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김형석,김원길,최유정,김정훈,최재욱,Kim, Hyeong Seok,Kim, Won Kil,Choi, Yu Jung,Kim, Jung-Hun,Choi, Jae-Wook 한국안전학회 2018 한국안전학회지 Vol.33 No.2
This study was conducted to assess the hazards of gasoline in relevance to the changes in octane numbers, and gasoline's spontaneous ignition temperature and instantaneous ignition temperature were measured. Spontaneous ignition temperature of regular gasoline was $301^{\circ}C$ for sample quantity of $100{\sim}125{\mu}{\ell}$. Spontaneous ignition temperature of middle gasoline was $380^{\circ}C$ for sample quantity of $125{\mu}{\ell}$ and that of premium gasoline was $400^{\circ}C$. As gasoline's octane numbers increased, their spontaneous ignition temperatures increased, and their instantaneous ignition temperature were almost identically $499^{\circ}C$ for sample quantity of $125{\mu}{\ell}$. In addition, activation energies of regular gasoline, middle gasoline, and premium gasoline were 10.48 Kcal/mol, 16.89 Kcal/mol, and 24.55 Kcal/mol respectively.
김형석,강상철,정지열,김현섭,김대용,김재훈,Kim, Hyeong-Seok,Kang, Sang-Chul,Jung, Ji-YouI,Kim, Hyun-Sup,Kim, Dae-Yong,Kim, Jae-Hoon 대한수의학회 2008 大韓獸醫學會誌 Vol.48 No.3
A two-year-old mixed breed sow was requested to the Veterinary Pathology Laboratory of Cheju National University with a clinical signs of severe abdominal pain and sudden death. Grossly, there was severe hemorrhage in abdominal cavity. Most of internal parenchymas and subcutaneous muscle showed severe pale discoloration. Both ovaries were enlarged with oval to round protruding multilobular masses and dark red in color. And they were firm and contained multiple small cysts in their cut surface. Histopathologically, numerous neoplastic granulosa cells had spherical-to-oval, hyperchromatic nuclei and scant eosinophilic cytoplasms were distributed with follicular pattern in ovarian masses. And the typical Call-Exner bodies, distinctive microcavityies, were observed in the center of small neoplastic follicles. Based on the gross and histopathologic findings, this case was diagnosed as granulosa cell tumor. In our best knowledge, this is believed to be the first report of granulosa cell tumor in a sow in Korea.
실시간 In-situ IR을 이용한 Glycidyl Azide Monomer(GAM)의 양이온중합 반응속도 연구
김형석,김관영,강신춘,노시태,김진석,유재철,최근배,Kim, Hyoung-Sug,Kim, Kwan-Yung,Kang, Shin-Choon,Noh, Si-Tae,Kim, Jin-Seuk,Yu, Jae-Chul,Choi, Keun-Bae 한국군사과학기술학회 2009 한국군사과학기술학회지 Vol.12 No.2
We synthesized glycidyl azide monomer(GAM) as a monomer for polymerization of glycidy azide polymer(GAP) which is a promising energetic prepolymer for a plastic-bonded explosive. Using quantitative real-tim in-situ infrared(in-situ IR) spectroscopy, kinetic study on the cationic ring opening polymerization of GAM was carried out. The reaction rate was obtained from monitoring the change of ether C-O stretching band($1050cm^{-1}$) in series IR spectra. The reaction was in accordance with the first-order reaction law for each of reaction temperature at 100/1 mole ratio of [GAM]/[$BF_3*etherate$]. In the ring opening polymerization of GAM, with ratio of [GAM]/[$BF_3*etherate$] to equal 100/1 at various temperature, the activation parameters obtained from the evaluation of kinetic data were ${\Delta}H^*$=14.34kcal/mol, ${\Delta}S^*=-12.31cal/mol{\cdot}K$ and $E_a$=14.89kcal/mol.
전층 각막이식 후 경면현미경, 초음파 각막두께측정계 및 Orbscan을 이용한 중심 각막두께 측정치의 비교
김형석,김준헌,김효명,송종석,Hyoung-Seok Kim,Jun Heon Kim,Hyo Myong Kim,Jong-Suk Song 대한안과학회 2007 대한안과학회지 Vol.48 No.2
Purpose: To compare the accuracy and reproducibility of central corneal thickness measured by non-contact specular microscopy, ultrasound pachymetry, and Orbscan in the post-penetrating keratoplasty eyes. Methods: Central corneal thickness was prospectively measured in eyes that had recieved penetrating keratoplasty at least 1 month before. One experienced technician measured all eyes using three methods; non-contact specular microscopy (Topcon SP-2000P; Topcon Corporation, Tokyo, Japan), Orbscan IIz (Orbtek; Bausch & Lomb, Rochester, USA), and ultrasound pachymetry (AL-2000; Tomey, Erlangen, Germany). Three consecutive measurements were performed using each method and the mean values and coefficient of variation were compared. Results: The mean values of central corneal thickness were 550.7±63.3 ?m with specular microscopy, 548.2±72.5 ?m with ultrasound pachymetry, and 472.5±151.7 ?m with Orbscan. There was no significant difference between the measurements obtained by specular microscopy and ultrasound pachymetry (p=0.53), and both methods showed high reproducibility. The corneal thickness measured by Orbscan was remarkably variable and in some patients, Orbscan was unable to measure corneal thickness. Conclusions: Non-contact specular microscopy appears to be an effective technique, potentially replacing ultrasound pachymetry for measuring central corneal thickness in the post-penetrating keratoplasty eyes.
포수제(捕收劑) 종류(種類)에 따른 공작석(孔雀石)의 부유선별(浮遊選別) 특성(特性)
김형석,김완태,한인규,김상배,Kim, Hyung-Seok,Kim, Wan-Tae,Han, In-Kyu,Kim, Sang-Bae 한국자원리싸이클링학회 2010 資源 리싸이클링 Vol.19 No.4
공작석의 부선에 적합한 포수제를 규명하기 위하여 각종 포수제의 종류에 따른 공작석의 부유선별 특성을 연구하였다. 공작석의 제타전위를 측정한 결과, 공작석의 등전점은 약 pH 8.2로, 등전점 이상의 pH에서는 공작석의 표면이 음(-)으로 하전되고, 등전점 이하에서는 양(+)으로 하전됨을 확인하였다. 공작석은 음이온 포수제인 sodium oleate와 Aeropromoter 845에 의해서 pH 5~11의 범위에서 97%이상 부유되었다. 그러나 alkyl hydroxamate 및 양이온 포수제인 dodecyl trimethyl ammonium chloride와 dodecyl ethyl methyl ammonium chloride에 의해서는 pH 5 이상에서 첨가량에 관계없이 15%미만으로 부유되었다. 공작석을 $(NH_4)_2S$로 황화처리한 후 potassium amyl xanthate로 부선하였을 때, 공작석은 97%이상 부유되었다. 이때 황화처리하지 않았을 때 보다 potassium amyl xanthate의 첨가량이 1/3 정도 적어졌고, 부선시간도 단축되었다. 따라서 공작석의 부선에 적합한 포수제는 potassium amyl xanthate와 음이온 포수제인 sodium oleate 및 Aeropromoter 845이었다. In order to select the proper collector for the flotation of malachite, we had floated malachite by using various collectors. When measuring the zeta potential of malachite, we knew that the point of zero charge of malachite is found at pH 8.2 and malachite particles are negatively charged above this pH value; and positively, below this pH value. The floatability of malachite by the anionic collectors like sodium oleate and Aeropromoter 845, was about 97% in pH 5~11 range, whereas that of malachite by alkyl hydroxamate and the cationic collector like dodecyl trimethyl ammonium chloride and dodecyl ethyl methyl ammonium chloride, was below 15% above pH 5 regardless of dosage increase of collector and flotation time. The malachite sulphidised by $(NH_4)_2S$ was floated above 97% by potassium amyl xanthate. The dosage of potassium amyl xanthate decreased and the flotation period shortened to one third than when it was not sulphidised by $(NH_4)_2S$. Therefore, potassium amyl xanthate and the anionic collectors like sodium oleate and Aeropromoter 845 can be used as the collector of malachite.
Trinitrotoluene의 환원반응에서 가스크로마토그래피 모니터링을 이용한 2,6-diamino-4-nitrotoluene의 합성
김형석,유재철,김호기,김새롬,최근배,정원복,서원준,김진석,Kim, Hyoung-Sug,Yu, Jae Chul,Kim, Ho Gi,Kim, Sae Rom,Choi, Keun Bae,Jung, Won Bok,Seo, Won Jun,Kim, Jin-Seuk 한국군사과학기술학회 2014 한국군사과학기술학회지 Vol.17 No.2
In this research, we investigated synthetic method of 2,6-DANT that can be used as a chain extender of urethane/urea and epoxy materials in a demilitarization method via chemical transformations considering environmental, economical aspects and stability of process. We was able to identify through GC monitoring that 2,4-DANT and 2,6-DANT were produced when we inject 'hydrazine monohydrate 3.3 eq. by TNT 1 eq.' with a fine metering pump for 30 minutes and then, reflux for an additional 2 hours. We was able to isolate only 2,6-DANT(99.3% purity and 45.0% yield) from mixture of 2,4-DANT and 2,6-DANT through the separating and refining methods using 2,6-DANT solubility in methanol and crystallinity of 2,6-DANT.
2차원 수치모형을 이용한 원형군락 하류의 흐름특성 수치모의
김형석,박문형,Kim, Hyung Suk,Park, Moonhyeong 한국수자원학회 2015 한국수자원학회논문집 Vol.48 No.11
본 연구는 식재된 개수로에서 흐름특성을 모의할 수 있는 수심 적분된 2차원 수치모형을 이용하여 원형 식생역 주변의 흐름을 수치모의하였다. 식생영향을 고려하기 위해 식생항력 항을 지배방정식에 추가하였고 다양한 식생체적비율(SVF) 조건에 따른 수치모의를 수행하였다. 흐름이 원형 식생역을 통과하고 하류에 저유속 구간인 후류영역(wake region)을 형성하며 식생체적비율이 0.08 이상이면 재순환 영역이 발생하였다. 재순환 발생위치는 식생체적비율이 감소하면 식생역에서 더욱 하류로 이동하였다. 후류영역을 지나 원형 식생역 양 측면에서 유발된 전단층들의 상호작용에 의해 von $K{\acute{a}}rm{\acute{a}}n$ 와열이 발생하였다. 원형 식생역 하류에서 발생하는 와류는 식생체적비율이 0.08 이상이 되면 나타나기 시작하였고 발생위치는 난류운동에너지가 최대값을 보이는 위치와 일치하였다. 최대 난류운동에너지는 식생체적비율이 감소하면 줄어드는 것으로 나타났고 최대값의 발생위치는 점점 하류로 이동하였다. This paper presents numerical simulations of flow around a circular patch of vegetation using a depth-averaged two-dimensional numerical model which is capable of simulating flow structure in vegetated open channel. In order to account for vegetation effect, drag force terms are included in governing equations. Numerical simulations are conducted with various solid volume fractions (SVF). Flow passes through a circular patch and low velocity region, which is called wake region, is formed downstream of the patch. When SVF is larger than 0.08, a recirculation is observed. The location of the recirculation is moved further downstream as SVF decreases. Von-$K{\acute{a}}rm{\acute{a}}n$ vortex street is developed beyond the wake region due to interaction between two shear layers induced by a circular patch of vegetation. The vortex is developed as SVF is larger than 0.08, and the location of the vortex is consistent with the maximum of turbulence kinetic energy. The location of the peak of turbulence kinetic energy is moved further downstream as SVF decreases.