착용한 실리콘 하이드로겔 콘택트렌즈의 표면침착과 투광성 변화

신형섭,박인지,장준규 대한시과학회 2014 대한시과학회지 Vol.16 No.2

Purpose: The purpose of this study was to observe the surface deposits on the worn silicone hydrogel lens by X-ray photoelectron spectroscopy(XPS) and to understand relation to the optical transmittances. Methods: After wearing plasma treated Lotrafilcon A silicone hydrogel lens, the components of the surface deposits and chemical bonds were analyzed by XPS, and measured the optical transmittance in accordance with the surface deposits. Results: At the beginning, mucin deposit occurred mainly and it occupied 40% of the deposits but there was no big increment in mucin deposit afterwards. The amount of the lipid deposit was smaller than mucin but it continued to increase up to 20%. 3.4% of the optical transmittance of the visible ray decreased by the first 5 days, and after that additional decrease of the optical transmittance was 1.2%. Conclusions: The deposits of hydrophilic surface of silicone hydrogel lens treated by plasma were mainly mucin and the lipid is deposited on the mucin deposit and slowly increased. The deposits reduce the optical transmittance, but the influence on the optical transmittance has decreased. 목 적: 착용한 실리콘 하이드로겔 렌즈 표면에 침착된 성분을 X-선광전자분광법으로 관찰하였으며, 투광성과의 관련성을 연구하였다. 방 법: 표면을 플라즈마 코팅한 Lotrafilcon A 재질의 실리콘 하이드로겔 렌즈를 착용한 다음, 표면에 침착물의 성분과 화학결합을 X-선광전자분광분석기(XPS)로 분석하였으며, 침착에 따른 광투과율을 관찰하였다. 결 과: 착용 초기에는 점액질의 침착이 주로 일어나 40% 이상이 되었으며, 그 이후에는 큰 증가가 없었다. 지방의 침착은 점액질보다 적지만 20%까지 계속 증가하였다. 가시광선의 광투과율은 착용 5일까지 3.4% 감소하였으며, 그 이후에 1.2% 정도 더 감소하였다. 결 론: 플라즈마 처리로 표면이 친수성인 실리콘 하이드로겔 렌즈의 침착은 주로 점액질에 의해 발생하며, 지방은 침착된 점액질에 쌓이면서 서서히 증가하였다. 침착물로 인하여 렌즈의 광투과율이 저하되었으나, 그 영향은 점차 감소하였다.

착용한 실리콘 하이드로겔 콘택트렌즈의 표면침착과 투광성 변화

신형섭,박인지,장준규 대한시과학회 2014 대한시과학회지 Vol.16 No.2

목 적: 착용한 실리콘 하이드로겔 렌즈 표면에 침착된 성분을 X-선광전자분광법으로 관찰하였으며, 투광성과의 관련성을 연구하였다. 방 법: 표면을 플라즈마 코팅한 Lotrafilcon A 재질의 실리콘 하이드로겔 렌즈를 착용한 다음, 표면에 침착물의 성분과 화학결합을 X-선광전자분광분석기(XPS)로 분석하였으며, 침착에 따른 광투과율을 관찰하였다. 결 과: 착용 초기에는 점액질의 침착이 주로 일어나 40% 이상이 되었으며, 그 이후에는 큰 증가가 없었다. 지방의 침착은 점액질보다 적지만 20%까지 계속 증가하였다. 가시광선의 광투과율은 착용 5일까지 3.4% 감소하였으며, 그 이후에 1.2% 정도 더 감소하였다. 결 론: 플라즈마 처리로 표면이 친수성인 실리콘 하이드로겔 렌즈의 침착은 주로 점액질에 의해 발생하며, 지방은 침착된 점액질에 쌓이면서 서서히 증가하였다. 침착물로 인하여 렌즈의 광투과율이 저하되었으나, 그 영향은 점차 감소하였다. Purpose: The purpose of this study was to observe the surface deposits on the worn silicone hydrogel lens by X-ray photoelectron spectroscopy(XPS) and to understand relation to the optical transmittances. Methods: After wearing plasma treated Lotrafilcon A silicone hydrogel lens, the components of the surface deposits and chemical bonds were analyzed by XPS, and measured the optical transmittance in accordance with the surface deposits. Results: At the beginning, mucin deposit occurred mainly and it occupied 40% of the deposits but there was no big increment in mucin deposit afterwards. The amount of the lipid deposit was smaller than mucin but it continued to increase up to 20%. 3.4% of the optical transmittance of the visible ray decreased by the first 5 days, and after that additional decrease of the optical transmittance was 1.2%. Conclusions: The deposits of hydrophilic surface of silicone hydrogel lens treated by plasma were mainly mucin and the lipid is deposited on the mucin deposit and slowly increased. The deposits reduce the optical transmittance, but the influence on the optical transmittance has decreased.

가역 감온 변색 겔형 염화 코발트/polyvinyl butyral을 이용한 온도 감지광섬유 센서 연구

황기섭 ( Ki Seob Hwang ),박재희 ( Jea Hee Park ),하기룡 ( Ki Ryong Ha ),이준영 ( Jun Young Lee ) 한국화학공학회 2014 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.52 No.4

염화코발트 용액을 사용하여 전자기파와 진동에 영향을 받지 않는 원거리 실시간 광섬유 온도 감지 센서를 개발하였다. 염화코발트 용액을 제조하기 위하여, 물과 에탄올은 부피 비율로 10%와 90%로 고정하고, 용해되는 염화코발트의 양을 다양하게 변화시켰다. 제조된 염화코발트 용액은 자외-가시선 분광 광도계를 사용하여, 온도 변화에 따른 655 nm 파장의 투과도를 측정하였다. 또한 제조된 30.8 mM 염화코발트 수화물 용액에 polyvinyl butyral을 용해시켜 겔화한후, 온도 변화에 따른 655 nm 파장의 투과도 측정 및 센서 적용 후 광 파워 분석을 실시하였다. 투과도와 광 파워 측정 결과, 25 ℃에서 66.8%와 149.5 nW, 70 ℃에서는 7.1%와 48 nW로 각각 나타나, 온도가 증가함에 따라 투과도와 광 파워 모두 감소하는 경향을 보였다. 본 실험에서 제조된 겔화 염화코발트/polyvinyl butyral은 온도 변화에 따라 655 nm 파장에 대한 광 투과도와 광 파워가 변하는 점을 이용하여 온도 변화를 감지하기 위한 광섬유 센서로 사용 가능함을 확인하였다. In this study, we developed an optical-fiber sensor using cobalt chloride solution to monitor temperature in real-time between long distance points unaffected by the electro-magnetic wave and the vibration. Cobalt chloride solutions were made using 10% water and 90% ethanol (v/v) solution. The transmittance of these solutions was analyzed on 655 nm using UV-Visible spectrometer regarding temperature change. Also 30.8 mM cobalt chloride solution was gelled by dissolving polyvinyl butyral and the transmittance of this was analyzed on 655 nm regarding temperature change. The results of transmittance and optical power measurement showed decrease of both transmittance and optical power with increase of temperature from 66.8% and 149.5 nW at 25 ℃ to 7.1% and 48 nW at 70 ℃, respectively. These results support the possibility of gelled cobalt chloride/polyvinyl butyral as an optical-fiber sensor to monitor temperature change.

ITO 박막의 전기저항과 광투과도 특성에 미치는 ZnO 첨가 효과

채홍철,홍주화,Chae, Hong-Choi,Hong, Joo-Wha 한국전기전자재료학회 2007 전기전자재료학회논문지 Vol.20 No.4

[ $In_2O_3-ZnO(IZO)$ ] and $In_2O_3-ZnO-SnO_2(IZTO)$ thin films were prepared on EAGLE 2000 glass webs in a Ar gas by RF-Magnetron sputtering. Electrical resistivity and optical transmittance of the films were investigated. IZO, IZTO film showed excellent optical transmittance of 85 % at the visible $400{\sim}$780 nm wavelength. Electrical properties of IZO film have $6.50{\times}10^{-4}{\Omega}cm$ (95 $In_2O_3$ : 5 ZnO wt.%) and $5.20{\times}10^{-4}{\Omega}cm$ (90 : 10 wt.%), IZTO film have $8.00{\times}10^{-4}{\Omega}cm$ (90 $In_2O_3$ : 3 ZnO : 7 $SnO_2$ wt.%) and $6.50{\times}10^{-4}{\Omega}cm$ (90 : 7 : 3 wt.%). Substitution of SnO to ZnO in ITO films showed slightly lower electrical conductivity than ITO film but showed similar optical transmittance.

Polymerization and Preparation of Functional Ophthalmic Material Containing Carbon Nanoparticles

Lee, Min-Jae,Sung, A-Young Materials Research Society of Korea 2018 한국재료학회지 Vol.28 No.8

This research is conducted to create a functional hydrogel ophthalmic lens containing nanoparticles. Carbon nanoparticles and PEGMEMA are used as additives for the basic combination of HEMA, MA, and MMA, and the materials are copolymerized with EGDMA as the cross-linking agent and AIBN as the thermal initiator. The hydrogel lens is produced using a cast-mold method, and the materials are thermally polymerized at $100^{\circ}C$ for an hour. The polymerized lens sample is hydrated in a 0.9 % saline solution for 24 hours before the optical and physical characteristics of the lens are measured. The refractive index, water content, contact angle, light transmittance, and tensile strength are measured to evaluate the physical and optical characteristics of the hydrogel lens. The refractive index, water content, contact angle, UV-B light transmittance, UV-A light transmittance, visible light transmittance, tensile strength and breaking strength of the hydrogel lens polymer are 1.4019~1.4281, 43.05~51.18 %, $31.95{\sim}68.61^{\circ}$, 21.69~58.11 %, 35.59~84.26 %, 45.85~88.06 %, 0.1075~0.1649 kgf and 0.1520~0.2250 kgf, respectively. The results demonstrate an increase in refractive index, tensile strength and breaking strength and a decrease in contact angle and light transmittance. Furthermore, the visible light transmissibility is significantly increased at PEG 10 %. It is clear that this material can be used for high-performance ophthalmic lenses with wettability, ultraviolet ray blocking effect, and tensile strength.

염료감응형 태양전지의 탄소나노튜브 상대전극의 광투과도와 전기화학적 특성이 에너지 변환 효율에 미치는 영향

한영문,황숙현,강명훈,김영주,김현국,김상효,배효준,최현광,전민현,Han, Young-Moon,Hwang, Sook-Hyun,Kang, Myung-Hoon,Kim, Young-Joo,Kim, Hyun-Kook,Kim, Sang-Hyo,Bae, Hyo-Jun,Choi, Hyon-Kwang,Jeon, Min-Hyon 한국전기전자재료학회 2011 전기전자재료학회논문지 Vol.24 No.4

In this work, electrochemical characteristics and optical transmittance of carbon nanotubes (CNTs) counter electrodes which had different amount of CNTs in CNTs slurries were analyzed. Two-step heat treatment processes were applied to achieve well-fabricated CNTs electrode. Three sets of CNTs electrodes and dye-sensitized solar cells (DSSCs) with CNTs counter electrodes were prepared. As the amount of CNTs increased, sheet resistance of CNTs electrode decreased. CNTs electrode with low sheet resistance had low electrochemical impedance and fast redox reaction. On the other hand, in case of CNTs counter electrode with low density of CNTs, performance of the dye-sensitized solar cell was improved due to its high optical transmittance. We found that the transmittance of CNTs counter electrode influence the performance of dye-sensitized solar cells.

Physical Properties of Ophthalmic Hydrogel Polymer Containing Zinc Oxide Nanoparticles

Sung, A-Young,Kim, Tae-Hun The Basic Science Institute Chosun University 2013 조선자연과학논문집 Vol.6 No.2

ZnO nanoparticles and vinyl pyridine were added to the mixture of MMA (methyl methacrylate), HEMA (2-hydroxy ethyl methacrylate) and NVP (N-vinylpyrrolidone) in a mould at various concentrations. Cross-linker EGDMA (ethyleneglycoldimethacrylate) and AIBN (azobisisobutyronitrile) initiator were finally added to the mixture and then heated at $80^{\circ}C$ for 60 min to prepare high-performance hydrogel ophthalmic lens. The physical properties of the hydrogel ophthalmic material were investigated by measuring the average value of refractive index, water content and optical transmittance. The refractive index of 1.429~1.450, water content of 34~41%, and visible transmittance of 78~90% were obtained. The material is possibly used to manufacture UV-block hydrogel contact lens.

Physical Properties of Ophthalmic Hydrogel Polymer Containing Zinc Oxide Nanoparticles

성아영,김태훈 조선대학교 기초과학연구원 2013 조선자연과학논문집 Vol.6 No.2

ZnO nanoparticles and vinyl pyridine were added to the mixture of MMA (methyl methacrylate), HEMA (2-hydroxyethyl methacrylate) and NVP (N-vinylpyrrolidone) in a mould at various concentrations. Cross-linker EGDMA (ethyleneglycoldimethacrylate) and AIBN (azobisisobutyronitrile) initiator were finally added to the mixture and then heated at 80oC for 60 min to prepare high-performance hydrogel ophthalmic lens. The physical properties of the hydrogel ophthalmic material were investigated by measuring the average value of refractive index, water content and optical transmittance. The refractive index of 1.429~1.450, water content of 34~41%, and visible transmittance of 78~90% were obtained. The material is possibly used to manufacture UV-block hydrogel contact lens.

Compact Infrared/Visible Laser Transmitter Featuring an Extended Detectable Trajectory

Haeng-In Kim,Hong-Shik Lee,이상신 한국광학회 2012 Current Optics and Photonics Vol.16 No.4

A miniaturized laser beam transmitter, in which a visible laser module at λ=650 nm is precisely stacked upon an infrared (IR) module at λ=905 nm, has been proposed and constructed to provide an IR collimated beam in conjunction with a collinear monitoring visible beam. In particular, the IR beam is selectively dispersed through a perforated sheet diffuser, so as to create a rapidly diverging close-range beam in addition to a highly defined long-range beam simultaneously. The complementary close-range beam plays a role in mitigating the blind region in the vicinity of the transmitter, which is inevitably missed by the main long-range beam, thereby uniformly extending the transmitter’s effective trajectory that is sensed by a receiver. The proposed transmitter was designed through numerical simulations and then fabricated by incorporating a diffuser sheet, perforated with an aperture of 2 mm. For the manufactured transmitter, the IR long-range beam was observed to have divergences of ~2.3 and 1.6 mrad in the fast and slow axes,respectively, while the short-range beam yielded a divergence of ~24 mrad. The angular alignment between the long-range IR and visible beams was as accurate as ~0.5 mrad. According to an outdoor feasibility test involving a receiver, the combination of the IR long- and short-range beams was proven to achieve a nearly uniform trajectory over a distance ranging up to ~600 m, with an average detectable cross-section of ~60×80 cm2.

Studies on optical-fiber sensor to monitor temperature using reversible thermochromic gel type cobalt(II) chloride/polyvinyl butyral

황기섭,하기룡,이준영 한국공업화학회 2014 한국공업화학회 연구논문 초록집 Vol.2014 No.0