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전력계통 구조물의 상태진단용 자가발전 무선 센서 노드 개발 및 평가
김창일 ( Chang Il Kim ),정영훈 ( Young-hun Jeong ),윤지선 ( Ji Sun Yun ),홍연우 ( Youn Woo Hong ),장용호 ( Yong-ho Jang ),최범진 ( Beom-jin Choi ),박신서 ( Shin-seo Park ),손천명 ( Chun Myung Son ),서덕기 ( Duck Ki Seo ),백종후 ( 한국센서학회 2016 센서학회지 Vol.25 No.5
A self-powered piezoelectric energy harvester was developed for the application in wireless sensor node. The energy harvester was evaluated with power generation characteristics for the wireless sensor node for structural diagnosis of the electric power system. The self-powered wireless sensor node was set to measure temperature, vibration frequency of the electric power system. A piezoelectric harvester composed of 7 uni-morph cantilevers (functionalized as 6 generators and 1 vibration sensor) was connected to be an array and revealed to produce significantly high output power of approximately 10 mW at 120 Hz under 3.4 g((1 g = 9.8 m/sec²). The wireless sensor node could work as the electric power generated by the developed piezoelectric harvester.
홍창일,김선구,김유진,이세일,Hong, Chang-Yil,Kim, Sun-Goo,Kim, Yu-Jin,Lee, Se-Il 대한성형외과학회 2010 Archives of Plastic Surgery Vol.37 No.4
Purpose: Facial tumor excision is a common cause of lower eyelid defect in old patients. Many methods have been introduced for the reconstruction of lower eyelid. However, conventional surgical method can cause various complications like scar, ectropion and unnatural color matching. Thus, we introduce a simple and aesthetically acceptable method for the reconstruction of lower eyelid defect. Methods: Three elderly patients with skin cancer in the unilateral lower eyelid were operated by the new method. Following a wide excision of skin cancer, subcilliary incision of lower blepharoplasty was carried out. Elevated skin flap of lower eyelid was redrapped for the correction of defect and the remnant skin from lateral portion of lower eyelid was used for full thickness skin graft (FTSG) to correct the remaining defect. Results: All grafts survived and color match of the graft was excellent without ectropion. Furthermore, wrinkles of the lower eyelid were improved after the blepharoplasty. Conclusion: Lower eyelid defect resulting from wide excision of malignant tumor in old patients could be reconstructed successfully by modifying the conventional lower eyelid blepharoplasty along with FTSG using the remnant skin.
Streptococcus dysgalactiae로부터 분리된 히알루론산과 황화된 유도체의 구조와 항염증 활성
홍창일(Chang-Il Hong),정의길(Eui-Gil Jung),한국일(Kook-Il Han),김용현(Yong Hyun Kim),이성희(Sung Hee Lee),이홍섭(Hong Sub Lee),한만덕(Man-Deuk Han) 한국생명과학회 2016 생명과학회지 Vol.26 No.5
히알루론산(HA, Hyaluronic acid)은 β-1, 3-N-acetyl glucosamine과 β-1, 4-glucuronic acid가 반복된 선형 폴리머 고분자로서 생물학적 활성 및 생체친화성 특성 때문에 의약 및 약학분야에서 중요한 분자로 여겨지고 있다. 본 연구는 HA을 S. dysgalactiae으로 얻고, 화학적 방법을 통해 황화된 히알루론산(S-HA, Sulfated hyaluronic acid)유도체를 합성하여 그 구조와 항염증 활성을 비교하였다. HA의 생산은 S. dysgalactiae를 5 l 생물반응기를 이용하여 대량 배양하여 수용성 히알루론산(HA-WS, water soluble hyaluronic acid)과 비수용성 히알루론산(HA-WI, water insoluble hyaluronic acid)을 분리 정제하였다. 특히 HA-WI를 황화시켜 황화된 히알루론산(S-HA) 유도체를 합성하였으며, 그 수율은 90%로 나타났다. 합성된 S-HA의 구조를 FT-IR 및 ¹H/<SUP>13</SUP>C-NMR를 통해 S. dysgalactiae 로부터 생산된 표준 HA, HA-WS 및 HA-WI와 비교 분석한 결과, 황으로 치환된 양상을 확인하였다. 또한, S-HA의 항염증 활성을 RAW 264.7 대식세포를 통해 확인한 결과, S-HA는 천연 형태의 HA (HA, HA-WS)보다 nitric oxide (NO)와 COX-2 및 PGE₂ 유전자 발현이 유의하게 낮게 발현되었다. 염증 매개 cytokine인 TNF-α (<80 pg/ml) 및 IL-6 (<100 pg/ml)의 생성도 S-HA가 천연 HA보다 낮은 수준으로 정량되었다. 이 같은 결과에서 황화된 S-HA은 천연 히알루론산보다 용해성이 우수하고 염증관련 사이토카인의 생성 억제를 통해 항염증 효과를 나타내므로 염증치료제, 성형 및 생체 적용 약물전달 소재로 그 활용이 기대된다. Hyaluronic acid (HA) is an important macromolecule in medical and pharmaceutical fields. HA is a natural and linear polymer composed of repeating disaccharide units of β-1, 3-N-acetyl glucosamine and β-1, 4-glucuronic acid. This work aimed to confirm the structural characteristics and anti-inflammatory activities of HA and its chemically sulfated-HA. HA was produced from a fed-batch fermentation process using Streptococcus dysgalactiae in a 5 l bioreactor. HA was isolated water-soluble form (HA-WS) and water-insoluble form (HA-WI) from culture medium, and was obtained chemically sulfated-derivative (S-HA) that resulted in a 90% yield from HA-WI. The structural features of the sulfated- HA (S-HA) were investigated by FT-IR and ¹H-NMR spectroscopy. The FT-IR and NMR patterns revealed the similarity in both the FTIR spectrum as well as NMR spectrum of both reference standard and purified HA from S. dysgalactiae. The anti-inflammatory activities of HA and S-HA were examined on LPS-induced RAW 264.7 cells. S-HA was significantly inhibited production of pro-inflammatory mediators such as nitric oxide (NO) and PGE₂ and the gene levels of iNOS and COX-2, which are responsible for the production of NO and PGE₂, respectively. Furthermore, S-HA also suppressed the overproduction of pro-inflammatory cytokine TNF-α (<80 pg/ml) and IL-6 (<100 pg/ml) compared to that of HA-WI. The present study clearly demonstrates that HA-S exhibits anti-inflammatory activities in RAW 264.7 macrophage cells.
진동 각도에 따른 유니몰프 압전 캔틸레버의 발전특성연구
김창일 ( Chang Il Kim ),윤지선 ( Ji Sun Yun ),박운익 ( Woon-ik Park ),정영훈 ( Young-hun Jeong ),홍연우 ( Youn Woo Hong ),조정호 ( Jeong-ho Cho ),백종후 ( Jong Hoo Paik ) 한국센서학회 2017 센서학회지 Vol.26 No.2
Energy source of a piezo-electric harvester is vibration. Sources of vibration are machineries operated with high frequencies, constructions and people operated with low frequencies and etc. In this study, we tried to figure out power generation properties over vibrations upon angles of a piezo-cantilever for applying them to movements of the construction and/or people, which are vibration sources at low frequencies. A uni-morph cantilever with a 59 mm × 29 mm × 0.2 mm piezo-electric element attached on a 71 mm × 46 mm × 0.25 mm copperplate was used. A spring was attached to the lower side of the cantilever and a mass was attached on the opposite side. Also, a structure with a specific angle which is an angle in between the ground and the cantilever was prepared and then, connected to a spring or the cantilever. Then, this structure was divided into the A-type and B-type and excited in the direction of z- axis. After that, the angle between the ground and the cantilever was changed and excited by 1 to 10 Hz upon the existence of a spring and/or a mass to compare power generation properties.
방전 플라즈마 소결법에 의한 ZnS 나노입자의 소결과 광학적 특성
김창일,김유비,여서영,홍연우,윤지선,박운익,정영훈,조정호,백종후,Kim, Chang-Il,Kim, You-Bi,Yeo, Seo-Yeong,Hong, Youn-Woo,Yun, Ji-Sun,Park, Woon-Ik,Jeong, Young-Hun,Cho, Jeong-Ho,Paik, Jong-Hoo 한국전기전자재료학회 2017 전기전자재료학회논문지 Vol.30 No.6
Zinc sulphide (ZnS) nanoparticles were fabricated by hydrothermal synthesis at $180^{\circ}C$ for 12 h. Two kinds of ZnS powder (hydrothermal synthesized ZnS and commercial ZnS) were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM) for phase and microstructure, respectively. The XRD patterns showed that all ZnS nanoparticles have a sphalerite (cubic) structure. The nanoparticles of two different ZnS powders were sintered by spark plasma sintering. The sintered ZnS were analyzed by XRD, SEM, and FT-IR. We found that the transmittance of the infrared region is highly dependent on the density and crystal structure of sintered ZnS and the purity of the starting ZnS powder.
3-3 진동 모드 압전 캔틸레버 에너지 하베스터의 제조 및 전기적 특성
이민선,김창일,윤지선,박운익,홍연우,백종후,조정호,박용호,장용호,최범진,정영훈,Lee, Min-seon,Kim, Chang Il,Yun, Ji-sun,Park, Woon-ik,Hong, Youn-woo,Paik, Jong-hoo,Cho, Jeong-ho,Park, Yong-ho,Jang, Yong-ho,Choi, Beom-jin,Jeong, Young-hu 한국전기전자재료학회 2017 전기전자재료학회논문지 Vol.30 No.5
A piezoelectric cantilever energy harvester (PCEH) driven in longitudinal (3-3) vibration mode was fabricated, and its electrical properties were evaluated by varying the resistive load. A commercial PZT piezoelectric ceramic with a high piezoelectric charge constant ($d_{33}$) of 520 pC/N and the interdigitated (IDT) electrode pattern was used to fabricate the PCEH driven in longitudinal vibration. The IDT Ag electrode embedded piezoelectric laminates were co-fired at $850^{\circ}C$ for 2 h. The 3-3 mode PCEH was successfully fabricated by attaching the piezoelectric laminates to a SUS304 elastic substrate. The PCEH exhibited a high output power of 3.8 mW across the resistive load of $100k{\Omega}$ at 100 Hz and 1.5 G. This corresponds to a power density of $10.3mW/cm^3$ and a normalized global power factor of $4.56mW/g^2{\cdot}cm^3$. Given the other PCEH driven in transverse (3-1) vibration mode, the 3-3 mode PCEH could be better for vibration energy harvesting applications.
표면처리에 의한 Carbon Black 의 표면물성변화
이창우,이창일,홍영호,홍인권,장윤호,함영민 ( Chang Woo Lee,Chang Il Lee,Young Ho Hong,In Kwon Hong,Yun Ho Jang,Yeong Min Hahm ) 한국공업화학회 1996 공업화학 Vol.7 No.4
카본블랙은 일반적으로 보강성, 착색성, 내후성, 내화학성 및 전기적 전도성 등의 다양한 특성을 가지고 있으나 매질과의 친화력이 낮아 이용하는데 어려움을 내포하고 있다. 따라서 본 연구에서는 카본블랙의 표면특성을 변화시켜 매질과의 친화력을 향상시키기 위하여 표면에 비교적 많은 기능기를 가지고 있는 channel black은 표면 카르복실기의 수소를 알칼리 금속과 치환하였고, 표면 기능기가 거의 존재하지 않는 furnace black은 질산으로 처리하였다. 이와 같이 표면의 특성을 변화시켜 카본블랙의 물성변화를 측정하고, 수용액 속에서의 분산특성을 연구하여 다음과 같은 결론을 얻을 수 있었다. 표면처리된 channel black의 경우 치환된 금속(Li, Na, K)의 이온반경이 증가함에 따라 입자 표면의 수화도 증가로 인하여 분산성이 향상되었고, 질산처리한 furnace black의 경우 산의 농도 및 반응온도에 비례하여 표면 기능기의 증대를 가져왔으며 반응시간에는 크게 영향을 받지 않음을 알 수 있었다. 또한 전해질 용액에서 pH 변화에 따른 제타전위를 측정한 결과 카본블랙 입자의 표면 전하밀도가 증가하고, 이에 따른 전기적 반발력 증가로 인한 분산성의 향상과 비교적 안정한 계를 이루고 있음을 확인하였다. Carbon Black has various advantageous properties such as reinforcement, tinting, weathering, chemical resistance, electrical resistance, etc., but it has poor affinity in the solution. The purpose of this study is to enhance dispersion in the aqueous solution by altering the surface characteristics. Two different treatments were applied for both channel black and furnace black respectively. Channel black was treated in alkaline solution to replace hydrogen of the carboxyl group with alkaline metal, Li, Na, K. Furnace black has few functional groups, and it was treated with HNO₃to increase the number of functional group on carbon black. It was seen that the substitution of alkaline metal on the surface of channel black enhances the degree of dispersion. Also the higher the acid concentration and reaction temperature, the more the number of some functional groups on the furnace black. Reaction time was not seen to be effective.
IDT 전극 패턴 임베디드 압전 에너지 하베스터의 특성
이민선,김창일,윤지선,박운익,홍연우,백종후,조정호,박용호,장용호,최범진,정영훈,Lee, Min-seon,Kim, Chang-Il,Yun, Ji-sun,Park, Woon Ik,Hong, Youn-Woo,Paik, Jong Hoo,Cho, Jeong Ho,Park, Yong-Ho,Jang, Yong-Ho,Choi, Beom-Jin,Jeong, Young-Hu 한국전기전자재료학회 2016 전기전자재료학회논문지 Vol.29 No.9
Piezoelectric thick films of a soft $Pb(Zr,Ti)O_3$ (PZT) based commercial material were produced by a conventional tape casting method. Thereafter, the interdigitated (IDT) Ag-Pd electrode pattern was printed on the $25{\mu}m$ thick piezoelectric film at room temperature. Co-firing of the 10-layer laminated piezoelectric thick films was conducted at $1,100^{\circ}C$ and $1,150^{\circ}C$ for 1 h, respectively. Piezoelectric cantilever energy harvesters were successfully fabricated using the IDT electrode pattern embedded piezoelectric laminates for 3-3 operation mode. Their energy harvesting characteristics were investigated with an excitation of 120 Hz and 1 g under various resistive loads (ranging from $10k{\Omega}$ to $200k{\Omega}$). A parabolic increase of voltage and a linear decrease of current were shown with an increase of resistive load for all the energy harvesters. In particular, a high output power of 3.64 mW at $100k{\Omega}$ was obtained from the energy harvester (sintered at $1,150^{\circ}C$).
Hard PZT IDE 유니몰프 캔틸레버의 압전 에너지 하베스팅 특성
이민선,김창일,윤지선,박운익,홍연우,조정호,백종후,박용호,장용호,최범진,정영훈,Lee, Min-seon,Kim, Chang-il,Yun, Ji-sun,Park, Woon-ik,Hong, Youn-woo,Cho, Jeong-ho,Paik, Jong-hoo,Park, Yong-ho,Jang, Yong-ho,Choi, Beom-jin,Jeong, Young-hu 한국전기전자재료학회 2017 전기전자재료학회논문지 Vol.30 No.8
A unimorph piezoelectric cantilever generator with an interdigitated electrode (IDE) was developed for vibration energy harvester applications driven in the longitudinal mode. Hard lead zirconate titanate (PZT) ceramic with a high $Q_m$ of 1,280 was used as the piezoelectric active material. Ten PZT sheets produced by tape casting were laminated and co-fired with an Ag/Pd IDE at $1,050^{\circ}C$ for 2 h. The approximately $280{\mu}m$-thick co-fired PZT laminate with the IDE was attached to a stainless steel substrate with an adhesive epoxy for the fabrication of an IDE unimorph cantilever. Its energy harvesting characteristics were evaluated: an output power of $1.1{\mu}W$ at 120 Hz across the resistive load of $700k{\Omega}$ was obtained, corresponding to a normalized power factor of $4.1{\mu}W/(G^2{\cdot}cm^3)$.