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黃正儀,朴斗元,吳相午,鄭倧在,朴裕哲,郭永佑 慶北大學校 1977 論文集 Vol.23 No.-
金屬실리콘과 鹽化메틸을 鹽化第一구리를 觸媒로 하여 메틸실란을 合成하고 메틸실란을 加水分解하여 실록산의 被膜을 만드는 方法을 調査하였다. 이들 被膜이 文化財 保護被膜이 될 수 있는가를 檢討하기 爲해서 材料를 文化財의 材質인 몇 가지 物質에 適用하여 膜의 性能을 調査하였다. 特히 撥水效果, 汲水量 耐久性等을 調査하였으며 外觀上 아무런 變化가 없는 좋은 被膜이 될수 있다는 結果를 얻었다. The organohalogensilicone was synthesized metal silicone and methylchloride applying the direct synthetic method using copperous chloride as catalyzer. The synthesized organosilane was hydrolyzed to siloxane by various method and coated on various materials which are composed of the cultural assets. The coating film was examined to decide whether it is profitable one to protect the assets from efflorescence or air pollution. Referring to the water repellency, permiability of water and the weather test of the film it was qualified that this film was good enough to apply to the cultural assets as protecting film.
수용액중에서 아세틸피리딘류의 해리에 미치는 온도와 압력의 영향
黃正儀,鄭在元,鄭載植 慶北大學校 1990 論文集 Vol.49 No.-
The dissociation constants of 2-, 3- and 4-acetylpyridine were measured by conductometric method in the temperature range from 15 to 40℃ and pressure up to 2,500bar. The dissociation constants of these substituted pyridines were increased as the temperature increase but decrease as the pressure. From the data thermodynamic properties were calculated and the Hammett plat were obtained. From these properties the characteristic properties of the dissociation reaction were discussed.
황정의,정재원,장경희 慶北大學校 自然科學大學 1987 自然科學論文集 Vol.5 No.-
The dissociation constants of 2, 3-, 2, 4-, 2, 5-and 3, 5-dimethylpyridine were measured by conductometric method at various temperatures (15∼40℃) and pressures (1∼2500 bar) in aqueous solution. The shift of dissociation constants of methylptridines from pyridine were explained by the I-effect and cooperative effect of the methyl groups. From the dissociation constants various thermodynamic properties were calculated and discussed the characteristics of the dissociation reactions.
黃正儀,裵俊雄,鄭倧在,鄭在元,張景喜 慶北大學校 物理化學硏究所 1986 硏究論文集 Vol.7 No.-
치환나프톨류(4-Cl-1-Naphthol, 6-Br-2-Naphthol, 8-NH_2-2-Naphthol)의 해리상수를 온도(25∼40℃)와 압력(1∼2000 bar)을 변화시키면서 분광학적 방법으로 측정했다. 이들의 해리상수는 치환기가 들어가므로서 모두 감소했다. 이것은 치환기의 I-효과로서 설명이 가능했으며 또 온도와 압력이 증가하면 해리상수도 증가하였다. 이들 해리상수로부터 반응의 열역학적 성질을 계산하여 반응의 성질을 알아보았다. The dissociation constants of 4-Cl-1-naphthol, 6-Br-2-naphthol, 8-NH_2-2-naphthol in aqueous solution were measured by spectroscopic method in the temperature range from 25 to 40℃ and pressure up to 2000bar. The dissociation constants were decreased as the substituents were inserted in naphthol from 4.4×10 exp(-10) to 5.82×10 exp(-11) as chloride compound and 2.5×10 exp(-10) to 3.44×10 exp(-11) or 4.21×10 exp(-11) as bromine or amino compounds, respectively. This decrease can be explained with the I- or R-effects of substituents. From the dissociation constants various thermodynamic properties were claculated and discussed the characteristics of the dissociation reaction.
Jung, Ui-Won,Choi, Jung-Yoo,Kim, Chang-Sung,Cho, Kyoo-Sung,Chai, Jung-Kiu,Kim, Chong-Kwan,Choi, Seong-Ho Wiley (John WileySons) 2008 Journal of periodontology Vol.79 No.10
<P>BACKGROUND: Anatomic and biomechanical limitations can jeopardize successful single implantation in the mandibular posterior area. To overcome the limitations, the design and the surface of the fixtures were modified. This study evaluated the cumulative survival rate (CSR) of mandibular molars replaced with a sand-blasted, large-grit, acid-etched (SLA) single implant or an anodized (ANO) single implant and examined associated factors, such as the surface treatment, position, and length and diameter of the implants. METHODS: One hundred ninety-three single implants restored with an SLA implant and 112 single implants restored with an ANO implant in the mandibular molar area were selected from subjects who had visited the Department of Periodontology, Dental Hospital of Yonsei University, from March 2001 through June 2006. In the SLA group, 123 and 70 implants were placed in the first and second molar area, respectively. In the ANO group, 55 and 57 implants were placed in the first and second molar area, respectively. The 1- to 6-year CSR of the SLA and ANO groups was calculated using the life-table analysis. In addition, associated factors, such as the surface treatment, position, and length and diameter of the implants, were compared and analyzed using the chi(2) test (P <0.05). RESULTS: Two of 193 implants in the SLA group failed, giving a CSR of 98.96%; four of 112 ANO implants failed, giving a CSR of 96.43%. There were no significant differences with regard to the surface treatment, position, and length and diameter of the implants. CONCLUSIONS: Despite the anatomic and biomechanical limitation in the mandibular posterior area, mandibular posterior single implants showed a high CSR during the observation period. Mandibular posterior single implants can be an effective and reliable treatment modality that is not affected by the surface treatment, position, or length and diameter of the implant.</P>
A hybrid technique for sinus floor elevation in the severely resorbed posterior maxilla
Ui-Won Jung,Ji-Youn Hong,이중석,김창성,조규성,최성호 대한치주과학회 2010 Journal of Periodontal & Implant Science Vol.40 No.2
Purpose: This study aimed to evaluate the effectiveness of the modified sinus floor elevation technique described hereafter as a “hybrid technique,” in 11 patients with severely resorbed posterior maxillae. Methods: Eleven patients who received 22 implants in the maxillary premolar and molar areas by the hybrid technique were enrolled in this study. A slot-shaped osteotomy for access was prepared on the lateral wall along the lower border of the sinus floor. The Schneiderian membrane was fully reflected through the lateral slot. Following drilling with the membrane protected by a periosteal elevator, the bone was grafted. All implants were placed simultaneously with sinus augmentation. The cumulative success rate was calculated and clinical parameters were recorded. Radiographic measurements were performed. Results: All implants were well maintained at last follow up (cumulative success rate=100%). The mean residual bone height, augmented bone height, crown-to-implant ratio, and marginal bone loss were 4.1±1.64 mm, 8.76±1.77 mm, 1.21±0.33 mm, and 0.34±0.72 mm, respectively. Conclusions: Simultaneous implant placement with sinus augmentation by hybrid technique showed successful clinical results over a 2-year observation period and may be a reliable modality for reconstruction of a severely resorbed posterior maxilla. Purpose: This study aimed to evaluate the effectiveness of the modified sinus floor elevation technique described hereafter as a “hybrid technique,” in 11 patients with severely resorbed posterior maxillae. Methods: Eleven patients who received 22 implants in the maxillary premolar and molar areas by the hybrid technique were enrolled in this study. A slot-shaped osteotomy for access was prepared on the lateral wall along the lower border of the sinus floor. The Schneiderian membrane was fully reflected through the lateral slot. Following drilling with the membrane protected by a periosteal elevator, the bone was grafted. All implants were placed simultaneously with sinus augmentation. The cumulative success rate was calculated and clinical parameters were recorded. Radiographic measurements were performed. Results: All implants were well maintained at last follow up (cumulative success rate=100%). The mean residual bone height, augmented bone height, crown-to-implant ratio, and marginal bone loss were 4.1±1.64 mm, 8.76±1.77 mm, 1.21±0.33 mm, and 0.34±0.72 mm, respectively. Conclusions: Simultaneous implant placement with sinus augmentation by hybrid technique showed successful clinical results over a 2-year observation period and may be a reliable modality for reconstruction of a severely resorbed posterior maxilla.
Ui-Won Jung,Soo-Kyoung Kim,Chang-Sung Kim,Kyoo-Sung Cho,Chong-Kwan Kim,Seong-Ho Choi 한국물리학회 2007 Current Applied Physics Vol.7 No.s1
The purpose of this study is to evaluate the eect of chitosan with absorbable collagen sponge (ACS) carrier on bone formation in therat calvarial defect model. New bone area and defect closure of the chitosan/ACS group were signicantly greater than those of the oth-ers at 8 weeks postsurgery (p < 0.01). Chitosan reconstituted with ACS has signicant potential to induce the regeneration of bone in ratcalvarial critical size defects.