크라온에테르를 이용한 탈륨(I) 이온 선택성 전극

김성민,정성욱,김진은,김재상,Sung Min Kim,Sung Uk Jung,Jineun Kim,Jae Sang Kim 대한화학회 1993 대한화학회지 Vol.37 No.8

Tl$^+$이온 센서로서 크라운 에테르 B15C5와 DB18C6를 중성운반체로 한 PVC 액체막 이온 선택성 전극을 제작하였다. 막용매로는 DOA, NPPE 및 NPOE를 사용하였으며 친유성 염, KTClPB의 농도를 변화시킨 여러가지 조성의 막을 시험하였다. B15C5와 DB18C6 막 전극의 감응전위는 농도범위, 10$^{-1}$∼10$^{-5}$M에서 직선으로 나타났으며 최대 기울기는 전극에 따라서 40∼55 mV/decade였다. 선택계수는 분리용액법으로 결정하였으며 알카리금속 이온, 알칼리토금속 이온 및 일부 전이금속 이온에 대하여 좋은 선택성을 나타냈다. 제작된 액체막 전극은 Ph > 3 에서 안정한 감응전위를 보였다. Poly(vinyl chloride)(PVC) membrane electrodes based on the lipophilic neutral carrier, dibenzo-18-crown-6(DB18C6) and benzo-15-crown-5 (B15C5) as the active sensors for Tl$^+$ ion have been prepared and tested in different content of the potassium tetrakis(4-chlorophenyl)borate (KTClPB) as lipophilic salt. Dioctyl adipate (DOA), 2-nitrophenyl phenyl ether (NPPE) and o-nitrophenyl actyl ether (NPOE) were used as plasticizing solvent mediators. Electrodes exhibited good linear responses of 40∼55 mV decade$^{-1}$ for Tl$^+$ ion within the concentration ranges 10$^{-1}$∼10$^{-5}$M TlNO$_3$. Selectivity coefficients of interfering ions (alkali metal, alkaline earth metal and some transition metal ions) for Tl$^+$-ISE were determined by separate solution method and were sufficiently small for most of them. These crown ether type ion-selective electrodes are suitable for use with aqueous solution at pH > 3.

모래분사법과 불투명 도재의 도포방법이 도재용착주조관의 전단결합강도에 미치는 영향

김성민,최성민,정인성,Kim, Sung-Min,Choi, Sung-Min,Chung, In-Sung 대한치과기공학회 2011 대한치과기공학회지 Vol.33 No.4

Purpose: This study was investigated the bonding strength of two kinds of Ni-Cr alloy with respect to the condition of surface treatment. Methods: The surface treatment was performed on the two kinds of Ni-Cr alloy (B alloy and R alloy) specimens, which were sandblasted with $50{\mu}m$, $110{\mu}m$, and $250{\mu}m$ aluminium oxide and were treated with opaque application (paste and wash opaque). The roughness on the surfaces of the specimens was observed. The metal-ceramic interfaces were analyzed with EPMA in order to ionic diffusion, and the shear test was performed. Results: The BA250 specimen, which has higher surface roughness, showed the highest bonding strength in B specimens. In R specimens, the bonding strength of RA110 specimen was the highest. Conclusion: B specimen formed a mechanical bond between metal-ceramic interfaces; however, in the case of R specimen, a chemical bond was formed between that interfaces. There was no significant statistical difference between the bonding strengths of two types of specimens (p>0.05).

상장간막동맥 증후군의 복강경 수술 및 3차원재건 복부 전산화단층촬영 영상을 이용한 추적관찰 -1예보고-

김성민,김성훈,권인규,김명준,형우진,최승훈,Kim, Seong-Min,Kim, Sung-Hoon,Kwon, In-Kyou,Kim, Myoung-Joon,Hyoung, Woo-Jin,Choi, Seung-Hoon 대한소아외과학회 2005 소아외과 Vol.11 No.2

Superior mesenteric artery (SMA) syndrome is a rare disorder caused by extrinsic compression of the third portion of the duodenum by the SMA. The operative treatment of choice is bypassing the obstructed duodenal segment by duodenojejunostomy. We report one case of SMA syndrome treated by laparoscopic duodenojejunostomy and followed up by 3D-reconstructive CT scan. A fifteen-year-old boy with intermittent vomiting and weight loss was admitted. Ultrasonography showed narrowing of the distance between the SMA and aorta. Hypotonic duodenography showed dilatation of duodenal third portion and barium stasis. On 3Dreconstructive CT scan, the angle between SMA and aorta was $37^{\circ}$. The postoperative course was uneventful. Three months later, he had gained 3 kg of weight and the angle between SMA and aorta increased to $38-39^{\circ}$ on 3D reconstructive CT scan. Laparoscopic duodenojejunostomy for bypassing the obstructive duodenum in SMA syndrome is a feasible and safe method.

매개변수 보정 전문가시스템을 이용한 HSPF 모형의 수문 매개변수 보정 및 적용성 평가

김성민,김상민,Kim, Sung Min,Kim, Sang Min 한국농공학회 2013 한국농공학회논문집 Vol.55 No.4

The purpose of this study was to evaluate the applicability of the HSPEXP expert system for the calibration of the Hydrological Simulation Program - Fortran (HSPF) for the study watershed. HSPEXP offers advice to the modeler, suggesting parameter changes that might result in better representation of a river basin and provides explanations supporting the recommended parameter changes. The study watershed, Sancheong, is located within the Nakdong River Basin and having the size of $1,072.4km^2$. Input data for the HSPF model were obtained from the landuse map, digital elevation map, meteorological data and others. Water flow data from 2006 to 2008 were used for calibration and from 2009 to 2010 were for validation. Using the HSPEXP expert system, hydrological parameters were adjusted based on total volume, then low flows, storm flows, and finally seasonal flows. For the calibration and validation period, all the HSPEXP model performance criteria were satisfied.

남강댐유역 내 주요 하천관측지점의 홍수유출량 추정을 위한 단위도 모형 비교연구

김성민,김성재,김상민,Kim, Sung-Min,Kim, Sung-Jae,Kim, Sang-Min 한국농공학회 2012 한국농공학회논문집 Vol.54 No.3

In this study, three different unit hydrograph methods (NRCS, Snyder and Clark) in the HEC-HMS were compared to find better fit with the observed data in the Namgang-Dam watershed. The Sancheong, Shinan, and Changchon in Namgang-Dam watershed were selected as the study watersheds. The input data for HEC-HMS were calculated land use, digital elevation map, stream, and watershed map provided by WAter Management Information System (WAMIS). Sixty six storms from 2004 to 2011 were selected for model calibration and validation. Three unit hydrograph methods were compared with the observed data in terms of simulated runoff volume, and peak runoff for the selected storms. The results showed that the coefficient of determination ($R^2$) for the peak runoff was 0.8295~0.9999 and root mean square error (RMSE) was 0.029~0.086 mm/day for calibration stages. In the model validation, $R^2$ for the peak runoff was 0.9061~0.9916 and RMSE was 0.030~0.088 mm/day which were more accurate than calibrated data. Analysis of variance showed that there was no significant difference among the three unit hydrograph methods.

2005년도 소아 서혜부 탈장치료 경향

김성민,김대연,김상윤,김성철,김우기,김재억,김재천,박귀원,서정민,송영택,오정탁,이남혁,이두선,전용순,정상영,정을삼,최금자,최순옥,한석주,허영수,홍정,최승훈,Kim, Seong-Min,Kim, Dae-Yeon,Kim, Sang-Yoon,Kim, Seong-Chul,Kim, Woo-Ki,Kim, Jae-Eok,Kim, Jae-Chun,Park, Kwi-Won 대한소아외과학회 2006 소아외과 Vol.12 No.2

Inguinal hernia is the most common disease treated by the pediatric surgeon. There are several controversial aspects of management 1)the optimal timing of surgical repair, especially for preterm babies, 2)contralateral groin exploration during repair of a clinically unilateral hernia, 3)use of laparoscope in contralateral groin exploration, 4)timing of surgical repair of cord hydrocele, 5)perioperative pain control, 6)perioperative management of anemia. In this survey, we attempted to determine the approach of members of KAPS to these aspects of hernia treatment. A questionnaire by e-mail or FAX was sent to all members. The content of the questionnaire were adapted from the "American Academy of Pediatrics (AAP) Section on Surgery hernia survey revisited (J Pediatr Surg 40, 1009-1014, 2005)". For full-term male baby, most surgeons (85.7 %) perform an elective operation as soon as diagnosis was made. For reducible hernia found in ex-preterm infants already discharged from the neonatal intensive care unit (NICU), 76.2 % of surgeons performed an elective repair under general anesthesia (85.8 %). 42.9 % of the surgeons performed the repair just before discharge. For same-day surgery for the ex-premature baby, the opinion was evenly divided. For an inguinal hernia with a contralateral undescended testis in a preterm baby, 61.9 % of surgeons choose to 'wait and see' until 12 month of age. The most important consideration in deciding the timing of surgery of inguinal hernia in preterm baby was the existence of bronchopulmonary dysplasia (82.4 %), episode of apnea/bradycardia on home monitoring (70.6 %). Most surgeons do not explore the contralateral groin during unilateral hernia repair. Laparoscope has not been tried. Most surgeons do not give perioperative analgesics or blood transfusion.

평판 가까이에 놓인 타원형 실린더 주위 유동에 관한 연구

김성민,이상준,Kim, Seong-Min,Lee, Sang-Jun 대한기계학회 1996 大韓機械學會論文集B Vol.20 No.8

Flow characteristics and aerodynamic forces acting on an elliptic cylinder placed in a plane boundary layer were investigated experimentally. Four cylinder models with axis ratio(major axis to minor axis, AR=A/B) of 1, 2, 3, and 4 having the same equivalent diameter were used in this experiment. The Reynolds number based on the equivalent diameter $D_e$(=20mm) was 13,000. In the case of circular cylinder, regular vortex shedding occurs for the cylinder gaps larger than G/B=0.3 and is not almost related to the boundary layer thickness. But, for the elliptic cylinders, the vortex shedding frequency is increased with increasing the gap ratio (G/B) and the axis ratio (AR) of elliptic cylinders. The maximum drag coefficient acting on a circular cylinder is mainly affected by the boundary layer thickness. But, the elliptic cylinders(AR$\geq$2), except for the smaller gap G/B<0.2, show a nearly constant drag coefficient which is much smaller than that of a circular cylinder. The base pressure on the flat plate decreases with increasing the axis ratio(AR) of the elliptic cylinder. In the case of a circular cylinder, the base pressure has the minimum value at the gap ratio G/B=0.4, but it occurs at G/D=2 for elliptic cylinders. The mean velocity of the cylinder wake is quickly recovered at a small cylinder height ratio(H/$\delta$), but the turbulent intensity is rapidly recovered at a large cylinder height ratio(H/$\delta$). The effective wake region in the plane boundary layer is shrinkaged with increasing the axis ratio(AR) of elliptic cylinder. And the drag coefficient and streamwise turbulent intensity of the elliptic cylinder with AR=4 are less than half of those for the circular cylinder(AR=1).

S-DMB와 2.4/5 GHz WLAN 신호 수신을 위한 이중 광대역 다이폴형 안테나의 설계 및 구현

김성민,양운근,Kim, Sung-Min,Yang, Woon-Geun 한국전자파학회 2006 한국전자파학회논문지 Vol.17 No.11

본 논문에서는 S-DMB(Satellite Digital Multimedia Broadcasting)와 2.4/5 GHz WLAN(Wireless Local Area Network) 신호 수신을 위한 이중 광대역 다이폴형 안테나를 설계 및 구현하였다. 제안된 안테나는 기존 모노폴형 이중 대역 안테나를 기본으로 하여 평면형 광대역 다이폴 형태로서 $8{\times}33.8{\times}1.68mm^3$ 크기로 구현되었다. 안테나는 1.6 mm 두께의 FR4 기판위에 인쇄되어 있는 형태로 중심부에 낮은 주파수 대역에서 동작하는 다이폴 형태의 안테나와 높은 주파수에서 공진 특성을 가지는 두 개의 대칭 구조로 구성된 공진 소자로 되어 있다. 또한 전산 모의 실험으로 각 주파수 대역에서 안테나의 표면에 전류가 밀집되는 곳을 확인하였다. 전류가 밀집된 부분의 길이를 조정함으로서 각 주파수 대역에서 독립적으로 공진 주파수를 변화시킬 수 있었다. 그리고 입력 임피 던스 대역폭$(VSWR\leq2)$이 2 GHz 대역에서 362 MHz(14.23 %), 5 GHz 대 역 에서 1188 MHz(22.13 %)로 광대역 특성을 나타내었다. 측정된 안테나의 최대 이득은 2 GHz 대역에서 4.33 dBi이고 5 GHz 대역에서 5.48 dBi로서 이득 면에서 개선되었다. 제작된 안테나는 전 방향성의 양호한 방사 패턴 특성을 갖는다. In this paper, we designed and implemented a dual wideband dipole type antenna for the reception of S-DMB (Satellite Digital Multimedia Broadcasting) and 2.4/5 GHz WLAN(Wireless Local Area Network) signals. The proposed antenna based on conventional monopole type dual band antenna was implemented as planar wideband dipole type antenna with the volume of $8{\times}33.8{\times}1.68mm^3$. The proposed antenna is printed type on FR4 substrate of 1.6 mm thick and composed of a dipole type antenna for low frequency band and two symmetric structured resonance elements for high frequency band. We confirmed antenna area with dense surface current for each frequency band with simulation. By varying the length of the antenna area with dense surface current, we could vary resonance frequency of each frequency band separately. Impedance bandwidths$(VSWR{\leq}2)$ are 362 MHz(14.23 %) for 2 GHz band and 1188 MHz(22.13, %) for 5 GHz band which show wideband characteristic. Measured maximum gains were 4.33 dBi for 2 GHz band and 5.48 dBi for 5 GHz band which showed improved performance. And the implemented antenna has a good omni-directional radiation pattern characteristic.

라플라스 신호원에 대한 최소평균제곱오차 홑 양자기의 지지역에 관하여

김성민,나상신,Kim, Seong-Min,Na, Sang-Sin 한국통신학회 2006 韓國通信學會論文誌 Vol.31 No.10C

이 논문은 라플라스 밀도 함수에 대한 최적 흩 양자기의 지지역의 증가는 양자점의 개수와 대수적인 관계가 있음을 보여준다. 구체적으로, 분산이 1인 라플라스 밀도함수에 대해서 양자정의 개수 N이 증가할 때 최적 양자기의 경계값에 의해 결정되는 지지역과 $\frac 3{\sqrt{2}}1n\frac N 2$의 비율이 1로 수렴함을 보여준다. 또한 극한 상한값을 유도하여 최적 지지역의 로그적 증가가 그 값을 초과하지 않음을 보였다. 이 결과들로부터 이전부터 경험적으로 연구되어 온 최적 지지역의 로그 증가를 확인 할 수 있다. This paper shows that the support growth of an optimum (minimum mean square-error) scalar quantizer for a Laplacian density is logarithmic with the number of quantization points. Specifically, it is shown that, for a unit-variance Laplacian density, the ratio of the support-determining threshold of an optimum quantizer to $\frac 3{\sqrt{2}}1n\frac N 2$ converges to 1, as the number of quantization points grows. Also derived is a limiting upper bound that says that the optimum support cannot exceed the logarithmic growth by more than a constant. These results confirm the logarithmic growth of the optimum support that has previously been derived heuristically.

신설 프리캐스트 콘크리트 포장 시공방법 및 설계지침 개발

김성민,박희범,양성철,한승환,Kim, Seong-Min,Park, Hee-Beom,Yang, Sung-Chul,Han, Seung-Hwan 한국도로학회 2008 한국도로학회논문집 Vol.10 No.2

This study was conducted to investigate the feasibility of the expedite construction of new pavement systems using precast concrete slabs and to develop the design and construction guide based on the results of the experimental construction. Half scale concrete slabs were designed and fabricated and the optimal reinforcement design, linkages between the slabs in the longitudinal and transverse directions, and the grouting methods were investigated. The experimental construction was performed fast and easily by assembling two slabs in the longitudinal direction and the other two in the transverse direction. The slabs were leveled and the pockets and the space between the slab bottom and the underlying layer were grouted. From the experimental construction, details about the design and construction of the precast pavements were acquired. Finally, the design and construction guide for the newly constructed precast concrete pavement systems was developed. 본 연구는 프리캐스트 콘크리트 슬래브를 이용한 급속 신설 도로 포장 공법의 국내 적용성을 분석하기 위한 기초 연구를 수행하고 시험시공을 통해 선설 프리캐스트 포장의 설계 및 시공 지침을 개발하기 위하여 수행되었다. 시험시공을 위해 가로, 세로, 깊이가 각각 실제 포장 슬래브의 1/2 크기인 슬래브를 설계하여 제작하였으며 이에 적합한 철근배근, 종방향과 횡방향의 연결부, 그라우팅 방법 등에 대하여 분석을 수행하였다. 이러한 슬래브를 이용하여 종방향과 횡방향으로 두 개씩 총 4 개의 슬래브를 연결하여 평탄성을 조절한 후 포켓 부분과 슬래브 하부의 공간을 그라우팅 함으로써 시공을 신속 용이하게 수행하였다. 시험 시공을 수행하며 프리캐스트 포장의 설계 및 시공과 관련된 세부 사항을 면밀히 분석하였으며 이에 바탕을 두어 프리캐스트 슬래브를 이용하여 급속하게 신설 도로를 건설할 때의 설계 및 시공 지침을 개발하였다.