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        신규 3작용성 메타크릴레이트의 치과용 광중합형 콤포짓트 레진용 단량체로서의 응용 연구

        김중곤,정찬문,김민성,김광만,김경남 大韓齒科器材學會 2001 대한치과재료학회지 Vol.28 No.4

        Tris[4-(2-hydroxy-3-methacryloxypropoxy)phenyl]methane(THMPM) was prepared easily from triphenylolmethane triglycidyl ether in good yield. As compared with composite resin formulated with difunctional bis-GMA, the physical properties of a newly developed composite resin formulated with trifunctional THMPM was evaluated. Cytotoxicity and acute toxicity of composite resin based on trifunctional THMPM evaluated according to ISO standard method. The depth of cure of the composite resin based THMPM was higher than that of the bis-GMA composite. There were no significant differences in flexural strength and water sorption between the composites resin based on THMPM and bis-GMA. The water-solubility value for the light-activated composite resins formulated with THMPM was much lower than that for a control bis-GMA composite. According to cytotoxicity evaluation, the composite resin based on THMPM showed very mild cytotoxicity with the response index of between 0/0 and 1/0. No acute toxicity of composite resin formulated with trifunctional THMPM was also observed. It is believed that THMPM is promising candidate for application as a photocurable dental composite resin.

      • 실리카흄을 흔입한 고강도 콘크리트 개발

        홍창우,김태경,김경진,김성환,김남윤,심도식,이정호,윤청호,백민경,원치문,박제선,이주형,정경일 강원대학교 석재복합신소재제품연구센터 1996 석재연 논문집 Vol.1 No.-

        콘크리트 구조물이 대형화됨에 따라 설계단면이 증대되어 상대적으로 많은 경제적 손실을 부담하게 된다. 따라서 단면을 감소시키면서도 소요의 하중에 안전한 구조물을 건설하기 위해서는 우선적으로 구조물 건설에 기초가 되는 고품질, 고내구성의 고강도 콘크리트 개발이 절실히 요구된다 본 연구에서는 일정 시멘트비 및 혼화재 비율하에서 소요의 워커빌리티가 확보되는 고강도 콘크리트를 시간과 온도의 변화에 따라 증기 양생하여, 압축, 인장, 휨강도 뿐만 아니라 파괴특성을 실험적으로 연구하였다. 시료 제작시 시멘트 입자 사이의 공극 및 불연속 영역을 충전하여 고밀도화하기 위한 콘크리트용 혼화재로 시멘트 비표면적이 상당히 작은 초미립 분말인 실리카흄을 이용하였다. 또한 AE감수제 및 고성능 유동화제를 사용하여 혼화재의 첨가에 의하여 발생될 수 있는 워커빌리티의 감소를 방지하였다. 실험결과에 의하면 일정 양생 지속 시간하에서 온도의 증가에 따라 콘크리트의 압축, 인장 및 휨강도가 전반적으로 증가하였다. 동일하게 일정 온도하에서 양생 지속시간이 커짐에 따라 강도들이 증가됨을 알 수 있었다. 따라서 상대적으로 높은 온도와 긴 지속 양생 조건하에서 파괴에 대한 저항력이 크게 나타났다. The compressible, tensible, and flexibleresistance of the high strength concrete is analyzed by the experimentation in the present study. For the test, we cure several samples with the silica fume as a mixture being become dense the spaces between the particle of cement under the variation of both the temperature and the curing-interval. Then, the superplasticizer and the ezcon are also used to satisfy the required workability for construction. The compressible, tensible, and flexible resistances to a stress are increased as increasing the temperature and the time interval for the curing. Therefore it is concluded that the overal fractural and mechanical properties is improved by mixing the silica fume into the cement.

      • 위 MALT 림프종에서 다발성 림프절 전이로 오인된 동시성 림프절 결핵 1예

        김성은,김규종,김도현,송준영,문대성,장리라,유찬희,문원,박무인,박선자,김영옥 고신대학교의과대학 2008 고신대학교 의과대학 학술지 Vol.23 No.2

        28세 남자가 내시경적 점막절제술을 통해 저등급 위MALT 림프종으로 진단되었다. 병기설정을 위해 18F-FDG PET 검사를 시행하였고 우측 쇄골상부, 우측상/하부 기관주위, AP window 부위에 강한 섭취가 관찰되어 전이성 림프절로 판단하였다. 그러나, 우측 쇄골상부 림프절에서 시행한 절제생검에서 만성육아종성염증소견이 관찰되었고 조직의 결핵 중합효소연쇄반응에서도 양성 반응을 보였다. 2개월간 항결핵제의 사용 후 시행한 추적 컴퓨터단층촬영 검사에서 림프절 크기의 감소를 보여 최종적으로 위 MALT 림프종에서 광범위 림프절 전이로 오인된 동시성 림프절 결핵으로 진단되었다. A 28-year-old man was diagnosed as gastric MALT lymphoma in diagnostic EMR (endoscopic mucosal resection). He subsequently underwent an 18F-FDG PET. 18F-FDG PET showed intense multifocal uptake in right supraclavicular, right upper and lower paratracheal, and AP window areas that was considered radiologically to represent widespread metastatic lymphadenopathy. Excisional biopsy of a supraclavicular lymph node, however, revealed chronic granulomatous lymphadenitis with a positive reaction of Tb-nested PCR. After antituberculosis treatment for 2 months, a follow-up CT scan showed complete resolution of the lesions. Intense 18F-FDG uptake could be due to an infectious process such as synchronous tuberculous lymphadenitis. Therefore, this could mimic a malignant condition such as lymphoma with extensive lymph node metastasis due to a false-positive finding, which may lead to a misdiagnosis.

      • 고려인삼의 홍삼 품질평가요인 분석

        정찬문,엄유리,김상민,이이,이문순 忠北大學校 農業科學硏究所 2012 農業科學硏究 Vol.28 No.2

        This study was conducted to evaluate the elements affect on the quality of red ginseng. For that purpose, we surveyed the relationship between the red ginseng quality and the properties of material ginseng, processing methods, root year, root size, production location, and cultivation methods. Six-year old raw ginseng caused higher inside cavity than younger one did and larger sized ginseng increased outside cracking and inside cavity but decreased inside white than smaller sized one did. The production location did not affect the quality of red ginseng. The red ginseng processed with the ginseng grown on upland field showed lower outside cracking and inside cavity than the red ginseng processed with the ginseng grown on paddy field did. In terms of cultivation method, transplanting method showed lower inside cavity and inside white rates than direct sowing method did. In conclusion, ginseng cultivation location and cultivation method affected on the quality of the red ginseng more than the root age, root size and production location did.

      • 自然科 相互作用 槪念 形成의 評價資料 開發에 관한 硏究 : 物體의 均衡과 電流와 磁氣場 單元을 중심으로

        文燦祜,金相玉 淸州大學校 科學敎育硏究所 1977 淸州大學校 科學敎育硏究所 Vol.1 No.-

        The newly developed science program is being carried out in our elementary school science. However, the materials evaluating children's formation of the basic concepts of science are not developed enough. Learning and teaching in our elementary schools are misled now by the evaluation materials which are made without understanding the elementary science curriculum sufficiently. The purpose of this study is to develop the evaluation materials with which we could find how much and accurately Korean children build up the the interaction concept of science. The concept in a child is formed by the individual experiences and operational thinking, and is accommodated and developed by understanding the relation among the concepts. Thus, we conclude that the interaction concept is formed by perceiving change of objects, by classifying the evidencies of interaction into several groups, by abstracting the common feature from them, and by understanding the relation between the interaction intensity and the conditions of arrangement of objects in the interaction medium. According to this viewpoint, we analyzed the behavioural objects for use in evaluating the children's formation of interaction concept as follows: 11. Knowledge on the scientific terms and symbols. 12. Knowledge on the special facts of interaction. 21. Knowledge on the evidencies of interaction. 22. Knowledge on the interacting objects. 23. Knowledge on the time and space of the interaction. 31. Interpretation of the interaction laws. 32. Understanding the organized factors of the interaction law. 33. Understanding the relations among the interaction variables. 34. Solving the interaction problem and applying the interaction law. Based upon the subject contents and the behavioural objects, we tried to develop the evaluation materials which have the validity for the science teaching objects and the utility in the large class size in Korean elementary schools. We made 64 items for evaluating the concept formation of the equilibrium of objects', and those items are divided into two parts: A and B, and are put to the test by the third garde students in the Attached Elementary School to Cheong Ju Junior Teachers College. The arithmetic mean score of that test is 68.0 Pearson r of the A and B is 0.63, and the total reliability coefficient is 0.77. We made also 74 items for evaluating the concept formation of ‘the electric current and magnetic field', and those are tested in two parts: A and B by the sixth grade students in the same school. The arithmetic mean score of the test is 78.4, Pearson r is 0.67, and the total reliability coefficient is 0.80. We calculated the item difficulty (P) and discriminating index(D.I.) for each item. These values are shown in the table of item analysis. (See Table <5> and <6>). The number of the good items, which meet the conditions that P value is from 20 to 80 and D.I. is larger than+0.20, is 29 in ‘the equilibrium of objects' and 34 in ‘the electric current and magnetic field'. Most of the items being not met the conditions have a large P value, and have a small D.I. value because of the large P value, but some of them may have a smaller p value and a larger D.I. value than the value shown at the Tale <5>and <6> in other schools, since the students chosen for testing our evaluation materials were selected through the entrance examination, and have been taught under the better science facilities of the school than the other school students, and most of them are in the good family background and have comparatively high I.Q. (i.e., mean score, about 115.7). We analyzed the items having very small P and D.I. values. As a result of the analysis, we will conclude that the reason that the items have such small values may be in the children's wrong concept formation. We think that even the some items being not met the condition it is reasonable to use for finding out the process of the children's concept formation and the effective teaching methods.

      • KCI등재
      • 자동차 바디용 강판의 열처리 특성에 관한 연구

        김순경,김문경,전언찬 東亞大學校 1998 東亞論叢 Vol.35 No.-

        As demand for various kinds and small lot products has been increasing, batch annealing has been appreciated for its small restriction for the operation. The cold spot of the coil is very important in the BAF(Batch annealing furnace) annealing process. Because of the annealing cycle time in the BAF, annealing was decided on the cold spot of the coil Development on the mechanical properties of steel sheet for the automobile body panel is very important in the BAF annealing process. Because of the heat treatment method in the BAF, mechanical properties was decided on the heat treatment method of the coil. So, we tested on the development of mechanical properties according to heat treatment method at the annealing furnace using the Ax atmospheric gas and the HNx atmospheric gas. As a result of several investigations. We confirmed the following characteristics mechanical properties was changed under the influence of the annealing cycle and the atmospheric gas. The cold spot of coil was the mid point of the B coil in the Ax atmospheric gas. And, atmospheric gas is very important in the high convection annealing furnaces. And so, we tested the effect, variation of cold spot, for hydrogen contents of atmosphric gas at the annealing furnace. As a result of several investigations. We confirmed the following characteristics after the heating and soaking, the cold spot of coil moved to 1/3 of coil thickness in the HNx atmospheric gas, but the mid point of the coil thickness is the cold spot in the Ax or H2 atmospheric gas. Therefore, the use of hydrogen instead of nitrogen as the protective gas, combined with high convection in batch annealing furnaces, has shown that considerable increases n furnace output and material quality are attaninable. Owing to the low density, high diffusion and reducing character of hydrogen, a better transfer resulting in uniform material temperatures and improved coil surfaces can be achieved.

      • KCI등재후보

        산란계 사료첨가제로서 크릴분말의 효과

        김종덕,장재익,유문일,정흥우,권찬호,오두식,김창현 한국국제농업개발학회 2004 韓國國際農業開發學會誌 Vol.16 No.1

        본 시험은 크릴 분말의 사료적 특성을 조사하고, 산란계 사료에 첨가하였을 때 계란의 생산성과 품질을 비교하기 위하여 수해하였다. 크릴 분말을 산란계 사료에 0, 1 및 2% 수준으로 첨가하여 216수에 6주간 사양시험을 실시하였다. 크릴분말의 일반성분은 수분 8.25%, 조단백질 50.52%, 조지방 16.67%, 조회분 15.72%로 단백질과 지방이 높은 동물성 사료원료였다. 그리고 무기질(15.72%), astaxanthin (10ppm) 및 콜레스테롤 함량 (780ppm) 또한 많았다. 산란율, 연파란율, 일일사료섭취량 및 난중은 처리간에 유의적인 차이가 없었다. 황고 및 난황색도는 크릴의 첨가수준이 높을수록 유의적으로 높아 산란계의 난질을 향상시키는 첨가제로서의 가능성을 보였다. 이상의 결과를 볼 때 크릴 분말은 단백질과 지방이 높은 동물성 사료이며, 산란계에서 천연착색제로의 가능성을 보였다. This experiment was conducted to evaluate the chemical composition of Antarctic Krill(Euphausia superba Dana) meal as feed, and to investigate the effect of its supplementation on productivity and egg quality of laying hen. A total of 216 layers at the age 43 weeks in commercial cage were fed for 6 weeks with 3 different diets containing 0, 1, and 2% Krill meal (KM). The chemical composition of KM was consisted of moisture 8.25%, crude protein 50.52%, crude fat 16.67%, curde ash 15.72%, indicating that KM contains large amount of protein and fat. Krill meal also contains large amounts of mineral(15.72%), astaxanthin(10ppm) and cholesterol(780ppm). No differences were found in egg production, broken and soft eggs, and feed intake among treatments. Dietary supplementation of KM resulted in increased egg yolk height(6.1㎜) and yolk color (2) compared with those of control, suggesting that KM can be used as a feed additive for yolk quality improvement. According to the results of this study, Krill meal can be supplemented in laying hen diets as protein and fat sources, and natural coloring pigment.

      • TiO₂ 담체상에서 귀금속 촉매의 휘발성유기화합물 산화특성

        김문찬,강경호,고선환 한국공업화학회 2005 응용화학 Vol.9 No.1

        In this study, monometallic Pt and bimetallic Pt-Ru, Pt-Ir were supported to TiO₂. In order to distribute metals uniformly, and Xylene, toluene and MEK were used as reactants. The monometallic or bimetallic catalysts were prepared by the excess wetness impregnation method and were characterized by XPS and BET analysis. As a result, Pt-Ru, Pt-Ir bimetallic catalysts were showed higher conversion than Pt monometallic catalyst. Pt-Ir bimetallic catalyst was showed highest conversion on the TiO₂ support. In the VOCs oxidation, Pt-Ir bimetallic catalyst had multipoint active sites, so it improved the range of Pt metal state. Therefore, bimetallic catalysts were higher conversion of VOCs than monometallic ones. In the kinetics, VOCs oxidation was appeared on the first order reaction. In this study, the use of small amount of Jr to Pt promoted oxidation conversion of VOCs.

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