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( Muruganantham Rethinasabapathy ),강성민,곽철환,허윤석 한국공업화학회 2018 한국공업화학회 연구논문 초록집 Vol.2018 No.0
Prussian blue (PB)/Chitosan (CS)/Graphene oxide (GO) has been syn-thesized and utilized as a potential adsorbent for the removal of cesium ions (Cs<sup>+</sup>) from aqueous solution. The effects of adsorbate concen-tration, reaction pH, and time on the removal efficiency of Cs<sup>+</sup> were investigated. The optimal pH and reaction time for the removal of Cs<sup>+</sup> were pH 7 and 24 h, respectively, with an adsorbent dosage of 20 mg. The adsorption isotherm is better fitted to the Freundlich model than the Langmuir model with a maximum Cs<sup>+</sup> adsorption capacity of 33 mg g-1. In addition, the kinetic study showed that the adsorption behavior followed a pseudo-second-order kinetics. The adsorbent showed good selectivity towards Cs<sup>+</sup> even in the presence of competitive cations. Therefore, it is expected that this composite can be used for the removal of radioactive cesium.
Three-dimensional porous graphene materials for environmental applications
Muruganantham Rethinasabapathy,Sung-Min Kang,Sung-Chan Jang,Yun Suk Huh 한국탄소학회 2017 Carbon Letters Vol.22 No.-
Porous materials play a vital role in science and technology. The ability to control their pore structures at the atomic, molecular, and nanometer scales enable interactions with atoms, ions and molecules to occur throughout the bulk of the material, for practical applications. Three-dimensional (3D) porous carbon-based materials (e.g., graphene aerogels/hydrogels, sponges and foams) made of graphene or graphene oxide-based networks have attracted considerable attention because they offer low density, high porosity, large surface area, excellent electrical conductivity and stable mechanical properties. Water pollution and associated environmental issues have become a hot topic in recent years. Rapid industrialization has led to a massive increase in the amount of wastewater that industries discharge into the environment. Water pollution is caused by oil spills, heavy metals, dyes, and organic compounds released by industry, as well as via unpredictable accidents. In addition, water pollution is also caused by radionuclides released by nuclear disasters or leakage. This review presents an overview of the state-of-the-art synthesis methodologies of 3D porous graphene materials and highlights their synthesis for environmental applications. The various synthetic methods used to prepare these 3D materials are discussed, particularly template-free self-assembly methods, and template-directed methods. Some key results are summarized, where 3D graphene materials have been used for the adsorption of dyes, heavy metals, and radioactive materials from polluted environments.
Muruganantham Koothappan,Roshana Devi Vellai,Iyyam Pillai Subramanian,Sorimuthu Pillai Subramanian 대한당뇨병학회 2018 Diabetes and Metabolism Journal Vol.42 No.3
Due to the multifactorial and multisystemic nature of diabetes mellitus, it is often treated with a combination of therapeutic agents having different mode of action. Earlier, we have synthesized several organozinc complexes and evaluated their safety and antidiabetic properties in experimental type 2 diabetes mellitus (T2DM). More recently, we have synthesized a metformin-3-hydroxyflavone complex and studied its antidiabetic efficacy in experimental rats. In the present study, a new zinc-mixed ligand (metformin-3-hydroxyflavone) was synthesized, characterized by spectral studies and its antidiabetic properties was evaluated in HFD fed—low dose streptozotocin induced T2DM in rats. The hypoglycemic efficacy of the complex was evaluated through oral glucose tolerance test, homeostasis model assessment of insulin resistance, quantitative insulin sensitivity check index and by determining the status of important biochemical parameters. Oral administration of the complex at a concentration of 10 mg/kg body weight/rat/day for 30 days significantly improved the glucose homeostasis. The complex possesses significant antidiabetic properties relatively at a less concentration than metformin-3-hydroxyflavone complex in ameliorating hyperglycemia.
Muruganantham Rethinasabapathy,강성민,Yuvaraj Haldorai,Narendranath Jonna,Manokaran Jankiraman,이고운,장성찬,Balasubramanian Natesan,노창현,허윤석 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.69 No.-
N-doped graphene supported quaternary electrocatalyst (PtRuFeCo/NG) was synthesized and evaluated for potential oxygen reduction (ORR) and methanol oxidation reaction (MOR) in fuel cells. The catalyst exhibited excellent MOR (strong CO tolerance, lower onset potential), ORR (four electron transfer) activities and delivered maximum power densities of 778 and 122 mW cm−2 with direct methanol and proton exchange membrane fuel cells, respectively. The N-doping and synergistic effects of alloying low-cost Fe and Co with Pt and Ru makes PtRuFeCo/NG as excellent bifunctional catalyst that greatly reduces the processing cost of fuel cell which is the major problem facing the fuel cell industry.
( Muruganantham Arunraja ),( Veluchamy Malathi ) 한국인터넷정보학회 2015 KSII Transactions on Internet and Information Syst Vol.9 No.7
Data redundancy has high impact on Wireless Sensor Network`s (WSN) performance and reliability. Spatial and temporal similarity is an inherent property of sensory data. By reducing this spatio-temporal data redundancy, substantial amount of nodal energy and bandwidth can be conserved. Most of the data gathering approaches use either temporal correlation or spatial correlation to minimize data redundancy. In Collective Prediction exploiting Spatio Temporal correlation (CoPeST), we exploit both the spatial and temporal correlation between sensory data. In the proposed work, the spatial redundancy of sensor data is reduced by similarity based sub clustering, where closely correlated sensor nodes are represented by a single representative node. The temporal redundancy is reduced by model based prediction approach, where only a subset of sensor data is transmitted and the rest is predicted. The proposed work reduces substantial amount of energy expensive communication, while maintaining the data within user define error threshold. Being a distributed approach, the proposed work is highly scalable. The work achieves up to 65% data reduction in a periodical data gathering system with an error tolerance of 0.6°C on collected data.
Balagurunathan, Muruganantham,Natarajan, Thrilok,Karthikeyan, Jothilakshmi,Palanisamy, Venkateshwaran The Korean Pediatric Society 2021 Clinical and Experimental Pediatrics (CEP) Vol.64 No.10
Background: Multisystem inflammatory syndrome in children (MIS-C) is a new hyperinflammatory variant that evolved during the coronavirus disease 2019 pandemic. Although the precise pathophysiology of MIS-C is uncertain, it is thought to be due to immune dysregulation occurring after recovery from acute infection. Purpose: Our study aimed to analyze the clinical spectrum, laboratory parameters, imaging characteristics, treatment strategies, and short-term outcomes of children with a diagnosis of MIS-C. Methods: This retrospective and prospective observational study included children less than 16 years of age who were admitted to the pediatric unit of a tertiary care teaching hospital in south India between August 2020 to January 2021 with a diagnosis of MIS-C according to World Health Organization criteria. Results: Twenty-one children were included in the analysis; all had fever with variable combinations of other symptoms. The mean age was 6.9 years; 71.4% were male. Gastrointestinal (80.9%) and cardiovascular (80.9%) systems were the most commonly affected. The majority of children had elevated inflammatory markers, and 16 (76.2%) had echocardiographic abnormalities mimicking Kawasaki disease. Eleven children (52.4%) required intensive care admission, 3 (14.3%) required supplemental oxygen, and 4 (19%) required inotropes. Nine (42.9%) were treated with intravenous immunoglobulin alone, 6 (28.6%) with steroids alone, and 3 (14.3%) with steroids and immunoglobulin. The median hospital stay was 6 days; there were no fatalities. Overweight/obesity, elevated ferritin, and mucocutaneous involvement were significantly associated with a prolonged hospital stay (≥7 days). Sixteen children (76.2%) were followed up till now and all of them had no clinical concerns. Conclusion: MIS-C is an emerging disease with variable presentation. A high index of suspicion is necessary for its early identification and appropriate management. Further research is essential for developing optimal treatment strategies.
Rethinasabapathy, Muruganantham,Kang, Sung-Min,Haldorai, Yuvaraj,Jonna, Narendranath,Jankiraman, Manokaran,Lee, Go-Woon,Jang, Sung-Chan,Natesan, Balasubramanian,Roh, Changhyun,Huh, Yun Suk Elsevier 2019 Journal of industrial and engineering chemistry Vol.69 No.-
<P><B>Abstract</B></P> <P>N-doped graphene supported quaternary electrocatalyst (PtRuFeCo/NG) was synthesized and evaluated for potential oxygen reduction (ORR) and methanol oxidation reaction (MOR) in fuel cells. The catalyst exhibited excellent MOR (strong CO tolerance, lower onset potential), ORR (four electron transfer) activities and delivered maximum power densities of 778 and 122mWcm<SUP>−2</SUP> with direct methanol and proton exchange membrane fuel cells, respectively. The N-doping and synergistic effects of alloying low-cost Fe and Co with Pt and Ru makes PtRuFeCo/NG as excellent bifunctional catalyst that greatly reduces the processing cost of fuel cell which is the major problem facing the fuel cell industry.</P> <P><B>Highlights</B></P> <P> <UL> <LI> First time, a quaternary catalyst is tested as bifunctional catalyst using NG as support. </LI> <LI> Exhibit higher ECSA (91m<SUP>2</SUP> g<SUP>−1</SUP>) and strong tolerance towards CO poisoning. </LI> <LI> Two to three-fold increase in MOR activity than other multi-metallic catalysts. </LI> <LI> Facilitate 4 electron transfer with high current in ORR (6.3mAcm<SUP>−2</SUP>). </LI> <LI> Greatly reduce the cost of the catalyst due to less Pt usage and addition of Fe and Co. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>