국가 안보와 방위산업 육성

김형선,Kim, Hyung-Seon 한국방위산업진흥회 1998 國防과 技術 Vol.- No.227

한반도 안보상황이 어떠한 상태가 되던간에 가장 중요한 것은 우리의 안보역량 확보 여부에 달려있다. 우리의 생존을 지키고 국가위상에 걸맞는 군사력의 유지는 필수적인 것이다. 과학기술과 첨단 무기체계가 주도할 미래의 정보전쟁에 대비하기 위해서는 군사기술의 자립이 매우 중요한 과제이다.

리튬이차전지용 Si/Cu/Graphite 복합체 음극의 전기화학적 거동

김형선,정경윤,조원일,조병원,Kim, Hyung-Sun,Chung, Kyung-Yoon,Cho, Won-Il,Cho, Byung-Won 한국전기화학회 2009 한국전기화학회지 Vol.12 No.2

탄소 피복된 Si/Cu 분말을 기계적인 볼-밀링(ball-milling) 방법과 고온에서 탄화수소가스 분해 방법에 의해 제조하여 리튬이차전지용 음극으로 사용하였고 이에 대한 전기화학적 거동을 조사하였다. 천연흑연(natural graphite)을 이용하여 탄소 피복된 Si/Cu/graphite 복합체 음극소재를 제조하였으며 천연흑연 음극소재와 전기화학적 특성을 비교하였다. 탄소 피복된 Si/Cu 음극의 가역적 비용량은 초기 10 싸이클까지 지속적인 증가를 나타냈다. 탄소 피복된 Si/Cu/graphite 복합체 음극의 가역적 비용량은 $0.25mA/cm^2$ 전류밀도에서 450mAh/g이고 초기 싸이클 효율은 81.3%로 나타났다. 복합체 음극의 싸이클 성능은 가역적인 비용량값을 제외하고 천연흑연 음극과 유사하게 나타났다. The carbon-coated Si/Cu powders were synthesized by mechanical ball-milling and hydrocarbon gas decomposition methods at high temperature. The carbon-coated Si/Cu powder was used as anode for lithium secondary battery and its electrochemical behavior was investigated. In addition, the carbon-coated Si/Cu/graphite composite anode material was prepared using natural graphite powder and their electrochemical characteristics were compared with natural graphite anode. The specific capacity of carbon-coated Si/Cu anode increased to the initial 10 cycles. The carbon-coated Si/Cu/graphite composite anode exhibited the reversible specific capacity of 450mAh/g and the first cycle efficiency of 81.3% at $0.25mA/cm^2$. The cycling performance of the composite anode was similar to that of pure graphite anode except the reversible specific capacity value.

Electrochemical Properties of Li1.1V0.75W0.075Mo0.075O2/Graphite Composite Anodes for Lithium-ion Batteries

김형선,Sang-Ok Kim,김용태,Ji Kwon Jung,Byung Ki Na,이중기 대한화학회 2012 Bulletin of the Korean Chemical Society Vol.33 No.1

Novel type Li1.1V0.9-2xWxMoxO2 powders were prepared by a solid-state reaction of Li2CO3, V2O3, WO2 and MoO2 precursors in a nitrogen atmosphere containing 10 mol % hydrogen gas, and assessed as anode materials in lithium-ion batteries. The specific charge and discharge capacities of the Li1.1V0.9-2xWxMoxO2 anodes were higher than those of the bare Li1.1V0.9O2 anode. The cyclic efficiency of these anodes was approximately 73.3%at the first cycle, regardless of the presence of W and Mo doping. The composite anode, which was composed of Li1.1V0.75W0.075Mo0.075O2 (20 wt %) and natural graphite (80 wt %), demonstrated reasonable specific capacity, high cyclic efficiency, and good cycling performance, even at high rates without capacity fading.

Poly ( ethylene oxide ) - Li 계 고분자 전해질의 전기화학적 특성 및 물리적 성질

김형선,조병원,윤경석,전해수 ( Hyung Sun Kim,Byung Won Cho,Kyung Suk Yun,Hai Soo Chun ) 한국공업화학회 1996 공업화학 Vol.7 No.3

분자량이 큰 Poly(ethylene oxide)[PEO] 고분자에 LiClO₄, LiCF₃SO₃ 등의 리튬염과 ethylene carbonate(EC), propylene carbonate(PC) 등의 가소제를 고정화시킨 고분자 전해질의 전기화학적 특성 및 물리적 성질을 조사하였다. 가소제가 첨가된 PEO-Li계 고분자 전해질은 상온에서 10^(-4)S/㎝의 이온 전도도를 보였고 4.5 V(vs. Li^+/Li)까지 높은 전기화학적인 안정성을 나타냄으로써 리튬 2차전지에 적용 가능한 것으로 나타났다. 리튬염 및 가소제의 첨가에 따라 PEO의 결정상이 감소되었고 특히 LiClO₄, PC 등이 LiCF₃SO₃, EC 등에 비하여 더 효과적인 것으로 나타났다. 리튬염의 농도가 증가할수록 고분자 전해질의 유리전이온도(T_g)는 증가되었으며 반면에 융점온도(T_m)는 감소하는 것으로 나타났다. 가소제가 첨가된 고분자 전해질은 6℃에서 결정화 되었다. Electrochemical characteristics and physical properties of polymer electrolyte which immobilized lithium salts such as LiClO₄ and LiCF₃SO₃ and plasticizers such as ethylene carbonate(EC) and propylene carbonate(PC) in high molecular weight polyethylene oxide)[PEO] polymer was investigated. PEO-Li based polymer electrolyte with plasticizers showed ionic conductivity of 10^(-4)S/㎝ at room temperature and high electrochemical stability up to 4.5 V(vs, Li^+/Li), so it can be applied to lithium secondary battery. The crystallinity of PEO decreased with the addition of lithium salts and plasticizers, especially LiClO₄ and PC showed more effective than LiCF₃SO₃ and EC. Glass transition temperature(T_g) of polymer electrolyte increased with increasing lithium salt concentration whereas melting temperature(T_m) decreased. Polymer electrolyte with plasticizers crystallized at 6℃.

학술발표회 초록 : ( 공업화학 (5) ) ; 리듐 이차전지용 고체고분자전해질의 특성

김형선,백지흠,조병원,윤경석 ( Hyung Sun Kim,Chi Hum Paik,Byung Won Cho,Kyung Suk Yun ) 한국화학공학회 1994 추계학술발표회 Vol.- No.-

Li/V₆O₁₃ 리튬 폴리머 전지의 성능

김형선,조병원,윤경석,전해수,Kim, Hyung-Sun,Cho, Byung-Won,Yun, Kyung-Suk,Chun, Hai-Soo 한국공업화학회 1996 공업화학 Vol.7 No.2

The performance of The performance of $Li/V_6O_{13}$ cell and the electrochemical properties of polymer electrolyte based on poly(acrylonitrile)[PAN] was investigated. The ionic conductivity of polymer electrolyte showed $2.3{\times}10^{-3}S/cm$ and the compatibility with lithium electrode was excellent. Also, it showed the electrochemical stability up to 4.3V(vs. $Li^+/Li$). The cell reaction of $Li/V_6O_{13}$ was dominated by the interfacial resistance between $V_6O_{13}$ electrode and polymer electrolyte. The diffusion coefficient of lithium ion within $V_6O_{13}$ was $2.7{\times}10^{-9}{\sim}4.2{\times}10^{-8}cm^2/sec$. The utilization of $V_6O_{13}$ active material was 95% at C/8($50{\mu}A/cm^2$) and 82% at C/4($100{\mu}A/cm^2$), respectively. $Li/V_6O_{13}$ 전지의 성능과 poly(acrylonitrile)[PAN]계 폴리머 전해질의 전기화학적인 성질을 조사 하였다. 폴리머 전해질의 이온 전도도는 상온에서 $2.3{\times}10^{-3}S/cm$를 보였으며 리튬 전극과의 상용성도 우수하였다. 또한 4.3V(vs. $Li^+/Li$)까지의 전기화학적인 안정성이 있는 것으로 나타났다. $Li/V_6O_{13}$ 전지 반응은 $V_6O_{13}$ 전극과 폴리머 전해질간의 계면 저항이 지배적 이었다. $V_6O_{13}$내의 리튬 이온의 확산 계수값은 $2.7{\times}10^{-9}{\sim}4.2{\times}10^{-8}cm^2/sec$로 나타났다. $V_6O_{13}$ 활물질의 이용률은 C/8($50{\mu}A/cm^2$)에서 95%였으며 C/4($100{\mu}A/cm^2$)에서는 82%로 각각 나타났다.

상황인식 기반 홈 로봇 서비스의 구현사례

김형선,Kim, Hyoung-Sun 서비스사이언스학회 2014 서비스연구 Vol.4 No.1

상황인식 기술은 유비쿼터스(스마트) 환경에서 지난 수년간 중요한 이슈로 떠오르고 있으며, 현재도 연구자들에 의해 많은 연구가 이루어 지고 있다. 상황인식 기술은 물리적인 환경으로부터 다양한 정보를 획득/가공하여 사용자에게 능동적인 서비스와 정보를 제공하는 컴퓨터 시스템이다. 상황인식 시스템은 각종 센서로부터 발생하는 낮은 수준의 상황정보를 높은 수준의 상황정보로 변환하여 사용자에게 원하는 서비스를 제공하는 환경을 만들어 준다. 본 논문에서는 물리적인 스마트 공간에 존재하는 각종 센서로부터 얻어진 하위단계(Low-level)의 Event-driven 센서정보를 온톨로지 기반 상황정보로 모델링 하여 상위단계(High-level) 상황정보로 변환하는 상황정보를 모델링하여 상황인식 시스템을 구현하였다. 또한 변환된 High-level 상황정보는 가상공간에서 ECA(Event, Condition, Action) 룰에 따라 사용자에게 언제 어디서나 사용자가 필요로 하는 능동적이고 지능적인 서비스를 제공하고, 스마트 홈 환경에서 사용자에게 다양한 가사 도우미 로봇 서비스의 구현 사례를 소개 하였다. Context-aware computing is an emerging paradigm to achieve ubiquitous computing environments by enabling computer systems to understand their situational contexts. A context-aware system uses context to provide relevant information and services to the user depending on the user's task. In this paper, we propose an ontology-based context-aware modeling methodology that transmits low-level contexts acquired by directly accessing various sensors in the physical environments to high-level contexts. With these high-level contexts, context-aware application can provides proactive and intelligent services using ECA (Event-Condition-Action) rules. We implemented a home robot service in smart office environment.

공간증강현실 기반 스마트 프로젝션 서비스

김형선,이주행,이아현,Kim, Hyoung-Sun,Lee, Joo-Haeng,Lee, Ah-Hyun 서비스사이언스학회 2015 서비스연구 Vol.5 No.1

공간증강현실(Spatial Augmented Reality, SAR) 기술은 초소형 프로젝터와 카메라로 구성되어 실제 사물을 인식하고, 물체 표면이나 주변에 상황에 적합한 정보 및 사용자 인터페이스를 투사(projection)하는 기술이며, 최근에는 소형 프로젝터의 등장으로 더욱 각광 받고 있는 기술이다. 본 논문에서는 공간증강현실 기술이 새로운 IT 패러다임으로 부각됨에 따라 이 기술을 이용하여 스탠드 형 모양에 프로젝터-카메라-프로세서를 설치하여 스마트 프로젝션(Smart Projection) 서비스 시스템을 구현하고, 적용한 서비스 구현사례를 소개 하고자 한다. Spatial Augmented Reality (SAR) technology perceives real world objects, and their contexts and augments appropriate information and user interfaces on or around the surface of the objects is a technique of projecting. A SAR device typically consists of a small projector and a camera and a processor, and this technology is becoming more widespread along with the advent of subminiature project In this paper, as the spatial augmented reality technology is being magnified as a new IT paradigm, we introduce our stand-type installation of projector-camera-processor components, discuss our implementation of smart projection service system, and present its use cases.

Three-axis Modification of Coordinates Enables Accurate Stereotactic Targeting in Non-human Primate Brains of Different Sizes

김형선,Goo-Hwa Kang,Hanlim Song,Ra Gyung Kim,Ji-Young Park,황정호,김형일 한국뇌신경과학회 2019 Experimental Neurobiology Vol.28 No.3

The brain grows with age in non-human primates (NHPs). Therefore, atlas-based stereotactic coordinates cannot be used directly to target subcortical structures if the size of the animal’s brain differs from that used in the stereotactic atlas. Furthermore, growth is non-uniform across different cortical regions, making it difficult to simply apply a single brain-expansion ratio. We determined the skull reference lines that best reflect changes in brain size along the X, Y, and Z axes and plotted the changes in reference-line length against the changes in body weight. The skull reference lines had a linear relationship with body weight. However, comparison of skull reference lines with body weight confirmed the non-uniform skull growth during postnatal development, with skull growth more prominent in the X and Y axes than the Z axis. Comparing the differences between the atlas-based lengths and those calculated empirically from plot-based linear fits, we created craniometric indices that can be used to modify stereotactic coordinates along all axes. We verified the accuracy of the corrected stereotactic targeting by infusing dye into internal capsule in euthanized and preserved NHP brains. Our axis-specific, craniometric-index-adjusted stereotactic targeting enabled us to correct for targeting errors arising from differences in brain size. Histological verification showed that the method was accurate to within 1 mm. Craniometric index-adjusted targeting is a simple and relatively accurate method that can be used for NHP stereotactic surgery in the general laboratory, without the need for high-resolution imaging.

장기요양 인정자의 신체적 및 정신적 기능 상태와 삶의 질과의 관계

김형선,배남규,권인선,조영채,Kim, Hyeong-Seon,Bae, Nam-Kyou,Kwon, In-Sun,Cho, Young-Chae 대한예방의학회 2010 예방의학회지 Vol.43 No.4

Objectives: This study was performed to determine the levels of quality of life (QOL) according to the grade of long-term care service for the elderly people who were admitted from long-term care insurance, and to reveal its association with the physical and mental functioning such as the Activity of Daily Living (ADL), the Instrumental Activity of Daily Living (IADL), the Center for Epidemiologic Studies Depression Scale (CES-D), and the Mini-Mental State Examination-Korean version (MMSE-K). Methods: The interviews were performed during the period from March 1 to May 31, 2009, for 958 elderly people in urban and rural areas. The questionnaire items included various indices such as the ADL, IADL, CES-D, and MMSE-K, as independent variables and the index of QOL, as the dependent ones. For statistical analysis, t-tests were used for the mean scores of QOL according to gender and the grade of long-term care services, and Spearman's correlation was used for each variable. The effects of physical and mental functioning for QOL were assessed by covariance structure analysis. The statistical significance was set at p<0.05. Results: The mean scores of QOL among all the subjects was $55.4{\pm}15.62$ (Grade I: $49.7{\pm}14.17$, Grade II: $56.8{\pm}14.62$, Grade III: $59.4{\pm}16.36$), and it was lower according to the higher grade of long-term care insurance. In terms of the correlation matrix of the QOL and the physical and mental function factors, the QOL showed positive correlation with the ADL, IADL and MMSE-K, while it had negative correlation with depression. On the analysis of covariance, mental functioning (depression and the MMSE-K) had a greater influence on the level of QOL than the physical functioning (ADL and IADL). Conclusions: The level of the QOL in the elderly people who were admitted from long-term care insurance was lower according to higher the grade of long-term care insurance. Also, the mental functioning (depression and MMSE-K) was more influential on the level of the QOL than the physical functioning (ADL and IADL).