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지중 내 TPH, Phenol의 확산방지를 위한 선택적 차수재 제조에 관한 연구
임호진,조우리,오승진,김수희,이재영,HoJin Lim,WooRi Cho,SeungJin Oh,SuHee Kim,JaiYoung Lee 한국지반신소재학회 2024 한국지반신소재학회 논문집 Vol.23 No.1
In this study, a selecvively block barrier was developed to prevent the spread of contaminants (TPH, Phenol) in the ground only when contamination occurs. The materials were used Jumunjin sand, bentonite, polyolefin elastomer and spill hound marine. First, the properties and environmental hazards characteristics of materials were analyzed for evaluated their usability. Then, the possibility of use as a barrier material was confirmed by analyzing the water permeability characteristics that change after 24 hours of contact with contaminants. As a result of the analysis, the pH of each component was similar to the general groundwater pH range. In addition, the toxicity characteristics and the possibility of dissolution of hazardous substances, it was determined that there was no environmental hazard as the content was below the regulation value. Lastly, when comparing the permeability coefficient before and after contact with the contaminant, the permeability coefficient of approximately α × 10<sup>-3</sup>cm/sec before contact was reduced to α × 10<sup>-6</sup>cm/sec after contact with the contaminant.
최명진,이홍규,강영일,임호진,최승기,Choi, Myung-Jin,Lee, Hong-Kyu,Kang, Young-Il,Lim, Ho-Jin,Choi, Seung-Ki 대한방사선방어학회 1991 방사선방어학회지 Vol.16 No.2
상온에서 사용할 수 있는 감마선 검출 소자로서 $HgI_2$ 소자의 응용성을 판단하기 위하여 기상 성장법으로 $HgI_2$ 단결정을 성장시켰고 이를 이용하여 검출 소자를 제작한 후 감마선 검출 특성을 조사하였다 성장된 단결정의 비저항과 전하 운반자 포획 밀도는 상온에서 각각 $10^{11}{\Omega}\;cm$와 $1.8{\times}10^{14}/cm^3$였으며 단결정의 Photoluminescence를 측정한 결과 성장된 $HgI_2$ 단결정의 밴드갭의 온도계수는 20K부터 77K에서 $-1.53{\times}10^{-4}eV/K$였다. 감마선 검출실험 결과 제작된 $HgI_2$ 검출 소자는 상온에서 우수한 계수 특성과 시간에 대한 선형적 축적 계수 특성을 나타내었으나 온도변화에 따라 계수의 특성의 변화는 심하였다. The $HgI_2$ single crystal which can be used for the ${\gamma}-ray$ detector at room temperature was grown by Temperature Oscillation Method. The low temperature photoluminescence, specific resistivity and trap concentration of $HgI_2$ single crystal were investigated. Three main luminescence bands were observed at 2.30eV, 2.20eV and 2.00eV at 20K, related to the excitons, I-vacancies and impurities, respectively. The specific resistivity and trap concentration of $HgI_2$ single crystal were $10^{11}{\Omega}\;cm\;and\;1.8{\times}10^{14}/cm^3$ at room temperature, respectively. Also the radiation detecting system was deviced by $HgI_2$ ${\gamma}-ray$ detector, one chip microprocessor, LCD module and personal computer. The prepared $HgI_2$ ${\gamma}-ray$ detector showed a good linearity of ${\gamma}-radiation$ dose for standard ${\gamma}-ray$.