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제올라이트 4A 분리막을 이용한 물/메탄올, 물/부탄올 혼합물의 투과증발 특성 연구: 실험 및 모형
문종호,오웅진,정재칠,여정구,이정현,김현욱,박영철,이동호,조철희 한국막학회 2017 멤브레인 Vol.27 No.6
본 연구에서는 (주)파인텍에서 제조한 제올라이트 4A 분리막을 이용하여 물/메탄올, 물/부탄올 혼합물의 투과증발 실험을 수행하였다. 분리막을 투과한 기체분자들은 액체질소트랩을 이용하여 포집하였으며, 기체크로마토그래피(TCD)를 이용하여 혼합물의 조성을 분석하였다. 실험을 통해 물과 메탄올(분리계수 최대 250 이상), 물과 부탄올(분리계수 최대 1,500 이상)의 혼합물에서 선택적으로 물을 분리하는 것을 확인하였다. GMS (generalized Maxwell Stefan) 이론을 적용하여 2성분 계의 투과증발 거동을 모사하였으며, 상수추정을 통하여 제올라이트 비지지체의 흡착상수 및 확산상수를 구하였다. 제올라이트 4A 분리막의 경우 기공의 크기가 물보다는 크고, 메탄올, 부탄올 보다는 작기 때문에, 알코올로부터 물을 분리시키는 공정에 적용시킬 수 있다. 바이오 에탄올 분리, 부탄올 분리, 막반응기, 하이브리드 반응-탈수 공정 등에 적용할 수 있을 것으로 사료된다. In this study, pervaporation performances of water/methanol and water/butanol mixture were evaluated using zeolite 4A membranes manufacutred by FINETECH by experimental works and numerical modeling. Permeation and separation characteristics, such as flux and separation factor, were analyzed by gas chromatography (TCD) and liquid nitrogen traps. Experiments have shown that water is selectively separated from a mixture of water and methanol (separation factor up to approximately 250) and water and butanol (separation factor up to approximately 1,500). Generalized Maxwell Stefan (GMS) theory was implemented to predict pervaporation behaviors of water/alcohol mixtures and diffusional coefficients of zeolite layer were obtained through parameter estimation using MATLAB Ⓡ optimization toolbox. Since the pore size of zeolite 4A are much larger than kinetic diameter of water molecules and smaller than those of methanol and butanol, zeolite 4A membranes can be applied to in situ water removal process such as membrane reactors or hybrid reaction-dehydration process.
문종호 한국공업화학회 2020 한국공업화학회 연구논문 초록집 Vol.2020 No.-
In this study, newly measured experimental data of carbon dioxide (CO<sub>2</sub>) solubilities in aqueous MEA (primary), DIPA (secondary), MDEA (tertiary), AMP (steric hindrance) and their mixture solutions are provided with thermodynamic models, such as Kent Eisenberg, Deshmukh Mather, electrolyte NRTL, electrolyte UNIQUAC models. The solubility measurements were carried out over a wide temperature range (313.15-403.15 K) and at various amine concentration conditions (20, 30, and 40 wt%) with static method. CO<sub>2</sub> partial pressure, liquid phase concentrations for all components including carbamates and bicarbonate, pH, the heats of absorption, and cyclic capacity for all amine concentrations, temperatures, and CO<sub>2</sub> loading conditions could obtained by using in house model.
IgE 수용체발현 및 혈청 IgE 농도와 T림프구 활성의 관계
문종호,이남민,김현태,어수택,정연태,김용훈,박춘식 대한천식알레르기학회 1991 천식 및 알레르기 Vol.11 No.3
The activation of T lymphocytes in peripheral blood and bornchial biopsies has been reported in patients with bronchial asthma, Thus we measured the concentration of serum IgE, specific IgE, subsets of lymphocyte, and its expression of FceRII, interleukin-2 receptor(IL -2R) and HLA-DR in 131 patients with bronchial asthma and 58 normal subjects to seacrh the effect of activation of T lymphocyte on the synthesis of IgE The results were as follows '. 1) The concentration of serum IgE was higher in patients with extrinsic and intrinsic bronchial asthma (EBA, IBA) and atopic control when compared with that of normal control (p<0. 05). And the IgE was lower in EBA with immunotherapy when compared with that of EBA without immunotherapy. 2) The percentage of FceRII positive non-T lymphocyte was higher in EBA when compared with that of IBA and normal control(p<0.05). But the percentage of FcRII positive non-T lymphocyte was well correlated with that af FceRII positive T lymphocyte in norrnal contrd and patients with bronchial asthma(r=0.2283, p =0.003). 3) The concentration of serum IgE was nat correlated with the concentraion of specific IgE and the percentage of FceRII positive non -T lytnphocyte, but the concentration of specific IgE was well correlated with the percentage af FcRII positive non-T lymphocyte(r=0.3613, p =0. 0015) . 4) The percentage of IL-2R positive T lymphocyte was higher in atopic control, IBA and EBA when compared with that of normal control, and the percentage of IL-2R positive helper T cell was higher in IBA when compared with that of normal control, The percentage af FcRII positive non-T lymphocyte was well correlated with the percentage of helper T cell, IL-2R positive helper T cell, HLA-DR positive T lymphocyte in normal control and patients with IBA and EBA. As result the activation of peripheral lymphocyte, especially helper T cell, may affect the synthesis of serurn IgE via the FceRII positive non- T lymphocyte.