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Zhang, Qing,Zhang, Xingyuan,Zhang, Wencheng,Pan, Jian,Liu, Ling,Zhang, Haitao,Zhao, Dong,Li, Zhi Korean Chemical Society 2011 Bulletin of the Korean Chemical Society Vol.32 No.9
Oleanolic acid (OA) as template molecule, polyamide-6 (PA6) as basement membrane and poly(styrene-comaleic acid) (PSMA) were used to prepare PA6/PSMA-OA molecularly imprinted composite membranes by phase inversion method in supercritical $CO_2$ ($ScCO_2$). The template molecule (OA), [poly(styrene-co-maleic anhydride) (PSMAH), PSMA, molecularly imprinted membranes (MIMs) imprinting OA and MIMs after elution were all characterized by Fourier transform infrared spectroscopy (FTIR). The conditions that were the mass ratio between PSMA and OA from 3:1 to 8:1, temperature of $ScCO_2$ from $35^{\circ}C$ to $50^{\circ}C$ and pressure of $ScCO_2$ 12 MPa to 17 MPa were studied. It was obtained the largest adsorption rate and purity of OA after adsorption of the resultant MIMs, 50.41% and 96.15% respectively. After using PA6 film and non-woven fabrics as basement membrane respectively, it was found that smaller aperture of PA6 was used as basement membrane, a higher adsorption rate and a higher purity of OA after adsorption of the MIMs were obtained, and so were the stability and reproducibility of the resultant MIMs. After template molecules being removed, the MIMs had effective selectivity hydrogen bonding to separately bind in the binary components to the template molecules-oleanolic acid.
Qing Zhang,Wencheng Zhang,Jian Pan,Ling Liu,Haitao Zhang,Dong Zhao,Zhi Li,Xingyuan Zhang 대한화학회 2011 Bulletin of the Korean Chemical Society Vol.32 No.9
Oleanolic acid (OA) as template molecule, polyamide-6 (PA6) as basement membrane and poly(styrene-comaleic acid) (PSMA) were used to prepare PA6/PSMA-OA molecularly imprinted composite membranes by phase inversion method in supercritical CO_2 (ScCO_2). The template molecule (OA), [poly(styrene-co-maleic anhydride) (PSMAH), PSMA, molecularly imprinted membranes (MIMs) imprinting OA and MIMs after elution were all characterized by Fourier transform infrared spectroscopy (FTIR). The conditions that were the mass ratio between PSMA and OA from 3:1 to 8:1, temperature of ScCO_2 from 35 ºC to 50 ºC and pressure of ScCO_2 12 MPa to 17 MPa were studied. It was obtained the largest adsorption rate and purity of OA after adsorption of the resultant MIMs, 50.41% and 96.15% respectively. After using PA6 film and non-woven fabrics as basement membrane respectively, it was found that smaller aperture of PA6 was used as basement membrane, a higher adsorption rate and a higher purity of OA after adsorption of the MIMs were obtained, and so were the stability and reproducibility of the resultant MIMs. After template molecules being removed, the MIMs had effective selectivity hydrogen bonding to separately bind in the binary components to the template molecules-oleanolic acid.
Design and simulation analysis of innerouter compound meshing silent-chain plate
Wencheng Wang,Hui Liu,Guoqing Cai,Pengcheng Zhang 대한기계학회 2023 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.37 No.9
This paper proposes a detailed parametric design method for a round-pin innerouter compound meshing silent-chain plate structure. A meshing design method for parameter harmonization among a silent chain, a sprocket hob, and an involute sprocket is proposed. To analyze the influence of extended arc parameters on the meshing process and impact, the extended arc parameter extension δ and height HY are considered as variables to formulate the motion-analysis model of the chain-drive system. The results reveal that the extended arc parameters δ and HY have a significant effect on the meshing process and the meshing impact. When δ and HY are optimal, the inner-outer compound meshing process of the chaindrive system can be smoothly realized; furthermore, the meshing impact force is minimal as it is reduced by more than 25 % compared to when only the outer meshing process occurs. Thus, the chain-plate structure is optimized.
Research on the Supply Chain Risk Assessment Based on the Improved LSSVM Algorithm
Wencheng Liu,Xianrong Zhang 보안공학연구지원센터 2016 International Journal of u- and e- Service, Scienc Vol.9 No.8
In the increasingly fierce market competition, the survival environment that enterprises are facing is increasingly harsh. This makes the supply chain is facing more and more uncertainly factors gradually on the operating environment. In addition, this increases the likelihood of the risk. Therefore, the research on the supply chain risk assessment has the important practical significance. In this paper, we put forward the assessment indexes of the supply chain risk. Then, we use the improved ACO method to optimize the parameters of the LSSVM method and we propose the improved LSSVM method. After that, we use the method to assess and study the risk of the supply chain. Finally, the experiment indicates that the reliability and validity of the evaluation system.
Jinhua Zhang,Huiyue Qian,Wencheng Liu,Hao Chen,Yang Qu,Zhidong Lin 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.6
A heterostructural composite composed of g-C3N4 and Bi2O3 was achieved by the one-pot and thermal-induced polycondensation method using melamine and Bi(NO3)3 as precursor at 550 ℃ under air atmosphere. The crystalline phase, components and morphologies of the as-prepared composites were investigated by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). Besides, the photocatalytic activity of composites was evaluated by degrading RhB aqueous solution at room temperature under visible light irradiation. Compared with bulk g-C3N4, the photocatalytic efficiency of the 0.5% Bi2O3/g-C3N4 (Bi–CN) was increased by up to four times. The introduction of Bi2O3 enhances not only the light absorption ability, but also the separation of photogenerated electron–hole pairs.
Proposals for the Development Trend of Copycat Product in China
Chenchuang,Zhang Mingyu,Wang Wencheng 인하대학교 정석물류통상연구원 2009 인하대학교 정석물류통상연구원 학술대회 Vol.2009 No.10
Copycat products in China are currently mainly in the condition of imitating the products of international companies and innovating their new products in terms of design and function. During the conversion process of enhancing brand, further developing the innovation and applying for a patent, many problems existed such as copycat inertia, disordered competition, low-end value chain and co existence of both well-run and ill-run enterprises. Therefore, a series of ideas are proposed in this article for the further development of copycat industry.
Xueqin Zhang,Wencheng Tu,Meitian Xiao,Yongjun Liu,Jing Ye 한국물리학회 2017 Current Applied Physics Vol.17 No.10
A one-step approach was developed to prepare carbon covered alumina (CCA) material by using Al-based MOFs (Al-PCP) as sacrificial template. Pt/CCA nanoparticle catalysts were characterized by using XRD, TGA, XPS, N2 sorption, SEM, TEM and elemental analysis and revealed that they retained the mesostructure with high Pt dispersion and had a CCA structure. Moreover, after reduced at 800 C, Pt/CCA-800 afforded the highest enantiomeric excess (84.8%) after chirally modified with cinchonidine at the second time reaction and can be recycled for more than 8 times without distinct loss of activity or enantioselectivity in the asymmetric hydrogenation of ethyl 2-oxo-4-phenylbutyrate.