전해생성(電解生成)된 염소(鹽素)에 의한 폐인쇄회로기판(廢印刷會路基板)으로부터 동(銅)의 침출(浸出)

김민석,이재천,정진기,김병수,김은영,Kim, Min-Seuk,Lee, Jae-Chun,Jeong, Jin-Ki,Kim, Byung-Su,Kim, Eun-Young 한국자원리싸이클링학회 2005 資源 리싸이클링 Vol.14 No.5

염산용액에서 전해생성 된 염소를 이용하여 폐프린터의 인쇄회로기판으로부터 동을 침출하는 연구를 수행하였다. 폐인쇄회로기판을 분쇄한 다음 입자크기가 $0.6{\sim}1.2mm$인 비자성 성분을 선별하여 침출실험을 행하였다. 비자성 분쇄물 중 금속성분의 평균함량은 45wt%이었으며, 동이 금속성분의 83.6wt% 이었다. 1 M 염산용액에서 전해생성된 염소에 의한 동의 침출반응은 전류밀도와 교반속도에 크게 영향을 받았다. 염산농도: 1 M, 전류밀도: $20mA/cm^2$, 침출온도: $50^{\circ}C$, 침출시간: 180분, 교반속도: 600rpm의 침출조건에서 동의 침출율은 98%로서 침출액에서 농도는 3.69g/l 해당하였다. 동의 침출반응에 대한 전해생성 된 염소의 이용율은 교반속도가 높고 인가전류밀도가 낮을 수록 높았다. 또한 침출반응 초기에는 알루미늄, 납, 주석 등의 기타금속 성분의 침출이 활발하고 동의 침출반응은 억제되었다. Electro-generated chlorine leaching of waste printed circuit boards was investigated in hydrochloric acid solutions. Non-magnetic component of $0.6{\sim}1.2mm$ was prepared by grinding, magnetic separation, and sieving. The non-magnetic component of pulverized printed circuit board contained about 45% of metal component, in which copper was about 83.6%. The leaching rate of copper was greatly affected by current density and agitation speed. The leaching of copper up to 98% was achieved at $20mA/cm^2$, $50^{\circ}C$, 180 minutes, and 600 rpm in 1M HCl solutions. Increasing agitation and lowering current density enhanced utilization efficiency of electro-generated chlorine. Leaching of copper was suppressed at the initial stage, while the minor metal elements, such as aluminum, lead, and tin, were dominantly leached out.

폐의 경흉 세침흡인 세포검사

김민석,박인애,박선후,박성신,김활웅,문경철,김영아,이혜승,박기화,서정욱,이현순,함의근,Kim, Min-Suk,Park, In-Ae,Park, Sun-Hoo,Park, Sung-Shin,Kim, Hwal-Wong,Moon, Kyung-Chul,Kim, Young-Ah,Lee, Hye-Seung,Park, Ki-Wha,Seo, Jeoug-Wook,Lee, Hy 대한세포병리학회 1999 대한세포병리학회지 Vol.10 No.1

The authors analysed 2,653 cases of transthoracic fine needle aspiration cytology of the lung to evaluate the diagnostic accuracy and its limitation. A comparison was made between the original cytologic and the final histologic diagnoses on 1,149 cases from 1,074 patients. A diagnosis of malignancy was established in 38.3% benign in 48.1%, atypical lesion in 2.3%, and inadequate one in 11.9% of the cases. Statistical data on cytologic diagnoses were as follows; specificity 98.9%: sensitivity of procedure, 76.8%: sensitivity of diagnosis, 95.5%: false positive 5 cases: false negative 18 cases: predictive value for malignancy, 98.8%: predictive value for benign lesion, 79.5%: overall diagnostic efficiency, 87.5%: typing accuracy in malignant tumor, 80%.

복시환자의 임상양상

김민석,최진,김정훈,김재석,이주화,Min Seok Kim,Jin Choi,Jung Hoon Kim,Jae Suk Kim,Joo Hwa Lee 대한안과학회 2013 대한안과학회지 Vol.54 No.11

Purpose: To evaluate the clinical features, causes and outcomes of patients with diplopia. Methods: All patients presenting with diplopia from October 2010 to March 2012 and followed up for more than 3 months were retrospectively investigated. Results: During the study period, 59 patients with diplopia were identified. There were 42 males and 17 females with an average age of 50 years. Binocular diplopia accounted for 54 cases (92%) and 5 cases (8%) had monocular diplopia. Cranial nerve palsies were the most common cause of binocular diplopia (28 cases, 52%). Within the cranial nerve palsies group, 14 cases (50%) were accompanied by hypertension or diabetes mellitus. Binocular diplopia spontaneously resolved in 35 cases (65%) by 3 months rising to 41 cases (76%) by 7 months. Thirteen (93%) out of 14 cases of cranial nerve palsies with hypertension or diabetes resolved spontaneously by 3 months. Conclusions: Binocular diplopia was caused most commonly by cranial nerve palsy and resolved after 3 months in 65% of patients. A spontaneous recovery from diplopia was observed after 3 months in 93% of patients with cranial nerve palsies and microvascular disease such as hypertension or diabetes. Therefore, the initial observation without additional treatment would be sufficient in these patients. J Korean Ophthalmol Soc 2013;54(11):1772-1777

실리콘 웨이퍼 에칭공정으로부터 발생(發生)된 폐산(廢酸)을 이용(利用)한 스테인리스 스틸의 산세거동(酸洗擧動) 연구(硏究)

김민석,안종관,김홍인,김주엽,안재우,Kim, Min-Seuk,Ahn, Jong-Gwan,Kim, Hong-In,Kim, Ju-Yup,Ahn, Jae-Woo 한국자원리싸이클링학회 2008 資源 리싸이클링 Vol.17 No.2

실리콘 웨이퍼 에칭공정에서 발생하는 폐산을 스테인리스 스틸 산세공정에서 재활용하고자 이를 이용한 산세 거동을 조사하였다. 폐산 원액은 $19.6g/L^{-1}$ 실리콘을 함유한 불산, 질산 및 초산의 혼산이었으며 침전법에 의한 실리콘 제거 전후 폐산들을 이용하여 304 스테인레스 스틸 표면 산화막의 제거 시 측정된 open circuit potential(OCP) 변화 거동은 매우 상이하였다. 폐산 원액을 사용한 경우에는 OCP가 높고 연속적인 변화를 보이는데 비하여 실리콘 제거 공정에서 얻어진 용액의 경우에는 불연속적인 OCP변화와 전위요동현상이 나타났다. 이러한 거동의 차이는 표면 부동태막의 형성 및 제거와 공식이 발생하는 정도의 차이에 기인하는 것으로 생각되며, 실리콘 제거 공정에서 산도가 낮아진 폐산에서 산화막 제거속도가 높고 공식발생이 현저하였다. 산세 후 시료의 표면 광택도에 가장 큰 영향을 주는 것은 산세 온도였으며, 산세온도가 높아질수록 표면 광택도는 감소하였다. 동일 산세 조건에서는 폐산 원액을 사용한 경우가 실리콘을 제거공정으로부터 얻어진 용액을 사용한 경우보다 광택도가 높았다. Pickling of oxidized 304 stainless steel has been investigated using rotating disk electrode in waste acid solutions generated from the etching process of silicon wafer in order to recycle them. The waste acid solution contained acetic, nitric, hydrofluoric acids, and silicon of $19.6g/L^{-1}$. Electrochemical behavior during the pickling was distinctively different between the original and silicon-removed acid solutions. Open circuit potential was continuously changed in the original solution, while it was discontinuously changed and fluctuated in the silicon-removed solution. Fast and abrupt removal of surface oxide layer with severe pitting was observed in the silicon-removed solution. It was found that solution temperature had the most influential effect on glossiness. Surface glossiness after pickling was decreased with solution temperature. At the same condition, the glossiness was higher in the original solution than in the silicon-removed solution.

자동차(自動車) 폐촉매(廢觸媒)의 침출액(浸出液)으로부터 시멘테이션에 의한 백금족(白金族) 금속(金屬)의 회수(回收)

김민석,김병수,김은영,김수경,류재욱,이재천,Kim, Min-Seuk,Kim, Byung-Su,Kim, Eun-Young,Kim, Soo-Kyung,Ryu, Jae-Wook,Lee, Jae-Chun 한국자원리싸이클링학회 2011 資源 리싸이클링 Vol.20 No.4

금속분말을 환원제로 사용하는 시멘테이션에 의하여 자동차 폐촉매의 침출액과 침출잔사의 세척액으로부터 백금족 금속을 환원 석출시켜 회수하는 연구를 수행하였다. 환원제로 사용한 알루미늄, 마그네슘 그리고 아연이 백금족 금속의 시멘테이션에 미치는 영향을 조사하였으며 알루미늄을 최적 환원제로 선정하였다. 침출액에 19.3 당량의 알루미늄을 첨가하고 $50{\sim}60^{\circ}C$에서 10분간 시멘테이션을 행하였을 때 백금, 팔라듐, 로듐의 환원석출율은 각각 99.3%, 99.4%, 90.2% 정도 이었다. 또한 세척액에 알루미늄을 45 당량 투입한 후 시멘터이션 반응을 통해 백금, 팔라륨, 로듐을 각각 97%, 97%, 90% 회수할 수 있었다. 그리고 회수한 환원석출물의 금속불순물들을 질산침출로 제거함으로써 백금족 금속의 품위를 약 10% 정도 향상시킬 수 있었다. The recovery of platinum group metals (PGMs) from the leach solution of spent auto-catalyst and the wash solution of the leach residue was investigated in the laboratory scale experiments by the cementation process using metal powders as the reductant. In this study, the effect of Al, Mg and Zn powders on the cementation process was particularly examined. Aluminum powder was selected as the most suitable reductant for the cementation of PGMs. At the cementation time of 10 minute under the aluminium stoichimetric amount of 19.3 and the reaction temperature of $50{\sim}60^{\circ}C$, the recovery of platinum group metals from the leach solution of the spent auto-catalyst was found to be 99.3%, 99.4%, 90.2% for Pt, Pd and Rh, respectively. Under the same conditions with the aluminium stoichimetric amount of 45, the recovery of platinum group metals from the wash solution of the leach residue of spent catalyst was observed to be 97%, 97% and 90% for Pt, Pd and Rh, respectively. In addition, it was possible to upgrade the platinum group metals in the precipitates obtained from the cementation process by about 10% through the removal of metal impurities by the nitric acid leaching at ambient temperature.

한.중.일 전통주거의 공간구조 및 공간이용 특성에 관한 비교연구 - 충효당, 4진 사합원, 니노마루고덴 사례를 중심으로 -

김민석,Kim, Min-Seok 한국주거학회 2011 한국주거학회 논문집 Vol.22 No.2

Until now, several comparative approaches were developed within the studies of Korean, Chinese, and Japanese traditional housings. In those studies, however, each space in the traditional houses was only treated in individual and fragmentary manners, and they lacked the interpretation of the topological attribute of each space within a holistic structure organized by unit spaces, and of the cultural-behavioral meaning of them within a holistic space-use pattern of the housing. The topological attribute and behavioral meaning can be analyzed and interpreted with the quantitative spatial analysis method such as Space Syntax. This study aims to analyze the traditional housings in Korea, China and Japan in the holistic aspect of spatial structure using Space Syntax, and to compare the analysis results with relating the structural attributes to the space-use pattern. In this study, the 'Banga' in Chosun era, the 'Siheyuan' in Ming-Ching era, and the 'Shoinzukuri' in Edo era were selected as the analysis subjects. The integration indices were calculated from the convex maps representing the subjects, and the common and different attributes of the three subjects were defined through comparative analyses.

염산(鹽酸)에 의한 CMSX-4 초내열합금(超耐熱合金)의 침출(浸出)

김민석,이재천,김은영,유영수,Kim, Min-Seuk,Lee, Jae-Chun,Kim, Eun-Young,Yoo, Young-Soo 한국자원리싸이클링학회 2010 資源 리싸이클링 Vol.19 No.5

CMSX-4 초내열합금의 순환활용을 위한 습식제련기술 개발의 일환으로 영신에서의 니켈, 코벨트, 크롬, 알루미늄 등 주요 구성 금속성분들의 침출 특성을 조사하였다. 염산농도에 따른 합금시료 내 주요 금속성분들의 침출율은 염산농도가 높아짐에 따라 증가하였으나, 3 M 이상에서는 둔화되었다 염산농도 4 M, 고액비 10 g/L, 침출시간 60 분 조건에서 침출온도가 높아짐에 따라 침출율은 급격히 증가하였으며, $90^{\circ}C$에서 니켈 93.2%, 알루미늄 89.9%, 코발트 80.4%, 크롬 79.1%의 침출율을 나타내었다. 한편 침출 초기에는 니켈과 알루미늄의 침출속도가 빠르고 60 분 이후 급격히 둔화되는 형태를 보인 반면 코발트와 크롬은 침출이 느리고 60 분 이후의 감소율만 상대적으로 적었다. 120 분 경과 시 주요 금속원소들의 침출율은 모두 99% 수준에 도달하였다. 고액비가 높아지면 침출율은 서서히 감소하였으며, 니켈과 알루미늄이 코발트와 크롬에 비하여 침출율 감소가 적었다. 염산농도 4 M, 침출온도 $90^{\circ}C$, 침출시간 120 분의 조건에서 고액비 125 g/L 이하의 조건이 주요 금속 성분의 침출에 효과적임을 확인하였으며, 이는 CMSX-4 합금의 금속학적 조직구조와 관련이 있는 것으로 생각된다. Leaching of CMSX-4 superalloy was done in hydrochloric acid solutions. The leaching behaviors of main alloy components, such as Ni, Co, Cr, Al, was investigated by controlling acid concentration, temperature, leaching time and pulp density. Increasing acid concentration enhanced the leaching rate till the rate decreased over 3 M acid concentration. Raising temperature increased the leaching amount of the metal components. After the leaching for 60 minutes at $90^{\circ}C$ and 10 g/L pulp density in 4 M acid solution, 93.2% nickel, 89.9% aluminum, 80.4% cobalt, and 79.1% chromium were leached. Nickel and aluminum were preferentially leached out, while the leaching rate of cobalt and chromium were relatively high only after 60 minutes, Increasing pulp density lowered the leaching rate and especially serious on cobalt and chromium, The optimum leaching condition for CMSX-4 was obtained at $90^{\circ}C$, 120 minutes, and less than 125 g/L in 4 M hydrochloric acid solution.

EQCM 을 이용한 수산화 니켈의 산화/환원 거동에 관한 연구 ( 1 )

김민석,황태섭,김광범 ( Min Seuk Kim,Tai Sup Hwang,Kwang Bum Kim ) 한국부식방식학회 1995 Corrosion Science and Technology Vol.24 No.1

EQCM 을 이용한 α - Ni ( OH )2 의 상변화 거동에 관한 연구

김민석,김광범 ( Min Seuk Kim,Kwang Bum Kim ) 한국부식방식학회 1997 Corrosion Science and Technology Vol.26 No.1

한반도 목표 표준강수지수(SPI) 산정에 관한 연구

김민석,문영일,Kim, Min-Seok,Moon, Young-Il 대한토목학회 2014 대한토목학회논문집 Vol.34 No.4

물은 인류와 동식물의 필요조건으로, 물 부족 상태 즉 가뭄은 전 세계적으로 가장 두려워하는 재해 중 하나이다. 본 연구는 지역적인 특성을 고려하여 가뭄을 판단하고 대응하기 위해 목표재현기간을 설정하고 한반도 전역을 대상으로 시 군 구 단위의 지역별 목표 표준강수지수를 산정하였다. 먼저 한반도에 위치한 30년 이상의 자료기간을 보유한 88개 기상관측소의 강우자료에서 월별강우자료를 추출하고 SPI (3)가뭄지수를 산정하였다. 산정된 SPI (3)에서 연도별 최저치를 추출하여 매개변수적 빈도해석과 경계핵밀도 함수를 이용한 비매개변수적 빈도해석을 실시하였다. 또한, 목표재현기간을 30년으로 설정하고 비매개변수적 빈도해석 결과에 티센비 적용하여 시 군 구 단위로 목표 표준강수지수를 산정하였다. 분석결과 가뭄의 심도와 빈도가 지역별로 크게 다르게 나타남을 확인 할 수 있었으며, 이는 한반도 가뭄의 판단과 대응을 위한 기초자료로 국가적인 수자원계획과 방재대책에 기여하고자 한다. Water is a necessary condition of plants, animals and human. The state of the water shortage, that drought is globally one of the most feared disasters. This study was calculated target standardized precipitation index with unit of region for judgment and preparation of drought in consideration of the regional characteristics. First of all, Standardized Precipitation Index (3) were calculated by monthly rainfall data from rainfall data more than 30 years of 88 stations. Parametric frequency and nonparametric frequency using boundary kernel density function were analysed using annual minimum data that were extracted from calculated SPI (3). Also, Target return period sets up 30 year and target SPI analysed unit of region using thiessen by result of nonparametric frequency. Analyzed result, Drought was entirely different from severity and frequency by region. This study results will contribute to a national water resources plan and disaster prevention measures with data foundation for judgment and preparation of drought in korea.