조기강도 발현형 AE감수제를 사용한 콘크리트의 특성에 관한 연구

황인성,김규동,이승훈,한천구 대한건축학회 2003 대한건축학회 학술발표대회 논문집 - 계획계/구조계 Vol.23 No.2

This study discusses the fundamental properties and early strength development of concrete using AE water reducing agent of early-strength type. According to the result, when AE water reducing agent of early-strength type is used, slump and air content loss is smaller than normal AE water reducing agent. While setting time is retarded with an increase of the adding amount of normal AE water reducing agent, it is maintained constantly regardless of the adding amount and faster than normal AE water reducing agent in the case of AE water reducing agent of early-strength type, and bleeding amount is larger than normal AE water reducing agent especially at early age. At curing temperature of 20℃, early compressive strength gains 5MPa, which side form can be removed, before 16 hours in the case of AE water reducing agent of early-strength type, but early compressive strength development is delayed in the case of normal AE water reducing agent. At curing temperature of 10℃, AE water reducing agent of early-strength type is also better than normal AE water reducing agent especially for early compressive strength development.

콘크리트 배합조건에 따른 수축저감제의 건조수축 특성

김영선 ( Kim Young-sun ),김광기 ( Kim Kwang-ki ),박순전 ( Park Soon-jeon ),김정선 ( Kim Jung-sun ) 한국건축시공학회 2017 한국건축시공학회지 Vol.17 No.3

최근 소비패턴의 변화에 따라 대형마트, 아울렛 및 물류창고 등과 같은 구조물들이 증가하고 있다. 이와 같은 구조물들은 초평탄 바닥부재를 포함하고 있기 때문에 소성 및 건조수축에 의한 슬래브 부재의 균열 억제 관리를 철저하게 실시한다. 슬래브 부재의 균열을 억제하기 위한 방안으로 화학적 균열저감 방법을 사용하고 있으며, 특히 수축저감제에 대한 사용검토가 증가하고 있다. 그러나 이에 대한 국내 연구결과는 부족한 상황이다. 본 연구에서는 수축저감제를 사용한 콘크리트의 수축특성과 배합요인 변동에 따른 건조수축 특성을 검토하였다. 국내 수축저감제는 해외 고급형 수축저감제와 성능이 유사한 것으로 나타났으며, 수축저감제 사용량이 증가할수록 건조수축 억제 효과는 높아지는 것으로 나타났다. 수축저감제 1.5%를 사용한 시험체는 재령 100일에서 수축저감제를 사용하지 않은 시험체에 비해 건조수축량이 약 절반으로 나타났다. 또한, 혼화재료 사용에 대해 특별한 성능변화는 없는 것으로 확인되었다. Recently, structures such as large retailers, outlets and warehouses have been increasing in accordance with changes in consumption patterns. Since these structures include ultra-flat slab members, they are thoroughly managed to control slab cracking by the plastic and drying shrinkage. In order to control the cracking of the slab member, a chemical crack reduction method is used. In particular, the use of the shrinkage reducing agent has been examined. However, domestic research results are limited. In this study, the shrinkage properties of concrete using shrinkage reducing agent and the drying shrinkage properties according to the mixing factors were investigated. The performance of domestic shrinkage reducing agent was appeared similar to that of overseas high-grade shrinkage reducing agent. As the shrinkage reducing agent usage increased, the drying shrinkage reduction effect increased. At the age of 100 days, the dry shrinkage rate of specimen with the shrinkage reducing agent of 1.5%was shown about half that of the specimen without the shrinkage reducing agent. The shrinkage reducing agent was gound to have no specific performance change for the use of the admixture.

AE 감수제 과다첨가가 콘크리트의 물리적 특성에 미치는 영향

한천구,한민철,이동규 한국건축시공학회 2008 한국건축시공학회지 Vol.8 No.1

This study is to investigate the influence of the over-added chemical agents, such as water reducing agent(WRA) and AE water reducing agent(AEWRA), on the physical properties of concrete to estimate the degree of damage due to over-added chemical agents. For the fresh concrete, slump and slump flow increased with the increase of WRA and AEWRA as expected. Material segregation phenomenon was observed with the over dosage of lignin based AEWRA about 4 times larger than recommended dosage. The over dosage of AE water reducing agent about 4 times larger than recommended dosage resulted in an increase of air contents remarkably. The set retardation occurred greatly with the increase of AEWRA and WRA, For the properties of the hardened concrete corresponding to the over dosage of AEWRA, it is found that compressive strength of over added AEWRA and WRA concrete are much smaller than those of base and recommended dosage concrete proportionally due to associated increasing air content.

Effect of reducing agents on the synthesis of anisotropic gold nanoparticles

Yoo Sunghoon,남동환,Singh Thangjam Ibomcha,Leem Gyu,이승현 나노기술연구협의회 2022 Nano Convergence Vol.9 No.5

The seed-mediated method is a general procedure for the synthesis of gold nanorods (Au NRs), and reducing agents such as ascorbic acid (AA) and hydroquinone (HQ) are widely used for the growth process. Further, they are mild reducing agents; however, when AA is used, controlling the size of Au NRs with a higher aspect ratio (localized surface plasmon resonance (LSPR) peak, λ Lmax > 900 nm) is challenging because it results in a faster growth rate of Au NRs. In contrast, when HQ is used, Au NRs with a higher aspect ratio can be synthesized as it slows down the growth rate of the Au NRs and greatly enhanced the λ Lmax . However, the increase in λ Lmax is still needs not satisfactory due to the limited enhancement in the aspect ratio of Au NRs due to utilization of single reducing agent. The growth kinetics of the Au NRs can be modulated by controlling the reducing power of the reducing agents. In such scenario, judicious use of two reducing agents such as AA and HQ simultaneously can help us to design Au NRs of higher aspect ratio in a controlled manner due to the optimum growth rate resulting from the combined effect of both the reducing agents. In this study, we investigated the effect of the two reducing agents by controlling the volume ratios. When the growth solution contains both the reducing agents, the growth of Au NRs is first initiated by the fast reduction of ­Au 3+ to ­Au + due to stronger reducing power of the AA and when the AA in the growth solution is completely utilized, further growth of the Au NRs continues as a result of the HQ thereby resulting to high aspect ratio Au NRs. Consequently, the LSPR peak (λ Lmax > 1275 nm) can be tuned by controlling the volume ratios of the reducing agents.

저점도형 감수제 및 고성능 감수제의 사용에 따른 시멘트 페이스트 성능 분석

손배근 ( Son Bae-geun ),한동엽 ( Han Dong-yeop ) 한국건축시공학회 2017 한국건축시공학회 학술발표대회 논문집 Vol.17 No.2

In order to improve the flow performance of high performance concrete, use of high performance water reducing agent and low viscosity type water reducing agent is a study of suitable range of use due to side effects. in this study, we aimed at reducing viscosity and yield value using high performance water reducing agent and low viscosity type water reducing agent, and this was evaluated using a rheometer. as a result of analysis of viscosity and yield value, it was found that the high performance water reducing agent has higher reduction effect than the low viscosity type water reducing agent. however, the larger the viscosity lowering effect is, the lower the usable range is, compared to general high performance water reducing agents, and it was found that sufficient consideration for this judgment of appropriate quantity is necessary.

라돈 저감제를 이용한 건축자재의 라돈 방출 저감 연구

박경북,이상혁,Park, Kyung-Buk,Lee, Sang-Houck 한국환경보건학회 2014 한국환경보건학회지 Vol.40 No.6

Objectives: A radon emission reducing agent was prepared using charcoal and zeolite, and the amount was measured after coating construction materials with the agent. The availability of the radon emission reducing agent was evaluated. Methods: Construction materials (red brick, cement brick, and gypsum board) coated with reducing agent were placed in a chamber to measure radon emissions. The construction materials were coated one through three times. The spread volume for brick and gypsum board was 50 mL and 75 mL per application, respectively. The amount of radon emitted was measured by RAD-7 after 48 hours. Results: The reduction ratio increased with the number of coatings, and the reduction ratios for red brick, cement brick, and gypsum board were 63.3, 73.6, and 58%, respectively, in the case of three coatings of RA-1. The reduction ratios for red brick, cement brick, and gypsum board were 42.8, 58.1, and 26.2%, respectively in the case of three coatings with RA-2. RA-1 was slightly better than RA-2 in radon emission reduction. Conclusions: Radon emissions from construction materials decreased according to the concentration of reducing agent coating, and it was more effective than existing methods.

3D 프린팅 콘크리트용 수축저감제 개발

이동규,유병현,손호정 한국산학기술학회 2019 한국산학기술학회논문지 Vol.20 No.12

3D 프린팅 콘크리트는 거푸집 없이 시공이 가능하기 때문에 비정형 구조물 건설이 용이하고, 연속시공에 따른 공사시간 단축 및 공사현장 인력 감소로 인한 인건비 절감이 가능하다는 장점이 있지만, 외부에 노출된 상태로 시공을 하기 때문에 콘크리트 내외부의 수분 손실에 의한 수축균열이 발생확률이 크다는 문제점이 있어 3D 프린팅 콘크리트의 내구성 향상을 위해서는 3D 프린팅 콘크리트의 수축저감 방안이 필수적으로 요구된다. 이에 본 연구에서는 글리콜계 및 알콜계 수축저감제 샘플 7종을 제조하여 그 성능을 평가하였고, 우수한 성능을 보인 수축저감제 샘플을 선별하여 이를 적용한 3D 프린팅 콘크리트의 기초적 특성을 확인하였다. 그 결과 수축저감제 사용 시 기존의 3D 프린팅 콘크리트 대비 압축강도가 10% 이상 증진되었고, 수축량은 36% 이상 감소되었다. 3D 프린팅 콘크리트용 수축저감제의 적용으로 압축강도 증진 및 건조수축량 저감이 가능하기 때문에 기존의 3D 프린팅 콘크리트 대비 내구성 향상이 가능하여 고품질의 3D 프린팅 콘크리트의 제조가 가능할 것으로 기대된다. Since 3D printed concrete can be constructed without formwork, it is easy to construct an atypical structure, and the construction time and labor cost can be reduced. However, since the construction is exposed to the outside, shrinkage cracking due to moisture loss inside and outside the concrete occurs. Therefore, in order to improve the durability of the 3D printed concrete, a shrinkage reduction plan of the 3D printed concrete is required. In this study, glycol-based and alcohol-based shrinkage reducing agents were fabricated and evaluated for their performance. The shrinkage reducing agent samples showing excellent performance were selected and applied to 3D printed concrete. As a result, the compressive strength was increased by more than 10% and the shrinkage was reduced by more than 36% when using a shrinkage reducing agent. It is expected that the production of high quality 3D printed concrete will be possible because it is possible to increase the compressive strength and reduce the amount of dry shrinkage by applying a shrinkage reducing agent for 3D printed concrete.

한국과 중국의 콘크리트용 화학 혼화제 품질 규정 비교

후윈야오 ( Hu Yun-yao ),임군수 ( Lim Gun-su ),김종 ( Kim Jong ),한민철 ( Han Min-cheol ),한천구 ( Han Cheon-goo ) 한국건축시공학회 2023 한국건축시공학회 학술발표대회 논문집 Vol.23 No.1

In this study, comparison of the quality standard of chemical admixtures between Korea and China is conducted. It is classified into three types of water reducing agents: standard, delayed, and accelerated according to the sensitivity and strength improvement of the sensitivity and strength of the agent. However, Chinese standards classify reducing agents only as standard, high efficiency, and high performance, and do not add AE agents into water reducing agent. On the other hand, that of Korea has a classification regulation for reducing agents added with AE agents.

콘크리트 하수관거 보수용 초속경 수중불분리 모르타르의 재료적 특성

이병재,이선목,방진욱,김윤용 한국구조물진단유지관리공학회 2020 한국구조물진단유지관리공학회 논문집 Vol.24 No.3

Among the sewage pipes installed in Korea, the length of concrete pipes exceeding 20 years is 66,334 km (42.5%). Deteriorated concrete sewer pipes need to be repaired due to the leakage of internal sewage, which causes problems such as sink holes by expanding the cavity around the pipeline. In this study, we tried to apply anti-washout underwater mortar with ultra rapid hardening cement and segregation reducing agent to sewage pipe repair. As a result of the setting time test, the final set time was delayed by up to 172% by incorporating segregation reducing agent. In the test for measuring the degree of mortar segregation in water, it was measured at pH 12 or less under all mixing conditions. In addition, the suspension amount was measured to be 50 mg / l or less to satisfy the KCI-AD102 standard by incorporating a segregation reducing agent. In terms of the average value of mortar compressive strength, by incorporating segregation reducing agent, the strength of the specimens produced in air was more than 80% of that of the specimens produced in water. Conversely, the bond strengths of the specimens produced in water were measured to be higher than those of the specimens produced in air. Water resistance was evaluated by measuring water absorption and water permeability. Water absorption and water permeability were reduced by 42.6% and 36.6%, respectively, by mixing segregation reducing agent. 국내에 설치된 하수관거 중에서 20년을 초과한 콘크리트관의 연장은 66,334km로서 전체의 42.5%를 차지한다. 열화된 콘크리트 하수관거에서는 내부 하수의 유출로 인해 관로 주변의 동공을 확장시켜 땅꺼짐 등의 문제도 발생시키기 때문에 이에 대한 보수를 통한 유지관리가 필요한 실정이다. 본 연구에서는 초속경시멘트 및 분리저감제를 적용한 수중불분리성 모르타르를 하수관거 보수에 적용하기 위한 기초연구를 수행하였다. 배합조건에 따른 응결시험 결과 분리저감제 혼입에 따라 종결이 최대 172%정도 지연되는 것으로 나타났다. 수중분리도는 분리저감제 0.3% 이상 혼입시 pH 12 이하로 측정되었고, 현탁액량은 분리저감제 0.2% 이상 혼입시 50mg/l이하로 측정되어 국내 KCI-AD102 기준을 만족하였다. 기건조건과 수중조건에서 타설하였을 때의 강도비 평가 결과, 분리저감제 혼입시 80% 이상의 강도비를 나타내어 국내 KCI-AD102 기준을 만족하였다. 부착강도는 분리저감제 혼입시 기건조건보다 수중조건에서 타설하였을 때 높은 강도로 측정되었다. 내수성 검토는 분리저감제 혼입량에 따른 흡수율과 투수성으로 평가하였고, 각각 42.6%, 36.6%의 성능개선을 확인하였다.

수축저감제 혼입에 따른 전력구 박스구조물의 건조수축균열 저감

우상균,김기중,이윤 한국구조물진단유지관리공학회 2016 한국구조물진단유지관리공학회 논문집 Vol.20 No.5

이 연구의 목적은 개착식 전력구 콘크리트에 발생하는 부등건조수축에 의한 균열특성을 파악하고, 수축저감제 혼입에 따른 건조수 축균열특성을 분석하는데 있다. 따라서 이 연구에서는 전력구 박스형 콘크리트 구조물의 부등건조수축에 의한 균열특성을 파악하기 위하여 세 가지 주요영향인자를 고려한 수치해석과 수치해석을 한 결과와 실제 전력구 타설을 하여 측정한 차이를 확인해 보았다. 본 연구로부터 건조 수축 시험체에 대한 건조수축량을 산정에 대한 해석 기법을 개발하였으며, 실제 전력구 타설 실험을 통해 종방향 및 횡방향 균열발생 가능성을 입증 하였다. 전력구 실증시험체 건조수축량 수치해석 결과, 균열저감 콘크리트 배합의 경우 종방향 및 횡방향 응력에 있어 일반배합에 비해 40~50%정도의 현저한 감소를 보이며, 이에 따라 균열저감 콘크리트를 전력구에 적용하였을 경우 현저한 균열감소 효과를 보일 것으로 예측된다. The purpose of this study is to examine the reduction effect of shrinkage reducing agent for drying shrinkage induced cracking and suggest the method of controlling the cracking in concrete box culvert for power transmission. Based on drying shrinkage cracking mechanism, it is necessary to perform the numerical analysis, which involves shrinkage reducing effect of shrinkage reducing agent. From the numerical results, it is found that cracking behavior for longitudinal direction and transverse direction due to differential drying shrinkage of box culvert can occur and the experimental observation of concrete cracks support the numerical predictions. The shrinkage reducing agent reduced the concrete cracking by 40~50%, which shows the methodology of controlling of drying shrinkage cracks in box culverts in real construction site.