소각로의 NOx 제어용 SCR 시스템의 암모니아 공급량제어

김인규,여태경,김환성,김상봉,Kim, In-Gyu,Yeo, Tae-Gyeong,Kim, Hwan-Seong,Kim, Sang-Bong 대한기계학회 1998 大韓機械學會論文集A Vol.22 No.2

This paper describes a modelling method for SCR(selective catalystic reduction) system in refuse incineration plant. We consider the SCR system as a single input and single output system. For modelling the SCR system, an auto regressive exogeneous(ARX) modelling method is used. In this case, we should design the white noise input for modelling and put it on the system as an input$(NH_3)$, and take an outlet NOx as an output. From these two relations, we design the ARX model with 45 second delay time and transform to a discrete system with sampling time of 0.5 second. Using the obtained SCR model, we verify that the outlet NOx is deeply related with stoker`s moving in boiler of refuse incineration plant.

대장중복증과 동반된 횡행결장간막의 이소성 췌장에서 유래된 가성낭종 1예

김인규,한석주,양경무,김호근,김명준,오정탁,황의호,Kim, In-Gyu,Han, Seok-Joo,Yang, Kyung-Mu,Kim, Ho-Geun,Kim, Myung-Joon,Oh, Jung-Tak,Hwang, Eui-Ho 대한소아외과학회 1998 소아외과 Vol.4 No.1

We have treated a case of pseudocyst of transverse mesocolon in 3-year-old male child. Operative findings demonstrated that the pseudocyst originated in the transverse mesocolon, and was not connected to the pancreas. A colonic duplication was found incidentally near the pseudocyst. On microscopic examination, ectopic pancreatic tissue was noted in the transverse mesocolon. This pseudocyst was thought to have originated from the ectopic pancreas of the transverse mesocolon. This is the first reported case of pseudocyst originated from ectopic pancreas of the transverse mesocolon, combined with a colonic duplication. The pathogenesis is discussed.

Strigol 유사체의 합성

김인규,홍영택,김성수,Kim In Kyu,Hong Young Tech,Kim Sung Soo 대한화학회 1992 대한화학회지 Vol.36 No.5

Strigol은 목화의 뿌리에서 추출된 천연물로서 벼, 옥수수, 사탕수수 등에 기생하는 피류(striga species) 등의 씨앗을 발아시키는데 월등한 효능을 보인다 $(10^{-12} ∼ 10^{-11}M, 80% 발아)$. 그런데 이러한 잡초는 오랜기간(15∼20년) 동안 흙속에서 휴면하고 있기 때문에 이들의 방제가 매우 어렵다. 이들을 방제할 수 있는 제초제 개발을 위해서 여러가지 strigol 유사체들인 3-methyl-4-(2-oxo-3,3a,6,6a-tetrahydro-2H-cyclopenta[b]furan-3-ylidenemethoxy)-but-2-en-4-olide(21), 4-(2-oxo-3,3a,6,6a-tetrahydro-2H-cyclopenta[b]furan-3-ylidenemethoxy)but-2-en-4-oilde(22), 3-methyl-4-(2-oxotetrahydrofuran-3-ylidenemethoxy)-but-2-en-4-olide(23), 4-(2-oxotetrahydrofuran-3-ylidenemethoxy)-but-2-en-4-olide(24)등을 합성하였다. Strigol, a natural product isolated from root exudates of cotton, was found to be an extremely potent seed germination stimulant for the parasitic plant, witchweed. Witchweed seeds can remain dormant in the soil for several years until favorable conditions prevail including exposure to some type of chemical germination stimulant. Several strigol analogues, 3-methyl-4-(2-oxo-3,3a,6,6a-tetrahydro-2H-cyclopenta[b]furan-3-ylidenemethoxy)-but-2-en-4-olide(21), 4-(2-oxo-3,3a,6,6a-tetrahydro-2H-cyclopenta[b]furan-3-ylidenemethoxy)but-2-en-4-oilde(22), 3-methyl-4-(2-oxotetrahydrofuran-3-ylidenemethoxy)-but-2-en-4-olide(23), and 4-(2-oxotetrahydrofuran-3-ylidenemethoxy)-but-2-en-4-olide(24), were synthesized.

달 탐사를 위한 Deep Space 주파수 대역 성능비교

김인규,문상만,Kim, In-Gyu,Mun, Sang-Man 한국천문학회 2012 天文學會報 Vol.37 No.2

국내의 우주개발진흥기본 계획에 의거하여 2020년 달 궤도선을 시작으로 2025년에는 달착륙선을 개발하여 달탐사에 참여하는 계획이 수립되었다. 달 탐사선이 발사되어 궤도에 진입하면 지상의 기지국과 명령/상태신호로 통신한다. 이러한 무선통신은 국제기구에서 제시된 주파수 스펙트럼을 기준으로 선정되어야 외부 시스템에 영향을 주거나 간섭을 받지 않는 안정적으로 무선통신을 수행할 수 있다. 주파수 스펙트럼 확보는 중요하여 달 탐사선이 발사되는 최소 7년 전부터 필요 주파수 대역을 선정하여 국제기구에 등록하여 허가를 받아야 한다. 본 논문에서는 앞으로 발사하게 되는 달 탐사선이 운용할 수 있는 주파수 대역 선정에 적절한 자료를 제공하기 위해 국제전기통신(ITU) 우주응용분야 보고서를 참조하여 Deep space 주파수 대역별 성능을 비교한 내용을 제시하였다.

청각 Codium fragile 의 성분 연구

김인규,강선영,In Kuy Kim,Seon-Yong Kang 대한화학회 1989 대한화학회지 Vol.33 No.3

There has been a continuing interest in the sterols and sterodis of marine organisms. The most exciting results of recent studies have been the characterization of a host of novel sterols, many with unique alkylation patterns in the side chain, but some with modified ring structures. The isolation and characterization of three sterols from the Korean alga codium fragile are presented. The major sterol was (24S)-24-ethylcholesta-5,25-dien-3${\beta}$-ol (clerosterol) and two minors are codisterodl and cholesterol. 해양 생물에는 육지 생물에 비해 훨씬 다양하고 특이한 구조의 sterol이 나타나고 있으며 이런 특질들은 화학자들에게 여러가지 흥미있는 생화학적 혹은 유기화학적인 관심을 불러 일으며 왔다. 본 연구에서는 한국산 청각(Codium fragile)으로부터 3개의 sterol 성분을 분리 확인하였다. 주 sterol 성분은 탄소가 29인 clerosterol 였으며 codisterol과 cholesterol도 소량 발견되었다.

Dolastatin 10 유사체의 합성

김인규,이병석,홍영택,최하순,권남연,Kim, In Gyu,Lee, Byeong Seok,Hong, Yeong Taek,Choe, Ha Sun,Gwon, Nam Yeon 대한화학회 1994 대한화학회지 Vol.38 No.10

Dolastatin 10의 유사체를 합성하기 위한 연구의 일환으로 여러 형태의 펩티드 화합물의 합성 경로를 연구하였다. 유사체의 합성에 사용된 4-amino-3-hydroxy acid는 에폭시 화합물의 아민에 의한 고리열림에 의하여 합성하였다. 이 비단백질 아미노산응로부터 주로 DCC 축합에 의하여 펩티드 화합물을 합성하였다. As a part of synthetic programs aimed at Dolastatin 10 analogues, synthetic pathway toward various peptides were investigated. 4-Amino-3-hydr> Transfer interrupted!nalogues were prepared by ring opening of epoxides with ammonia in MeOH. Several peptides were prepared starting from these unusual amino acids through using mainly DCC coupling.

Bis(p-nitrophenyl) sulfide의 새로운 합성방법

김인규,노장숙,In Kyu Kim,Jang Sook Noh 대한화학회 1974 대한화학회지 Vol.18 No.6

Phase transfer catalyst를 사용하여 p-chloronitrobenzene으로부터 bis(p-nitrophenyl) sulfide를 수득율이 좋고, work-up이 간편하게 합성하였다. Using a phase transfer catalyst, a convenient route to bis(p-nitrophenyl) sulfide was investigated. The yield was higher than the known method, and the work-up was also much easier than the conventional method.

자기공명영상으로 분류한 소아 임파관종 주사 요법의 평가

김인규,문석배,신현백,서정민,이석구,Kim, In-Kyu,Moon, Suk-Bae,Baek, Sin-Hyen,Seo, Jeong-Meen,Lee, Suk-Koo 대한소아외과학회 2009 소아외과 Vol.15 No.2

Pediatric lymphangioma can occur at any site. However the neck is the most common site. There are two treatment modalities (surgical excision and intralesional injection) for lymphangiomas. But, the treatment guide line for lymphangioma has not been established, yet. The aim of this study is to establish the treatment guide line based on our experience with lymphangiomas. Medical records of 82 cases of lymphangioma were reviewed retrospectively. On MRI (magnetic resonance image) findings, lymphangiomas were divided into 4 groups by the proportion of the cyst bigger than 2 cm in diameter of the tumor; group A-proportion of cyst occupies more than 75%, group B-proportion of the cyst 50~75%, group C-25~50%, and D in less than 25%. All patients were treated with OK-432 intralesional injection as the initial treatment. The effective response rates of OK-432 in group A & B were 88.2% and 88.8%, respectively. Group C response was 38.0% and D only 20.0%. Twenty-three patients received surgical excision. The result of surgical excision was generally satisfactory. Surgical site infection occurred in 1 case and postoperative bleeding in 1 case. Theses results indicate that intralesional injection of OK-432 could be the first line therapy in group A & B. In group C, OK-432 would be better as the first line therapy than surgery. For the group D, surgical excision should be the first line of treatment.

에스테르엔올 음이온의 Claisen 자리옮김 반응에 의한 Permethrin의 합성

김인규,강석구,홍장후,In-Kyu Kim,Suk-Ku Kang,Jang-Hoo Hong 대한화학회 1986 대한화학회지 Vol.30 No.6

(${\pm}$)시스- 및 트란스-3-(2,2-디클로로비닐)-2,2-디메틸-1-시클로프로판 카르복시산 3-페녹시벤질을 2-메틸-3-부텐-2올($\underline{2}$)을 출발물질로하여 입체선택적으로 합성하였다. 아세트산과 무수아세트산의 존재하에서 2-메틸-3-부텐-2-올을 알릴자리옮김 반응에 의해 아세트산3-메틸-2-부텐-일($\underline{3}$)을 얻은 다음 이 아세트산 알릴($\underline{3}$)의 [3,3] 시그마 자리옮김 반응에 의해 ${\gamma},\;{\delta}$-불포화산($\underline{4}$)을 얻었다. 3,3-디메틸-4-펜텐산($\underline{4}$)을 SOCl$_2$로 처리하고 3-페녹시벤질알코올로 에스테르화 시켜 알코올 부분이 구축된 3,3-디메틸-4-펜텐산 3-페녹시벤질($\underline{6}$)을 얻어서 사염화탄소의 첨가 후 그리화에 의해 (+)시스-및 트란스-3-(2,2-디클로로비닐)-2,2-디메틸-1-시클로프로 판카르복시산 3-페녹시벤질을 합성하였다 A stereoselective synthesis of 3-phenoxybenzyl (${\pm}$)-cis and trans-3-(2,2-dichlorovinyl)-2,2-dimethyl-1-cyclopropanecarboxylic acid starting from readily available 2-methyl-3-buten-2-ol($\underline{2}$) is described. Allylic rearrangement of 2-methyl-3-buten-2-ol, in the presence of acetic acid and acetic anhydride gave 3-methyl-2-butenyl acetate($\underline{3}$). The [3,3] sigmatropic rearrangement of the allyl acetate($\underline{3}$), as the silylketene acetal, produced the ${\gamma},\;{\delta}$-unsaturated acid($\underline{4}$). Treatment of 3,3-dimethyl-4-pentenoic acid($\underline{4}$) with SOCl2 followed by esterification with 3-phenoxybenzyl alcohol yielded 3, 3-dimethyl-4-pentenoic acid ester($\underline{5}$). Addition of carbon tetrachloride to the olefin ester($\underline{6}$) furnished 4,6,6,6-tetrachloro-3,3-dimethylhexanoic acid ester ($\underline{7}$). Cyclization with potassium t-butoxide and elimination of hydrogen chloride afforded 3-phenoxybenzyl (${\pm}$) cis- and trans-3-(2,2-dichlorovinyl)-2,2-dimethyl-1-cyclopropanecarboxylic acid.

한국산 해면의 지질 성분 연구

김인규,박선구,박성혜,장성근,Kim In Kyu,Park Sun Ku,Park Sung Hye,Jhang Sung Keun 대한화학회 1991 대한화학회지 Vol.35 No.1

한국 남해안 소흑산도에서 채집한 해면 V.japonica H.로부터 통상적인tetradecanoic 및 hexadecanoic methyl ester 이외에 탄소가 홀수인 pentadecanoic, heptadecanoic methyl ester와 가지달린 12-methyltetradecanoic, 14-methylpentadecanoic, 15-methylhexadecanoic 및 14-methylhexadecanoic methyl ester가 발견되었으며, 주 sterol 성분으로는 cholesterol과 소량의 ergost-25-ene-3,5,6-triol이 검출되었다. 한편, 여수 돌산도에서 채집한 해면 H.sinapium의 주 sterol성분은 5${\alpha}$-cholestan-3${\beta}$-ol이었고 cholesterol은 소량으로 얻어졌다. 지방산으로는 팔미틴산, 팔미토레인산, 올레인산, 스테아린산 및 리놀레인산 에틸에스터 이외에 상당량의 arachidonic산 에틸에스터가 함유되어 있었다. 상기 지역에서 채집한 또 다른 해면에서는 상당량의 tetradecanoic tetradecyl 및 hexadecyl ester와 sterol 성분으로 cholesteryl acetic 및 fatty acid ester가 함유되어 있었다. Various sterols and uncommon fatty acids have been isolated from the three species of Korean marine sponges. Odd-numbered pentadecanoic, heptadecanoic methyl ester and branched 12-methyltetradecanoic, 14-methylpentadecanoic, 15-methylhexadecanoic and 14-methylhexadecanoic methyl ester were isolated along with common tetradecanoic and hexadecanoic methyl ester from Heteropiidae sponge Vosmaeropsis japonica Hozawa collected from Sohuksan island of the Korea sea. Futher elution with more polar solvent gave 5${\alpha}$-cholestan-3${\beta}$-ol along with minor amount of ergost-25-ene-3${\beta}$,5${\alpha}$,6${\beta}$-triol. On the other hand, marine sponge Hymeniacidon sinapium collected from Yesu Dolsan island of the Korea sea was shown to contain 5${\alpha}$-cholestan-3${\beta}$-ol, along with minor amount of cholesterol, palmitic, palmitoleic, oleic, stearic, linolenic, and arachidonic acid ethyl ester. Unknown marin sponge collected from the same region was shown to contain large amount of tetradecanoic tetradecyl and hexadecyl ester and cholesteryl acetic and fatty acid ester.