황에 저항성을 가지는 수성가스 전환반응 촉매의 연구 II. CoMo 촉매의 활성에 미치는 알칼리 금속염의 영향

김준희,이호인,Kim, Joon Hee,Lee, Ho In 대한화학회 1998 대한화학회지 Vol.42 No.6

황피독에 저항성을 가지는 수성가스 전환반응용 CoMo 계열 촉매에 알칼리금속염 첨가가 반응활성에 미치는 영향에 대하여 연구하였다. 알칼리금속염의 음이온과 양이온의 각각에 대한 영향을 알아보기 위하여 크게 두 경우로 나누어 촉매를 제조하였다. 그 하나는, 양이온을 K로 고정시키고 음이온을 변형시킨 경우로서, 반응활성의 변화는 BET 표면적의 변화로 설명되었다. 다른 한 경우는, 음이온을 $NO_3^-$로 고정시키고 알칼리금속 이온을 변형시킨 경우로서, Li가 첨가된 촉매의 활성이 가장 뛰어났으며 다른 양이온의 경우에는 서로 비슷한 낮은 활성을 보였다. 알칼리금속의 첨가량의 변화에 따른 BET 표면적의 변화와 반응활성의 변화가 같은 경향을 보였다. 알칼리금속염의 양이온을 변화시킨 경우에는 BET 표면적과 정8면체 배위구조 속의 $Mo^{6+}$에 대한 정4면체 배위구조 속의 $Mo^{6+}$의 비, 즉 $Mo^6+[T]/Mo^{6+}[O]$ 값의 복합적인 관계를 통해 반응활성의 변화를 설명할 수 있었다. The effect of alkali metal salt on the activity of Co-Mo catalyst which has high resistance to sulfur poisoning for water gas shift reaction(WGSR) was studied. Two groups of catalysts were prepared to investigate the effects of anion and cation in alkali metal salts. For K-doped catalysts made with various potassium salts having different anion, the catalytic activity was explained to depend mainly on the BET surface area. Among the catalysts prepared by various nitrates of alkali metal as precursor, the Li-doped catalyst showed the best activity, and the others did not make significant differences giving relatively low activities. And the change of BET surface area by varying the loading of alkali metal showed a similar trend to that of activity. In this case, the activity was dependent on both BET surface area and the ratio of $Mo^{6+}$ with a tetrahedral coordination symmetry to $Mo^{6+}$ with an octahedral one, $Mo^6+[T]/Mo^{6+}[O]$ value.

감기 임상시험 가이드라인 제정을 위한 최신 임상시험 연구 분석

김관일,이호정,이범준,정희재,정승기,이준희,Kim, Kwan-il,Lee, Ho-jung,Lee, Beom-joon,Jung, Hee-jae,Jung, Sung-ki,Lee, Jun-hee 대한한방내과학회 2016 大韓韓方內科學會誌 Vol.37 No.1

Objectives: The aim of this study was to help develop a guideline for the common cold. We searched recent clinical studies of the common cold in Western medicine and reviewed their objectives, inclusion and exclusion criteria, primary outcome, secondary outcome, and assessment tools to establish evidenced-based guideline.Methods: We searched electronic databases (Cochrane Library, MEDLINE, EMBASE) to identify eligible randomized controlled trials (RCTs) about the common cold for the last 10 years. We included 29 RCTs and showed their research summary via their objectives, participants, interventions, control, treatment duration, and results. We also analyzed the definition of the common cold presented in the article, inclusion and exclusion criteria, primary and secondary outcomes, and assessment tools.Results: We reported the aforementioned areas in detail. At first, the definition of the common cold was confused across the articles. Second, herbal medication clinical trials for the common cold have been extensively studied recently. Third, the eligibility criteria frequently included the Jackson Symptom score. Fourth, validated assessment tools (i.e., the Wisconsin Upper Respiratory Symptom Survey-21) have only been used in a few recent studies.Conclusions: Our research will be helpful to establish Korean herbal medicine clinical trial guidelines for the common cold.

연구논문 - 촉매분과 : 수성가스 전환반응용 CoMo 촉매의 활성에 미치는 알칼리 금속염의 영향

김준희,이호인 ( Joon Hee Kim,Ho In Lee ) 한국공업화학회 1997 한국공업화학회 연구논문 초록집 Vol.1990 No.3

N/A Effects of alkali metals and anions on CoMo catalysts for water gas shift reaction were studied. For CoMo/γ-Al₂O₃ catalysts made by impregnation, the doping of alkali metals like lithium enhanced the activity. For K-doped catalysts made with the potassium salts having different anions, the activity increased with increasing BET surface area. Among the catalysts prepared by nitrates as precursor, Li-doped catalyst showed the best activity, and the others did not make significant differences giving a relatively low activity. Both BET surface area and TPR did not show significant differences in the catalysts doped with alkali metals in the form of nitrates. However, the activity of the Li-doped catalyst was remained relatively constant with the amount of Li doped, whereas those of other catalysts changed with the amount of Li doped.

욕지도(경남) 산림식생 유형구분과 공간분포 특성

이보라,이호상,김준수,조준희,오승환,조현제,Lee, Bora,Lee, Ho-Sang,Kim, Jun-Soo,Cho, Joon-Hee,Oh, Seung-Hwan,Cho, Hyun-Je 한국산림과학회 2022 한국산림과학회지 Vol.111 No.3

욕지도는 한반도 남동부 남해안의 끝에 위치하고 있는 섬 크기 15 km²의 유인도서로 현존산림은 대부분 대상식생(substitutive vegetation)으로 구성되어 있다. 본 연구는 욕지도 산림식생의 생태적 보전과 관리에 필요한 기초정보 제공을 위하여 식물사회학적 방법을 적용하여 현존식생 유형을 구분하고 상관 우점종 중심의 현존식생도를 작성하여 공간적 분포특성을 파악하였다. 현존식생은 총 8개 유형으로 구분되었고, 2개 군락(community), 4개 아군락(subcommunity), 6개 변군락(variant), 그리고 2개 아변군락(subvariant)의 식생단위 체계로 구성되어 있었으며, 대개 인간간섭, 입지환경, 천이단계, 그리고 성립기간 등에 따라 종조성적 차이를 반영하고 있었다. 종다양성 지수는 현존식생 유형 간 모두 유의한 차이가 있었는데, 전반적으로 종풍부도, 종다양도, 그리고 종균재도는 해발고도가 높아짐에 따라 통계적으로 다소 유의한 증가 경향을 보였으며, 초본성 식물종이 가장 높은 정(+)의 상관관계를 보였다. 이러한 결과는 비교적 낮은 해발고도를 가진 산지에서는 중간영역효과(mid-domain effect, MDE)로 해발고도가 높아짐에 따라 종다양성이 증가한다는 McCain의 연구 결과와 일치하는 경향을 보였다. 욕지도 산림식생은 외부간섭이 없는 한 혼효림 도중 단계를 거쳐 잠재적으로 상록활엽수가 우점하는 산림으로 천이가 이루어질 것으로 판단되었다. Yokjido is a 15-km² inhabited island located at the tip of the southeastern coast of the Korean Peninsula. Its forest is mostly composed of substitutional vegetation. Our aim was to provide basic information necessary for the conservation and management of the forest vegetation in Yokjido. We classified the types of existing vegetation using methods of the Zurich-Montpellier school of phytosociology. The resulting vegetation map shows the dominant tree species in the top canopy-layer. A total of 8 vegetation types were identified, which were arranged into a vegetation unit hierarchy of 2 communities, 4 sub-communities, 6 variants, and 2 subvariants. Evaluations of each type showed large and small differences in floristic composition, which reflect anthropogenic influences, site conditions, succession stages, and the establishment period. Moreover, vegetation types differed significantly in terms of species diversity indices; in particular, overall species richness, species diversity, and species evenness tended to increase significantly as the elevation increased. The herbaceous plant species showed the highest positive (+) correlation to x. These results were consistent with those of McCain, who reported that species diversity increases in mountainous areas with relatively low elevations due to the mid-domain effect. The forest succession in Yokjido will potentially enter a mixed-forest stage and then proceed to become an all-evergreen broad-leaved forest.

직접 메탄올 연료전지용 산화극 제조 변수가 성능에 미치는 영향

김준희,하흥용,오인환,홍성안,이호인,Kim, Joon-Hee,Ha, Heung-Yong,Oh, In-Hwan,Hong, Seong-Ahn,Lee, Ho-In 한국전기화학회 2003 한국전기화학회지 Vol.6 No.1

Single cell performance has been investigated and characterized with variables in the fabrication of DMFC anode. The performance was checked as a function of ionomer content which affects ion conductivity in the catalyst layer, and catalyst slurry solvent which determines structure of agglomerates consisting of an ionomer and a catalyst. Anode with total ionomer to catalyst ratio of 0.6 showed the best performance and the lowest polarization resistance. Also, electrochemically effective surface area increased with ionomer content. As solubility of the ionomer decreases with decreasing solvent polarity, the size of agglomerates consisting of a catalyst and an ionomer became larger in the less polar solvent. The anode using DPK $(\varepsilon=12.60)$ as a solvent, which is less polar than generally-used water or alcohol species, showed the maximum performance and the lowest polarization resistance. 직접 메탄을 연료전지(DMFC)의 산화극 제조 변수들에 따른 단위전지의 성능변화 관찰 및 특성분석을 수행하였다. 촉매층에서의 이온 전도도에 영향을 주는 이오노머의 양과, 이오노머와 촉매의 결합구조를 결정하는 촉매 슬러리의 용매를 변수로 하였다 전체 이오노머의 비가 0.6일 때 최고 성능을 보였으며 분극 저항도 가장 작게 나타났다. 전기화학적 활성면적도 이오노머가 늘어날수록 증가하였다. 극성이 작은 용매일수록 이오노머가 잘 용해되지 않아 촉매 응집체의 크기가 커졌다 기존의 물이나 알코올 종류의 용매들에 비해 극성이 낮은 DPK $(\varepsilon=12.60)$를 사용하여 제조한 전극이 가장 높은 성능을 보였으며 낮은 분극 저항 값을 가졌다.

용융탄산염 연료전지에서 알칼리 탄산염에 의한 Ni/MgO 촉매의 피독

문형대(Hyeung Dae Moon),김준희(Joon Hee Kim),하흥용(Heung Yong Ha),임태훈(Tae Hoon Lim),홍성안(Sung Ahn Hong),이호인(Ho In Lee) 한국공업화학회 1999 공업화학 Vol.10 No.5

N/A N/A

연구논문 : 의약화학 ; 만가닥버섯에서 분리된 hypsiziprenol A의 HepG2 세포주기진행의 저해효과

장종선 ( Jong Sun Chang ),손종근 ( Jong Keun Son ),이호 ( Gao Li ),오은정 ( Eun Jung Oh ),김지영 ( Ji Young Kim ),박선희 ( Sun Hee Park ),배준태 ( Joon Tae Bae ),김현정 ( Hyun Jeong Kim ),이인선 ( In Seon Lee ),김옥미 ( Ok Mi Kim 영남대학교 약품개발연구소 2004 영남대학교 약품개발연구소 연구업적집 Vol.14 No.-

수성가스 전환반응용 CoMo 촉매의 활성에 미치는 알칼리 금속염의 영향

김준희,이호인 한국공업화학회 1997 응용화학 Vol.1 No.2

Effects of alkali metals and anions on CoMo catalysts for water gas shift reaction were studied. For CoMo/γ-Al₂O₃ catalysts made by impregnation, the doping of alkali metals like lithium enhanced the activity. For K-doped catalysts made with the potassium salts having different anions, the activity increased with increasing BET surface area. Among the catalysts prepared by nitrates as precursor, Li-doped catalyst showed the best activity, and the others did not make significant differences giving a relatively low activity. Both BET surface area and TPR did not show significant differences in the catalysts doped with alkali metals in the form of nitrates. However, the activity of the Li-doped catalyst was remained relatively constant with the amount of Li doped, whereas those of other catalysts changed with the amount of Li doped.

Conditioning Effect on the Performance of Direct Methanol Fuel Cell

Kim, Joon-Hee,Ha, Heung Yong,Oh, In-Hwan,Hong, Seong-Ahn,Lee, Ho-In 한국공업화학회 2004 응용화학 Vol.8 No.1

Appropriate conditioning process is required prior to a steady-state operation of direct methanol fuel cell (DMFC). Different methods for conditioning a membrane-electrode assembly (MEA) were applied, and the conditioning periods were generally between 12 and 48 hours except in a special case. The conditioning process affected the cell performance by some variables such as conditioning temperature, circulation of reactants, and application of electric load. In this study, we identified the major factor for it and elucidated the phenomena occurring in the anode during conditioning. In order to measure the resistance and the capacitance affecting the performance of MEAs, Nyquist plots were obtained by using an impedance analysis technique.

사람 정상중이점막 상피세포의 계대 배양과 분비세포로의 분화 유도

이호기,윤주헌,박홍준,문성균,정명현,김희남 대한이비인후과학회 1999 대한이비인후과학회지 두경부외과학 Vol.42 No.8