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순천시의 생활폐기물 발생량 예측 및 재활용시설의 용량산정에 관한 연구
허관,문옥란,왕승호,Hu, Kwan,Moon, Ok-Ran,Wang, Seung-Ho 유기성자원학회 2001 유기물자원화 Vol.9 No.4
The purpose of this study is to provide basic information for a future countermeasure municipal and to establish several wastes policy after investigating solid wastes from Sunchon City. In addition, this research can be supported to manage of recycling plant and to reuse plant of each wastes. Results are as bellows after checking up and analysis type of waste in Sunchon city Unit solid waste generation rate from single family is $0.50kg/person{\cdot}day$, and total solid wastes are 41.9ton/day. Unit solid waste generation rate from apartments is $0.45kg/person{\cdot}day$, and solid wastes generation is 55.5ton/day. Unit solid waste generation rate from agricultural is $0.22kg/person{\cdot}day$ and total solid wastes are 13.5ton/day. That show total amount of municipal solid wastes from residential are 110.9ton/day. Unit solid waste generation rate from traditional markets is $1.85kg/person{\cdot}day$, and solid waste total volume is 5,400kg/day. Unit solid waste generation rate from small store is $2.03kg/person{\cdot}day$, and solid waste total are 25,101kg/day. Therefore, this show that total wastes are 30.50kg from downtown and commercial area. Solid waste quantity from Industrial area (Factory region) is 8.5ton and in case of school and hospitals are 7.2kg/day and 3.0kg/day. Solid waste amount from Institutional is 6.6kg/day. Food wastes were eliminated from municipal solid wastes as standard 63.4ton/day, and combustible wastes were 126.9ton/day. If it schedule about 5 years (by 2006) as durable year for food wastes treatment plant, it is expected 42.5ton/day for treatment capacity. We can judge that it is effective to be set 2 lines equipment ${\times}25ton/day$ as treatment ability under considering unexpected working condition such as any repair, trouble and an electrical load. If it schedule about 10 years (by 2011) as durable year for food wastes treatment plant, it is expected 150 ton/day for treatment capacity. We can conclude that it is effective to be set 2 lines equipment ${\times}80ton/day$ as treatment ability under considering working condition such as low loaded operating and the repair for incineration. 순천시 생활계폐기물의 배출특성을 제시하고 장래 폐기물대책을 수립하는 기본적인 자료로 정보를 제공하고자 폐기물별 자원화시설의 용량을 산정하고 재활용시설의 운영관리 및 제반폐기물정책 수립에 활용하도록 하기 위해서 조사분석하여 다음과 같은 결과를 얻었다. 일반주택의 배출량원단위는 0.50kg/인${\cdot}$일로 배출량은 41.9톤/일, 공동주택의 배출량원단위는 0.45kg/인${\cdot}$일로 배출량은 55.5톤/일, 읍 면지역의 배출량원단위는 0.22kg/인${\cdot}$일로 배출량은 13.5톤/일로 나타나 주택지역의 생활계폐기물 배출량은 110.9톤/일이다. 재래시장의 배출량원단위는 1.85kg/상가 일로 배출량은 5,400kg/일이며, 소규모점포의 배출량원단위는 2.03kg/상가 일로 배출량은 25,101kg/일로 나타나 상가지역의 생활계폐기물 배출량은 30,501kg/일이다. 공장지역에서 배출되는 사업장생활계폐기물은 1일 평균 8.3톤, 학교와 병원 및 업무지역에서 배출되는 생활계폐기물의 1일 평균배출량은 각각 7.2kg과 3.0kg 및 6.6kg이다. 생활폐기물 중에서 음식물쓰레기는 평균 63.4톤/일 배출되었으며, 소각대상 가연성폐기물은 126.9톤/일 배출되었다. 음식물쓰레기처리시설의 내구년도를 약 5년(2006년도)으로 계획하면 처리대상량은 1일 42.4톤이 예상되며, 저부하 운전이나 고장보수로 인한 가동중지 등의 문제를 고려하여 처리능력을 25톤/일${\times}$2계열로 설치하는 것이 효율적일 것으로 판단된다. 소각처리시설의 내구년도를 약 10년(2011년도)으로 계획하면 처리대상량은 1일 150톤/일이 예상되며, 저부하 운전이나 고장보수로 인한 소각작업 중지 등의 문제를 고려하여 처리능력을 80톤/일${\times}$2계열로 설치하는 것이 효율적일 것으로 판단된다.
Tylosin Production by Mutant Resistant to Oleic Acid
최두복,문옥란,윤미란,지성남,신대윤,Choi, Du-Bok,Choi, On-You,Moon, Ok-Ran,Yoon, Mi-Ran,Ji, Sung-Nam,Shin, Dae-Yewn Korean Society of Environmental Health 2005 한국환경보건학회지 Vol.31 No.5
Streptomyces fradiae로부터 Tylosin을 효율적으로 생산하기 위해 지방산 내성균주을 분리 했다. 여러 지방산중에서 oleic acid 1.6 g/l 이상이 첨가될 때 세포 성장이 완전히 저해 되었다. 그러나 oleic arid 1.2 g/l에서 얻어진 TM-224-1 균주는 최대 균체농도와 tylosin 생산이 얻어졌다. 또한 oleic acid 소비속도는 parent strain 비해 3.8배 증가했다. Oleic acid 내성균주, TM-224-1 균주와 parent strain을 이용해서 jar fermentor에서 균체농도, tylosin 생산, 그리고 rapeseed oil 소비를 표준조건하에 5일동안 비교하였다. TM-224-1 균주을 이용할 경우 균체 농도는 초기에 parent strain비해 증가했으나 배양중반부터는 감소하기 시작했다. rapeseed oil 소비의 경우는 거의 비슷했다. 그러나 Tylosin 생산 수율은 parent strain 비해 약 3.2배 증가했다. When rapeseed oil as the carbon source was used for tylosin production from Streptomyces fradiae TP-1239 was very sensitive to oleic acid. Cell growth was restrained by adding 0.8 g/l of oleic acid to the culture broth. Mutant strain TM-224-1 resistant to 1.2 g/l of oleic acid was obtained by screening in solid and liquid media containing oleic acid. The uptake rate of oleic acid by TM-224-1 was approximately 3.8 fold higher than the parent strain. For comparing the TM-224-1 and the parent strain, batch cultures were carried out in a jar fermentor. Cell growth of TM-224-1 strain was higher than the parent strain after two days of culturing. However, after four days of culturing, it was similar to that of the parent strain. The amount of rapeseed oil consumed by TM-224-1 and the parent strain were 60.5 and 78.2 g/l, respectively. The production and yield of tylosin was aproximately 2.0 and 3.2 fold higher than the parent strain, respectively. From these results, it was concluded that this mutant, which was resistant to oleic acid, has improved tylosin production.
신대윤,지성남,문옥란,김지영,서동우,조영관,Shin Dae-Yewn,Ji Sung-Nam,Moon Ok-Ran,Kim Ji-Yeong,Suh Dong-Woo,Cho Young-Kwan 한국환경보건학회 2004 한국환경보건학회지 Vol.30 No.5
The objective of this investigation was to evaluate applicability of precoat filtration that can be substituted for rapid sand filter of conventional water treatment system(CWTS). Precoat filter used in this experiment are candle filter. Element disk of candle are pore size $10{\mu}m(R),\;20{\mu}m(B)$ And diatomaceous earth are cake pore size $3.5{\mu}m$(Standard Super- Cel; A), $7{\mu}m$(Hyflo Super-Cel; B) and $17{\mu}m$(Celite 545RV; C). $2kg/m^2$ diatomaceous earth is used for precoating, it coated candle in $5{\sim}6mm$ thickness. 1. Al adsorption dosages by diatomaceous earth used in experimental we Hyflo Super-Cel 0.843mg/g, Standard Super-Cel 0.782 mg/g and Celite 545RV 0.766 mg/g. 2. Filtrate of precoat filter during 60min are R-C combination 20.7($m^3/m^2$)>B-C 18.3($m^3/m^2$)>B-B 15.0($m^3/m^2$)> R-B 12.9($m^3/m^2$)> R-A 11,093($l/m^2$). 3. Water quality of precoat filter effluent are thus. $KMnO_4$ consumption are $1.10{\sim}2.20mg/l$, removal rate are $30.9{\sim}65.6\%$. They are R-A 1.10(mg/l)(removal rate $65.6\%$). R-C(2.20 mg/l)(removal rate $30.9\%$). 4. $Al^{3+}$ are not detected with all combination, removal rate $100\%$. 5. Considering water quality and flux, continued running time of R-A combination is 7 hr. Accumulated filtrate are $74.4 m^3/m^2$, average flux is $177.2 l/m^2{\cdot}min$. And filtrate per diatomaceous earth 1g are 37.2 l. 6. R-A effluent's water quality are $KMnO_4$ Consumption 1.10(mg/l), DOC 1.161 mg/1, Al 0.0 mg/1, $UV_{254}$ 0.016/cm, Turbidity 0.1(NTU). R-A combination is suitable to precoat filtration for the settling basin effluent treatment.
목재방부제(CCA) 오염토양의 소성가공 굴껍질을 이용한 비소 안정화
문덕현 ( Deok Hyun Moon ),정경훈 ( Kyung Hoon Cheong ),김태성 ( Tae Sung Kim ),김지형 ( Jee Hyeong Khim ),최수빈 ( Su Bin Choi ),문옥란 ( Ok Ran Moon ),옥용식 ( Yong Sik Ok ) 韓國環境農學會 2009 한국환경농학회지 Vol.28 No.4
폐굴껍질을 분쇄하여 만든 안정화제 NOS와 NOS를 900℃에서 2시간 소성하여 제작한 안정화제 POS를 비소오염토양에 적용시켜 처리하여 28일 동안 습윤양생 시켜 토양오염공정시험기준 (1N HCl 추출)에 따라 비소 가용능을 평가하였다. NOS와 POS 모두 오염토양 무게대비 함량이 증가할수록 비소오염 토양안정화에 효율적이었다. 특히 주성분이 방해석인 NOS에 비해, 주성분이 생석회인 POS가 안정화에 매우 효과적이었다. 입경에 따른 안정화 효율을 분석한 결과 -#20 mesh가 -#10 mesh보다 대체적으로 좀 더 효율적이었다. 오염토양 대비 -#10 mesh POS 20% 첨가 시 습윤양생 28일 후 1N HCl 추출로 가용성 평가시 12 mg/kg으로 분석되어 토양환경보전법의`나`지역 우려기준인 20 mg/kg을 만족하였다. 그러나 -#20 mesh NOS 20% 첨가 시 같은 용출법으로 169 mg/kg로 분석되어 POS를 안정화제로 사용시 NOS보다 매우 효과적임을 알 수 있었다. SEM-EDX를 통한 비소 안정화 기작은 불용성 물질인 Ca-As 침전물에 기인한 것으로 판단되며 또한 CAHs, CSHs와 같은 포졸란 물질도 비소 농도 저감에 기여하는 것으로 사료된다. Arsenic (As) is known to be very toxic and carcinogenic to human beings. Arsenic contaminated soil was collected from a timber mill site at Busan Metropolitan City, Korea, where chromated copper arsenate (CCA) had been used to protect wood from rotting caused by insects and microbial agents. The soil was stabilized using both natural oyster shells (NOS) and calcinated oyster shells (POS). The calcination of natural oyster shells was accomplished at a high temperature in order to activate quicklime from calcite. Two different oyster shell particle sizes (-#10 mesh and -#20 mesh) and curing periods of up to 28 days were investigated. The stabilization effectiveness was evaluated based on the Korean Standard Test (KST) method (1N HCl extraction). The stabilization results showed that the POS treatment was more effective than the NOS treatment at immobilizing the As in the contaminated soils. A significant As reduction (96%) was attained upon a POS treatment at 20 wt% and passed the Korean warning standard of 20 mg/kg (`Na` area). However, an As reduction of only 47% (169 mg/kg) was achieved upon a NOS treatment at 20 wt%. The -#20 mesh oyster shells seem to perform better than the -#10 materials. The scanning electron microscopy (SEM)-energy dispersive X-ray spectroscopy (EDX) results showed that As immobilization was strongly associated with Ca and O in the presence of Al and Si.