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Elastic Behavior of Zeolite Mesolite under Hydrostatic Pressure
이용재,이용문,성동훈,장영남,Lee, Yong-Jae,Lee, Yong-Moon,Seoung, Dong-Hoon,Jang, Young-Nam The Korean Society of Economic and Environmental G 2009 자원환경지질 Vol.42 No.5
제올라이트 메소라이트($Na_{5.33}Ca_{5.33}Al_{16}Si_{24}O_{80}{\cdot}21.33H_2O$)에 대한 고압에서의 회절자료가 200 마이크론 크기로 단색화 된 방사광가속기 X-선원과 다이아몬드 앤빌셀을 사용하여 5 GPa까지 측정되었다. 물과 알코올을 사용한 수압 하에서 메소라이트의 초기 탄성 특성은 0.5 GPa에서 1.5 GPa 사이에서 일어나는 ab-평면의 연속적인 팽창과 c-축 상의 수축에 기인한 전체적인 격자부피의 팽창으로 관찰된다. 이후의 압력에서는 회절패턴의 변화로부터 질서-무질서 전이의 증거가 보여진다. 메소라이트의 c-축에 평행한 채널에는 양이온으로서 소디움과 칼슘이 b-축 방향으로 1:2 비율의 질서 있는 배열을 보이고 있는데 이로 인해 1.5 GPa까지 에서는 이러한 배열의 증거인 $3b_{natrolite}$ 격자패턴이 관찰된다. 격자부피의 확장 이후 1.5 GPa 이상에서 2.5 GPa 까지 에서는 격자부피 변화의 정도가 약해지며, 양이온의 무질서적인 배열에 의한 $b_{natrolite}$ 격자패턴이 관찰된다. 이후 압력의 계속된 증가는 점진적인 격자부피의 감소를 유발시키며 새로운 형태의 질서 있는 배열상을 지시하는 $3c_{natrolite}$ 격자패턴으로의 변화를 보여준다. 이로부터 압력에 의한 초수화 상태의 메소라이트는 질서-무질서-질서 형태의 채널 내부 혹은 채널간의 양이온 배열패턴 변화를 겪는 것으로 추정할 수 있다. Powder diffraction patterns of the zeolite mesolite ($Na_{5.33}Ca_{5.33}Al_{16}Si_{24}O_{80}{\cdot}21.33H_2O$), with a natrolite framework topology were measured as a function of pressure up to 5.0 GPa using a diamond-anvil cell and a $200{\mu}m$-focused monochromatic synchrotron X-ray. Under the hydrostatic conditions mediated by pore-penetrating alcohol and water mixture, the elastic behavior of mesolite is characterized by continuous volume expansion between ca. 0.5 and 1.5 GPa, which results from expansion in the ab-plane and contraction along the c-axis. Subsequent to this anomalous behavior, changes in the powder diffraction patterns suggest possible reentrant order-disorder transition. The ordered layers of sodium- and calcium-containing channels in a 1:2 ratio along the b-axis attribute to the $3b_{natrolite}$ cell below 1.5 GPa. When the volume expansion is completed above 1.5 GPa, such characteristic ordering reflections disappear and the $b_{natrolite}$ cell persists with marginal volume contraction up to ca. 2.5 GPa. Further increase in pressure leads to progressive volume contraction and appears to generate another set of superlattice reflections in the $3c_{natrolite}$ cell. This suggests that mesolite in the pressure-induced hydration state experiences order-disorder-order transition involving the motions of sodium and calcium cations either through cross-channel diffusion or within the respective channels.
김종인(Jong In Kim),김태남(Tae Nam Kim),이용재(Yong Jae Nam) 한국강구조학회 1990 韓國鋼構造學會誌 Vol.2 No.2
Stochastic dynamic analysis of suspension bridge subject to random wind loads were carried out by mode-displacement method and mode-acceleration method. The computed dynamic characteristics are vertical and torsional vibrations of NAM-HAE BRIDGE. From numerical results, it was found that mode-acceleration method, which formulated in this paper, was more reliable and economical than mode-displacement method.
김종인(Jong In Kim),김태남(Tae Nam Kim),이용재(Yong Jae Lee) 한국강구조학회 1990 韓國鋼構造學會誌 Vol.2 No.2
Stochastic dynamic analyses of suspension bridge subject to random wind loads were carried out by mode-displacement method and mode-acceleration method. The computed dynamic characteristics are vertical and torsional vibrations of NAM-HAE BRIDGE. From numerical results, it was found that mode-acceleration method, which formulated in this paper, was more reliable and economical than mode-displacement method.
이규빈,이정은,제병일,이용재,박영훈,최영환,손병구,강남준,강점순,Lee, Gyu-Bin,Lee, Jung-Eun,Je, Byoung-Il,Lee, Yong-Jae,Park, Young-Hoon,Choi, Young-Whan,Son, Beung-Gu,Kang, Nam-Jun,Kang, Jum-Soon 한국환경과학회 2020 한국환경과학회지 Vol.29 No.2
The purpose of this study was to investigate the effect of shading on the growth and productivity of strawberries. Photosynthesis was normally achieved under natural light without shading treatment, and vegetative growth of under- and aboveground part of strawberry plants were excellent. Strawberry fruit productivity and quality were different depending on shading conditions. In natural light, they were improved possibly by balanced vegetative and reproductive growth. However, under light-shading conditions with insufficient sunshine, photosynthetic activity deteriorated and carbohydrate production was therfore inadequate; this adversely affected plant height and quality. The negative effects were more pronounced at 50% shading condition. Shading treatments resulting in insufficient sunshine had a detrimental impact on plant productivity and growth; this implies that proper shading conditions could heip improve yield and fruit quality.
발아온도 및 Spermine, Putrescine이 딸기의 화분 발아에 미치는 영향
이정은,김현도,제병일,이용재,박영훈,최영환,손병구,강남준,강점순,Lee, Jung-Eun,Kim, Hyeon-Do,Je, Byoung-Il,Lee, Yong-Jae,Park, Young-Hoon,Choi, Young-Whan,Son, Beung-Gu,Kang, Nam-Jun,Kang, Jum-Soon 한국환경과학회 2020 한국환경과학회지 Vol.29 No.4
This study was conducted to determine the optimum conditions for the treatment of polyamine to promote pollen germination and improve the fruiting rate by overcoming fertilization defects in low-temperature strawberry cultivation. The optimum temperature for pollen germination of strawberries was 30 ℃ for Seolhyang and 25 ℃ for Maehyang, and Seolhyang had a higher pollen germination rate than that of Maehyang. The addition of polyamines, namely spermine and putrescine to the medium improved the pollen germination rate and spermine treatment showed a better effect than putrescine treatment. The proper polyamine type and treatment concentration for enhancing the potency of pollen germination was 500 μM of spermine for both Seolhyang and Maehyang, which improved the pollen germination rate by 19-23% compared with that of the control. However, combined treatment of spermine and putrescine, resulted in a lower germination rate lower than that of the single treatment. Our results indicated that the treatment of polyamines during flowering in protected cultivation of strawberrise can improve the fruiting rate by overcoming the problem of poor pollen germination due to low temperature.
이규빈,이정은,제병일,이용재,박영훈,최영환,손병구,강남준,강점순,Lee, Gyu-Bin,Lee, Jung-Eun,Je, Byoung-Il,Lee, Yong-Jae,Park, Young-Hoon,Choi, Young-Whan,Son, Beung-Gu,Kang, Nam-Jun,Kang, Jum-Soon 한국환경과학회 2020 한국환경과학회지 Vol.29 No.3
The purpose of this study was to investigate the effects of defoliation treatment on the growth and yield of strawberries. There was a remarkable growth in the above-ground part and root of untreated strawberry plants possibly due to higher amount of photosynthesis, while overall plant growth was suppressed as the level of defoliation treatment increased. In both the "Seolhyang" and "Maehyang" cultivars examined, defoliation treatment resulted in small fruits and a low number of fruits per plant. Notably, 50% defoliation significantly reduced the number of fruits per plant to 8.2, compared to 13.8 in untreated plants. Defoliation treatment also negatively influenced the fruit quality including color, sugar content, and solid-acid rate. However, no significant changes in fruit firmness was observed in either cultivar. Therefore, retaining enough leaves without defoliation treatment can be important to increasing fruit yield, producing high quality fruits and saving labor required for defoliation.
AI 이온 주입된 p-type 4H-SiC에 형성된 Ni/AI 오믹접촉의 전기 전도 특성
주성재,송재열,강인호,방욱,김상철,김남균,이용재,Joo, Seong-Jae,Song, Jae-Yeol,Kang, In-Ho,Bahng, Wook,Kim, Sang-Cheol,Kim, Nam-Kyun,Lee, Yong-Jae 한국전기전자재료학회 2009 전기전자재료학회논문지 Vol.22 No.9
Ni/Al ('/' denotes deposition sequence) contacts were deposited on Al-implanted 4H-SiC for ohmic contact formation, and the conduction properties were characterized and compared with those of Ni-only contacts. The thicknesses of the Ni and Al thin film were 30 nm and 300 nm, respectively, and the films were sequentially deposited bye-beam evaporation without vacuum breaking. Rapid thermal anneal (RTA) temperature was varied as follows : $840^{\circ}C$, $890^{\circ}C$, and $940^{\circ}C$. The specific contact resistivity of the Ni contact was about $^{\sim}2\;{\pm}\;10^{-2}\;{\Omega}{\cdot}cm^2$, However, with the addition of Al overlayer, the specific contact resistivity decreased to about $^{\sim}2\;{\pm}\;10^{-4}\;{\Omega}{\cdot}cm^2$, almost irrespective of RTA temperature. X-ray diffraction (XRD) analysis of the Ni contact confirmed the existence of various Ni silicide phases, while the results of Ni/Al contact samples revealed that Al-contaning phases such as $Al_3Ni$, $Al_3Ni_2$, $Al_4Ni_3$, and $Ab_{3.21}Si_{0.47}$ were additionally formed as well as the Ni silicide phases. Energy dispersive spectroscopy (EDS) spectrum showed interfacial reaction zone mainly consisting of Al and Si at the contact interface, and it was also shown that considerable amounts of Si and C have diffused toward the surface. This indicates that contact resistance lowering of the Ni/Al contacts is related with the formation of the formation of interfacial reaction zone containing Al and Si. From these results, possible mechanisms of contact resistance lowering by the addition of Al were discussed.