Facile and controllable synthesis of nitrogen self-doped chitosan-derived carbon for high-performance Li-ion batteries

Xia Wentao,Cheng Miao,Hu Jing,Liu Qianqian,Wei Tao,Wang Ruirui,Li Wanfei,Liu Bo 한국탄소학회 2024 Carbon Letters Vol.34 No.1

N-doping content and configurations have a significant effect on the electrochemical performance of carbon anodes. Herein, we proposed a simple method to synthesize highly N self-doped chitosan-derived carbon with controllable N-doping types by introducing 2ZnCO3·3Zn(OH)2 into the precursor. The as-synthesized NC-CS/2ZnCO3·3Zn(OH)2 electrode exhibited more than twice the reversible capacity (518 mAh g−1 after 100 cycles at 200 mA g−1) compared to the NC-CS electrode, superior rate performance and outstanding cycling stability. The remarkable improvement should be mainly attributed to the increase of N-doping content (particularly the pyrrolic-N content), which provided more active sites and favored Li+ diffusion kinetics. This study develops a cost-effective and facile synthesis route to fabricate high-performance N self-doped carbon with tunable doping sites for rechargeable battery applications.

The comparison and optimization of zirconia, alumina, and zirconia-alumina supported PtSnIn trimetallic catalysts for propane dehydrogenation reaction

Liu-Liu Long,Ke Xia,Wan-Zhong Lang,Li-Ling Shen,Qiang Yang,Xi Yan,Ya-Jun Guo 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.51 No.-

The zirconia, alumina, and zirconia-alumina (xZr-Al) supported PtSnIn catalysts were prepared andcomparatively studied for propane dehydrogenation reaction. The structure–function relationships ofthe resultant catalysts are well elucidated upon several state-of-art physico-chemical characterizations. The results show that xZr-Al used as support for trimetallic PtSnIn catalysts exhibits the significantcatalytic performances. The PtSnIn/08Zr-Al catalyst has the highest Pt dispersion accompanied with thesmallest average Pt particles, and it presents the initial propane conversion and propylene selectivityabove 55.0% and 98.0% respectively. The initial propane conversions afterfive reaction–regenerationcycles are all above 55.0% and only decrease little ( 3%).

Fault-Tolerant Control for 5L-HNPC Inverter-Fed Induction Motor Drives with Finite Control Set Model Predictive Control Based on Hierarchical Optimization

Li, Chunjie,Wang, Guifeng,Li, Fei,Li, Hongmei,Xia, Zhenglong,Liu, Zhan The Korean Institute of Power Electronics 2019 JOURNAL OF POWER ELECTRONICS Vol.19 No.4

This paper proposes a fault-tolerant control strategy with finite control set model predictive control (FCS-MPC) based on hierarchical optimization for five-level H-bridge neutral-point-clamped (5L-HNPC) inverter-fed induction motor drives. Fault-tolerant operation is analyzed, and the fault-tolerant control algorithm is improved. Adopting FCS-MPC based on hierarchical optimization, where the voltage is used as the controlled objective, called model predictive voltage control (MPVC), the postfault controller is simplified as a two layer control. The first layer is the voltage jump limit, and the second layer is the voltage following control, which adopts the optimal control strategy to ensure the current following performance and uniqueness of the optimal solution. Finally, simulation and experimental results verify that 5L-HNPC inverter-fed induction motor drives have strong fault tolerant capability and that the FCS-MPVC based on hierarchical optimization is feasible.

Transcriptomic and gene expression changes in response to postharvest surface pitting in ‘Lingwu Long’ jujube fruit

Xia Liu,Tengyue Wang,Lan Chen,Limei Li,Yong Wang,Xihong Li,Yage Xing 한국원예학회 2018 Horticulture, Environment, and Biotechnology Vol.59 No.1

‘Lingwu Long’ jujube (Ziziphus jujuba cv. Mill) is a fresh fruit variety that is popular in China. Low temperature storage isan important method for retaining fruit quality postharvest. However, jujube fruits are susceptible to surface pitting underlow temperature storage. Therefore, we performed transcriptome analysis to investigate the changes in gene expression insurface-pitted jujube fruit (SPF). First, we developed cDNA libraries of SPF and surface-intact fruit (SIF) that had beenstored at − 1 ± 0.5 °C. As a result, 21,136,649 and 21,663,126 high-quality clean reads were generated and 47,386 contigswere obtained. Second, we performed sequences annotation by gene description and gene ontology (GO term) analysis,which clustered the genes into three functional groups. A total of 2706 predicted proteins were assigned to specific metabolicpathways by the Kyoto Encyclopedia of Genes and Genomes database. An analysis of differential gene expression betweenSPF and SIF revealed more than 1210 genes that are differentially expressed in jujube in response to surface-pitting under lowtemperature storage, which are involved in lipid, carbohydrate, energy, amino acid, terpenoids, and polyketides metabolism,as well as membrane transport, signal transduction, translation, signal transduction, and biosynthesis of other secondarymetabolites. We investigated the pattern of phenylalanine ammonia lyase gene expression in SPF by quantitative reversetranscriptionPCR analysis. Our results provide new insights into the biology of surface pitting in jujube, which occurs underlow temperature storage. Our findings help confirm the low-temperature tolerance pathways that function in postharvest fruit.

Genome-wide identification and evolutionary analysis of WOX gene family in cucurbit crops

Li Chun,He Zhen,Liang Genyun,Yang Nan,Cai Peng,Liang Ying,Li Yuejian,Fang Chao,Liu Duchen,Xia Feng,Liu Xiaojun 한국원예학회 2024 Horticulture, Environment, and Biotechnology Vol.65 No.1

The WUSCHEL-related homeobox (WOX) gene family is essential for plant growth and development. However, the identifi cation and evolutionary analysis of WOX genes in the Cucurbitaceae have not been well investigated. In the present work, we performed a genome-wide analysis to identify WOX genes in eleven cucurbit crops. In total, 127 WOX genes were identifi ed in eleven cucurbit crops, and classifi ed into three diff erent clades: the ancient clade, the intermediate clade and the WUS clade. The same clade has comparable gene organization and conserved motif patterns. The cis -acting ele ment analysis revealed that WOX genes were involved in light, hormone and stress in cucurbit crops. Gene duplication analysis indicated that dispersed duplication and whole genome duplication were the two primary causes of WOX genes expansion. There were 24 and 129 gene pairs found within cucurbit crops, and between Cucumis sativus and other cucur bit crops, respectively. After gene duplication, all WOX genes were subjected to substantial purifying selection pressure according to the selective pressure analysis. Functional divergence analysis revealed that ancient and intermediate clades may have descended from some essential amino acid sites rather than diff erent evolution rate. Our research provides a comprehensive analysis of WOX genes which will be helpful for further research into their function study in Cucurbita ceae plants.

Acid-doped polyaniline membranes for solar-driven interfacial evaporation

Xia Li,Dongmin Yue,Fei Liu,Jingtong Yu,Bing-Bing Li,De Sun,Xin Ma 한국화학공학회 2023 Korean Journal of Chemical Engineering Vol.40 No.1

Interface solar desalination technology is an important green and sustainable strategy to solve the freshwater crisis. Herein, polyaniline (PANI) membranes were prepared by immersion precipitation phase inversion (NIPs) method and using for solar-driven water evaporation. To improve the light absorption rate of the PANI membrane, acid doping modification was carried out to the membrane. The results show that the polyaniline-p-toluene sulfonic acid (PANI-PTSA) membrane modified by p-toluene sulfonic acid (PTSA) has microporous structure, and the hydrophilicity was greatly improved after modification. The water evaporation rate and solar energy conversion efficiency of PANI-PTSA membrane were 1.38 kg/(m2h) and 80.7% under 1 kW/m2 sunlight irradiation, respectively, significantly improved compared to the original membrane. Due to the electrostatic repulsion effect of PANI-PTSA on anion charged SO − 3 , Na+ is separated from Cl−, which reduces the salt crystallization in the evaporator, indicating that PANI-PTSA membrane has certain salt resistance in solar desalination experiments. This work provides a simple method to prepare the PANI-PTSA membrane with high efficiency and salt resistance that has huge potential for practical application of interface solar desalination technology.

Input/output-to-state Stability of Switched Nonlinear Systems with an Improved Average Dwell Time Approach

Li-Xia Liu,Rong-Wei Guo,Shu-Ping Ma 제어·로봇·시스템학회 2016 International Journal of Control, Automation, and Vol.14 No.2

This paper investigates the input/output-to-state stable (IOSS) property of the switched systems underaverage dwell time (ADT) switching signals in two cases: 1) all of the subsystems are IOSS, 2) parts of the subsystemsare IOSS, and proposes a number of new results on stability analysis. First, we present a new IOSS resultfor the switched nonlinear systems whose subsystems are IOSS with an improved ADT method. Second, extendingthe improved ADT method to unforced nominal switched nonlinear systems in which parts of subsystems arestable, we establish a new stability analysis result. IOSS property of switched nonlinear systems in which parts ofsubsystems are IOSS, we show that if the average dwell time is large enough and if the fraction of time where oneof the non-IOSS system is active is not too big, then IOSS property of the switched system can be established. Itshould be pointed that the main results obtained in this paper have some advantages over the exiting ones. Finally,two illustrative examples with simulation verify the correctness and validity of our results.

Significance of Thrombocytosis in Clinicopathologic Characteristics and Prognosis of Gastric Cancer

Li, Fang-Xuan,Wei, Li-Juan,Zhang, Huan,Li, Shi-Xia,Liu, Jun-Tian Asian Pacific Journal of Cancer Prevention 2014 Asian Pacific journal of cancer prevention Vol.15 No.16

Purpose: We aimed to study the relationship between thrombocytosis and clinical features of gastric cancerfocussing on platelet counts and gastric cancer progression through different TNM stages. Methods: According to the normal range of platelet count in our institution, 1,596 patients were divided to two groups: a thrombocytosis group (120 patients, > $400{\times}1000/{\mu}L$) and a control group (1,476 patients, ${\leq}400{\times}1000/{\mu}L$). Results: The incidence of thrombocytosis was 7.5%. Higher platelet counts were observed in patients with older age, larger tumor size, deeper invasion, lymph node metastasis, distant metastasis and advanced TNM stage. In multivariate logistic regression, tumor size, depth of tumor invasion, lymph node metastasis and TNM stage were independent risk factors for thrombocytosis of gastric cancer patients. On prognostic analysis, age, tumor size, tumor location, histologic type, depth of tumor invasion, lymph node metastasis, distant metastasis and TNM stage and platelet count were important factors. Tumor size, invasion depth, lymph node metastasis, TNM stage and the platelet count were independent prognostic factors. Conclusion: Thrombocytosis is associated with clinical features of gastric cancer patients and correlates with a poor prognosis.

Reusable and Efficient Polystryrene-supported Acidic Ionic Liquid Catalyst for Mononitration of Aromatic Compounds

Li, Li Xia,Ling, Qi Long,Liu, Zu Liang,Xing, Xiao Dong,Zhu, Xiao Qin,Meng, Xiao Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.10

A series of polystyrene-supported 1-(propyl-3-sulfonate)-3-methyl-imidazolium hydrosulfate acidic ionic liquid (PS-$[SO_3H-PMIM][HSO_4]$) catalysts were prepared and tested for mononitration of simple aromatics compounds with nitric acid. It was found that the reactivity of the catalysts increased with increasing $[SO_3H-PMIM][HSO_4]$ content. The para-selectivity was not only related to the $[SO_3H-PMIM][HSO_4]$ content but also the substituent groups in aromatics. A reaction mechanism of nitration over this new catalyst was proposed. The catalytic activity of this catalyst decreased slightly after fifth runs in the synthesis of nitrotoluene.

Fault-tolerant analysis of two boost inverters for open-end winding induction motor drives

Li, Chunjie,Wang, Guifeng,Li, Hongmei,Li, Fei,Xia, Zhenglong,Liu, Zhan The Korean Institute of Power Electronics 2021 JOURNAL OF POWER ELECTRONICS Vol.21 No.4

An open-end winding induction motor drive system fed by two boost inverters with fault-tolerant capability is presented to improve the reliability and safety of the drive system. The boost inverters consist of an impedance-source network and a two-level inverter. It can realize the boost/buck function. An analysis of its fault-tolerance is presented in detail. Short circuits and open circuits are commonly considered as the two main types of faults. Therefore, the fault types of the dual boost inverters are analyzed and diagnosed. Then, two different fault-tolerant schemes are presented. The presented fault-tolerant inverters are restructured through the power switch itself. In addition, different SVPWM methods are addressed. A simulation model and an experimental platform are constructed. Simulation and experimental results verify the fault tolerance of the drive system.