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Microwave Absorption Enhancement of Fe/C Core–Shell Hybrid Derived from a Metal-Organic Framework
Liuyang Heng,Zilong Zhang,Shuai Wang,Xiqiao Chen,Xiubo Jia,Zhixiang Tang,Yanhong Zou 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2019 NANO Vol.14 No.1
Core–shell structured Fe/C have been successfully derived from a metal-organic framework for microwave absorbing. Based on the measured electromagnetic parameters, it is found that the maximum reflection loss (RL) of Fe/C reaches 40 dB at 5.8 GHz with a thickness of 3.0 mm and the broadest absorption bandwidth (RL < -10 dB) is up to 6.0 GHz (from 11.2 to 17.2 GHz) with a thickness of 1.5 mm. The excellent microwave absorption is mainly ascribed to the multiple reflections, good impedance matching, dielectric loss and interface polarization originating from the core–shell structure. It is believed that Fe/C can be a promising microwave absorbing material.
Influence of oil pipe corrosion defects on the sealing performance of annular BOP
Liangliang Dong,Yuan Tang,Liuyang Wang 국제구조공학회 2022 Structural Engineering and Mechanics, An Int'l Jou Vol.84 No.3
Due to corrosion defects on the surface of the oil pipe, the sealing performance of the annular blowout preventer (BOP) decreases, and the leakage of toxic and harmful gases such as H2S and SO2 will threaten the safety of operators on the well. Therefore, this paper establishes the FE model for evaluating the sealing performance of BOP-oil pipe corrosion defects, which is based on the rubber large deformation theory and rubber core sealing mechanism, and designs the experiment of BOP sealing performance to verify the accuracy of the FE model. The sealing performance of BOP sealing oil pipe with corrosion defects is studied. The research results show that the sealing performance of BOP is more sensitive to the axial size of corrosion defects. With the increase of oil pipe outer diameter, the critical size of defects increases continuously. The sensitivity of radial and depth dimensions is low, When for 88.9 mm outer diameter oil pipe, the axial critical size of corrosion defect is 20 mm, the radial critical size is 16 mm and the critical depth is 2 mm. Fit the formula between the outer diameter of oil pipe and the piston increment. According to the formula, the operator can calculate the piston stroke increment required by the BOP to complete the sealing when the oil pipe is corroded.
Core@shell MOFs derived Co2P/CoP@NPGC as a highly-active bifunctional electrocatalyst for ORR/OER
Weijia Gong,Hongyu Zhang,Liuyang Zhou,Ya Yang,Jiashuo Wang,Heng Liang 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.106 No.-
In this study, Co2P/CoP hybrid nanoparticles (NPs) imbedded on the surface of core–shell metal–organicframeworks (MOFs) derived three-dimensional N, P co-doped graphitized carbon (Co2P/CoP@NPGC) areprepared via direct pyrolysis of P-containing MOF precursors. P dopant dosage is tailored to adjust activesites and crystalline phases of Co2P/CoP@NPGC. The active Co2P and CoP NPs and the synergistic effectfrom the Co-Nx/C and Co-P/C active sites and porous NPGC make the dominant contributions to theORR/OER. For ORR, the half-wave potential of Co2P/CoP@NPGC-1 is 0.93 V, which is superior to that ofPt/C (E1/2 = 0.875 V). As for OER, Co2P/CoP@NPGC-1 displays a lower overpotential (ƞ = 340 mV) comparedto RuO2 (ƞ = 380 mV, at 10 mA cm2). The Co2P@CoOOH heterojunction guarantees intrinsic conductivity. Furthermore, doping with N and P can modify the surface electronic structure of catalyst to lower theenergy of oxygen adsorption and dissociation, which are beneficial to enhance the ORR and OER activity. Additionally, its bifunctional activity parameter (DE) for ORR and OER is only 0.64 V, which is lower thanthat of Pt/C and RuO2 (0.76 V). Therefore, this work proposes a new sight into constructing a competitivecore–shell MOFs derived electrocatalyst for ORR/OER.
Xiong Song,Liangui Nie,Junrong Long,Junxiong Zhao,Xing Liu,Liuyang Wang,Da Liu,Sen Wang,Shengquan Liu,Jun Yang 대한약리학회 2023 The Korean Journal of Physiology & Pharmacology Vol.27 No.1
Hypothyroidism alone can lead to myocardial fibrosis and result in heart failure, but traditional hormone replacement therapy does not improve the fibrotic situation. Hydrogen sulfide (H2S), a new gas signaling molecule, possesses antiinflammatory, antioxidant, and anti-fibrotic capabilities. Whether H2S could improve hypothyroidism-induced myocardial fibrosis are not yet studied. In our study, H2S could decrease collagen deposition in the myocardial tissue of rats caused by hypothyroidism. Furthermore, in hypothyroidism-induced rats, we found that H2S could enhance cystathionine-gamma-lyase (CSE), not cystathionine β-synthase (CBS), protein expressions. Finally, we noticed that H2S could elevate autophagy levels and inhibit the transforming growth factor-β1 (TGF-β1) signal transduction pathway. In conclusion, our experiments not only suggest that H2S could alleviate hypothyroidism- induced myocardial fibrosis by activating autophagy and suppressing TGF-β1/ SMAD family member 2 (Smad 2) signal transduction pathway, but also show that it can be used as a complementary treatment to conventional hormone therapy.
Liu, Yang,Wang, Xiaofeng,Liu Li,Wu, Bin,Yang, Qin Techno-Press 2022 Advances in nano research Vol.13 No.1
The present research investigates the dynamic behavior of a rotating functionally graded (FG) nonlocal cylindrical beam. The cylindrical beam is mathematically modeled via third-order beam theory linked with nonlocal strain gradient theory. The tube structure is made of functionally graded materials composed of Aluminum oxide coated on the Nickel, which the mechanical properties vary in the tube radius direction according to the power law. The bending harmonic force is applied in the tube length middle. The nonlocal spinning equations of the tube are derived via the energy method of the Hamilton principle, and they are solved via a robust numerical procedure for different boundary conditions. The main application of the rotating nanostructures is for the production of small-scale motors and devices and the drug-delivery application, the presented results can help the researcher have a better view regarding the different conditions.
Liu, Yang,Wang, Chonglong,Liu, Zhengzhu,Xu, Jingen,Fu, Weixuan,Wang, Wenwen,Ding, Xiangdong,Liu, Jianfeng,Zhang, Qin Asian Australasian Association of Animal Productio 2012 Animal Bioscience Vol.25 No.8
Neonatal Fc receptor (FcRn) gene encodes a receptor that binds the Fc region of monomeric immunoglobulin G (IgG) and is responsible for IgG transport and stabilization. In this report, the 8,900 bp porcine FcRn genomic DNA structure was identified and putative FcRn protein included 356 amino acids. Alignment and phylogenetic analysis of the porcine FcRn amino acid sequences with their homologies of other species showed high identity. Tissues expression of FcRn mRNA was detected by real time quantitative polymerase chain reaction (Q-PCR), the results revealed FcRn expressed widely in ten analyzed tissues. One single nucleotide polymorphism (SNP) (HQ026019:g.8526 C>T) in exon6 region of porcine FcRn gene was demonstrated by DNA sequencing analysis. A further analysis of SNP genotypes associated with serum Classical Swine Fever Virus antibody (anti-CSFV) concentration was performed in three pig populations including Large White, Landrace and Songliao Black pig (a Chinese indigenous breed). Our results of statistical analysis showed that the SNP had a highly significant association with the level of anti-CSFV antibody (At d 20; At d 35) in serum (p = 0.008; p = 0.0001). Investigation of expression and polymorphisms of the porcine FcRn gene will help us in further understanding the molecular basis of the antibody regulation pathway in the porcine immune response. All these results indicate that FcRn gene might be regarded as a molecular marker for genetic selection of anti-CSFV antibody level in pig disease resistance breeding programmes.
Ultrathin MEMS thermoelectric generator with Bi2Te3/(Pt, Au) multilayers and Sb2Te3 legs
Liu Yang,Mu Erzhen,Wu Zhenhua,Che Zhanxun,Sun Fangyuan,Fu Xuecheng,Wang Fengdan,Wang Xinwei,Hu Zhiyu 나노기술연구협의회 2020 Nano Convergence Vol.7 No.8
Multilayer structure is one of the research focuses of thermoelectric (TE) material in recent years. In this work, n-type 800 nm Bi 2 Te 3 /(Pt, Au) multilayers are designed with p-type Sb 2 Te 3 legs to fabricate ultrathin microelectromechanical systems (MEMS) TE devices. The power factor of the annealed Bi 2 Te 3 /Pt multilayer reaches 46.5 μW cm −1 K −2 at 303 K, which corresponds to more than a 350% enhancement when compared to pristine Bi 2 Te 3 . The annealed Bi 2 Te 3 /Au multilayers have a lower power factor than pristine Bi 2 Te 3 . The power of the device with Sb 2 Te 3 and Bi 2 Te 3 /Pt multilayers measures 20.9 nW at 463 K and the calculated maximum output power reaches 10.5 nW, which is 39.5% higher than the device based on Sb 2 Te 3 and Bi 2 Te 3 , and 96.7% higher than the Sb 2 Te 3 and Bi 2 Te 3 /Au multilayers one. This work can provide an opportunity to improve TE properties by using multilayer structures and novel ultrathin MEMS TE devices in a wide variety of applications.