생분해성 플라스틱이 포함된 유기성 생활 쓰레기의 퇴비화

신창호,김영진,이상일,장상희,조무환,신부영 영남대학교 환경문제연구소 2000 環境硏究 Vol.19 No.2

준 생산용 퇴비화 장치를 이용하여 생분해성 플라스틱을 포함하는 유기성 도시생활쓰레기기의 퇴비화를 연구하였다. 유기성 도시생활쓰레기는 실제 도시생활쓰레기 구성비에서 무기물을 제외한 유기성 물질만의 비로 만들어 사용하였다. 유기성 도시생활쓰레기를 구성하는 각각의 물질에 대한 생분해도를 ISO법으로 측정하였고, 퇴비의 화학적 물리적 특성도 조사하였다. 구성 물질에 대한 생분해도 결과에서, 생분해성 고분자를 포함한 각 물질들은 퇴비화에 충분한 생분해도를 나타내는 것으로 밝혀졌다. 또한, 유기성 도시 생활쓰레기로부터 비독성의 퇴비를 얻을 수 있음을 알았다. The composting study of organic municipal solid waste containing biodegradable plastic was performed by using pilot scale composting apparatus. The organic municipal solid waste(OMSW) was artificially prepared for composting. The composition of artificial OMSW was the same as that of real municipal solid waste excluding inorganic waste. The biodegradability of individual component of OMSW was studied according to the ISO method. The chemical and physical characteristics were also observed. Biodegradability study revealed that every component of OMSW including biodegradable plastic had sufficient degradability for real composting. And it was found that non-toxic compost could be produced from OMSW containing biodegradable plastic.

분해성 폴리에틸렌 필름의 생분해 및 광분해성에 관한 연구

신부영,장상희,정병욱 嶺南大學校 工業技術硏究所 1997 工業技術硏究所論文集 Vol.25 No.2

Photo-biodegradable master batch was prepared by using mechanical and thermal oxidation that in general occur during polymer processing operation. Master batches were prepared by melt mixing in air circumstance, respectively. High density polyethylene(HDPE) sheets containing 20 wt.% photo-biodegradable M/Bs were prepared by compression molding and we observed the photodegradability under the mercury-vapor lamp. The sheet of containing M/B prepared above 95% of its original elongation and very brittle within 120 hours irradiation, however, pure HDPE sheet still retained about 80% original elongation for 120 hours irradiation. Under the natural sunlight, photo-biodegradable HDPE films lost about 98% of its original elongation at break for 8weeks outdoor exposure in summer. The common film still retained 75% of its original elongation at the same period. Surface morphology of the films was examined by using scanning electron microscopy(SEM). The effects of water on the mechanical properties and morphology of film were examined during the irradiation. In the case of biodegradation test, incubator test were performed simultaneously. Microorganism (fungi) growth in photo-biodegradable film surface was augmented by exposed time increasingly.

수용성 및 가식성 콩 단백질/�틴 블렌드 필름 제조 및 물성 연구

김성철,신용섭,정세환,유성구,박인식,김봉식,신부영 한국공업화학회 2003 응용화학 Vol.7 No.2

The manufacture of edible/biodegradable films or coatings can potentially add value to soy protein, Such films can find using as edible or nonedible food packaging materials. The effect of soy protein film-forming solutions on film formation, tensile properties of soy protein/pectin blend films were changed significantly by the amount of glycerol and the ratio of soy protein/pectin. Moreover mechanical properties of soy protein/pectin-montmorillonite clay have been studied. Tensile strength and modulus decreases as the relative humidity increased while with increasing relative humidity elongation at break increased.

분해성 고분자를 이용한 지속성 비료에 관한 연구

장상희,신부영,조무환,이일희 嶺南大學校 環境問題硏究所 1997 環境硏究 Vol.16 No.2

요약문농작물에 사용된 비료중 30~705가 농작물의 영양분으로 이용되고, 나머지는 지표수 에 의하여 하천으로 유입되거나, 지하수로 스며든다. 이러한 이유로 경제적 손실과 더불어 지하수에 질소 성분이 농축되어 식수 오염에 큰 영향을 미친다. 본 연구에서는 고분자 가공 기술을 응용하여 120。C에서 무정형 폴리 프로필렌과 요소비료를 혼합하여 지속성 비료 제 조를 제조하였다. 제조된 지속성 비료는 25。C 수중에서 비료성분의 방출속도를 측정하였 다. AbstractIt is estimated that only 30∼70% of the fertilizer applied in agriculture is used for plant nutrition, the rest is carried away by ground water or lost through mtrification-denitrification. Apart from the economic loss due to wastage, severe environmental problems arise due to increasing nitrate concentration in public drinking water. The fertilizer urea was mixed with APP (atactic polypropylene) by super mixer at 120 'C. The rate of fertilizer release was determined by checking dissolution rate in water at 25。C.

忠州市 主幹線 道路邊 建築外部色彩에 關한 硏究

崔生吉,孫泰鎭,柳顯紀,辛同寅,梁富弘,尹勝照,朴碩鉉 忠州大學校 1998 한국교통대학교 논문집 Vol.33 No.2

In order to understand the influence of colours on the urban design of a city, a portion of the central Chung-Ju was chosen as the study area, and three cases were researched as colours. These surveyed colours are analysed in their hue, value and chroma. It was necessary to determine the colours of 272 buildings exterior in all in order formulate the findings presented in this study. The result of this study can be briefly summerised as the following ; 1) The trends in the use of colour turn out like this ; 55.3% of the building were Y(yellow), YR(yellow-green), R(red) Family in Hue, abour 33.9% of them were within 8.0-8.9 and 26.6% were within 7.0-7.9 on the value scale, and about 48.5% of them were within 1.0-1.9, 2.0-2.9 and 3.0-3.9 on the chroma scale. 1) For case 1 on the exterior colours of buildings, about 57.8% were Y and YR family in Hue, about 53.7% were 8.0-8.9 and 7.0-7.9 in Value, and about 49.6% of them were within 1.0-3.9 in chroma. 2) For case 2 on the exterior colours of buildings, about 52.4% were Y and R family in Hue, about 65.1% were 7.0-8.9 in Value, and about 46% were 1.0-2.9 in Chroma. 3) For case 3 on the exterior colours of buildings, about 55.7% were Y and YR Family in Hue, about 72.1% were 7.0-8.9 in Value, and about 31.1% were 2.0-2.9 in Chroma. In summary, the colours of the building surveyed in central Chung-Ju can be characerized as Y, YR, R, N family in Hue, 7.0-7.9, 8.0-8.9 in Value registered in 1.0-1.9, 2.0-2.9, 3.0-3.9 in Chroma. The observed exterior colours show a tendency toward Yellow in Hue, High in Value and low in Chroma. Generally, the majority of the colours is light rather than strong in tone.

완전 생분해성과 광분해성을 갖는 필름에 대한 연구

이상일,서석훈,홍경민,신용섭,장상희,신부영 영남대학교 공업기술연구소 2001 工業技術硏究所論文集 Vol.29 No.1

Bio-and-photodegradable polymer composites were prepared by blending biodegradable aliphatic polyester and photodegradable master batch(M/B). Photodegradability, biodegradability, thermal properties and mechanical properties were investigated. The biodegradability of EnPol(G4600) composites decreased wish increasing the amount of M/B, while that of EnPol(G8000) composites increased. Tensile strength and elongation decreased with increasing the time of outdoor exposure and the amount of M/B but modulus comparatively maintained. The mechenical properties decreased as the content of M/B increased, while the melting temperature unchanged.

퇴비화법에 의한 플라스틱 필름의 생분해도 연구

정병욱,신창호,김영진,장상희,신부영 영남대학교 공업기술연구소 1999 工業技術硏究所論文集 Vol.27 No.1

Aerobic composting apparatus was set up using International Organization for Standardization(ISO) and ultimate biodegradability of plastic films was evaluated by measurement of released carbon dioxide at the end of test. Test materials were polycaprolactone(PCL), PCL/starch composite with various composition, photo-degradable, bio-destructible film, and high density polyethylene(HDPE) film. After 45 days, PCL and PCL/starch(70/30) composite films were degraded to 37% and 60%, respectively. This fact revealed that starch in PCL elevated the biodegradability of matrix PCL. Although photo-degradable and bio-destructible films also evolved carbon dioxide, matrix polymer(HDPE) was not degraded by microorganisms in compost. This fact was indirectly supported thermogravimetric analysis and morphology of film before and after composting.

콩 단백질/펙틴/몬모릴로나이트 나노복합 필름의 특성 및 산소 투과도 연구

정세환,김성철,조규순,신용섭,장상희,홍기헌,이태진,신부영 嶺南大學校 工業技術硏究所 2004 工業技術硏究所論文集 Vol.32 No.2

In this study, Mechanical property, thermal property, watervapor, and oxygen permeability of biodegradable Soy protein/Pectin-montmorillonite nanocomposite, prepared with Na^(+)-MMT, have been studied. X-ray diffraction and TEM experiments an polymer/silicate composite samples demonstrated that the intercalation of polymer chains leads to increase in the spacing between silicate layers. In addition, it were found that the intercalated Soy protein/Pectin/montmorillonite nanocomposite were prepared. It was found that the addition of only a small of clay was enough to improve the thermal stability and mechanical property of Soy protein/Pectin/montmorillonite nanocomposite. watervapor of Soy protein/Pectin/montmorillonite nanocomposite was generally lower than that of Soy protein/Pectin. oxygen permeability of Soy protein/Pectin/montmorillonite nanocomposite was generally lower than that of Soy protein/Pectin.

사람 YB-1 유전자의 프로모터에 결합하는 핵인자에 관한 연구

김유리,한상원,류필열,김경근,안봉환,신부안 全南大醫大 2001 전남의대학술지 Vol.37 No.1

전분/펙틴/몬모릴로나이트 나노복합 필름의 특성 및 산소 투과도 연구

서석훈,서길수,유성구,신용섭,정세환,김성철,배광수,이태진,장상희,신부영 한국공업화학회 2003 공업화학 Vol.14 No.8

Na^(+)-MMT로부터 제조한 생분해성 전분/펙틴/몬모릴로나이트 나노복합재료의 기계적 특성, 열적 특성, 그리고 산소 투과성을 연구하였다. XRD와 TEM의 결과로부터 고분자의 삽입으로 인하여 실리케이트 층간 간격이 증가하였으며, 또한 삽입형 전분/펙틴/몬모릴로나이트 나노복합재료임을 확인하였다. 합성된 전분/펙틴/몬모릴로나이트 나노복합재료의 경우 적은 양의 MMT로부터 기계적 특성과 열적 안정성이 우수함을 보였다. 그리고 전분/펙틴/몬모릴로나이트 나노복합재료의 산소 투과성은 고분자 매트릭스에 분산되어 있는 몬모릴로나이트에 의하여 현저히 저하됨을 보여주었다. Mechanical property. thermal property. and oxygen permeability of biodegradable Pectin/Starch-montmorillonite nanocomposite, prepared with Na-MMT, have been studied X-ray diffraction and TEM experiments on polymer/silicate composite samples demonstrated that the intercalation of polymer chains leads to increase in the spacing between silicate layers. In addition, it were found that the intercalated Starch/Pectin/monotmorillonite nanocomposite were prepared. It was found that the addition of only a small amount of clay was enough to improve the thermal stability- and mechanical property of Starch/Pectin/montmorillonite nanocomposite. Oxygen permeability of Starch/Pectin/montmorillonite composite was generally lower than that of pectin/starch.