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        Syntheses, Structures and Luminescent Properties of Two Novel M(II)-Phen-SIP Supramolecular Compounds (M = Co, Ni)

        Yu-Lan Zhu,Shuai Shao,Kui-Rong Ma,Xue-Ling Tang,Li Cao,Hui-Chao Zhao 대한화학회 2012 Bulletin of the Korean Chemical Society Vol.33 No.4

        Two metal compounds, [Co(phen)2(H2O)2]·2H2SIP·2H2O 1 and [Ni(phen)3]·2H2SIP·3H2O 2, have been obtained by incorporating 1,10-phenanthroline (phen) and 5-sulfoisophthalic acid monosodium salt (NaH2SIP) ligands under hydrothermal conditions. Meanwhile, the two compounds were characterized by element analysis, IR, XRD, TG-DTA and single-crystal X-ray diffraction. Both 1 and 2 present 3D supramolecular structures via O–H···O hydrogen bond interactions. Luminescent properties for 1 and 2 were also studied. The compound 1 has two fluorescence emission peaks centered at 398 nm attributed to the intraligand emission from the SIP ligand and at 438 nm assigned to the combined interaction of intraligand π*-π transitions of the phen ligand and ligand-to-metal-charge-transfer (LMCT) transitions (λex = 233 nm). The compound 2 shows one emission band centered at 423 nm with a shoulder peak at 434 nm which may be originated from the intraligand π*-π transitions of the phen ligand (λex = 266 nm).

      • SCOPUSKCI등재

        Syntheses, Structures and Luminescent Properties of Two Novel M(II)-Phen-SIP Supramolecular Compounds (M = Co, Ni)

        Zhu, Yu-Lan,Shao, Shuai,Ma, Kui-Rong,Tang, Xue-Ling,Cao, Li,Zhao, Hui-Chao Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.4

        Two metal compounds, $[Co(phen)_2(H_2O)_2]{\cdot}2H_2SIP{\cdot}2H_2O$ 1 and $[Ni(phen)_3]{\cdot}2H_2SIP{\cdot}3H_2O$ 2, have been obtained by incorporating 1,10-phenanthroline (phen) and 5-sulfoisophthalic acid monosodium salt ($NaH_2SIP$) ligands under hydrothermal conditions. Meanwhile, the two compounds were characterized by element analysis, IR, XRD, TG-DTA and single-crystal X-ray diffraction. Both 1 and 2 present 3D supramolecular structures via O-H${\cdots}$O hydrogen bond interactions. Luminescent properties for 1 and 2 were also studied. The compound 1 has two fluorescence emission peaks centered at 398 nm attributed to the intraligand emission from the SIP ligand and at 438 nm assigned to the combined interaction of intraligand ${\pi}^*-{\pi}$ transitions of the phen ligand and ligand-to-metal-charge-transfer (LMCT) transitions (${\lambda}_{ex}$ = 233 nm). The compound 2 shows one emission band centered at 423 nm with a shoulder peak at 434 nm which may be originated from the intraligand ${\pi}^*-{\pi}$ transitions of the phen ligand (${\lambda}_{ex}$ = 266 nm).

      • KCI등재

        Study on Calculation Method of Long Term Deformation of RAC Beam based on Creep Adjustment Coefficient

        Chao Liu,Zhenyuan Lv,Chao Zhu,Guoliang Bai,Yu Zhang 대한토목학회 2019 KSCE JOURNAL OF CIVIL ENGINEERING Vol.23 No.1

        The creep shrinkage of concrete is an important factor in the long-term deformation of concrete structures. It is also a key link for solving long-term deformation calculation accuracy and complex calculation forms. In this paper, a 1200-day long-term deformation test was conducted on beams with 0%, 50%, and 100% substitution ratios of recycled coarse aggregate. Meanwhile, based on the principle of virtual work, the creep coefficient of recycled concrete is introduced into the calculation of additional curvature of the beam section, and the formula for calculating the long-term deformation of recycled concrete is established. According to the size of recycled coarse aggregate, through the calculation of creep and shrinkage of concrete, the regeneration adjustment coefficient of concrete creep and shrinkage, the calculation results into three typical model of ordinary concrete creep and shrinkage, creep and shrinkage of concrete and regeneration model of deformation calculation of long period, the calculated and experimental results agree well; based on this, the deflection increase coefficient is proposed, which simplifies the long-term calculation formula. It not only can meet the calculation accuracy requirements, but also can be easily adapted to engineering promotion.

      • SCIESCOPUSKCI등재

        Longevity, tumor, and physical vitality in rats consuming ginsenoside Rg1

        Chao-Chieh Hsieh,Chiung-Yun Chang,Tania Xu Yar Lee,Jinfu Wu,Suchada Saovieng,Yu-Wen Hsieh,Maijian Zhu,Chih-Yang Huang,Chia-Hua Kuo The Korean Society of Ginseng 2023 Journal of Ginseng Research Vol.47 No.2

        Background: Effects of the major ginsenoside Rg1 on mammalian longevity and physical vitality are rarely reported. Purpose: To examine longevity, tumor, and spontaneous locomotor activity in rats consuming Rg1. Methods: A total of 138 Wistar rats were randomized into 2 groups: control (N = 69) and Rg1 (N = 69). Rg1 (0.1 mg/kg per day) were orally supplemented from 6 months of age until natural death. Spontaneous mobility was measured by video-tracking together with body composition (dual energy x-ray absorptiometry) and inflammation markers at 5, 14, 21, and 28 months of age. Results: No significant differences in longevity (control: 706 days; Rg1: 651 days, p = 0.77) and tumor incidence (control: 19%; Rg1: 12%, p = 0.24) were observed between the two groups. Movement distance in the control group declined significantly by ~60% at 21 months of age, together with decreased TNF-α (p = 0.01) and increased IL-10 (p = 0.02). However, the movement distance in the Rg1 group was maintained ~50% above the control groups (p = 0.01) at 21 months of age with greater magnitudes of TNF-α decreases and IL-10 increases. Glucose, insulin, and body composition (bone, muscle and fat percentages) were similar for both groups during the entire observation period. Conclusion: The results of the study suggest a delay age-dependent decline in physical vitality during late life by lifelong Rg1 consumption. This improvement is associated with inflammatory modulation. Significant effects of Rg1 on longevity and tumorigenesis were not observed.

      • KCI등재

        Beneficial effects of natural Jeju groundwaters on lipid metabolism in high-fat diet-induced hyperlipidemic rats

        Yan-chao Wang,Jin-miao Lu,Hui-zi Jin,Ai-niu Ma,Jin-yang Zhang,Nian Gong,Qi Xiao,Bin Zhu,Ying-fang Lv,Na Yu,Wei-dong Zhang,Yong-xiang Wang 한국영양학회 2014 Nutrition Research and Practice Vol.8 No.2

        BACKGROUND: Groundwater is believed to possess many beneficial effects due to its natural source of various minerals. In this study, we examined the effects of natural Jeju groundwater S1 (SamdasooTM), S2 and S3 pumped up from different locations of Jeju Island, Korea, along with local tap water, on body weight gain, serum lipids and lipoproteins, and liver histopathology in high-fat diet-induced hyperlipidemic rats. MATERIALS/METHODS: Rats were randomly and equally divided into 6 groups. Different water samples were supplied to the hyperlipidemic rats as their daily drinking water and the widely-used anti-hyperlipidemic drug simvastatin was used as a positive control. Body weight, serum lipids and lipoproteins were measured weekly. Liver weight, liver index and liver histopathology were examined after the execution of the rats. RESULTS: After drinking Jeju groundwaters for two months, S2 but not S3 significantly reduced weight growth and serum triglycerides levels and increased high density lipoprotein-C (HDL-C) without affecting total cholesterol or LDL-C. S1 and particularly S2 significantly reduced the severity of liver hypertrophy and steatosis. All Groundwaters had much higher contents of vanadium (S3>S2>S1>>tap water) whereas S1 and S2 but not S3 markedly blocked autoxidation of ferrous ions. CONCLUSION: Jeju Groundwater S1 and particularly S2 exhibit protective effects against hyperlipidemia and fatty liver and hypothesize that the beneficial effect of Jeju Groundwaters may be contributed from blockade of autoxidation of ferrous ions rather than their high contents of vanadium.

      • KCI등재

        Robust variable selection in partially varying coefficient single-index model

        Huiming Zhu,Zhike Lv,Keming Yu,Chao Deng 한국통계학회 2015 Journal of the Korean Statistical Society Vol.44 No.1

        By combining basis function approximations and smoothly clipped absolute deviation(SCAD) penalty, this paper proposes a robust variable selection procedure for a partiallyvarying coefficient single-index model based on modal regression. The proposed proceduresimultaneously selects significant variables in the parametric components and thenonparametric components. With appropriate selection of the tuning parameters, we establishthe theoretical properties of our procedure, including consistency in variable selectionand the oracle property in estimation. Furthermore, we also discuss the bandwidthselection and propose a modified expectation–maximization (EM)-type algorithm for theproposed estimation procedure. The finite sample properties of the proposed estimatorsare illustrated by some simulation examples.

      • KCI등재

        Parameterized Modeling of Spatially Varying PSF for Lens Aberration and Defocus

        Wang Chao,Chen Juan,Jia Hongguang,Shi Baosong,Zhu Ruifei,Wei Qun,Yu Linyao,Ge Mingda 한국광학회 2015 Current Optics and Photonics Vol.19 No.2

        Image deblurring by a deconvolution method requires accurate knowledge of the blur kernel. Existingpoint spread function (PSF) models in the literature corresponding to lens aberrations and defocus are eitherparameterized and spatially invariant or spatially varying but discretely defined. In this paper, aparameterized model is developed and presented for a PSF which is spatially varying due to lens aberrationsand defocus in an imaging system. The model is established from the Seidel third-order aberrationcoefficient and the Hu moment. A skew normal Gauss model is selected for parameterized PSF geometrystructure. The accuracy of the model is demonstrated with simulations and measurements for a defocusedinfrared camera and a single spherical lens digital camera. Compared with optical software Code V, thevisual results of two optical systems validate our analysis and proposed method in size, shape and direction. Quantitative evaluation results reveal the excellent accuracy of the blur kernel model

      • KCI등재

        Overexpression of the MYB transcription factor MYB28 or MYB99 confers hypersensitivity to abscisic acid in arabidopsis

        Yong-Tao Yu,Zhenwu Zhu,Kai Lu,Chao Bi,Shan Liang,Xiao-Fang Wang,Da-Peng Zhang 한국식물학회 2016 Journal of Plant Biology Vol.59 No.2

        The phytohormone abscisic acid (ABA) plays a vital role in plant development and response to abiotic stress, and many components in ABA signaling remain to be discovered to fully understand the highly complex ABA signaling network. Here we reported that over-expression of MYB28 or MYB99, two R2R3 MYB transcription factors in Arabidopsis thaliana, confers hypersensitivity to exogenous ABA during seed germination, cotyledon greening and early seedling growth. However, both myb28-1 and myb99-1 knockout mutants exhibit wild-type ABA phenotypes most likely due to a functional redundancy of the multiple MYB members. Real-time PCR analysis shows that over-expression of the MYB28 or MYB99 changes expression of a subset of ABA-responsive genes. Collectively, these findings suggest that MYB28 and MYB99 play important, positive roles in ABA signaling during seed germination and early seedling growth.

      • KCI등재

        The role of PDIA3 in myogenesis during muscle regeneration

        Xi Peng,Chao Wang,Yuanjiao Zhu,Dan Wu,Zien Wang,Xiaoli Xu,Yan Shi,Gang Yang,Yongming Yu 생화학분자생물학회 2020 Experimental and molecular medicine Vol.52 No.-

        Beta 3 (β3) integrin plays an important role in the initiation of myogenesis in adult muscle. Protein disulfide isomerases (PDIs) can activate β3 integrin in various cells to promote cell migration, adhesion and fusion. However, the effect of PDIs on myogenesis during muscle regeneration has not been elucidated. Here, we report that PDIA3 expression is induced in regenerating myofibers. The inhibition of PDIA3 in muscle injuries in mice disrupts myoblast differentiation, impairs muscle regeneration, and ultimately aggravates muscle damage. Moreover, PDIA3 expression is upregulated and observed on the cell surfaces of myoblasts during differentiation and fusion. The inhibition of extracellular PDIA3 with an anti-PDIA3 monoclonal antibody attenuates β3 integrin/AKT/mTOR signal activity, inhibits myoblast differentiation, and blocks the fusion of myoblasts. Thus, PDIA3 may be a mediator of myoblast differentiation and fusion during muscle regeneration.

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