고품질 쌀의 품종별 영양성분 및 취반 특성

우관식,이석기,이병원,김정주,이지혜,이유영,이병규,김현주,Woo, Koan Sik,Lee, Seuk Ki,Lee, Byong Won,Kim, Jeong-Ju,Lee, Jihae,Lee, Yu-Young,Lee, Byoungkyu,Kim, Hyun-Joo 한국식품영양학회 2018 韓國食品營養學會誌 Vol.31 No.2

The objective of this study was to evaluate quality properties of high quality rice. Seven rice varieties, Dabo, Daebo, Samkwang, Sindongjin, Sukwang, Jinsumi, and Haiami, were investigated for proximate contents and physicochemical characteristics. Moisture content was highest in the Jinsumi (13.13%). Protein and lipid content was highest in the Haiami. The amylose content of the rice cultivars was 20.15~22.51%. The degree of amylopectin polymerization (DP) was analyzed, and in all cultivars, DP 13-24 content was found to be highest, at more than 53%, whereas DP ${\geq}37$ content was lowest, at less than 5.81%. With regard to free sugar, maltose content in rice was the highest (${\geq}46%$). Toyo value of rice was highest in Samkwang, Daebo, and Jimsumi. Palatability characteristics were highest in Daebo and Jimsumi. Thus, the results of this study suggested that Samkwang, Daebo, and Jinsumi can be effectively used as processed cooked rice, though further studies should be required regarding changes in the quality of rice after cooking.

파종시기에 따른 중북부 지역 재배 녹두 품종의 품질 및 이화학 특성

우관식,김성국,정건호,김현주,이지혜,이병원,이유영,이병규,Woo, Koan Sik,Kim, Sung Kook,Jung, Gun Ho,Kim, Hyun-Joo,Lee, Ji Hae,Lee, Byong Won,Lee, Yu Young,Lee, Byoung Kyu 한국식품영양학회 2018 韓國食品營養學會誌 Vol.31 No.5

The proximate compositions, quality and physicochemical characteristics of mung-bean cultivars cultivated in the north-central region of South Korea with different seeding periods were evaluated. A significant difference was noted in the proximate compositions and chromaticity of mung-beans according to cultivars and different seeding periods. Crude ash and protein content decreased with the delay in seeding period and a slight increase in carbohydrate content was observed. Redness of the other five cultivars increased with the delay in seeding period except for the cultivar Jangan, while the yellowness decreased in cultivars Geumsung and Jangan. Water binding capacity of the $1^{st}$, $2^{nd}$ and $3^{rd}$ seeding on the cultivar Eoul was 115.15, 99.76 and 96.31%, respectively, and a decrease in the binding capacity was observed with the delay in seeding periods. Water solubility index and swelling power were significantly different among cultivars. Total polyphenol content of $1^{st}$ and $2^{nd}$ seeding on the cultivar Jangan was 8.59 and 8.57 mg GAE/g, respectively, and a decrease was observed with the delay in seeding periods except for the cultivar Sohyeon. Total flavonoid content of $1^{st}$ seeding on the cultivar Jangan was 5.25 mg CE/g, which decreased with the delay in seeding periods. DPPH radical scavenging activity of $1^{st}$ seeding on the cultivars Geumsung and Kyungseon was 2.44 and 2.32 mg TE/g, respectively, which decreased with the delay in seeding periods. The BTS radical scavenging activity of $1^{st}$ seeding on the cultivar Jangan was 6.98 mg TE/g. In the present study, the variations in phenol content and radical scavenging activity were observed to be dependent on the cultivars and seeding periods.

종자친과 화분친을 달리한 옥수수의 품질 및 이화학 특성

우관식,배환희,정건호,손범영,김현주,Woo, Koan Sik,Bae, Hwan Hee,Jung, Gun Ho,Son, Beom-Young,Kim, Hyun-Joo 한국식품영양학회 2021 韓國食品營養學會誌 Vol.34 No.4

This study investigated on the chemical components, quality characteristics, antioxidant compounds, and activity of maize hybrids according to the cultivar, and breeding maize seeds crossed with seed and pollen parent. The moisture, crude fat, crude ash, crude protein, carbohydrate, and amylose contents of maize hybrids were significantly different among cultivars, and seeded and pollinated maize. The L-, a- and b-value of maize hybrids were 39.81~47.21, -0.01~0.55 and 5.85~18.47, respectively. Water binding capacity, water solubility index and swelling power were 123.29~153.32, 4.69~5.76 and 20.11~21.47%, respectively. The phenolic compounds and radical scavenging activity of maize hybrids were significantly different among cultivars, and seeded and pollinated maize. Total polyphenol and flavonoid contents of maize hybrids were 1,335.41~1,876.29 ㎍/g and 184.24~453.95 ㎍ CE/g, respectively. The DPPH and ABTS radical scavenging activities were 171.75~239.16 and 299.44~364.09 mg TE/100 g, respectively. As a result, it could be used as a basic data for cultivating phenol compounds and antioxidant activity in maize breeding.

재배방법에 따른 팥의 항산화 특성 및 앙금의 품질 특성

우관식,송석보,고지연,김영복,김욱한,정헌상,Woo, Koan Sik,Song, Seok Bo,Ko, Jee Yeon,Kim, Young Bok,Kim, Wook Han,Jeong, Heon Sang 한국식품영양학회 2016 韓國食品營養學會誌 Vol.29 No.1

재배방법에 따라 팥의 항산화 성분과 항산화 활성의 차이를 조사하고, 생산된 팥에 대해 앙금을 제조하여 품질특성을 분석하고자 하였다. 총 polyphenol 및 flavonoid 함량은 재배방법에 따라 유의적인 차이를 보이는 것으로 나타났으며(p<0.05), DPPH 및 ABTS radical 소거활성 또한 재배방법에 따라 유의적인 차이를 보이는 것으로 나타났고, 다른 품종에 비해 홍언이 높았다. 충주팥, 홍언 및 아라리의 습물중 앙금 수율은 각각 296.64~339.01, 271.36~282.24 및 268.21~292.32%, 건물중앙금 수율은 각각 71.68~85.41, 77.90~85.19 및 74.15~78.65%로 재배방법에 따라 유의적인 차이를 보이는 것으로 나타냈다(p<0.05). 습물 및 건물 앙금의 명도는 충주팥과 아라리는 약간의 유의적인 차이를 보였으나(p<0.05), 홍언은 유의적인 차이를 보이지 않았고, 적색도와 황색도는 재배방법에 따라 유의적인 차이를 보이는 것으로 나타났다(p<0.05). 평균입자 직경은 충주팥, 홍언 및 아라리가 각각 66.21~98.80, 61.62~97.07 및 $82.96{\sim}106.71{\mu}m$로 재배방법별로 유의적인 차이를 보이는 것으로 나타났다(p<0.05). 앙금의 미세구조는 타원형 모양의 입자로 세포막과 단백질이 둘러싸서 표면이 거친 것을 볼 수 있다. 수분결합력, 용해도 및 팽윤력 또한 재배방법에 따라 유의적인 차이를 보였다(p<0.05). We evaluated the antioxidant properties of adzuki beans and the quality characteristics of sediment using various cultivation methods. There were significant differences in total polyphenol and flavonoid contents in beans grown using different methods of cultivation (p<0.05). Also, DPPH and ABTS radical-scavenging activities were significantly different depending on cultivation method (p<0.05). The sediment yield before drying of Chungju-pat, Hongeon, and Arari was 296.64~339.01, 271.36~282.24, and 268.21~292.32%, respectively, and the sediment yield after drying was 71.68~85.41, 77.90~85.19, and 74.15~78.65%, respectively. The L-value of Chungju-pat and Arari sediments revealed a significant difference given different cultivation methods (p<0.05), but Hongeon sediment did not show a significant difference. There was a significant difference in the a- and b-value of adzuki bean sediments cultivated using different methods (p<0.05). The particle size of Chungju-pat, Hongeon, and Arari sediments was 66.21~98.80, 61.62~97.07, and $82.96{\sim}106.71{\mu}m$, respectively, and all were significantly different depending on cultivation method (p<0.05). There were also significant differences in the water absorption index, water solubility index, and swelling power when different cultivation methods were used (p<0.05).

열처리한 국산 감초추출물의 항산화활성

우관식,황인국,노영희,정헌상,Woo, Koan-Sik,Hwang, In-Guk,Noh, Young-Hee,Jeong, Heon-Sang 한국식품영양과학회 2007 한국식품영양과학회지 Vol.36 No.6

국산 감초를 처리온도, 시간 및 첨가수분함량을 변수로하여 열처리한 다음 에틸아세테이트와 에탄올로 추출하여 성분 및 생리활성 변화를 분석하고 반응표면분석으로 최적화 조건을 조사하였다. 에틸아세테이트 추출물의 추출수율은 $130^{\circ}C$, 3시간, 가수량 50%일 때 10.90%로 무처리구의 0.80%보다 높았으며, 에탄올 추출물은 $120^{\circ}C$, 2시간, 가수량 20%로 처리한 시료가 25.00%로 무처리구의 15.80%보다 높았다. 총 폴리페놀 함량은 열처리구가 무처리구보다 높았으며, 에탄올 추출물의 $120^{\circ}C$, 2시간, 가수량 20% 처리구가 845.67 mg/100 g으로 무처리구의 277.00 mg/100 g보다 높았다. 항산화활성($IC_{50}$)은 열처리구가 무처리구보다 높게 나타났으며, 에틸아세테이트 추출물 $120^{\circ}C$, 2시간, 가수량 20% 처리구에서 0.53 g/L로 무처리구의 12.34 g/L보다 매우 높게나타났다. 총항산화력(AEAC)은 모든 처리구에서 무처리구보다 높게 나타났는데 에틸아세테이트 추출물 $120^{\circ}C$, 2시간, 가수량 40% 처리구에서 1,584 mg AA eq로 무처리구의 1,263 mg AA eq보다 높게 나타났다. 본 연구결과 감초의 항산화활성, 총 폴리페놀 함량 등을 증가시키기 위한 최적의 열처리 조건은 $120^{\circ}C$, 2시간, 가수량 $20{\sim}40%$로 판단되었다. Antioxidative activity and polyphenol contents of heated licorice in Korea extracted by ethyl.acetate (EtOAc) and ethyl.alcohol (EtOH) were evaluated at various heating temperatures (110, 120, 130, 140, and $150^{\circ}C$), times (1, 2, 3, 4, and 5 hr), and moisture contents (10, 20, 30, 40, and 50%). Maximum extraction yields of EtOAc extract was 10.9% at $130^{\circ}C$, 3 hr, and 50% moisture content and that of EtOH extract was 25.0% at $120^{\circ}C$, 2 hr, and 20% moisture content, whereas those of control were 0.8 and 15.8%, respectively. The highest total polyphenol content was 845.67 mg/100 g in EtOH extract at $120^{\circ}C$, 2 hr, and 20% moisture content (control: 277.00 mg/100 g). The antioxidative activity ($IC_{50}$) was the highest value of 0.53 mg/mL in EtOAc extract at $120^{\circ}C$, 2 hr, and 20% moisture content (control: 12.34 mg/mL). The highest ascorbic acid equivalent antioxidant activity value of 1,584 mg ascorbic acid (AA) eq was obtained from EtOAc extract at $120^{\circ}C$, 2hr, and 40% moisture content (control: 1,263 mg AA eq). Optimum heating conditions for the improvement of antioxidative activity of licorice in Korea was $120^{\circ}C$, 2 hr, and $20{\sim}40%$ moisture content.

부재료 첨가에 따른 별미장의 향기특성

우관식(Koan Sik Woo),한서영(Seo Young Han),윤향식(Hyang-Sik Yoon),이준수(Junsoo Lee),정헌상(Heon-Sang Jeong),김행란(Haeng-Ran Kim) 한국식품영양과학회 2006 한국식품영양과학회지 Vol.35 No.6

생황장에 양파를 첨가하였을 때와 무장과 비지장에 표고버섯을 첨가하였을 때, 그리고 찌금장에 다시마를 첨가하였을 때 휘발성 성분을 추출하여 분석ㆍ동정하였다. 생황장은 furfural, benzeneacetaldehyde, n-hexadecanoic acid 등이 많이 검출되었고 양파 첨가구에서 1-hexanol, 2,5-dimethylthiophene은 숙성 4일 후에 각각 0.07, 0.11 ppm이 검출되었다. 생황장은 발효 4일된 시료에서 향기성분의 함량이 비교적 높게 나타났으며, n-hexadecanoic acid의 경우 발효 4일된 시료는 발효초기 함량보다 10배 이상 높게 나타났다. 무장에서의 1H-indole과 phenol은 발효초기에는 대조구에서 각각 130.02, 85.38 ppm이었고, 6일째에는 각각 129.68, 95.99 ppm이었다. 표고버섯 첨가시 1H-indole은 각각 121.90 ppm에서 114.44 ppm으로, phenol은 각각 87.48 ppm에서 75.64 ppm으로 감소하였다. 3-Allyl-6-methoxyphenol, γ-dodecalactone 등은 대조구에서 검출이 되었으며, 1,2,4-trithiolane, 2-buthyl-2-octenal은 표고버섯 첨가구에서 검출되었다. 비지장에서는 2,4-decadienal이 대조구는 발효초기에는 2.76 ppm, 발효 1일에는 6.46 ppm, 2일에는 5.02 ppm이 검출되었고 표고버섯 첨가구는 발효초기에는 2.92 ppm, 발효 1일에는 3.84 ppm, 2일에는 3.60 ppm이 검출되어 표고버섯 첨가시 함량이 감소하는 것으로 나타났다. Furfural은 증가하는 경향을 보였고, 1,2,4-trithiolane과 lenthionine은 표고버섯 첨가한 시료에서만 검출되었다. 찌금장은 tetramethylpyrazine, hexadecanal, tetradecanoic acid methyl ester, n-hexadecanoic acid, linoleic acid ethyl ester 등이 검출되었고 발효가 진행되어도 이들 성분의 변화는 적었지만, linoleic acid ethyl ester는 감소하였다. 전제적으로 부재료를 첨가하였을 경우에 장 특유의 이취로 알려진 pyrazine류나 hexadecanoic acid 등의 지방산의 함량이 감소하는 것으로 나타났다. Aroma compounds in four different Byeolmijang made from optional ingredient addition were extracted by SDE (simultaneous steam distillation extraction) and analyzed with GC (gas chromatography) and GC/MS (mass-spectrometry). The major aroma compounds in the four different Byeolmijang during aging were 1-octene-3-ol, hexanal, benzeneacetaldehyde, benzaldehyde, furfural, pyrazine, furan and phenol type com-pounds. Generally, benzeneacetaldehyde, benzaldehyde, furfural and phenol type compounds were increased during aging. On the other hand, 1-octen-3-ol, hexanal and furan were decreased during aging. Furfural, 2-furanmathanol and benzeneacetaldehyde in Sanghwangjang, 3-methyl-1-butanol, phenol and 1H-indole in Mujang, hexanal, 1-octen-3-ol and 2,4-decadienal in Bizijang and hexanal, tetramethylpyrazine and 2-methoxy-4-vinylphenol in Jigeumjang were identified as major aroma compounds, respectively. Generally, the major aroma compound in four different Byeolmijang with optional ingredient was similar with control and pyrazine, furan and phenol type compounds were decreased to addition with optional ingredient. The major aroma compound in Sanghwangjang with optional ingredient (onion) were 1-hexanol and 2,5-dimethylthiophene and the major aroma compounds were 1,2,4-trithiolane and 2-buthyl-2-octenal in Mujang with optional in-gredient (Letinus edodes). Furfural, benzaldehyde, benzeneacetaldehyde, 1,2,4-trithiolane and lenthionine were detected in Bizijang due to the addition of powdered Letinus edodes. Linaool and β-lonone were detected in Jigeumjang due to the addition of powdered red pepper.

품종 및 재배시기에 따른 조와 기장의 항산화성분 및 항산화활성

우관식(Koan Sik Woo),이재생(Jae Saeng Lee),고지연(Jee Yeon Ko),송석보(Seuk Bo Song),서혜인(Hye In Seo),서명철(Myung Chul Seo),오병근(Byeong Geun Oh),곽도연(Do Yeon Kwak),남민희(Min Hee Nam),오인석(In Seok Oh),정헌상(Heon Sang Jeong) 한국식품영양과학회 2012 한국식품영양과학회지 Vol.41 No.3

조와 기장의 항산화성분 및 항산화활성에 미치는 재배시기의 영향을 규명하고자 재배시기를 달리하여 수확된 시료메탄올 추출물의 항산화성분 및 항산화활성을 분석하였다. 재배시기에 따른 조와 기장 메탄올 추출물의 총 폴리페놀, 플라보노이드, 탄닌 등의 항산화성분의 함량과 DPPH 및 ABTS radical 소거활성은 품종 및 재배시기별로 유의적인 차이를 보이는 것으로 나타났다. 총 폴리페놀 함량은 황금조, 청차조, 삼다메 및 경관1호의 경우 만기재배에서, 경관2호는 보통기재배에서, 강해조는 조기와 만기재배에서 비교적 높은 함량을 보였고 기장의 경우 전체적으로 만기재배에서 높은 함량을 나타냈다. 총 플라보노이드 함량은 황금조와 경관2호는 보통기재배에서, 청차조, 삼다메 및 경관1호는 조기재배에서, 강해조는 만기재배에 높은 함량을 보였고 기장은 만기재배에서 높은 함량을 보였다. 총 탄닌 함량은 황금조는 조기재배에서, 청차조, 삼다메 및 강해조는 만기재배에서, 경관2호는 보통기재배에 높은 함량을 보였고 기장은 만기재배에서 조기나 보통기재배보다 높은 함량을 보였다. 조의 DPPH radical 소거활성은 황금조, 삼다메 및 강해조는 만기재배에서, 청차조와 경관2호는 보통기재배에서, 경관1호는 조기재배에서 높은 활성을 나타냈으며, 기장은 전체적으로 만기재배에서 높은 활성을 나타내었다. ABTS radical 소거활성은 황금조, 경관1호 및 강해조는 만기재배에서, 청차조, 삼다메 및 경관2호는 보통기재배에서 높은 활성을 나타내었고 기장은 만기재배에서 높은 활성을 나타내었다. 이상의 항산화성분 함량 및 항산화활성을 분석한 결과에서 조의 경우 조기재배보다는 보통기 내지 만기재배가 유리할 것으로 보이며, 기장은 만기재배가 유리할 것으로 생각된다. Effects of cultivation time on the antioxidant contents and activities of foxtail millet and proso millet were determined. The cultivation times were early-season (ES), normal-season (NS), and late-season (LS), and the cultivated varieties were Hwanggeum-cho (HGC), Cheongcha-cho (CCC), Samdamae (SDM), Gyeongkwan 1 (GK 1), Gyeongkwan 2 (GK 2), Ganghae-cho (GHC), Hwanggeum-gijang (HGG), Manhongchal-gijang (MHCG), Byeoruk-gijang (BRG), Norangchal-gijang (NRG), and Whin-gijang (WG). The total polyphenol, flavonoid, tannin content, and DPPH and ABTS radical scavenging activities of the methanolic extracts of foxtail millet and proso millet showed significant differences according to cultivation variety and time. The highest total polyphenol content of foxtail millet was 29.33 ㎎ of gallic acid equivalent (GAE)/g of sample in GK 1 at LS, whereas that of proso millet was 23.48 ㎎ of GAE/g of sample in BRG at LS. The highest total flavonoid content of foxtail millet was 2.12 ㎎ of catechin equivalent (CE)/g of sample in CCC at ES, whereas that of proso millet was 4.49 ㎎ of CE/g of sample in BRG at LS. The highest total tannin content of foxtail millet was 14.07 ㎎ of tannic acid equivalent (TAE)/g of sample in SDM at LS, whereas that of proso millet was 15.59 ㎎ of TAE/g of sample in BRG at LS. The highest DPPH radical scavenging activity of foxtail millet was 7.71 ㎎ of TE/g of sample in CCC at NS, whereas that of proso millet was 12.66 ㎎ of TE/g of sample in BRG at LS. The highest ABTS radical scavenging activity of foxtail millet was 8.05 ㎎ of TE/g of sample in GK 1 at LS, whereas that of proso millet was 34.46 ㎎ of TE/g of sample in BRG at LS. Generally, HGC, GK 1, and GHC had more beneficial effects at LS than ES or NS, whereas CCC, SDM, and GK 2 had more beneficial effects at NS than ES or LS, and proso millet had more beneficial effects at LS than ES or NS.

유색미 첨가 밥의 품질 및 이화학 특성에 미치는 취반방법의 영향

우관식(Koan Sik Woo),김현주(Hyun-Joo Kim),조동화(Dong-Hwa Cho),이석기(Seuk Ki Lee),박혜영(Hye Young Park),심은영(Eun-Yeong Sim),이춘기(Choon Ki Lee),전용희(Yong Hee Jeon),오세관(Sea Kwan Oh) 한국식품영양과학회 2018 한국식품영양과학회지 Vol.47 No.3

취반방법이 유색미밥의 항산화 활성에 미치는 영향을 살펴보기 위해 유색미 비율별(0, 5, 10, 15 및 20%)로 첨가했을 때 취반방법별로 제조한 유색미밥의 기능성분 및 라디칼 소거 활성을 살펴보았다. 아밀로그램 특성은 유색미 혼합비율이 증가함에 따라 최고점도, 최저점도, 강하점도, 최종점도, 치반점도가 유의적으로 감소하였다. 건강홍미의 수분결합력은 혼합비율이 증가함에 따라 증가하였고 조생흑찰은 감소하였으며, 팽윤력은 감소, 용해도는 증가하는 경향을 보였다. 유색미의 혼합비율별 식미 특성은 외관, 경도, 찰기 및 밸런스는 백미에 비해 떨어지는 것으로 나타났다. 유색미 혼합비율과 취반방법에 따른 유색미밥의 총 폴리페놀, 플라보노이드 함량 및 라디칼 소거 활성은 유색미의 혼합비율이 증가함에 따라 유의적으로 증가하였다. 총 폴리페놀 및 플라보노이드 함량은 조생흑찰 20% 첨가, 10% 발효주정을 첨가하여 일반밥솥으로 취반한 경우 각각 461.83 μg GAE/g sample 및 127.38 μg CE/g sample로 높게 나타났다. 유색미밥의 주요 페놀 화합물은 protocatechuic acid, p-coumaric acid 및 ferulic acid 등으로 나타났다. 건강홍미의 DPPH 및 ABTS 라디칼 소거 활성은 20% 첨가, 10% 발효주정을 첨가하여 압력밥솥으로 취반한 경우 각각 13.38 및 29.29 mg TE/100 g sample로 나타났고, 조생흑찰은 20% 첨가, 10% 발효주정을 첨가하여 일반밥솥으로 취반한 경우 각각 34.00 및 49.59 mg TE/100 g sample로 높은 활성을 나타내었다. 이상의 결과 유색미밥은 발효주정을 첨가하여 취반하였을 때 높은 라디칼 소거 활성을 나타내어 소량의 발효주정을 첨가하여 밥을 짓는 방법은 산업적으로 이용이 가능할 것으로 생각된다. This study was conducted to compare the quality and physicochemical characteristics of cooked-rice containing various amounts of colored rice (0, 5, 10, 15, and 20%) and prepared using different cooking methods(general and high pressure). The cooked-rice containing colored rice was prepared using general and high pressure cookers with and without fermented alcohol. Amylogram characteristics decreased with increasing amounts of colored rice. In addition, the water binding capacity of Geonganghongmi (red rice) increased as the amount of colored rice increased; however, that of Josaengheugchal (black rice) decreased. Moreover, swelling power decreased with increased addition of colored rice, and water solubility index increased. Additionally, the palatability of samples containing colored rice were lower than those of white rice. The total polyphenol, flavonoid contents, and radical scavenging activity were increased with the addition of colored rice. Furthermore, the total polyphenol and flavonoid contents in rice cooked with 20% Josaengheugchal and 10% fermented alcohol were 461.83 μg gallic acid equivalents/g sample and 127.38 μg catechin equivalents/g sample, respectively. The predominant phenolic compounds in cooked-rice amended with colored rice were protocatechuic acid, p-coumaric acid and ferulic acid. Finally, the 1,1-diphenyl-2-picrylhydrazyl and 2,2’-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) radical scavenging activities of rice cooked with 20% Josaengheugchal and 10% fermented alcohol were 34.00 and 49.59 mg Trolox equivalent/100 g sample, respectively. Overall, the results of this study indicated that the antioxidative properties of colored rice and cooking method can be used as basic data to describe processed manufactured products.

전처리조건에 따른 망초(Erigeron canadensis L.) 에탄올 추출물의 항산화활성

우관식(Koan Sik Woo),송석보(Seuk Bo Song),오병근(Byeong Geun Oh),서명철(Myung Chul Seo),고지연(Jee Yeon Ko),이재생(Jae Saeng Lee),강종래(Jong Rae Kang),남민희(Min Hee Nam),정헌상(Heon Sang Jeong) 한국식품영양과학회 2009 한국식품영양과학회지 Vol.38 No.9

망초의 항산화성분 및 활성 측정을 통하여 대표적인 항산화성분인 총 폴리페놀 및 플라보노이드, 탄닌, chlorophyll 함량과 DPPH radical 소거활성 및 ABTS cation decolorization assay에 의한 총 항산화력을 측정하였다. 생물상태 망초 추출물의 총 폴리페놀, 플라보노이드, 탄닌 및 chlorophyll 함량은 각각 63.32, 27.71, 161.19 및 428.85 ㎎/g으로 나타났다. 40℃에서 열풍 건조한 시료의 경우 각각 89.25, 33.44, 210.44 및 229.29 ㎎/g으로 나타났으며, 끓는물에 2분간 데친 후 48시간 40℃에서 열풍 건조한 시료는 각각 115.49, 45.51, 252.54 및 283.07 ㎎/g으로 나타나 대체적으로 생물상태보다 함량이 높은 것으로 나타났다. 생물상태 망초 추출물의 전자공여능(EDA, %)의 IC50은 5.5527 ㎎/mL, 총항산화력은 192.78 ㎎ AA eq/g sample로 나타났다. 40℃에서 열풍 건조한 시료의 경우 각각 0.4710 ㎎/mL 및 194.05 ㎎ AA eq/g sample로 나타났으며, 끓는 물에 2분간 데친 후 48시간 40℃에서 열풍 건조한 시료는 각각 0.4135 ㎎/mL 및 242.40 ㎎ AA eq/g sample로 나타나 대체적으로 생물상태보다 항산화활성이 높은 것으로 나타났다. In order to investigate the potential characteristics of horseweed (Erigeron canadensis L.) recognized with weeds for the application to food industry, the antioxidative properties of horseweed were measured with total polyphenol, flavonoid, tannin, chlorophyll contests and antioxidant activities. Total polyphenol, flavonoid, tannin, and chlorophyll content were 63.32, 27.71, 161.19, and 428.85 ㎎/g in the extracts of fresh horseweed (FHE), respectively. The extracts of dry horseweed (DHE) on 40℃ for 48 hr were 89.25, 33.44, 210.44, and 229.29 ㎎/g, and the extracts of dry horseweed after blanching (BDHE) were 115.49, 45.51, 252.54, and 283.07 ㎎/g, respectively. IC50 of EDA (electron donating ability, %) and AEAC (L-ascorbic acid equivalent antioxidant capacity) were 5.5527 ㎎/mL and 192.78 ㎎ AA eq/g sample in the FHE, respectively. The DHE were 0.4710 ㎎/mL and 194.05 ㎎ AA eq/g sample, and the BDHE were 0.4135 ㎎/mL and 242.40 ㎎ AA eq/g sample, respectively. Horseweed, where the antioxidant activity is excellent, is thought to be potentially useful with foodstuffs.

침지용매에 따른 숙지황의 품질특성

우관식(Koan Sik Woo),송대식(Dae Sik Song),이준수(Junsoo Lee),이희봉(Bee-Bong Lee),정헌상(Heon-Sang Jeong) 한국식품과학회 2007 한국식품과학회지 Vol.39 No.3

숙지황의 제조에 미치는 침지용매의 영향을 살펴보기 위하여 건지황을 막걸리와 증류수에 24시간 침지한 후 구증구포하여 숙지황을 제조하면서 증수에 따른 catalpol, 5-HMF, polyphenol, flavonoid, 항산화활성 및 ACE 저해활성 등을 분석하였다. Catalpol 함량은 건지황에서 631.4 ppm으로 나타났으며, 증수가 증가할수록 급격히 감소하였고 막걸리 침지는 8증(75.84 ppm)까지, 증류수 침지 처리구는 9증(61.27 ppm)까지만 검출되었다. 5-HMF, 총 폴리페놀, 총 플라보노이드 함량은 증수가 증가할수록 증가하였으며, 5-HMF는 막걸리 침지는 13증(0.40%) 이후에, 증류수 침지 처리구는 11증(0.40%) 이후에 시판 숙지황의 함량과 비슷하였고 총 폴리페놀 함량과 총 플라보노이드 함량은 막걸리와 증류수침지 처리구 모두 14증에서 가장 높은 함량을 나타내었다. 전자공여능은 건지황과 시판 숙지황 모두 1 ㎎/㎖의 농도에서 각각 19.44 및 52.49%이었으며, 막걸리와 증류수침지 시료 모두 14증에서 각각 66.80 및 75.60%로 증가하였다. 총 항산화력도 처리증수가 증가할수록 증가하였다. ACE 저해활성은 건지황과 시판 숙지황 모두 1 ㎎/㎖의 농도에서 각각 28.70 및 49.37%로 이었으며, 처리 증수가 증가할수록 증가하여 막걸리와 증류수침지 시료 모두 10증에서 각각 93.23 및 94.78%로 가장 높은 활성을 나타내었다. This study was performed to investigate the effects of pre-soaking methods on the preparation of Rehmannia radix Preparata (R.P). The R. radix L (R.L) was soaked in distilled water and traditional Korean wine for 24 hr, then the soaked R.L was treated with a traditional nine-time steaming process. Next, catalpol, 5-hydroxymethyl-2-furaldehyde (5-HMF), polyphenols, flavonoids, antioxidant activities, and ACE inhibition activity were analyzed for the R.P produced by the different methods. The catalpol content of the R.L was 631.4 ppm, but the content decreased as steaming increased to 8-9 times. The 5-HMF, polyphenol, and flavonoid contents of the RL were 0.12 ㎎/g, 5.09 ㎎/g, and 0.83 ㎎/g, respectively, and these increased gradually with increasing steaming times. As the steaming times of the distilled soaking water increased, the antioxidant activities of 1 ㎎/㎖ increased from 19.44% to 75.60% at 14 times of steaming. The ACE inhibition activities of 1 ㎎/㎖ of the distilled soaking water increased from 28.70% to 94.78% at 10 times of steaming, but decreased afterward.