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      • KCI등재후보
      • 전도도법에 의한 치환 피리딘들의 해리상수 측정과 그의 온도와 압력에 따른 영향

        黃正儀,鄭倧在,金學成,尹永炷,朴義煥 慶北大學校 物理化學硏究所 1985 硏究論文集 Vol.6 No.-

        Generally, pyridine and most of substituted pyridines act as base in aqueous solutions. The strengths of their basicities can be expressed quantitatively by the dissociation constant of base or its conjugated acid. Generally, the acidity of substituted pyridines can be expressed by K_a of the following reaction. ◁그림삽입▷(원문을 참조하세요) The dissociation constants of these subtituted pyridines have not been reported under high pressure but under atmospheric pressure. In this papers, the dissociation constants of some substituted pyridines were measured under high pressure by the conductometry. From the ionic conductivity of hydrogen ion, the dissociation constants(K_a) were calculated. The K_a values were increased with increasing temperature and were decreased with increasing pressure. The characteristics of dissociation process of some substituted pyridines were deduced from the thermodynamic properties calculated from the dissociation constants.

      • 유산양 유방염에 대한 Chitosan 약침의 치료 효과

        황수현,서진석,김덕환,김명철,신상태,전무형,南三郞,김영찬,이우근,표수일 충남대학교 수의과대학 동물의과학연구소 1999 動物醫科學硏究誌 Vol.7 No.-

        To improve the therapeutic method for mastitis, treatment effect of chitosan pharmacopuncture was examined in three milking goats(A,B and C). Mastitis was artificially induced in two milking goats(A and B) and one goat(C) was naturally infected case with mastitis. The acupoint used was Yang-Ming and chitosan suspensions(provided from Tottory University, Japan: 30㎎ of chitosan/㎖)were injected to the acupoint with 5㎖/time for 3 days, respectively. As for the change of somatic cells in milk along with chitosan pharmacopuncture, they showed a decreasing tendency after increase on the 3rd day in all udders of B. In addition, as for the change of total leukocyte counts of peripheral blood with chitosan pharmacopuncture, they showed a decreasing tendency after increase on the 3rd day in B and C except A which showed a increasing tendency until on the 7th day. In the change of neutrophil/lymphocyte(N/L) ratio, increasing tendency was seen in A and C but increasing tendency after slight decrease was observed in B. Further, in the change of serum total protein and A/G ratio, serum total protein content was decreased after slightly increase on the 3rd day in A, and they were decreased after increase until on the 7th day in B and C, respectively. As for the change of A/G ratio, different pattern increasing tendency was shown in A, B and C.

      • 전도도법에 의한 치환 피리딘들의 해리상수 측정과 그의 온도와 압력에 따른 영향

        黃正儀,鄭倧在,金學成,尹永炷,朴義煥 慶北大學校 1984 論文集 Vol.38 No.-

        Generally, pyridine and most of substituted pyridines act as base in aqueous solutions. The strengths of their basicities can be expressed quantitatively by the dissociation constant of base or its conjugated acid. Generally, the acidity of substituted pyridines can be expressed by K_a of the following reaction. ◁그림 삽입▷ (원문을 참조하세요) The dissociation constants of these subtituted pyridines have not been reported under high pressure but under atmospheric pressure. In this papers, the dissociation constants of some substituted pyridines were measured under high pressure by the conductometry. From the ionic conductivity of hydrogen ion, the dissociation constants (K_a) were calculated. The K_a values were increased with increasing temperature and were decreased with increasing presure. The charateristics of dissociation process of some substituted pyridines were deduced from the thermodynamic properties calculated from the dissociation constants.

      • KCI등재
      • 프리캐스트 포스트텐션 콘크리트 넓은 보-기둥 내부 접합부의 비탄성 거동

        황재환,최윤철,김영찬,김대중,임재형,권기혁,문정호,이리형 대한건축학회 2003 대한건축학회 학술발표대회 논문집 - 계획계/구조계 Vol.23 No.2(구조계)

        The purpose of this paper is to evaluate the response of Precast Prestressed Concrete Interior Wide Beam-Column Joint subjected to cyclic lateral loading. To this end, the experimental investigation was performed with six half-scale specimens of interior connection. The design parameters are the beam to column depth ratio, and the number of tendons within column core. One of the specimens, IJH-6, is modeled for the connection at the top floor of a structure. The test results showed that the specimens sufficiently resist up to limiting drift ratio of 0.035 in accordance with the provisional standard by ACI of acceptance criteria for concrete special moment frames.

      • 연재생공장의 작업환경 개선에 따른 연폭로 지표의 변화

        황영민,황인철,이용환 高神大學校保健科學硏究所 1998 보건과학연구소보 Vol.8 No.-

        To establish the relation of time sequence between environment exposure and biological indices, eighteen workers who were diagnosed to lead poisoning in 1993 and since then have worked at two lead recycling factories in Pusan were followed up. The lead in urine and blood and ZPP as biological indices for lead exposure and air lead level were analyzed and reviewed for four years. The results were as follows; 1. There were no statistical differences between two factories for age, work duration, smoking, and alcohol drinking. There were no differences among most work processes but in dissolution and casting process for age and work duration between two factories(p<0.05). 2. Time sequence for lead concentration in blood and urine, air lead level, and blood ZPP was statistically significant(p<0.01). 3. All lead exposure indices in dissolution and casting process were significantly higher than in collection, storage, and shipping process(p<0.05). 4. All lead exposure levels were significantly decreased at 1995 after environmental intervention such as the local exhaust ventilation and vacuum cleaning of floor in 1994. Through these results, it was confirmed that environmental intervention is very important in the occupational health care. Therefore, government and occupational health agencies should persistently endeavor to improve the working environment of hazardous factories.

      • KCI등재

        두가지 혈류 유발방법에 의한 새로운 심폐소생술(이중 혈류 유발 심폐소생술)장치의 개발

        황성오,김현,조준휘,오범진,임종천,최경훈,윤정한,이승환,김영식,이강현,이윤선 大韓應急醫學會 1999 대한응급의학회지 Vol.10 No.2

        Background: There have been many efforts to augment blood flow during cardiopulmonary resuscitation. These efforts have focused on maximizing the effect of cardiac pump or thoracic pump alone. However, considering that the heart is the biggest blood reservoir and increase of intrathoracic pressure can generate blood flow, simultaneous exploitation of both mechanisms may have synergistic effect. We hypothesized that simultaneous chest constriction in addition to sternal compression by standard CPR may have additive hemodynamic effects by preventing deformation of the chest and increase of intrathoracic pressure. Methods and results: we built a new mechanical device to perform compression and thoracic constriction simultaneously. The device consists of two main elements. Piston in the center is to depress the sternum. Strap is to constrict the thorax circumferentially. Strap is attached to both sides of the piston. When the piston is pushed down, it depresses the sternum and pulls on the thoracic strap. To determine strap width to produce optimal hemodynamic effect, we measured hemodynamic parameters with variable widths of strap in two dogs after induction of ventricular fibrillation. Result of the experiment showed that 10cm wide strap was determined to be most effective. We also determined optimal depth of compression to produce maximal hemodynamic effect with animal experiments using two dogs. Animal experiments showed that the highest aortic pressure could be generated when the stemum was depressed to 5 cm. Cardiopulmonary resusciation using a new device could generate higher systolic aortic pressure, coronary perfusion pressure and end-tidal carbon dioxide tension in comparison with standard cardiopulmonary resuscitation in a pilot animal study using two dogs. Conclusion: New cardiopulmonary resuscitation method using a mechanical device designed by us could perform sternal compression and simultaneous thoracic constriction, and generate better hemodynamic effects than standard cardiopulmonary resuscitation in pilot animal experiments.

      • KCI등재

        방사성 폐기물 시멘트 고화체로 부터의 ?? 및 ?? 용출특성 연구

        황선태,이경주,최길웅,박헌휘,김환영 대한방사선 방어학회 1985 방사선방어학회지 Vol.10 No.2

        방사성폐기물 처리, 처분의 안정성 평가를 위하여 방사성 고화체에서 용출되는 137Cs과 90Sr의 방사능 용출율과 누적용출분율을 계측·분석하여 시멘트를 사용한 방사성 고화체에서 Cs+과 Sr++의 용출특성을 조사하였다. 모의방사성 폐액의 몰농도, 시멘트의 종류, 첨가물질 및 붕산농도 등을 변화시키면서 sodium silicate법과 중화법으로 원주형 시멘트 고화제를 제작하였다. 여기에서 가압경수로형 원자력 발전소의 모의 농축폐액의 시멘트 고화체로부터 용출연구는 IAEA의 추천방법에 따라서 수행되었다. 실험결과는 대부분 이미 보고된 연구자료들과 잘 일치하고 있으나 수밀성 시멘트 고화체에서는 상당히 높은 방사능 용출율을 보여주고 있음으로써 방사성 폐기를 고화체에 그 사용이 적합하지 않음을 알게 된다. For the safety assessment of radwaste treatment and disposal, the leaching characteristics of Cs++ and Sr++ from the cement-solidified radwastes was investigated by means of the survey and analysis of the activity leach rate and cumulative leach fraction of 137Cs and 90Sr leaching from solidified radwastes. The cylindrical cement-solidified samples were made by the sodium silicate method and neutralization method changing the mole density of simulated liquid radwaste, type of cement, adding material and concentration of boric acid. The leaching study was carried out by the method using simulated PWR concentrated liquid radwaste solidified in cement that had been processed following the recommendations of IAEA. All the experimental results are in well accordance with the research data reported previously, but the watertight cement-solidified radwastes show rather high leach rate of radioactivity. It is learned, therefore, that the watertight cement is not adequate as the material for the solidified radwastes.

      • 都市公營開發事業에 對한 考察

        조길환,황의진,김영곤 여수대학교 1998 論文集 Vol.13 No.2

        This Paper studied the background and characteristics of the adopted public development among the system of housing land development that is executing in our country nowadays And it defined the reasons of problems that is caused by a social change in the Project of public development at the level of city public development toward a service that the public development effects to the City planning. So it would like to propose reform methods in develo-ping housing area to give basic data in establishing system of city public development by the local selfgoverning body as the methods for a construction of effective city space and smooth supply of housing area is presented as follows. First : In order to ensure a legitimacy of an exercise of government power for the business of public development, the gualification of a practical system of public development is to be strengthened. According to the guideline of the policy of city development or nation's housing or land, the condition of Yelated areas, the characteristics of business subject, the system of public development is to be selected. The object of the public development such as the developing business of residential land for the low-incomed class, the suitable business that is developed by the pu-blic, the developing business of land in national basic industries is to be realized and objectified more. Second : A differtial application of distribution price of the residential land according to not only the distribution of residential land related with housing construction business and its use or object but also the storage of public land and reformation of system and distribution object of public development land through an activation of the system of land selling in advance. Third : The idleness one of planning developed land such as a rational management for restriction of privaty ownership of developing profit, the establishment of effective restoration system of the developed profit, and establishment of land developing fund is to be controlled. Fourth : To ensure a reinvestment resources for continuous propulsion of the city developing business, its effective propulsion of developing business by a preaying distribution and induction of land demand and distribution acceleration ncouragement of purchase interest) is to be drived. So the distribution acceleration and fund revulsion is to be smooth with a rational reform of a distribution method by a minimization of dependency degree of outer fund in an early period of development and establishment of inverstment resources by a restoring profit of the public development. Fifth : A method of activation in city developing business is to be considered by a diversity of the developing subject. Sixth : The search for distribution method of space for city environment and the enlargement method of equipment space is to be considered.

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