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Cadmium Sulphide Nanorods: Synthesis, Characterization and their Photocatalytic Activity
Giribabu, Krishnamoorthy,Suresh, Ranganathan,Manigandan, Ramadoss,Vijayaraj, Arunachalam,Prabu, Raju,Narayanan, Vengidusamy Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.9
Cadmium sulphide (CdS) nanorods were prepared by a single precursor thermal decomposition (SPTD) method. The formation of CdS nanorods and their structure, morphology and elemental composition were studied by means of FT-IR, XRD, FE-SEM, HR-TEM and EDAX analysis. Photoluminescence (PL) and lifetime measurements were recorded to study the luminescence properties of the material. The PL spectrum of the CdS nanorods showed one broad peak and four shoulders and the cause for this emission was discussed. The PL emissions from the band edge and deep trap state of the CdS nanorods were studied by lifetime measurements. Further, the synthesized CdS nanorods showed an increase in efficiency of photocatalytic degradation of methylene blue (MB) and rhodamine B (RhB). The increase in the photocatalytic activity was attributed to the mixed phase of the CdS nanorods.
Giribabu, K.,Haldorai, Y.,Rethinasabapathy, M.,Jang, S.C.,Suresh, R.,Cho, W.S.,Han, Y.K.,Roh, C.,Huh, Y.S.,Narayanan, V. ELSEVIER 2017 CURRENT APPLIED PHYSICS Vol.17 No.8
<P>In this study, poly(methyl orange) (PMO) was synthesized by electrodeposition onto a glassy carbon electrode (GCE), and the resulting structure was examined for the determination of 4-nitrophenol (4-NP). Cyclic voltammetry revealed that the PMO-modified GCE (PMO/GCE) exhibited excellent electrocatalytic activity for the oxidation of 4-NP in a 0.5-M phosphate buffer solution. In contrast, the bare GCE showed no oxidation peak. Interestingly, PMO/GCE exhibited an oxidation peak at approximate 0.93 V, and the background current was higher than that of the bare GCE. Furthermore, the developed electrochemical sensor exhibited a linear relationship with the 4-NP concentration from 600 nM to 10 mu M, and the limit of detection was 170 nM (signal/noise = 3). The sensor demonstrated excellent selectivity, good stability, and reproducibility. It was applied to the determination of 4-NP in water samples by the standard addition method and gave recoveries of 99.2-100.9%. (C) 2017 Elsevier B.V. All rights reserved.</P>
Giribabu, Krishnan,Oh, Seo Yeong,Suresh, Ranganathan,Kumar, Sivakumar Praveen,Manigandan, Ramadoss,Munusamy, Settu,Gnanamoorthy, Govindhan,Kim, Jun Yeong,Huh, Yun Suk,Narayanan, Vengidusamy Springer-Verlag 2016 Mikrochimica acta Vol.183 No.8
<P>We describe the preparation of a nanohybrid consisting of nitrogen doped reduced graphene oxide and CuS nanoparticles (N-rGO/CuS) by in-situ microwave irradiation at weight ratios of 25/75, 50/50, and 75/25. The resulting nanohybrids were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, FTIR, spectroscopy, scanning electron and transmission electron microscopy, electrochemically by cyclic voltammetry and electrochemical impedance analysis. It is shown that the CuS nanoparticles are evenly decorated onto the N-rGO surface. The nanohybrids was placed on glassy carbon electrode (GCE) where they showed electro-reductive activity towards picric acid, typically at working voltages between -0.2 and -0.8 V (vs. SCE). Effects of pH value and scan rate were evaluated, and it is shown that two electrons are involved in electro-reduction. The detection limits of the GCE modified with various N-rGO/CuS hybrids (with 25/75, 50/50, and 75/25 wt%) are 6.2, 3.2, and 0.069 mu M respectively. The method demonstrates its applicability in sensing of picric acid with good reproducibility.</P>
Giribabu, D.,Das, Maloy,Kumar, Amit Techno-Press 2016 Wind and Structures, An International Journal (WAS Vol.22 No.6
This paper deals with the comparison of different control strategies for the Induction generators in wind energy conversion system. Mainly, two types of induction machines, Self excited induction generator (SEIG) and doubly Fed Induction generators (DFIG) are studied. The different control strategies for SEIG and DFIG are compared. For SEIG, Electronic load Controller mechanism, Static Compensator based voltage regulator are studied. For DFIG the main control strategy namely vector control, direct torque control and direct power control are implemented. Apart from these control strategies for both SEIG and DFIG to improve the performance, the ANFIS based controller is introduced in both STATCOM and DTC methods. These control methods are simulated using MATLAB/SIMULINK and performances are analyzed and compared.
D. Giribabu,Maloy Das,Amit Kumar 한국풍공학회 2016 Wind and Structures, An International Journal (WAS Vol.22 No.6
This paper deals with the comparison of different control strategies for the Induction generators in wind energy conversion system. Mainly, two types of induction machines, Self excited induction generator (SEIG) and doubly Fed Induction generators (DFIG) are studied. The different control strategies for SEIG and DFIG are compared. For SEIG, Electronic load Controller mechanism, Static Compensator based voltage regulator are studied. For DFIG the main control strategy namely vector control, direct torque control and direct power control are implemented. Apart from these control strategies for both SEIG and DFIG to improve the performance, the ANFIS based controller is introduced in both STATCOM and DTC methods. These control methods are simulated using MATLAB/SIMULINK and performances are analyzed and compared.
Krishnan Giribabu,Yuvaraj Haldorai,Muruganantham Rethinasabapathy,장성찬,Ranganathan Suresh,조완섭,한영규,노창현,허윤석,Vengidusamy Narayanan 한국물리학회 2017 Current Applied Physics Vol.17 No.8
In this study, poly(methyl orange) (PMO) was synthesized by electrodeposition onto a glassy carbon electrode (GCE), and the resulting structure was examined for the determination of 4-nitrophenol (4-NP). Cyclic voltammetry revealed that the PMO-modified GCE (PMO/GCE) exhibited excellent electrocatalytic activity for the oxidation of 4-NP in a 0.5-M phosphate buffer solution. In contrast, the bare GCE showed no oxidation peak. Interestingly, PMO/GCE exhibited an oxidation peak at approximate 0.93 V, and the background current was higher than that of the bare GCE. Furthermore, the developed electrochemical sensor exhibited a linear relationship with the 4-NP concentration from 600 nM to 10 mM, and the limit of detection was 170 nM (signal/noise ¼ 3). The sensor demonstrated excellent selectivity, good stability, and reproducibility. It was applied to the determination of 4-NP in water samples by the standard addition method and gave recoveries of 99.2e100.9%.
Krishnan Giribabu,Sung-Chan Jang,Yuvaraj Haldorai,Muruganantham Rethinasabapathy,Seo Yeong Oh,Arunkumar Rengaraj,Young-Kyu Han 한국탄소학회 2017 Carbon Letters Vol.23 No.-
In this study, magnetite (Fe3O4) nanoparticles were electrochemically synthesized in an aqueous electrolyte at a given potential of -1.3 V for 180 s. Scanning electron microscopy revealed that dendrite-like Fe3O4 nanoparticles with a mean size of < 80 nm were electrodeposited on a glassy carbon electrode (GCE). The Fe3O4/GCE was utilized for sensing chloramphenicol (CAP) by cyclic voltammetry and square wave voltammetry. A reduction peak of CAP at the Fe3O4/GCE was observed at 0.62 V, whereas the uncoated GCE exhibited a very small response compared to that of the Fe3O4/GCE. The electrocatalytic ability of Fe3O4 was mainly attributed to the formation of Fe(VI) during the anodic scan, and its reduction to Fe(III) on the cathodic scan facilitated the sensing of CAP. The effects of pH and scan rate were measured to determine the optimum conditions at which the Fe3O4/GCE exhibited the highest sensitivity with a lower detection limit. The reduction current for CAP was proportional to its concentration under optimized conditions in a range of 0.09-47 μM with a correlation coefficient of 0.9919 and a limit of detection of 0.09 μM (S/N=3). Moreover, the fabricated sensor exhibited anti-interference ability towards 4-nitrophenol, thiamphenicol, and 4-nitrobenzamide. The developed electrochemical sensor is a cost effective, reliable, and straightforward approach for the electrochemical determination of CAP in real time applications.
Cadmium Sulphide Nanorods: Synthesis, Characterization and their Photocatalytic Activity
Krishnamoorthy Giribabu,Ranganathan Suresh,Ramadoss Manigandan,Arunachalam Vijayaraj,Raju Prabu,Vengidusamy Narayanan 대한화학회 2012 Bulletin of the Korean Chemical Society Vol.33 No.9
Cadmium sulphide (CdS) nanorods were prepared by a single precursor thermal decomposition (SPTD) method. The formation of CdS nanorods and their structure, morphology and elemental composition were studied by means of FT-IR, XRD, FE-SEM, HR-TEM and EDAX analysis. Photoluminescence (PL) and lifetime measurements were recorded to study the luminescence properties of the material. The PL spectrum of the CdS nanorods showed one broad peak and four shoulders and the cause for this emission was discussed. The PL emissions from the band edge and deep trap state of the CdS nanorods were studied by lifetime measurements. Further, the synthesized CdS nanorods showed an increase in efficiency of photocatalytic degradation of methylene blue (MB) and rhodamine B (RhB). The increase in the photocatalytic activity was attributed to the mixed phase of the CdS nanorods.
Huma Shahzad,Nelli Giribabu,Muniandy Sekaran,Naguib Salleh 한국식품영양과학회 2015 Journal of medicinal food Vol.18 No.12
Quercetin could have profound effects on uterine morphology and proliferation, which are known to be influenced by estrogen. This study investigated the effect of quercetin on these uterine parameters in the presence and in the absence of estrogen. Ovariectomized adult female rats received peanut oil, quercetin (10, 50, and 100 mg/kg/day), estrogen, or estrogen + quercetin (10, 50, or 100 mg/kg/day) treatment for 7 consecutive days. At the end of the treatment, uteri were harvested for histological and molecular biological analyses. Distribution of proliferative cell nuclear antigen (PCNA) protein in the uterus was observed by immunohistochemistry. Levels of expression of PCNA protein and mRNA in uterine tissue homogenates were determined by Western blotting and real-time polymerase chain reaction, respectively. Our findings indicated that administration of 10 mg/kg/day of quercetin either alone or with estrogen resulted in decreased uterine expression of PCNA protein and mRNA with the percentage of PCNA-positive cells in uterine luminal and glandular epithelia markedly reduced compared with estrogen-only treatment. Changes in uterine morphology were the opposite of changes observed following estrogen treatment. Treatment with 100 mg/kg/day of quercetin either alone or with estrogen resulted in elevated PCNA protein and mRNA expression. In addition, the percentages of PCNA-positive cells in the epithelia, which line the lumen and glands, were increased with morphological features mimicking changes that occur following estrogen treatment. Following 50 mg/kg/day quercetin treatment, the changes observed were in between those changes that occur following 10 and 100 mg/kg/day quercetin treatment. In conclusion, changes in uterine morphology and proliferation following 10 mg/kg/day quercetin treatment could be attributed to quercetin’s antiestrogenic properties, while changes that occur following 100 mg/kg/day quercetin treatment could be attributed to quercetin’s estrogenic properties.
Vilian, A.T. Ezhil,Giribabu, Krishnan,Choe, Sang Rak,Muruganantham, Rethinasabapathy,Lee, Hoomin,Roh, Changhyun,Huh, Yun Suk,Han, Young-Kyu Elsevier Sequoia 2017 Sensors and actuators. B Chemical Vol.251 No.-
<P><B>Abstract</B></P> <P>In the present study, we employ a straightforward, benign strategy to prepare thiol-functionalized reduced graphene oxide (S-RGO) using methionine as the sulphur source and reducing agent. The immobilization of horseradish peroxidase (HRP) over the AuNPs/S-RGO was developed by incorporating AuNPs on the S-RGO surface. The fabricated HRP/AuNPs/S-RGO electrode exhibits a remarkable decrease in the overpotential and a significantly increased oxidation peak current of bisphenol A (BPA) compared with the bare glassy carbon electrode (GCE) and AuNPs/S-RGO electrode. The biosensor shows an excellent amperometric analytical performance with a low detection limit of 2.6×10<SUP>−12</SUP> M and a linear range from 2.0×10<SUP>−11</SUP> to 1.18×10<SUP>−9</SUP> M, with the response time <2s for BPA. From the results, the apparent Michaelis-Menten constant was calculated as 8.14nM. The HRP/AuNPs/S-RGO biosensor exhibited faster response, adequate storage stability, inexpensive, simple fabrication with disposability, satisfactory reproducibility and repeatability, and outstanding selectivity. Finally, the constructed biosensor was utilized successfully for detecting BPA in tomato juice and milk samples with acceptable results.</P> <P><B>Highlights</B></P> <P> <UL> <LI> HRP/AuNPs/S-RGO biocomposite has been prepared to determine bisphenol A. </LI> <LI> The AuNPs/S-RGO is a promising platform for HRP immobilization. </LI> <LI> The biosensor exhibits excellent stability, reproducibility and high selectivity. </LI> <LI> It exhibits LOD of 2.6×10<SUP>−12</SUP> in a wide linear range from 2.0×10<SUP>−11</SUP> to 1.18×10<SUP>−9</SUP> M. </LI> <LI> It detects bisphenol A in real samples such as tomato juice and milk. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>