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Agrawal Pankaj,Newbold Sally,Busaidi Ayisha Al,Kapoor Ritika R,Thomas Nick,Aylwin Simon JB,Buchanan Charles R,Arya Ved Bhushan 대한소아내분비학회 2022 Apem Vol.27 No.4
Pituitary apoplexy typically presents with acute headache, vomiting, visual disturbance, and confusion. Herein, we report a rare presentation of ischemic stroke due to pituitary apoplexy. A 16.5-year-old male presented with reduced Glasgow Coma Scale (GCS) score, slurred speech, right-sided hemiparesis, and bitemporal hemianopia. Magnetic resonance imaging of the brain showed a large hemorrhagic sellar/suprasellar mass and an area of cortical T2/FLAIR hyperintensity with corresponding diffusion restriction in the middle cerebral artery territory. Computed tomography (CT) intracranial angiogram showed luminal occlusion of the clinoid and ophthalmic segments of both internal carotid arteries (ICAs, left>right) due to mass pressure effect. Biochemical investigations confirmed hyperprolactinemia and multiple pituitary hormone deficiencies. Stress-dose hydrocortisone was commenced with cabergoline, followed by urgent endoscopic transsphenoidal debulking of the tumor (subsequent histology showing prolactinoma). Postoperative CT angiogram showed improved caliber of ICAs. Intensive neurorehabilitation was implemented and resulted in complete recovery of motor and cognitive deficits. At the last assessment (18.8 years), the patient remained on complete anterior pituitary hormone replacement without cabergoline. Pituitary apoplexy is a medical emergency requiring prompt recognition and treatment and should be suspected in patients presenting with sudden, severe headache; nausea; or visual disturbance and meningism. Ischemic stroke is a rare manifestation of pituitary apoplexy in the pediatric population.
Agrawal Khushabu,Patil Vilas,Ali Fida,Rabelo Matheus,우원종,조은철,Yi Junsin 한국물리학회 2021 Current Applied Physics Vol.26 No.-
The HF treatment removes the native oxide and lays behind the dangling bonds over the Si surface which causes the increment in density of interface traps (Dit) through the direct deposition of high-k dielectric on Si. Here, we propose the facile method for reduction of interface traps and improvement in barrier height with the (NH4)2S treatment on Al2O3/Si interfaces, which can be used as the base for the non-volatile memory device. The AFM was used to optimize the treatment time and surface properties, while XPS measurements were carried out to study the interface and extract the barrier height (ΦB). The short period of 20 s treatment shows the improvement in the barrier height (1.02 eV), while the one order reduction in the Dit (0.84 × 1012 cm2/eV) of sulfur passivated Al/Al2O3/Si MOS device. The results indicate the favorable passivation of the dangling bonds over the Si surfaces covered by sulfur atoms.
QUANTIFICATION OF β-GALACTOSIDASE TO MEASURE INTESTINAL DAMAGE IN ROTAVIRUS INFECTED CALVES
Agrawal, D.K.,Singh, N.P. Asian Australasian Association of Animal Productio 1993 Animal Bioscience Vol.6 No.3
Quantitative ${\beta}$-galactosidase estimation in the intestinal mucosal cells of calves with diarrhea under experimental conditions due to rotavirus were undertaken. A quantitative decrease of 40-70% in ${\beta}$-galactosidase activity was observed in proximal and middle segments of the small intestine of the infected calves, more so in the middle segments. The decrease in the distal part of the intestine, however, was lesser (5 to 30%). The decrease in the activity was more marked on the day 2 to 6 post infection indicating the degree of the damage of the villi of the small intestine.
Agrawal, Meenakshi,Jain, Sonika,Agarwal, Anshu,Dwivedi, Jaya,Sharma, Swapnil,Kishore, D. 경희한의학연구센터 2012 Oriental Pharmacy and Experimental Medicine Vol.12 No.2
Exceedingly facile protocols based on the reactivity of corresponding oxoketenedithioacetal (4), 2-(dimethylaminomethylene) ketone (5), ${\beta}$-oxoenolether (6) and ${\alpha}$, ${\beta}$-unsaturated ketone (7) resulted from 7-ethyl-3,4 dihydroazepino[3,2-b] carbazole-2,5 (1H,7H)-dione (3) on its reaction with base catalyzed condensation of (a) $CS_2+$ MeI (b) DMF-DMA (c) H-COOEt and (IV) $C_6H_5CHO$ respectively, has been explored to provide an easy access of their isoxazole and pyrazole annulated analogues (8-13) of medicinal interest. The key compound 3 from which, the synthesis proceeded was in turn realized on the reaction of commercial 3-amino-9-ethyl carbazole (1) with ethyl succinyl chloride, under the conditions of Friedel-Crafts acylation followed by cyclocondensation of the resulting intermediate 2 with PPA. Isoxazolo and pyrazolo annulated analogues of carbazolo condensed azepinone derivatives (8-13) were screened for their in-vitro antimicrobial potential against various bacterial and fungal species. Besides this pyrazole derivative (8) was also evaluated for its CNS depressant potential in mice using photoactometer.
Agrawal, Anju,Sailani, Riya,Gupta, Beena,Khandelwal, C.L.,Sharma, P.D. Korean Chemical Society 2012 대한화학회지 Vol.56 No.2
The kinetics of oxidation of nicotinic acid by peroxomonosulfate (PMS) has been studied in acetate buffers. Stoichiometry of the reaction corresponds to the reaction of one mole of the oxidant with a mole of nicotinic acid. N${\rightarrow}$O product has been confirmed both by UV visible and IR spectroscopy. The reaction is second order viz. first order with respect to each reactant. Activation parameters have also been evaluated. A plausible reaction mechanism is mentioned and the derived kinetic rate law accounts for experimental observations.
Agrawal, Arpana,Tchoe, Youngbin,Kim, Heehun,Park, Joon Young Elsevier 2018 APPLIED SURFACE SCIENCE - Vol.462 No.-
<P><B>Abstract</B></P> <P>The mechanism of surfaces/interfaces and precise control of growth morphology is a key parameter for any specific device application. Herein, we report on a qualitative growth study of molecular beam epitaxy-grown polycrystalline InAs thin films on a lattice-mismatched Si(1 0 0) substrate using atomic force microscopy. The height-height correlation function (HHCF) and power spectral density function (PSDF) were employed to analyze the surface structures. Clear oscillatory behavior in the HHCF for sufficiently larger lateral distances suggests a mound-like morphology, which was confirmed by the existence of a characteristic frequency peak in the PSDF. The growth mechanism is described qualitatively by the Schwoebel barrier (roughening) effect coupled with the Mullins diffusion model (smoothing effect).</P> <P><B>Highlights</B></P> <P> <UL> <LI> HHCF and PSDF were employed to analyze the surface structures. </LI> <LI> Oscillatory behavior in HHCF for larger lateral distances suggests mound-like morphology. </LI> <LI> Existence of characteristic frequency peak in the PSDF further supports mound-like structure. </LI> <LI> Growth mechanism is well explained by the Schwoebel barrier effect coupled with the Mullins diffusion model. </LI> </UL> </P>
Rejuvenating rice proteomics: Facts, challenges, and visions
Agrawal, Ganesh Kumar,Jwa, Nam-Soo,Iwahashi, Yumiko,Yonekura, Masami,Iwahashi, Hitoshi,Rakwal, Randeep WILEY-VCH Verlag 2006 Proteomics Vol.6 No.20
<P>Proteomics is progressing at an unprecedented pace, as can be exemplified by the progress in model organisms such as yeast, bacteria, and mammals. Proteomics research in plants, however, has not progressed at the same pace. Unscrambling of the genome sequences of the dicotyledoneous Arabidopsis thaliana (L.) and monocotyledoneous rice (Oryza sativa L.) plant species, respectively, has made them accessible reference organisms to study plant proteomics. Study of these two reference plants is expected to unravel the mystery of plant biology. Rice, a critically important food crop on the earth, has been termed a “cornerstone” and the “Rosetta stone” for functional genomics of cereal crops. Here, we look at the progress in unraveling rice proteomes and present the facts, challenges, and vision. The text is divided into two major parts: the first part presents the facts and the second part discusses the challenges and vision. The facts include the technology and its use in developing proteomes, which have been critically and constructively reviewed. The challenges and vision deal with the establishment of technologies to exhaustively investigate the protein components of a proteome, to generate high-resolution gel-based reference maps, and to give rice proteomics a functional dimension by studying PTMs and isolation of multiprotein complexes. Finally, we direct a vision on rice proteomics. This is our third review in series on rice proteomics, which aims to stimulate an objective discussion among rice researchers and to understand the necessity and impact of unraveling rice proteomes to their full potential.</P>
Wine Quality Classification with Multilayer Perceptron
Agrawal, Garima,Kang, Dae-Ki The Institute of Internet 2018 International Journal of Internet, Broadcasting an Vol.10 No.2
This paper is about wine quality classification with multilayer perceptron using the deep neural network. Wine complexity is an issue when predicting the quality. And the deep neural network is considered when using complex dataset. Wine Producers always aim high to get the highest possible quality. They are working on how to achieve the best results with minimum cost and efforts. Deep learning is the possible solution for them. It can help them to understand the pattern and predictions. Although there have been past researchers, which shows how artificial neural network or data mining can be used with different techniques, in this paper, rather not focusing on various techniques, we evaluate how a deep learning model predicts for the quality using two different activation functions. It will help wine producers to decide, how to lead their business with deep learning. Prediction performance could change tremendously with different models and techniques used. There are many factors, which, impact the quality of the wine. Therefore, it is a good idea to use best features for prediction. However, it could also be a good idea to test this dataset without separating these features. It means we use all features so that the system can consider all the feature. In the experiment, due to the limited data set and limited features provided, it was not possible for a system to choose the effective features.