비정합 결정구조를 갖는 $(LaS)_xVS_2(x\approx 1.18)$의 결정구조적 특성연구

조남웅,유광수,정형진 한국세라믹학회 1994 한국세라믹학회지 Vol.31 No.6

Single crystals of misfit layered (LaS)xVS2(x 1.18) were grown using LaCl3(or I2) as a mineralizer (or transport agent) for the single crystal X-ray diffraction analysis. Procession photographs of (LaS)xVS2(x 1.18) were analyzed as the stacking structure of two kinds of LaS-and VS2-subcell. The result shows that two sublattices have common periodicities along the a*-and c*-axes, respectively, but not along the b*-axis. Sublattice dimensions of LaS and VS2 layers along b-axis were 5.67$\AA$ and 3.42$\AA$, respectively. Their ratio was 1.657 which is very close to 5/3.

Build and Performance Test of a 3-cell Solid Oxide Fuel Cell Stack

조남웅,황순철,한상무,양충진 한국세라믹학회 2007 한국세라믹학회지 Vol.44 No.8

A 3-cell stacked anode-suported solid oxide fuel cell was designed and fabricated to achieve a complete gas seal and the facil estacking of components. The stack was assembled with a unit cell with 10 ×10 cm2 area, and each cell was interconnected by astainless steel 430 separator using a proprietary sealant sheet. The stack performance was examined at various gas flow rates o fH2+3.5vol% H 2O, and air at a fixed temperature of 800oC. No gas leakage was found from the sealing between cells and inter-connects within a measurement system in this research during a prolonged time of 500 h in operation. The test resulted in anopen circuit voltage of 3.12 V, a peak power of 149 W, and a power density of 0.61 W/cm2, while the long term durability of thepower showed 19.1% degradation during the prolonged time of 50 h when tested at 800oC.

Batch Lot Size와 Setup을 고려한 Two Stage MIP 생산계획 최적화 모형

조남웅 대한산업공학회 2013 대한산업공학회 춘계학술대회논문집 Vol.2013 No.5

Demand-Production Time Bucket 불일치 환경에서 Multi-Machines Track 공정의 Production Planning & Scheduling MIP 최적화 모형

조남웅,장용성,이현복,남영일 대한산업공학회 2014 대한산업공학회 추계학술대회논문집 Vol.2014 No.11

$LiAl_5O_8-LiFe_5O_8$ 합성과 결정구조 해석

조남웅,김찬욱,장세기,유광수 한국결정성장학회 1997 韓國結晶成長學會誌 Vol.7 No.2

$LiCO_3, Al_2O_3, Fe_2O_3$ 혼합물을 1620K에서 반응시켜 리튬전지의 음극재료로 응용이 가능한 스핀넬형 $LiAl_{2.5}/Fe_{2.5}O_8$를 합성하였다. XRD의 Rietveld 해석을 통하여 결정구조 해석을 하였다. 고용체의 공간군은 $P4_3$32(a=8.1293$\AA$)이고, 결정구조해석의 최종 Residual index는 약 5%정도이었다. 역 스핀넬구조에서 양이온 $Al^{3+}, Fe^{3+}$은 4-배위와 6-배위로 위치하고, $Li^+$은 4b, 12d의 6-배위자리에 존재하였다. The pseudo-spinel type solid solution, $LiAl_{2.5}/Fe_{2.5}O_8$ was prepared by reaction of $LiCO_3, Al_2O_3, Fe_2O_3$ mixture at 1620K, which can be used for cathode material in lithium batteries. Its structure was investigated by Rietveld profile-analysis of XRD in detail. The space group of solid solution is $P4_3$32(a=8.1293$\AA$) and the final residual index of structure refinement was about 5%. Cations $Al^{3+}, Fe^{3+}$ are located at both tetra- and octahedral-coordination and $Li^+$ ions are occupied in the octahedral 4b-, 12d-site of the inverse spinel.

부하조정용 Na-S ESS용 전지 개발현황 및 전망

조남웅,Jo, Nam-Ung 대한전기협회 2014 전기저널 Vol.- No.446

Batch Lot Size와 Setup을 고려한 Two Stage MIP 생산계획 최적화 모형

조남웅 한국경영과학회 2013 한국경영과학회 학술대회논문집 Vol.2013 No.5

$(1-x)CaTiO_3-x(La_{1/3}Nd_{1/3})TiO_3$계의 결정구조 해석 및 마이크로파 유전 특성

조남웅,성경필,문종하,최주현 한국결정성장학회 1998 한국결정성장학회지 Vol.8 No.3

$CaCO_3,\;LaO_3,\;Nd_2O_3\;TiO_2의 혼합물을 1673K에서 소결하여 마이크로파 유전체 세라믹스재료로 응용이 가능한 (1-x)$CaTiO_3-x(La_{1/3}Nd_{1/3}TiO_3\;(0\letextrm x\le0.8)$계를 합성하였다. (1-x))$CaTiO_3-x(La_{1/3}Nd_{1/3}TiO_3\;(0\lex\le0.8)$계의 격자 정수는 x가 증가함에 따라 증가하였다. XRD의 Rietveld profile-analysis를 통하여 (1-x))$CaTiO_3-x(La_{1/3}Nd_{1/3}TiO_3\;(0\le \textrm {x} \le0.8)$계의 결정구조를 해석하였다. $0\le \textrm {x}\le0.8$의 모든 영역에서 양이온 $La^{3+},Nd^{3+}$는 $Ca^{2+}$ 자리에 점유하였다. x=0.6까지는 $CaTiO_3$와 같은 공간군 Pnma를 그대로 유지하였으며, x가 증가함에 $TiO_6$의 비틀림과 변형은 점차 감소하였다. x=0.8에서는 새로운 공간군 $Pmn2_1$으로 결정구조의 변화를 보였다. (1-x)$CaTiO_3-x(La_{1/3}Nd_{1/3}TiO_3\;(0\le \textrm {x}\le0.8)$계의 비유전율($\epsilon$r)은 x가 증가함에 따라 지수 함수적으로 감소하였다. 공진 주파수의 온도계수($\tau_f$)는 x=0.6까지 증가함에 따라 감소하였으나 x=0.8에서는 결정구조의 변화와 더불어 다시 증가하였다. Q.$\tau_f$값은 x=0.2에서는 13800(GHz)을 나타낸 후 0$0.4\le \textrm {x}\le0.8$ 영역에서는 2000 (GHz)의 매우 낮은 값을 나타내었다. $CaTiO_3-x(La_{1/3}Nd_{1/3}TiO_3\;(0\le \textrm x\le0.8)$ system was prepared by reaction of $CaCO_3,\;LaO_3,\;Nd_2CO_3$ and ,$TiO_2$ mixture at 1673 K, which can be applied for microwave dielectric ceramic materials. The lattice parameters of(1-x))$CaTiO_3-x(La_{1/3}Nd_{1/3}TiO_3\;(0\le \textrm x\le0.8)$ system increased with the increase of x. Its structure was investigated by Rietveld profile-analysis of XRD in detail. Cations $ La^{3+}$ and Nd^{3+}$ were located at the $Ca^{2+}$ site in the range of $0\le \textrm x\le0.8$. crystal structure in $;(0\le \textrm x\le0.6)$ maintained space group Pnma with CaTiO_3 structure. The tiled and distorted $TiO_6$ was gradually released with the increase of x in $0\le \textrm x\le0.6$ .The structure was changed to a new space group of $Pmn2_1$ at the x value of 0.8. The relative dielectric constant $(\epsilon_r)$ of $(1-x)CaTiO_3-x(La_{1/3} Nd_{1/3})TiO_3$ ($(0\le \textrm x\le0.8)$) system was exponentially decreased by with the increased of x. The temperature coefficient of resonant frequency $(\tau_f)$ decreased with the increase of x in $0\le \textrm x\le0.6$ and then increased again at x=0.8 due to the change of crystal structure. The value of Q$\cdot f_o$ was 13800 (GHz) at x=0.2 and was very low under 2000 (GHz) in 0.4$\leq$x$\leq$0.8.

$(LaS)_xCrS_2(x{\approx}1.20)$의 결정구조와 자기적 특성

조남웅,유광수,정형진,Jo, Nam-Ung,Yu, Gwang-Su,Jeong, Hyeong-Jin 한국재료학회 1994 한국재료학회지 Vol.4 No.6

Crystal Structure and Magnetic Properties of $(LaS)_xCrS_2(x \approx 1.20$)가 1273K에서 $La_S_3$ , Cr, S의 혼합물의 반응으로부터 합성되었다. $(LaS)_xCrS_2( x\approx 1.20$)의 XRD회절 pattern은 monoclinic의 LaS-부격자, triclinic의 $CrS_{2}$-부격자와 그들의 초격자로서 해석되었다. 부격자의 온도의존성을 저온에서 X-선 회절분석으로 조사하였다. 77K~실온의 온도역에서 $(LaS)_xCrS_2(x \approx 1.20$)의 자기자화율을 Faraday balance법으로 측정하였다. $(LaS)_xCrS_2(x \approx 1.20$)은 실온 $\sigma$ -H plot에서 paramagnetic한 거동을 나타내었다. 관측된 유효자기 moment($\mu_{eff}$)는 $Cr^{3+}$을 spin-only에 의한 것과 $La^{3+}$을 spin-only와 orbital에 의한 것으로 계산할 경우 잘 일치되었다. The $(LaS)_xCrS_2(x \approx 1.20$) of the incommensurate misfit layer was systhesized from reactant mixture of$La_S_3$,Cr and S at 1273K. Powder X-ray diffration of $(LaS)_xCrS_2(x \approx 1.20$) was indexed as a complex structure consisted with a monoclinic LaS-sublattice, a triclinic $CrS_{2}$-sublattice and their superlattice. The temperature dependence of sublattice dimension was investigated by the X-ray diffraction analysis at low temperature. The magnetic susceptibility of $(LaS)_xCrS_2(x \approx 1.20$) was measured between 77K and room temperature using a Faraday balance method. $(LaS)_xCrS_2(x \approx 1.20$) was paramagnetic on a $\sigma$-H plot at room temperature. The observed effective magnetic moment( p dr) was in fair agreement with the value calculated by spin-only contribution for $Cr^{3+}$ and spin and orbital contribution for $La^{3+}$.

Ag 집전체를 적용한 평판형 SOFC 단전지

조남웅,황순철,이인성,Cho, Nam-Ung,Hwang, Soon-Cheol,Lee, In-Sung 한국세라믹학회 2007 한국세라믹학회지 Vol.44 No.12

Current collectors of SOFC play a significant role on the performance of power generation. In this study a single cell stacked SOFC was assembled using Ag-mesh as a cathode current collector, and evaluated its performance. No gas leakages of the single cell stack occurred in the tests of gas detection and OCV measurement. The OCV and initial power of the stack were 1.09V and $0.45W/cm^2$, respectively, under the flow rates of air at 2,500 cc/min and $H_2$ at 1,000 cc/min at the test temperature of $750^{\circ}C$. A degradation rate of 44.0% was measured during the prolonged time of 307 h. The relatively low durability of the tested single cell stack was found to be the evaporation of Ag-mesh at the current corrector.