure was 89.0 dB. The maximum exposure level was 105.1 dB. Conclusion: The high numbers of no-detection rates for hazardous substance exposure shows that there is no need to do a work environment measurement. Therefore, alternatives are necessary for improving the efficiency and reliability of the work environment measurement. Moreover, to prevent noise damage, reducing noise sources from automation, shielding, or sound absorbents are necessary.

공기순환장치 적용 오존 플라즈마 살균장치 개발

안준 ( June An ),전영남 ( Young-nam Chun ) 한국산업보건학회 (구 한국산업위생학회) 2021 한국산업보건학회지 Vol.31 No.1

Objectives: The purpose of this study was to develop a new sterilization plasma device that would be proficient at sterilizing and removing pathogenic bacteria and viruses, and applicable to air purification systems. Methods: In order to understand the performance characteristics, the discharge characteristics of a packed bed DBD reactor and the ozone reduction characteristics of an ozone filter installed at the outlet of the reactor were investigated. Results: The novel packed-bed DBD reactor was proposed, and it was confirmed that the plasma discharge was uniformly and stably discharged throughout the entire layer, and sufficient ozone was generated for sterilization. The ozone filter was tested for three methods: adsorption, adsorption-decomposition, and catalytic decomposition. When the filter thickness was 30 mm, the ozone concentrations were 0.03 ppm, 0.01 ppm, and 0.21 ppm, respectively. The adsorption and adsorption-decomposition methods satisfied the EPA standard of less than 0.05ppm, but the catalytic decomposition method did not. Conclusions: It was confirmed that the adsorption-decomposition method has relatively excellent ozone filter performance and can provide the best ozone filter.

소리의 종류와 크기에 따른 일과성 청력 역치 상승과 회복의 차이

이채관 ( Chae Kwan Lee ) 한국산업보건학회 (구 한국산업위생학회) 2020 한국산업보건학회지 Vol.30 No.4

Objective: This study aimed to investigate the differences in temporary threshold shift (TTS) and recovery patterns according to different types of sound and volume. Methods: TTS and recovery patterns were assessed for eight students after 30-minute exposure to both 70.0 dB and 90.0 dB of factory noise (noise) as well as music. TTS was measured before exposure and two minutes post exposure, and recovery patterns were evaluated every 10 minutes for one hour. The subjects performed activities of daily life and sleeping times as usual but taking drugs or drinking alcohol were prohibited. The experiment was repeated three times with an interval of at least 16 hours. ANOVA and T-test were carried out using SPSS 19.0 for Windows. Results: The hearing threshold of all subjects before exposure was less than 30 dB at all frequencies. Mean TTSs of 70 dB noise and 90 dB noise exposure were 0.14 and 4.48 dB (p<0.001). Meanwhile, the difference in music was insignificant (-0.63 dB and 0.55 dB, p=0.063). A significance in the difference was also found between the mean TTS of music and noise exposure, more obviously at 90.0 dB (p<0.001) than at 70 dB (p=0.232). The TTS differences were found frequency-wise in terms of sound type. Mean TTS by frequency was higher at 4,000 and 6,000 Hz than at other frequencies, and higher in noise than music at the same sound pressure. The TTS difference in each frequency between both sound types was significant at 90 dB (p<0.001). Subjects mostly recovered from TTS in one hour after exposure, but not with 90 dB-noise exposure. Conclusion: TTS and recovery patterns were different depending on the sound type. When exposed to factory noise, TTS was greater and recovery time was longer compared to music at the same sound pressure. These results suggested that the difference in cognitive processes and psychological factors according to the type of sound causes a change in TTS and recovery.

국외 질식재해 예방규정 비교를 통한 국내 규정 개선방안

임대성 ( Dae Sung Lim ),이승길 ( Seung Kil Lee ),김치년 ( Chi-nyon Kim ),조기홍 ( Kee Hong Cho ),이광용 ( Gwang Yong Yi ) 한국산업보건학회 (구 한국산업위생학회) 2021 한국산업보건학회지 Vol.31 No.1

Objectives: ‘Confined space’ was only defined in the Safety and Health Regulations as a place where oxygen deficiency and hydrogen sulfide must be dealt with at the time of the initial enactment (1982). The danger of fire and explosion were added in 2003. We will compare and review the regulations related to confined space work under the current safety and health rules alongside regulations in other countries and prepare a plan to improve the system through enhanced clarity and execution. Methods: In a comparison of systems for the prevention of suffocation in confined spaces in major countries (Germany, United States, Japan) different concepts of the definition of confined spaces in different countries apparently due to differences in each country's legal implementation system, accident analysis methods, the status of safety and health implementation in workplaces, the precautions against actual confined space work, and the definition of confined spaces were found to be not much different between Korea and the other foreign countries. Results: In the case of Germany and the United States, a confined space is defined as a contextual concept rather than a place, so more careful attention is needed from operators or enclosed space managers as it is often necessary to judge the actual workplace. In the case of Korea and Japan, the interior of the place is mainly defined as a place, especially in the case of Japan, which concentrates on oxygen deficiency and hydrogen sulfide poisoning. Conclusions: For measures to improve regulations on the prevention of suffocation accidents in Korea, I would like to propose three major measures to improve the system in the rules on domestic industrial safety and health standards. It is necessary to prepare and provide a guide to ensure that the 18 types of confined spaces currently defined as confined spaces are clearly understood by field management supervisors or workers.

소규모 세탁소의 휘발성유기화합물 발생 특성과 종사자의 건강에 미치는 영향

박옥현 ( Ok-hyun Park ),이경석 ( Kyoung-seok Lee ),민경우 ( Kyoung-woo Min ),조광운 ( Gwang-woon Cho ),윤관주 ( Kwan-ju Yoon ),정원삼 ( Won-sam Jeong ),조영관 ( Young-gwan Cho ),김은선 ( Eun-sun Kim ),양진석 ( Jin-seok Yang ) 한국산업보건학회 (구 한국산업위생학회) 2016 한국산업보건학회지 Vol.26 No.2

Objectives: The objective of this study was to evaluate the generating characteristics of VOCs and the exposure effect to chemicals among laundry workers and to identify the current status of occupational safety and health through health check-ups. Methods: During the six-month period from April to September 2015, this study quantitatively measured seven VOCs in ten laundries and carried out health examinations on 35 workers. Results: Comparing the monitoring results for the ten laundries, they were classified into three groups by ventilation system, dry-cleaning and size of shop. The average concentration of toluene, chlorobenzene, xylene, ethylbenzene, benzene, styrene and TCE were 23.9, 15.6, 5.5, 2.8, 0.9, 0.3 and 1.3 ㎍/m3, respectively. During dry-cleaning, VOC concentrations were 1.3-8.9 times higher than usual. On the other hand, at night the concentrations of toluene, chlorobenzene, xylene, ethylbenzene, benzene, styrene and TCE were 64.3, 41.5, 12.2, 6.3, 1.1, 1.2 and 6.6 ㎍/m3, respectively. The health checkup results for the 35 workers showed that 13 workers were diagnosed as normal, while 22 workers were diagnosed as requiring continuous monitoring or re-checkup of liver and hematogenous functions. Conclusions: Although the results of exposure evaluation to VOCs did not exceed reference value and items had a low correlation with health checkup items, it is necessary to improve indoor air quality due to VOC volatilization from clothes

연구활동종사자 작업환경측정 결과 및 제도개선 방향

황제규 ( Je-gyu Hwang ),변헌수 ( Hun-soo Byun ) 한국산업보건학회 (구 한국산업위생학회) 2020 한국산업보건학회지 Vol.30 No.4

Objectives: The characteristics of research workers are different from those working in the manufacturing industry. Furthermore, the reagents used change according to the research due to the characteristics of the laboratory, and the amounts used vary. In addition, since the working time changes almost every day, it is difficult to adjust the time according to exposure standards. There are also difficulties in setting standards as in the manufacturing industry since laboratory environments and the types of experiments performed are all different. For these reasons, the measurement of the working environment of research workers is not realistically carried out within the legal framework, there is a concern that the accuracy of measurement results may be degraded, and there are difficulties in securing data. The exposure evaluation based on an eight-hour time-weighted average used for measuring the working environment to be studied in this study may not be appropriate, but it was judged and consequently applied as the most suitable method among the recognized test methods. Methods: The investigation of the use of chemical substances in the research laboratory, which is the subject of this study, was conducted in the order of carrying out work environment measurement, sample analysis, and result analysis. In the case of the use of chemical substances, after organizing the substances to be measured in the working environment, the research workers were asked to write down the status, frequency, and period of use. Work environment measurement and sample analysis were conducted by a recognized test method, and the results were compared with the exposure standards (TWA: time weighted average value) for chemical substances and physical factors. Results: For the substances subject to work environment measurement, the department of chemical engineering was the most exposed, followed by the department of chemistry. This can lead to exposure to a variety of chemicals in departmental laboratories that primarily deal with chemicals, including acetone, hydrogen peroxide, nitric acid, sodium hydroxide, and normal hexane. Hydrogen chloride was measured higher than the average level of domestic work environment measurements. This can suggest that researchers in research activities should also be managed within the work environment measurement system. As a result of a comparison between the professional science and technology service industry and the education service industry, which are the most similar business types to university research laboratories among the domestic work environment measurements provided by the Korea Safety and Health Agency, acetone, dichloromethane, hydrogen peroxide, sodium hydroxide, nitric acid, normal hexane, and hydrogen chloride are items that appear higher than the average level. This can also be expressed as a basis for supporting management within the work environment measurement system. Conclusions: In the case of research activity workers' work environment measurement and management, specific details can be presented as follows. When changing projects and research, work environment measurement is carried out, and work environment measurement targets and methods are determined by the measurement and analysis method determined by the Ministry of Employment and Labor. The measurement results and exposure standards apply exposure standards for chemical substances and physical factors by the Ministry of Employment and Labor. Implementation costs include safety management expenses and submission of improvement plans when exposure standards are exceeded. The results of this study were presented only for the measurement of the working environment among the minimum health management measures for research workers, but it is necessary to prepare a system to improve the level of safety and health.

화학사고 주변 지역 거주자의 보건환경 관리를 위한 건강위해성 평가 방법 개발에 관한 연구

박시현 ( Sihyun Park ),박세정 ( Sejung Park ),박태현 ( Taehyun Park ),윤단기 ( Danki Yoon ),정종현 ( Jonghyeon Jung ),강성규 ( Sungkyu Gang ),이동수 ( Dongsoo Lee ),서영록 ( Youngrok Seo ),안연순 ( Yeonsoon An ),이철민 ( Cheolmin 한국산업보건학회 (구 한국산업위생학회) 2018 한국산업보건학회지 Vol.28 No.1

Objectives: This research is part of a study to be conducted over five years starting from 2017 by the Ministry of Environment on the development of technologies to evaluate the impact of chemical accidents on the human body. Methods: For this research, a five-stage specific study method was developed. Results: In brief, the developed health risk assessment method can be summarized as follows. First, a health risk assessment system was built based on the guidelines set forth by the USA NRC/NAS. Second, based on the disease manifestation theory, the health risk assessment method was divided into 1) a carcinogenic health risk assessment method focused on all carcinogens except non-genotoxic carcinogens and 2) a non-carcinogenic health risk assessment method focused on noncarcinogens including non-genotoxic carcinogens. Third, the detailed contents of the health risk assessment method were developed in four stages (hazard identification, dose-response assessment, exposure assessment, and risk determination) through theoretical consideration of the assessment of the level of health risk related to chemical exposure. Finally, a health risk assessment methodology, classified into stages to address acute, subacute/subchronic, and chronic conditions was developed after considering the physicochemical behavior of hazardous chemicals upon implementation of countermeasures after a chemical accident. Conclusions: A method to evaluate the health risks related to toxic chemicals generated by chemical accidents was developed. This study was performed with the purpose of developing a mathematical health risk assessment method to evaluate the health effects of exposure to hazardous chemicals upon implementation of emergency countermeasures after chemical accidents.

한국 요양보호사 산업재해의 연도별 변화추이

손미아 ( Mia Son ),전거송 ( Geo-song Jeon ),배동철 ( Dong-chul Bae ),손병창 ( Byungchang Son ),김태운 ( Taeun Kim ),윤재원 ( Jae-won Yun ) 한국산업보건학회 (구 한국산업위생학회) 2021 한국산업보건학회지 Vol.31 No.2

Objectives: To investigate the trends of industrial injuries among long-term health care workers in Korea Methods: T7866 injuries were selected from the total industrial injuries approved by the Industrial Accident Compensation Insurance Act(Occupational Safety and Health Act) among long-term health care workers between 2007 and 2016 in Korea. We analyzied the trends of industrial injuries according to work process, occurrence type, and causes. Results: The industrial injuries among long-term health care workers increased since 2012. The mostly occurred area for industrial injuries were low back areas, which is related that the most serious industrial injuries occurred when the one long-term healthcare worker lift manually the recipient, from bed(ondol, Korean floor heating system) to a wheelchair, bed to bath bed, and wheelchair to bath chair. In addition to this, lack of workforce, increased work intensity due to overwork contributed the increasing of occupational injury. Conclusions: This study suggests that the main causes of industrial injuries were Lack of facilities and equipment for small private long-term care institutions, The physical load that goes into lifting the recipient directly, work intensity such as excessive workload and increased work speed. We suggest that the social publicization of long-term care service for the elderly, avoiding ways to lift recipients directly, introducing lifting machines as well as improving working methods, and reducing the workload of caregivers are required.

탄소나노튜브 복합체 취급 작업자의 공기 중 입자상 물질 노출 특성

권지운 ( Jiwoon Kwon ),김성호 ( Sungho Kim ),장미연 ( Miyeon Jang ) 한국산업보건학회 (구 한국산업위생학회) 2020 한국산업보건학회지 Vol.30 No.1

Objectives: The purpose of this case study is to assess workers’ exposure to carbon nanotubes (CNTs) and characterize particles aerosolized during the process of producing CNT-enabled polytetrafuoroethylene(PTFE) composites at a worksite in Korea. Methods: Personal breathing zone and area samples were collected for determining respirable concentrations of elemental carbon (EC) using NIOSH(National Institute for Occupational Safety and Health) Method 5040. Personal exposure to nano-sized particles was measured as the number concentration and mean diameter using personal ultrafine particle monitors. The number concentration by particle size was measured using optical particle sizers (OPS) and scanning mobility particle sizers (SMPS). Transmission electron microscopy (TEM) area samples were collected on TEM grids and analyzed to characterize the size, morphology, and chemistry of the particles. Results: Respirable EC concentrations ranged from 0.04 to 0.24 μg/m³, which were below 23% of the exposure limit recommended by NIOSH and lower than background concentrations. Number concentrations by particle size measured using OPS and SMPS were not noticeably elevated during CNT-PTFE composite work. Instant increase of number concentrations of nano-sized particles was observed during manual sanding of CNT-PTFE composites. Both number concentrations and mean diameters did not show a statistically significant difference between workers handing CNT-added and not-added materials. TEM analyses revealed the emission of free-standing CNTs and CNT-PTFE aggregate particles from the powder supply task and composite particles embedded with CNTs from the computer numerical control (CNC) machining task with more than tens of micrometers in diameter. No free-standing CNT particles were observed from the CNC machining task. Conclusions: Significant worker exposure to respirable CNTs was not found, but the aerosolization of CNTs and CNT-embedded composite particles were observed during handing of CNT-PTFE powders and CNC machining of CNT-PTFE composites. Considering the limited knowledge on the toxicity of CNTs and CNT composite particles to date, it seems prudent to take a precautionary approach for the protection of workers’ health.