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Xinwei Yang,Cheng Yang,Shujuan Hou,Yiqi Mao 대한기계학회 2021 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.35 No.11
This work provide theoretical understandings for the enzyme-degradable PCL, and assist its structural designs and engineering applications. An energy-dependent evolution model is developed to reflect the enzyme-triggered decrystallization of crystals and the further dissolution by applying a chain-broken chemical reaction. Then, the mechanical properties of the enzyme-degradable semicrystalline PCL is modelled through the homogenization-based procedure by the volume-average of a collection of laminated inclusions with crystals and amorphous phase. A dual-phase-lag diffusion model is advanced to solve the enzyme concentrations in the PCL. The model is calibrated by the experiments and then applied for the chemomechanical properties of the PCL when under enzyme conditions. Some numerical examples are conducted to discuss effects of the enzyme concentration and the crystallinity on the crystallographic axe evolution as well as the overall chemomechanical properties of the semicrystalline PCL.
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Fupeng Li,Kai Huang,Jinbing Wang,Kai Yuan,Yiqi Yang,Yihao Liu,Xianhao Zhou,Keyu Kong,Tao Yang,Jian He,Chunjie Liu,Haiyong Ao,Fengxiang Liu,Qian Liu,Tingting Tang,Shengbing Yang 한국생체재료학회 2023 생체재료학회지 Vol.27 No.00
Background Although biomedical implants have been widely used in orthopedic treatments, two major clinical challenges remain to be solved, one is the bacterial infection resulting in biofilm formation, and the other is aseptic loosening during implantation due to over-activated osteoclastogenesis. These factors can cause many clinical issues and even lead to implant failure. Thus, it is necessary to endow implants with antibiofilm and aseptic looseningprevention properties, to facilitate the integration between implants and bone tissues for successful implantation. To achieve this goal, this study aimed to develop a biocompatible titanium alloy with antibiofilm and anti-aseptic loosening dual function by utilizing gallium (Ga) as a component. Methods A series of Ti-Ga alloys were prepared. We examined the Ga content, Ga distribution, hardness, tensile strength, biocompatibility, and anti-biofilm performance in vitro and in vivo. We also explored how Ga3+ ions inhibited the biofilm formation of Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) and osteoclast differentiation. Results The alloy exhibited outstanding antibiofilm properties against both S. aureus and E. coli in vitro and decent antibiofilm performance against S. aureus in vivo. The proteomics results demonstrated that Ga3+ ions could disturb the bacterial Fe metabolism of both S. aureus and E. coli, inhibiting bacterial biofilm formation. In addition, Ti-Ga alloys could inhibit receptor activator of nuclear factor-κB ligand (RANKL)-dependent osteoclast differentiation and function by targeting iron metabolism, then suppressing the activation of the NF-κB signaling pathway, thus, showing their potential to prevent aseptic loosening. Conclusion This study provides an advanced Ti-Ga alloy that can be used as a promising orthopedic implant raw material for various clinical scenarios. This work also revealed that iron metabolism is the common target of Ga3+ ions to inhibit biofilm formation and osteoclast differentiation.
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Yinglin Yan,Haichao Qin,Yiqi Wei,Rong Yang,Yunhua Xu,Liping Chen,Qiaole Li,Mangmang Shi 대한화학회 2018 Bulletin of the Korean Chemical Society Vol.39 No.5
Recently, three dimensional graphene aerogel (3DGA) supported sulfur microparticles was used as a cathode material for lithium?sulfur batteries, which was considered as one of the most promising next generation rechargeable batteries due to its ultra?high theoretical specific capacity (1675 mAh/g). However, the mechanical strength of 3DGA remains an issue for further application. Herein, a strengthened 3DGA (S3DGA) was achieved by soaking in a low concentration ammonia solution at a relative low temperature. Then the S3DGA loaded sulfur (S3DGA?S) was cut into a round piece and directly used as a cathode without additional binders or conductive additives in Li?S batteries. The mechanical strength, microstructure, and electrochemical properties were investigated by compare with a 3DGA prepared without strengthen. The S3DGA?S presented good mechanical strength, excellent capacity retention, and lower electrochemical impedance.
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Zhenjie Li,Xuezhi Yang,Jun Ma,Mingfei Ban,Yiqi Liu 전력전자학회 2024 JOURNAL OF POWER ELECTRONICS Vol.24 No.3
This paper proposes a main-auxiliary cooperative receiving coil (MA-coil) with a lower space occupation rate and a simple control based on the time-sharing working principle, which can effectively improve the anti-misalignment capability of a dynamic wireless charging (DWC) system. First, the structure and circuit topology of the MA-coil are designed. The two auxiliary coils (A-coil) are connected in reverse series and symmetrically placed on both sides of the main coil (M-coil). Second, the output performance of the MA-coil in the y-direction is calculated based on the time-sharing working principle. The A-coil works by itself and enhances the output power when side shift occurs. Third, the most suitable ratio of coil width w M and w A is determined. The anti-misalignment performance and the effective side shift range are compared through simulation between the MA-coil in this case and the square coil. Finally, an experimental prototype is built to verify the feasibility of the proposed structure, and experimental results obtained from the prototype are basically consistent with the theoretical analysis. The anti-misalignment capability of the MA-coil is more than 20% higher than that of the square coil.
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