용매열법을 이용한 CuInSe₂ 나노 입자 합성

김기현,전영갑,박병옥,윤경훈,Kim Ki-Hyun,Chun Young-Gab,Park Byung-Ok,Yoon Kyung-Hoon 한국재료학회 2004 한국재료학회지 Vol.14 No.10

$CuInSe_2$ (CIS) nanoparticles of chalcopyrite structure were directly synthesized by a solvothemal method in an autoclave with diethylamine as a solvent. A morphology change of the nanoparticles was observed as a function of reaction temperatures and times. Dense rod-type CIS nanoparticles with width of $5\sim10mm$ and length in the range of 30-80 nm were obtained at $180^{\circ}C$ for 36 hrs whereas spherical particles with diameter in the range of 5-10 nm were observed at $250^{\circ}C$ for 36 hrs. The formation of the rod-like nanoparticles in diethylamine, without double N-chelation, was explained by the Solution-Liquid-Solid (SLS) mechanism.

JFET 영역의 이중이온 주입법을 이용한 Power MOSFET의 온저항 특성에 관한 연구

김기현,김정한,박태수,정은식,양창헌,Kim, Ki Hyun,Kim, Jeong Han,Park, Tae-Su,Jung, Eun-Sik,Yang, Chang Heon 한국전기전자재료학회 2015 전기전자재료학회논문지 Vol.28 No.4

Device model parameters are very important for accurate estimation of electrical performances in devices, integrated circuits and their systems. There are a large number of methods for extraction of model parameters in power MOSFETs. For high efficiency, design is important considerations of a power MOSFET with high-voltage applications in consumer electronics. Meanwhile, it was proposed that the efficiency of a MOSFET can be enhanced by conducting JFET region double implant to reduce the On-resistance of the transistor. This paper reports the effects of JFET region double implant on the electrical properties and the decreasing On-resistance of the MOSFET. Experimental results show that the 1st JFET region implant diffuse can enhance the On-resistance by decreasing the ion concentration due to the surface and reduce the On-resistance by implanting the 2nd Phosphorus to the surface JFET region.

유문사친(儒門事親)에 나타난 소아(小兒)와 관련된 이론(理論)과 치법(治法)에 대한 고찰(考察)

김기현,장규태,김장현,정우병,Kim, Ki-Hyun,Chang, Gyu-Tae,Kim, Jang-Hyun,Jung, Wu-Byung 대한한방소아과학회 2005 대한한방소아과학회지 Vol.19 No.2

Objective : Rumenshiqin(儒門事親) was compiled by Zhang Zi Huo(張子和) of the Jin(金) Dynasty of China. He invented unique medical theory and treatment such as three excretive methods(perspiratory, vomitory and purgative therapy). The aim of this study was to make the best use of the therapeutic theory of Rumenshiqin(儒門事親) connected with pediatrics. Methods: We conducted literature search in detail for contents of Rumenshiqin(儒門事親) and reviewed various kinds of books. Results : Zhang Zi Huo(張子和) recognized that children had pure-yang bodies(純陽之體) and emphasized that children need to prevent heat-stagnation(鬱熱) and asthenic yin(損陰). He instructed that a principle of raising such as wearing thin clothes, eating fresh food, harboring little desire and little anger, and taking temperate medicine. He described that pathogenic factors were mistake of rearing, misuse of medicine, exogenous factor, and excessive emotion. Conclusion : According to the above results, it is concluded that his therapeutic theory should be used at present.

북동태평양지역의 방산충 생층서 및 고해양환경 연구

김기현,박정희,Kim, Ki-Hyune,Park, Jeoung-Hee 한국해양과학기술원 1999 Ocean and Polar Research Vol.21 No.2

Radiolarian assemblages from KODOS area were analyzed in order to understand the biostratigraphy and paleoceanography of deep-sea sediment from the Northeast Equatorial Pacific. The sediment core was divided into two or three units on the basis of the chemical and physical properties. In the upper sediment, mixtures of Quaternary and Tertiary radiolarians are found indicating active reworking processes. Dissolution of radiolarians seem to increase with depth. Radiolarians are seldom in Unit III presumably due to dissolution and corrosion. The middle part of unit I appears to correspond to Collosphaera invaginata Zone (0.21 Ma). Unit II belongs to Collosphaera tuberosa Zone. Based on the absence of Stylatractus universus, we estimate its age to be younger than 0.42 Ma. Based on our analyses of radiolarians in Unit I and II, we estimated the age of unit III as Tertiary, particularly from Oligocene to Miocene. There may to be hiatuses of more than 3 My from late Miocene to Pliocene, which probably resulted from erosion and dissolution by the Antarctic Bottom Water Sedimentation rates during Quaternary range from 0.15 to 0.50 mm/ky with significant variabilities among stations. Radiolarians in the study area were mostly warm-water species.

광투과 관측시스템의 분석기능 평가: 기상인자에 따른 DOAS 시스템의 검정

김기현,김민영,Kim, Ki-Hyun,Kim, Min-Young 한국지구과학회 2001 한국지구과학회지 Vol.22 No.1

선관측에 기초한 DOAS와 같은 광투과 분석방식의 계측능과 기상인자와의 관계를 평가하기 위해, 서울시의 반포지역을 중심으로 약 14개월(1999. 6${\sim}$2000. 8) 동안 확보된 3대 기준성 오염물질(SO$_2$, NO$_2$, O$_3$)과 주변 환경변수와의 관계를 여러 가지 통계적 방식으로 분석하였다. 본 연구 결과에 의하면, DOAS의 계측능은 오염물질간 또는 기상인자간에서도 비교적 뚜렷한 경향성을 갖는 것이 확인되었다. 그리고 이러한 경향성은 계절과 같은 시간적 요인에 따라복잡하게 변화할 수 있는 것으로 나타났다. 특히 SO$_2$나 NO$_2$,와 같은 항목의 경우, 여러 가지 요인의 차이에도 불구하고 계측능이 일정한 수준을 유지할 수 있는 것으로 나타났다. 반면 O$_3$의 경우, 기상조건의 변화에 상대적으로 민감한 변화를 보였다. 기상인자들간의 관계를 비교한 결과, 풍향, 풍속, 일사량과 같은 요인들이 성능에 민감한 영향력을 행사할 가능성이 큰 것으로 나타났다. 마지막으로 두 기기간의 농도차이를 조절하는 요인들을 상관분석을 통해 비교한 결과, 풍속, 일사량, 기온 등의 요인이 증가할수록 계측기간의 농도차가 줄어들었다. 반대로 오염물질의 농도가 증가하는 방향으로 흐를 경우, 계측기간의 오차는 상대적으로 증폭되는 방향으로 변화하였다. 따라서 DOAS로부터 계측된 자료를 해석하기 위해서는 기상인자를 포함하는 주변 환경인자의 변화에 대한 해석을 동시에 수행하는 것이 중요할 것으로 사료된다. To evaluate the influence of meteorological conditions on the performance of DOAS (Differential Optical Absorption Spectroscopy) system, we analyzed the concentrations of three criteria pollutants and relevant environmental parameters measured during 14 month periods between Jun. 1999 and Oct. 2000. According to our study, the performance of DOAS can be sensitively influenced via various manners (such as among different chemicals and/or between different time periods). It turns out that O$_3$ exhibits most frequently the weakest agreement between two systems. When comparison was made among different meteorological parameters, the strongest variability was seen from such ones as windspeed, wind direction, and irradiance. In addition, the absolute differences in measured concentrations between two systems were compared against various environmental parameters by means of linear regression analysis. Results of this analysis indicated that the differences between the two tend to decrease with the increase of such parameters as windspeed. It is thus concluded on the basis of our study that the simultaneous evaluation of meteorological data should be an essential step toward the accurate assessment of pollutant concentration data obtained by DOAS measurement system.

나노 Fe 분말을 이용하여 사출 성형된 Fe 소결체의 제조

김기현,임재균,최철진,이병택,Kim Ki-Hyun,Lim Jae-Hyun,Choi Chul-Jin,Lee Byong-Taek 한국재료학회 2004 한국재료학회지 Vol.14 No.11

The injection molded Fe sintered bodies were fabricated using two kinds of Fe powders haying 50 nm and $3\sim5{\mu}m$ in diameter. In the using of Fe powder having 50 nm in diameter, the comparatively dense bodies ($94\sim97\%$) were obtained even at low sintering temperature ($600\sim700^{\circ}C$), while in the sintered bodies ($1000^{\circ}C$) using $3\sim5{\mu}m$ Fe powder, their relative densities showed low values about $93\%$, although they were strongly depend on the sintering temperature and volume ratio of Fe powder and binder. In the sintered bodies using of 50 nm Fe powders, the volume shrinkage and grain size increased as the sintering temperature increased, but the values of hardness decreased. In the sample sintered at $650^{\circ}C$, the values of relative density, volume shrinkage and grain size were $96\%,\;37\%\;and\;0.97{\mu}n$, respectively and the minimum value of wear depth was obtained due to combination of fine grain and comparatively high density.

저가의 cryogenic milling 비진공법을 이용한 나노입자 CuInSe₂ 광흡수층 제조

김기현,박병옥,Kim, Ki-Hyun,Park, Byung-Ok 한국결정성장학회 2013 韓國結晶成長學會誌 Vol.23 No.2

$CuInSe_2$(CIS) chalcopyrite 물질은 고효율 박막 태양전지를 위한 광흡수층의 물질로 매우 잘 알려져 있다. 최근 태양광 산업의 흐름은 안정적인 재료 개발과 가격 경쟁력 있는 태양전지를 위한 효율적인 제조 공정을 일치시키는 것이다. 저가의 CIS 광흡수층 위해 다양한 방법으로 제조를 시도하였고, 본 논문에서는 CIS 광흡수층을 저가형으로 제조를 위해 상용화되는 6 mm pieces를 사용하여 high frequency ball milling과 cryogenic milling을 이용해 CIS 나노입자를 얻었다. 그리고, CIS 광흡수층은 불활성 분위기의 glove box 안에서 milling된 나노입자를 사용하여 paste coating법으로 제조하였다. Chalcopyrite CIS 박막은 기판온도 550도에서 30분간 셀렌화 한 후 성공적으로 제조되었으며, Al/ZnO/CdS/CIS/Mo 구조의 CIS 태양전지는 evaporation, sputtering 및 chemical bath deposition(CBD) 등 다양한 증착 방법으로 각각 제조하였다. 결론적으로, 나노입자를 이용한 CIS 태양전지 전기적 변환효율은 1.74 %를 얻었으며, 개방전압(Voc)는 29 mV, 합선전류밀도(Jsc)는 35 $mA/cm^2$, 그리고 충진율(FF)은 17.2 %였다. 나노입자 CIS 광흡수층은 energy dispersive spectroscopy(EDS), x-ray diffraction(XRD) 그리고 high-resolution scanning electron microscopy(HRSEM) 등으로 특성 분석을 하였다. Chalcopyrite material $CuInSe_2$ (CIS) is known to be a very prominent absorber layer for high efficiency thin film solar cells. Current interest in the photovoltaic industry is to identify and develop more suitable materials and processes for the fabrication of efficient and cost-effective solar cells. Various processes have been being tried for making a low cost CIS absorber layer, this study obtained the CIS nanoparticles using commercial powder of 6 mm pieces for low cost CIS absorber layer by high frequency ball milling and cryogenic milling. And the CIS absorber layer was prepared by paste coating using milled-CIS nanoparticles in glove box under inert atmosphere. The chalcopyrite $CuInSe_2$ thin films were successfully made after selenization at the substrate temperature of $550^{\circ}C$ in 30 min, CIS solar cell of Al/ZnO/CdS/CIS/Mo structure prepared under various deposition process such as evaporation, sputtering and chemical vapor deposition respectively. Finally, we achieved CIS nanoparticles solar cell of electric efficient 1.74 % of Voc 29 mV, Jsc 35 $mA/cm^2$ FF 17.2 %. The CIS nanoparticles-based absorber layers were characterized by using EDS, XRD and HRSEM.

한국 황해지역의 DMS 분포특성에 대한 연구 - 덕적도를 중심으로

김기현,김지영,송기범,김나영,이강웅,배귀남,Kim, Ki-Hyun,Kim, Ji-Young,Song, Ki-Bum,Kim, Na-Young,Lee, Gang-Woong,Bae, Gwi-Nam 한국지구과학회 2000 한국지구과학회지 Vol.21 No.1

황해지역에서 생성 및 배출되는 자연황화합물의 규모를 정량적으로 구명하기 위한 노력의 일환으로, 본 연구진은 황해에 위치한 덕적도를 주 측정점으로 설정하고 대기 중에 존재하는 DMS의 농도분포를 1999년 4월과 9월 2차례의 집중측정기간을 통해 측정하였다. 그리고 이에 덧붙여 1999년 6월에는 청도-인천간 해상실험을 통해 황해상의 DMS 농도를 측정하였다. 덕적도를 중심으로 시행한 양 측정기간 중 DMS의 농도값은 4월 측정의 경우 평균과 표준오차가 $24.0{\pm}40.5$ pptv(n=40)인데 반해 9월 측정의 경우 $61.1{\pm}37.9$ pptv(n=35)로 나타났다. 그리고 선상실험에서 측정한 DMS 값은 대체로 배경농도에 가까운 낮은 농도범위를 갖는 것으로 밝혀졌다. DMS의 농도분포는 일반적으로 불규칙한 양상을 보였지만, 주변 기상인자의 변화경향과 유사하게 변화하는 것으로 나타났다. 본문에서는 이러한 연구결과와 기존의 연구결과 등을 연계하여 잠정적인 연간 배출량규모를 4Gg 대로 추정하였다. 이러한 배출규모는 과거 제주지역 등을 중심으로 측정한 결과에 비해 상대적으로 낮은 수치인데, 시간적 및 공간적으로 대표성이 강한 보다 객관적인 배출량을 산정하기 위해서는 추가적인 측정 자료의 축적이 요구된다. This study was performed to accumulate database for natural sulfur emissions in the Yellow Sea region of Korea. The atmospheric concentrations of dimethylsulfide(DMS) were measured during two intensive field experiments (April and September 1999) from Duk-Juk Island located in the Yellow Sea. Ship-measurement of DMS was made additionally between Chungdo(China) and Inchun(Korea) across the Yellow Sea during June 1999. The mean(and ISD) of DMS concentrations in Duk-Juk Island during two field campaigns was $24.0{\pm}40.5$(n=40, April) and $61.1{\pm}37.9$ pptv(n=35, September), respectively. The atmospheric DMS measured from ship experiments was generally low and close to the background concentrations in the open sea area. The temporal distributions of DMS concentration were complicated in some sense but comparable to those of ambient meteorological parameters. On the basis of our measurements of atmospheric DMS(and evidence found from previous studies), the sea-to-air flux of DMS in the Yellow Sea is estimated to be about 4Gg S/yr. This amount of natural S emissions is relatively lower than the estimates derived for Cheju Island. Therefore, additional experiments may be desperate to derive more reliable figures for natural sulfur emissions in the Yellow Sea region.

HEVC를 위한 저면적 고성능 다중 모드 1D 변환 블록 설계

김기현,류광기,Kim, Ki-Hyun,Ryoo, Kwang-Ki 한국정보통신학회 2014 한국정보통신학회논문지 Vol.18 No.1

본 논문에서는 연산 시간이 긴 곱셈기 패스를 낮은 주파수에서 동작하는 저면적의 HEVC(High Efficiency Video Coding)용 다중 모드 일차원 변환 블록을 구현하는 효율적인 방법을 제시하였다. 제시한 방법은 전체 면적을 줄이기 위하여 일반적인 변수와 변수를 입력으로 받는 곱셈기 대신 행렬의 계수 특성을 이용한 상수와 변수를 입력으로 받는 상수 곱셈기를 사용하였다. 상수 곱셈기 사용으로 인하여 전체적인 처리량을 증가시켰으며 늘어난 처리량으로 인해 남는 동작 사이클을 이용하여 연산시간이 많이 걸리는 곱셈기 부분에 멀티 사이클 패스를 구성하여 곱셈기의 동작 주파수를 낮게 하면서 전체 연산량은 유지시켰다. TSMC 0.18um CMOS 공정 라이브러리를 이용하여 실제 하드웨어를 구현한 결과 4k($3840{\times}2160$) 영상을 기준으로 최소 동작 주파수는 186MHz이고 최대 동작 주파수는 300MHz이다. This paper suggest an effective idea to implement an low area multi-mode one dimension transform block of HEVC(High Efficiency Video Coding). The time consuming multiplier path is designed to operate on low frequency. Normal multipliers dealing with variable operands are replaced with smaller constant multipliers which do the product with constant coefficient and variable only using shifters and adders. This scheme increases total multiplier counts but entire areas are reduced owing to smaller area of constant multiplier. Idle cycles caused by doubled multipliers enable to use multi-cycle paths on the cycle eating multiplier data path. Operating frequency is lowered by multi-cycle path but total throughput is maintained. This structure is implemented with TSMC 0.18 CMOS process library, and operated on 186MHz frequency to process a 4k($3840{\times}2160$) image. Max operating frequency is 300MHz.

열파이프의 구조와 원리

김기현,Kim, Ki-Hyun 대한설비공학회 1989 설비저널 Vol.18 No.2