자동차 폐촉매를 이용한 휘발성유기화합물(VOC)의 제어기술

서성규,문정선 여수대학교 1999 論文集 Vol.14 No.2

The characteristics and the combustion activities of a waste automotive catalyst were carried out in this study. Methanol was selected as a model VOC(Volatile Organic Compound) and the combustion activity was examined in a fixed bed reactor. The characteristics of waste automotive catalyst was investigated by EA(Elemental Analysis). ICP-AES(Inductively Coupled Plasma-Atomic Emission Spectrophotometer) and BET(Brunauer-Emmett-Teller) analysis. Carbon deposit amount was decreased with increasing pretreatment temperature and air. Conversion of methanol at the reaction temperature of 100℃ was above 90% on the regenerated catalyst with air,60cc/min,400℃.1hr. The selectivities of HCHO and HCOOCH₃were decreased with increasing reaction temperatures. And combustion activity of a waste automotive catalyst was decreased with mileage. Catalytic activity of a waste automotive catalyst for methanol combustion was increased with acid treatment, and the order of acid effect was summarized as follows : HNO₃>HCL>H₂SO₄>CH₃COOH. Finally, we might say that the regenerated waste automotive catalyst by regeneration method has a excellent catalytic activity for VOC combustion.

초내열합금 CM247LC의 미세조직 및 인장 특성에 미치는 진동 및 접종처리의 영향

徐晟文,芮大喜,金仁守,趙昌龍 대한금속재료학회 2002 대한금속·재료학회지 Vol.40 No.12

Effects of vibration(V) and inoculation(I) during casting on the microstructure and tensile properties of nickel-base superalloy CM247LC were investigated. The vibration treatment with a frequency of 10 ㎐ was effective to refine the grain size and decrease the microporosity level to some extent. The vibration treatment for the inoculated mold developed the grains of the casting into fine equiaxed grains compared with columnar grains of the casting with vibration free inoculated mold. The existing phases of CM247LC alloy such as finely dispersed cuboidal γ', MC, and grain boundary precipitates were not influenced by the vibration and/or inoculation treatment. The fine equiaxed grained CM247LC had excellent tensile properties compared with those of the columnar grains. The tensile behavior of CM247LC alloy at 760℃ showed different aspects with respect to the grain size change and which was carefully analyzed by fractographic investigations.

자동차 폐촉매의 특성 및 VOCs 연소활성

서성규,문정선 麗水大學校 産業基術硏究所 1999 産業基術硏究所 論文集 Vol.8 No.-

The characterization of waste automotive catalyst was examined by EA(Elemental Analysis) and ICP-AES(Inductively Coupled Plasma-Atomic Emission Spectrophoto meter) analysis. The content of Pt, Pd and Rh in waste automotive catalyst was 1,228ppm, and 233ppm in Excel and 581ppm, 1,883ppm, and 255ppm in Pride. The combustion performance of waste automotive catalyst was investigated for acetaldehyde and toluene as a model VOCs in a fixed bed reactor at atmospheric pressure. The number of estimated waste automotive catalyst was 427,520 in 1997. Carbon deposit amount was higher in front brick than rear brick of catalyst, and increased with mileage. Catalytic activity of waste automotive catalyst for acetaldehyde and toluene combustion was very excellent, and decreased with mileage.

석유화학 BTX 공정 점토탑에서의 악취 및 공정 부식 방지에 관한 연구

서성규,정채훈,문정선 여수대학교 산업기술지역개발연구소 2000 産業基術硏究所 論文集 Vol.9 No.-

offensive odors affect man's olfactory sense and cause repulsiveness. In recent years, the problem of offensive odors is becoming more complicated and diversed. The emitted offensive odors from petrochemical BTX process gave rise to a serious corrosion problem of benzene tower and offensive odor problem. The main purpose in this study is to investigate process corrosion and odor generation from clay tower of petrochemical BTX process which were assumed to be the conversion of sulfur compounds over clay into hydrogen sulfide. As a result of this study, when traces of thiophenes and mercaptans are present in the clay tower, these components are broken down by the clay. The forming H□S in this step will be concentrated in the benzene tower top. In order to remove the occurred hydrogen sulfide, Fe-chelate catalyst is used. Removing efficiency is better than 99%.

대학캠퍼스와 광양만 주변지역의 대기질에 관한 연구

서성규,이선원,문정선 國立 麗水大學校 環境問題硏究所 2000 環境硏究論文集 Vol.3 No.-

By the air quality standard of korea, the 7 major pollutants should be continuously monitored; that is SO_(2), NO_(2), O_(3), CO, PM10, TSP and Pb, At present, air monitoring system is furnished at 6 site around Kwangyang-bay which has been assigned to the air pollution special measure area as well as the air quality regulation area. According the measurement results of the university campus, the present levels of pollutants were not exceed the limit level of air quality standard, but the levels of some pollutants were high at special period of a day. It may be recommended to monitor continuously for the long-term. The monitoring results of SO_(2), NO_(2), O_(3) and CO showed that SO_(2), NO_(2) and CO level were well within the limit levels of air quality standard. The O_(3) levels were not exceed the limit levels of air quality standard, but high enough to concern based on one and eight hour average levels. Especially for monitoring data at Weollae-dong district The O_(3) levels were approaching the limit levels of air quality standard. The pattern of O_(3) and NO_(2) increase due to the photo-oxidation in the industrial district was not similar th that residential district

1866∼7년 데이 드레스(day dress)의 설계 및 디자인 분석

김문숙,이서희,오현남,한성지,김현주 서울여자대학교 자연과학연구소 1996 자연과학연구논문집 Vol.7 No.-

As the current stage of the fashion begins to follow the styles of the past, the study on the past costume is getting more important, and as the methodology of the study accurately approached study through the rehabilitation of the past costume is more needed than the simple rearrangement of the historical documents. By this methodology, this study can be positioned as a recreation activity. The results of the study are as follows. 1) Style : The general silhouetts is the late crinoline style which is the period from 1860s to just before bustle. The dress is one-piece composed of fitted bodice, and skirt which the front is flat, side and back is triangular shape to the skirts. 2) Color and Material : the main color is pale stone and the sub-color is ivory and blue. The dress is made of a silk surface and cotton back and partly satin and velvet. 3) Pattern and sewing : the dress is together sewing comnined with lining and fabric. The skirt is gored skirt, the number of patterns is plenty because of the plenty of width of skirt. The double piping has various effect not only to decorate but also to conceal the seam, support the silhouette. 4) Detail : The general detail is double piping which are repeatedly used to decorate stand collar, bands of sleeve, froint bodice and gored panel seam of skirt. And the fringe and velvet ribbon are used to decorate the dress. 5) Structural characteristics : The double piping, velvet ribbon and twilled cotton are used to emphasize structural characteristics of crinoline style. And the waistband which is backed with a webbing band to reinforce it is also the structural characteristics. Synthetically, the 1886~7 day dress has the characteristics of transitional stage in which the chararcteristics of the costume of 1860s and the remnants of the characteristics of the previous costume style, and shows the characteristics of day dress well in terms of the style, color and fabrics, pattern and sewing, detail, and structural characteristics.

Langmuir 이중탐침법에 의한 플라즈마 특성 진단

김성훈,서문규 청주대학교 산업과학연구소 2007 産業科學硏究 Vol.24 No.2

Plasma parameters of the remote, inductively-coupsad plasma system were measured by Langmuir double probe technical. Effects of the plasma power, reaction pressure on the electron density(n_(e)) and electron temperature(T_(e)) in the plasma were investigated. Electron dtlsities are measured in the range of 0.3∼6.5×10^(10)cm^(-3), and electron temperatures were in the range of 2∼7×10⁴ K. The electron dtlsity is increased with the plasma power and reaction pressure, but the electron temperature is found to be strongly deptldtlt on the reaction pressure rather than the plasma power.

플라즈마 중합된 아크릴산 필름의 합성

김성훈,서문규 청주대학교 산업과학연구소 2007 産業科學硏究 Vol.24 No.2

Plasma-polymerized acrylic acid films were synthesized on Si wafer and KBr pelsat by remote-PECVD. Effects of the oxygtl addition, substrate temperature and indirect plasma method on the growth rate and chemical bonding and composelion of the film were investigated. The growth rate was decreased welh substrate temperature. The changes of chemical structure and chemical tlvironment of the films were characterized by fourier transformed infrared(ETIR) spectroscopy and X-ray photoelectron spectroscopy(XPS) analyses and curve fitting techniques.

중부지역 옥수수 파종기에 따른 생육단계 및 수량성 변화

서종호, 문중경, 정건호, 서민정, 구자환, 박장환, 배환희, 신성휴, 권영업 忠北大學校 農業科學硏究所 2014 農業科學硏究 Vol.30 No.2

Maize hybrids were planted on April 1, April 25, May 20 and June 15 in 2012, 2013 at the experimental paddy and upland fields in Suwon city , respectively to know changes of growth stage and yield according to different planting time. Maize planting on April 1 was not recommended because total growing days at planting on April 1 was not different with that at planting on April 25 due to many days from planting to emergence over 20 days at planting on April 1. Total growing days were not much different among three planting time after April 25 because days from silking to maturity was lengthened though days from planting to silking was shortened at later planting time. Stalk weight was decreased as planting time was delayed, particularly at planting times after May 20 at paddy field by excess water injury during early growth stage. But, grain yield was not low as in May and June. It is needed to introduce early maturity maize variety as Yanganok at late planting for higher grain yield and enough time for soil preparation for next winter crops

정상 성인에 경구 투여한 Cefixime 두 정제의 생물학적 동등성 비교

강진양,서성훈,이경태,문창훈,강진한,이동건,최정현,신완식 대한화학요법학회 2000 대한화학요법학회지 Vol.18 No.4

목적 : 식품의약안전청 고시 제 1998-86호(1998. 8.26) "생물학적 동등성 시험 기준"에 의하여 섹심 캅셀(시험약, 한국유나이트제약)과 슈프락스 캅셀(대조약, 동아제약)의 생물학적 동등성을 비교 검토하였다. 방법 : 2×2 라틴 방격법에 따라 건강한 성인 남성 지원자 20명에게 cefixime 100㎎씩 경구투여하였다. 약제투여 후 12시간까지 일정간격으로 채혈하였고 각 피험자들의 혈중약물농도 데이터로부터 구한 Area under the concentration (AUC), C_(max), T_(max) 등의 생체이용률 파라미터에 대해 통계학적으로 고찰하여 두 제제간의 생물학적 동등성을 평가하였다. 결과 : AUC, C_(max), T_(max)에 대한 평균값의 차가 각각 1.26%, 3.73%, 6.21%로서 모두 대조약의 20% 이내에 들어 생물학적 동등성 판정기준의 전제조건을 만족하였다. 분산분석 결과 AUC, C_(max), T_(max)의 각 비교 항목에 있어서 모두 유의수준 α=0.05의 군/순서효과 검정에서 F비가 F 분석표의 한계값보다 작아 교차시험이 제대로 이루어졌음을 확인할 수 있었으며, AUC, C_(max), T_(max) 각 비교항목에 있어서 유의수준 α=0.05에서 대조약에 대한 최소검출차(Δ)가 각각 17.74%, 17.05%, 15.67%로 모두 20% 이내이었으며, 검출력(1-β)도 모두 0.8 이상으로 나타나 생물학적 동등성 판정기준을 만족시켰다. 또 AUC, C_(max), T_(max) 각 비교항목에 있어서 대조약에 대한 생체이용률 차이의 신뢰한계(δ)가 ±20% 이내이어야 한다는 생물학적 동등성 판정기준을 모두 만족시켰다. 결론 : 이상의 실험결과로 시험약은 대조약에 대하여 생물학적 동등성 평가항목인 AUC, C_(max), T_(max)에서 모두 판정기준을 만족시켜 시험약은 대조약과 생물학적으로 동등하다고 사료된다. Background : The study was designed to compare the bioeqivalence between the test (CEXIME®. United Korea. Co., Ltd) and control (SUPRAX®. Dong-a Pharm. Co.. Ltd) capsules of cefixime. Methods : Twenty. healthy, male volunteers completed the study Each subject ingested single dose (100 ㎍) of the control and test drugs in 2?2 crossover design with a week drug-free interval between the doses. Blood samples were collected serially up to 12 hours and plasma concentrations of cefixime were measured by high-performance liquid chromatography with UV detection. A non-compartmental approach was used for analysis of the concentration-time data. Results : The area under the curve (AUC), the maximum concentration of drug (C_(max)). and time to reach C_(max)(T_(max)) did not show any significant difference between the two preparations by ANOVA. The mean differences of AUC, C_(max), and T_(max) were within 20% of the control drug, those were 1.26%. 3.73%. and 6.21%. respectively. The confidence limits of three parameters were satisfied the bioeqivalence criteria. Conclusion : These results suggest that the test drug was bioequivalent with the control drug.